請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/82191完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 侯嘉洪(Chia-Hung Hou) | |
| dc.contributor.author | Chu-Yun Cheng | en |
| dc.contributor.author | 鄭筑云 | zh_TW |
| dc.date.accessioned | 2022-11-25T06:33:26Z | - |
| dc.date.copyright | 2021-11-06 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-07-20 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/82191 | - |
| dc.description.abstract | "近年來水資源的匱乏以及能源的需求日益提升，開發新穎的脫鹽技術，以低能耗的方式提供新興水資源(如海水淡化、再生水)，成為國際間重要的研究課題。而在現今的脫鹽技術中，亦有其各自的限制。因此，氧化還原液流式電池脫鹽技術(redox-flow battery desalination, FBD)被進一步提出，其使用氧化還原液流電池材料(redox-flow battery, RFB)作為液流式電極，透過氧化還原反應及電子遷移的機制去除水中離子，以期能將此技術應用於高鹽度溶液的脫鹽。 本研究的目的為開發FBD模組系統，探討脫鹽過程中的反應機制與重要的操作參數，並驗證其在海水淡化的應用可行性。在本研究中，FBD模組具有四個通道，包含陽極室、陰極室、淡室與濃室，並利用鐵氰化物/亞鐵氰化物(ferri-/ferrocyanide)作為氧化還原液流電池材料，探討電壓(0.2, 0.4, 0.6, 0.8 V)、鐵氰化物/亞鐵氰化物濃度(5, 10, 50, 100 mM)與氯化鈉濃度(介於3000至35000 mg/L)，對於脫鹽效能及能耗表現的影響。在此FBD系統中，若對其施加外部電場，氧化還原液流電池材料將於陽極室發生氧化反應，由亞鐵氰化物氧化為鐵氰化物，同時於陰極室發生還原反應，由鐵氰化物還原為亞鐵氰化物。為了達到電荷平衡，陽極室和淡室中的陽離子會通過陽離子交換膜(cation exchange membrane, CEM)，分別往濃室及陰極室移動；而淡室中的陰離子則會通過陰離子交換膜(anion exchange membrane, AEM)向濃室遷移。因此，淡室中的離子將不斷被去除，相反地，濃室中的離子將持續被濃縮。由於FBD系統以氧化還原液流電池材料取代固定式電極，進行離子的去除，其在電場下可不斷發生氧化還原反應的特性，使得FBD系統具有無限的脫鹽容量。此外，FBD模組的四通道設計使其能夠同時產生淨水及濃水，達成完全連續的操作程序。 以處理初始濃度為3000 mg/L的氯化鈉溶液為例，在施加電壓為0.2 V、鐵氰化物/亞鐵氰化物濃度為100 mM時，其平均脫鹽速度和單位莫耳能耗分別為65.8 μg/min-cm2及18.1 kJ/mole。當初始氯化鈉濃度增加至35000 mg/L，其平均脫鹽速度亦提升至96.2 μg/min-cm2，單位莫耳能耗則為20.6 kJ/mole。相較於過去針對RO(約20.8–27.5 kJ/mole)和ED(約23.2–26.5 kJ/mole)的研究結果，FBD對較低鹽度或高鹽度溶液進行脫鹽時，均具有較低的能耗。由此可知，因驅使氧化還原反應發生所需的電壓相對較低，使得FBD系統在處理高鹽度溶液時，亦能維持良好的脫鹽性能與較低的能耗。此外，本研究將透過各項指標及水質分析，以評估FBD系統應用於真實海水的可行性。FBD系統對真實海水進行脫鹽時，其單位莫耳能耗為23.9 kJ/mole，並可將總溶解固體濃度(total dissolved solids, TDS)由39200 mg/L降至約1840 mg/L。其中，鈣離子(Ca2+)、鎂離子(Mg2+)及硫酸根離子(SO42–)的去除率均可達到99%以上，而鈉離子(Na+)及氯離子(Cl–)去除率則分別為96%與95%。從本研究的實驗結果可知，FBD系統為一個極具潛能的低能耗電化學脫鹽技術，具有較大的脫鹽濃度範圍，有助於海水淡化的應用與發展。" | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-25T06:33:26Z (GMT). No. of bitstreams: 1 U0001-1907202114432800.pdf: 12168438 bytes, checksum: e993edbe28756989d677e1ef2f442ef0 (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | 誌謝 i 中文摘要 iv Abstract vi Contents viii List of Figures x List of Tables xiv Abbreviations xv Chapter 1 Introduction 1 1.1 Background 1 1.2 Motivation and Objectives 1 Chapter 2 Theory and Literature Review 3 2.1 Electrochemical Desalination Technologies 3 2.1.1 Electrodialysis 5 2.1.2 Capacitive Deionization 7 2.1.3 Battery Electrode Deionization 11 2.2 Redox-flow Battery 13 2.3 Redox-flow Battery Desalination 19 Chapter 3 Experimental 27 3.1 Materials and Instruments 27 3.2 Research Design 30 3.3 Electrochemical Characterization 31 3.4 Setup of FBD System 33 3.5 Key Performance Indicators 37 Chapter 4 Results and Discussion 39 4.1 Characteristics of Redox-flow Battery 39 4.2 Desalination Performance of FBD System 41 4.3 Effect of Applied Voltage with Anolyte and Catholyte Concentration on Desalination Performance 44 4.4 Effect of Initial NaCl Concentration on Desalination Performance 53 4.5 Long-term Cycling Stability of FBD 62 4.6 A Practical Study of Seawater Desalination 65 Chapter 5 Conclusions and Suggestions 75 5.1 Conclusions 75 5.2 Suggestions 78 References 79 | |
| dc.language.iso | en | |
| dc.subject | 能源消耗 | zh_TW |
| dc.subject | 氧化還原液流式電池脫鹽技術 | zh_TW |
| dc.subject | 海水淡化 | zh_TW |
| dc.subject | redox-flow battery desalination | en |
| dc.subject | seawater desalination | en |
| dc.subject | energy consumption | en |
| dc.title | 氧化還原液流式電池脫鹽技術應用於低能耗海水淡化之研析 | zh_TW |
| dc.title | Redox-flow battery as a low-energy approach for electrochemical desalination of seawater | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 李公哲(Hsin-Tsai Liu),董瑞安(Chih-Yang Tseng),童國倫 | |
| dc.subject.keyword | 氧化還原液流式電池脫鹽技術,海水淡化,能源消耗, | zh_TW |
| dc.subject.keyword | redox-flow battery desalination,seawater desalination,energy consumption, | en |
| dc.relation.page | 86 | |
| dc.identifier.doi | 10.6342/NTU202101568 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2021-07-21 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
| dc.date.embargo-lift | 2026-07-21 | - |
| 顯示於系所單位： | 環境工程學研究所 | |
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