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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 牟中原(Chung-Yuan Mou) | |
| dc.contributor.author | Rong-Guang Wu | en |
| dc.contributor.author | 吳榮光 | zh_TW |
| dc.date.accessioned | 2022-11-25T06:35:12Z | - |
| dc.date.copyright | 2022-02-18 | |
| dc.date.issued | 2022 | |
| dc.date.submitted | 2022-02-10 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/82295 | - |
| dc.description.abstract | "近年來隨著電池應用領域的發展，人們對電池的能量密度要求越來越高，希望以更輕、更小的電池驅動手邊的電器。在此需求下，下一代的電池系統一直是被科學界廣為研究的領域。而無陽極鋰金屬電池(Anode Free Lithium Metal Battery, AFLMB)，則被視為下一代的電池系統的候選者之一；其組裝時透過去除傳統鋰離子電池的陽極材料，大幅度的提升能量密度，同時降低成本並增加安全性。然而在電池充放電過程中，鋰金屬在陽極端電鍍與剝除，因著電場的的不勻性，會生成不可預測的鋰枝晶，並在循環過程生成「死鋰」，造成鋰金屬的損耗，使得無陽極鋰金屬電池面臨電池容量衰退快速的問題。 在本研究工作中，我們將具有規則垂直孔洞的中孔洞二氧化矽材料(SBA15(⊥))塗佈於銅箔上作為陽極，使鋰金屬電鍍於陽極表面時的形貌更加平整，避免鋰枝晶的生成，並使鋰金屬的可逆性顯著提升。在NMC532 | zh_TW |
| dc.description.abstract | Cu的系統中，透過SBA15(⊥)修飾的負極應用於無陽極鋰金屬電池，在前10圈的庫倫效率維持至95%以上的高可逆度，使電池的半衰期在0.1C的充放電環境中提高至20圈，優於單純銅箔做電極的電池性能。而為了釐清電池優化的主因，我們進行對照實驗，更換不同種類的二氧化矽奈米材料作為塗佈修飾的材料，發現只有SBA15(⊥)塗佈的電極具有優化的效果。為了進一步了解SBA15(⊥)於無陽極鋰金屬電池的貢獻，在研究過程中，我們使用掃描式電子顯微鏡及能量色散光譜進行分析，觀察鋰金屬的變化，發現SBA15(⊥)修飾的電極具有最平整且最緻密的電鍍鋰。同時我們更進一步用同步輻射中心的低銳角X光散射光譜，證實SBA15(⊥)修飾的電極具有最大的鋰單晶。 " | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-25T06:35:12Z (GMT). No. of bitstreams: 1 U0001-0802202208541500.pdf: 7666021 bytes, checksum: 1c90cd719b35b9940662e817a94a74db (MD5) Previous issue date: 2022 | en |
| dc.description.tableofcontents | 論文口試委員審定書 i 謝誌 ii 摘要 iii Abstract iv Table of Contents vi List of Figures xi List of Tables xix Abbreviation xx Chapter 1 Introduction 1 1.1. Background 1 1.2. The Concept of Anode-free Lithium Metal Battery 3 1.2.1. Modification of the Electrolyte 4 1.2.2. Modification of the Current Collector 6 1.3. Advanced Separators for Lithium Metal Batteries 9 1.3.1. Optimizing the Performance of Polyolefin Membranes 9 1.3.2. Controlling the Dendrite Growth Direction 10 1.3.3. Developing a Novel Separator Material 11 1.4. A Brief Introduction of Mesoporous Silica Nanoparticles 13 1.4.1. MCM41 13 1.4.2. SBA15 14 1.5. Motivation 16 Chapter 2 Material and Method 19 2.1. Chemicals 19 2.2. Instruments 22 2.2.1. Scanning Electron Microscopy (SEM) 22 2.2.2. Energy-dispersive X-ray Spectroscopy (EDX) 22 2.2.3. Nitrogen Adsorption Analysis 23 2.2.4. Cyclic Voltammetry (CV) 23 2.2.5. Galvanostatic Charge/Discharge Measurements 24 2.2.6. Electrochemical Impedance Spectroscopy (EIS) 24 2.2.7. Grazing Incidence X-ray Scattering 24 2.3. Synthetic Procedures 27 2.3.1. Synthesis of Mesoporous Silica Nanosheets with Perpendicular and Open Channels (SBA15(⊥)) 27 2.3.2. Synthesis of Mesoporous Silica Film (MSTF) on Anodic Aluminum Oxide (AAO) 27 2.3.3. Synthesis of Pore-Expanded Mesoporous Silica Nanoparticles (MSNs) 29 2.4. Batteries Preparation 30 2.4.1. Anode Electrode Preparation 30 2.4.2. Preparation of Conventional Electrolyte 31 2.4.3. CR2032 Coin Cell 32 2.4.4. Pouch Cell Assemble 35 Chapter 3 Artificial Thin Film on Current Collector in Anode Free Lithium Battery 37 3.1. Characterization of Mesoporous Silica Nanoparticles 37 3.1.1. Scanning Electron Microscopy 37 3.1.2. Nitrogen Adsorption-Desorption Isotherm 39 3.1.3. Fourier-transform Infrared Spectroscopy 41 3.1.4. Grazing Incidence Small Angle X-ray Scattering 43 3.2. Characterization of Mesoporous Silica Nanoparticles Coating on Copper Foil 45 3.2.1. Scanning Electron Microscopy 45 3.2.2. Grazing Incidence Small Angle X-ray Scattering 47 3.2.3. Contact Angle Measurement 49 3.3. Performance Comparison 50 3.3.1. Anode-Free Lithium Metal Battery Measurement 50 3.4. Phenomena of Mesoporous Silica nanoparticles Coating 53 3.4.1. Cyclic Voltammetry 53 3.4.2. X-ray Photoelectron Spectroscopy 54 3.4.3. Investigation of the Lithium Morphology 55 3.4.4. Crystalline of Lithium Deposition 68 3.4.5. Electrochemical Impedance Spectroscopy 73 3.5. Summary 75 Chapter 4 Artificial Thin Film on Anodic Aluminum Oxide (AAO) as separator in Pouch Cell 77 4.1. Characterization of MSTF⊥AAO 77 4.1.1. Scanning Electron Microscopy 77 4.1.2. Grazing Incidence Small Angle X-ray Scattering 80 4.2. Performance Comparison 82 4.2.1. Lithium Metal Battery Measurement 82 4.2.2. Anode-Free Lithium Metal Battery Measurement 84 4.3. MSTF-AAO after cycling 87 4.4. Investigation of the Dead Lithium 88 4.4.1. Morphologies of Dead Lithium after Cycling in LMB 88 4.4.2. Morphologies of Dead Lithium after Cycling in AFLMB 90 4.5. Summary 92 Chapter 5 Recommendations of Future Works 95 Reference 96 | |
| dc.language.iso | en | |
| dc.subject | SBA15(⊥) | zh_TW |
| dc.subject | 無陽極鋰金屬電池 | zh_TW |
| dc.subject | 中孔洞二氧化矽奈米材料 | zh_TW |
| dc.subject | Anode-free Li metal battery | en |
| dc.subject | mesoporous silica nanomaterials | en |
| dc.subject | SBA15(⊥) | en |
| dc.title | 中孔洞奈米二氧化矽材料於無陽極鋰金屬電池的應用 | zh_TW |
| dc.title | Application of Mesoporous Silica Nanomaterial in Anode-Free Lithium Metal Batteries | en |
| dc.date.schoolyear | 110-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 吳恆良(Mong-Hsun Tsai),黃炳照(Li-Han Chen),(Yuh-Pyng Sher) | |
| dc.subject.keyword | 無陽極鋰金屬電池,中孔洞二氧化矽奈米材料,SBA15(⊥), | zh_TW |
| dc.subject.keyword | Anode-free Li metal battery,mesoporous silica nanomaterials,SBA15(⊥), | en |
| dc.relation.page | 104 | |
| dc.identifier.doi | 10.6342/NTU202200359 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2022-02-11 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| dc.date.embargo-lift | 2027-02-09 | - |
| 顯示於系所單位： | 化學系 | |
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| U0001-0802202208541500.pdf 未授權公開取用 | 7.49 MB | Adobe PDF | 檢視/開啟 |
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