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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/82027完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳延平(Yan-Ping Chen) | |
| dc.contributor.author | Yu-Hsuan Ho | en |
| dc.contributor.author | 賀宇旋 | zh_TW |
| dc.date.accessioned | 2022-11-25T05:34:20Z | - |
| dc.date.available | 2026-07-28 | |
| dc.date.copyright | 2021-08-20 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-07-28 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/82027 | - |
| dc.description.abstract | " 本研究以高壓相平衡設備採用等容溫度循環法以及高壓差式掃描熱卡計進行二氧化碳與甲烷水合物之熱力學實驗量測，亦使用高壓設備進行二氧化碳與甲烷水合物生成之誘導時間量測，以起始壓力為變因，固定系統之操作溫度，並探討添加聚乙烯亞胺、羧甲基纖維素鈉造成之影響。本研究熱力學實驗探討之壓力範圍為：二氧化碳系統由1.516至3.683 MPa，甲烷系統由4.910至12.656 MPa。誘導時間量測之恆溫溫度為:二氧化碳系統274.65 K，甲烷系統280.07 K。 研究結果顯示，聚乙烯亞胺為二氧化碳水合物熱力學抑制劑，其最大抑制效果為0.5 wt.% 聚乙烯亞胺在1.978 MPa下抑制0.9 K。在較低壓力條件下，0.5 wt.% 聚乙烯亞胺抑制效果優於 5.0 wt.%，在較高壓力條件下趨勢則相反，另外添加不同分子量的聚乙烯亞胺，抑制效果幾乎相同，分子量25,000之聚乙烯亞胺平均抑制效果為0.62 K，分子量750,000之聚乙烯亞胺平均抑制效果為0.58 K。在誘導時間實驗中，聚乙烯亞胺為二氧化碳水合物生成促進劑，其中以0.5 wt.% 聚乙烯亞胺促進效果最佳，在起始壓力為3.125 MPa的情況下，誘導時間從40.03分鐘縮短為21.25分鐘，且初始壓力愈高，誘導時間也愈短。在甲烷水合物系統中，添加聚乙烯亞胺對相平衡條件幾乎沒有影響。使用高壓差式掃描熱卡計進行解離溫度量測，其起始解離溫度與等容溫度循環法之結果較接近。聚乙烯亞胺為甲烷水合物生成抑制劑，其抑制效果以0.5 wt.% 聚乙烯亞胺最佳，在10 MPa的情況下，誘導時間從0.75分鐘延長至6.95分鐘。 羧甲基纖維素鈉為二氧化碳水合物熱力學抑制劑，其抑制效果隨著添加濃度提高而增加。最大抑制效果為2.0 wt.% 羧甲基纖維素鈉在1.952 MPa下抑制0.67 K。在誘導時間實驗中，羧甲基纖維素鈉為二氧化碳水合物生成抑制劑，此外反應器的幾何形狀對誘導時間之結果有很大的影響。在起始壓力為3.125 MPa的情況下，兩個不同的反應釜誘導時間分別從40.03分鐘延長至84.10分鐘 (P100)，0.60分鐘延長至16.99分鐘 (PP100)。在甲烷水合物系統中，添加羧甲基纖維素鈉對相平衡條件幾乎沒有影響，且使用高壓差式掃描熱卡計量測解離溫度，可以發現加入不同濃度(1.0、2.0 wt.%)和不同分子量 (90,000、250,000)其結果都相同，起始解離溫度與純水系統幾乎一致。" | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-25T05:34:20Z (GMT). No. of bitstreams: 1 U0001-2707202122085800.pdf: 4634848 bytes, checksum: 43b8ec36ab03ee766a91d2afde6fbaef (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | 誌謝 I 摘要 III Abstract V Table of Contents VIII Tables XI Figure caption XV Chapter 1 Introduction 1 Chapter 2 Apparatus and Experiment 19 2.1 Materials 19 2.2 Apparatus 19 2.3 Experimental Procedures 21 2.3.1 Experimental Procedures for Phase Boundary of CO2/CH4 hydrates .21 2.3.2 Kinetic Experimental Procedures 26 2.4 Experimental Data Analysis 27 2.4.1 Thermodynamic Experimental Data Analysis 27 2.4.2 Kinetic Experimental Data Analysis 29 Chapter 3 Effect of Polyethylenimine on Carbon Dioxide and Methane Hydrate Dissociation Conditions and Induction Time for Hydrate Formation 40 3.1 Dissociation Conditions of Carbon Dioxide Hydrates 40 3.2 Dissociation Conditions of Carbon Dioxide Hydrates in the Presence of Polyethylenimine 40 3.3 Induction Time for Carbon Dioxide Hydrate Formation in the Presence of Polyethylenimine 42 3.4 Dissociation Conditions of Pure Methane Hydrates 44 3.5 Dissociation Conditions of Methane Hydrates in the Presence of Polyethylenimine 44 3.6 Induction Time for Methane Hydrate Formation in the Presence of Polyethylenimine 46 Chapter 4 Effect of Sodium Carboxymethyl Cellulose on Carbon Dioxide and Methane Hydrate Dissociation Conditions and Induction Time for Hydrate Formation 70 4.1 Dissociation Conditions of Carbon Dioxide hydrates in the presence of Sodium Carboxymethyl Cellulose 70 4.2 Induction Time for Carbon Dioxide Hydrate Formation in the Presence of Sodium Carboxymethyl Cellulose 71 4.3 Dissociation Conditions of Methane Hydrates in the Presence of Sodium Carboxymethyl Cellulose 73 Chapter 5 Conclusions 93 REFERENCES 96 附錄 114 | |
| dc.language.iso | en | |
| dc.subject | 羧甲基纖維素鈉 | zh_TW |
| dc.subject | 氣體水合物 | zh_TW |
| dc.subject | 相平衡 | zh_TW |
| dc.subject | 誘導時間 | zh_TW |
| dc.subject | 聚乙烯亞胺 | zh_TW |
| dc.subject | Induction time | en |
| dc.subject | Gas hydrate | en |
| dc.subject | Polyethylenimine | en |
| dc.subject | Sodium carboxymethyl cellulose | en |
| dc.subject | Phase equilibrium | en |
| dc.title | 添加聚乙烯亞胺、羧甲基纖維素鈉對於二氧化碳及甲烷水合物熱力學與動力學之實驗量測 | zh_TW |
| dc.title | Measurement of Thermodynamic and Kinetic Data of Carbon Dioxide and Methane Hydrate in the Presence of Polyethylenimine and Sodium Carboxymethyl Cellulose | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳立仁(Hsin-Tsai Liu),蘇至善(Chih-Yang Tseng),蔡榮進 | |
| dc.subject.keyword | 氣體水合物,聚乙烯亞胺,羧甲基纖維素鈉,相平衡,誘導時間, | zh_TW |
| dc.subject.keyword | Gas hydrate,Polyethylenimine,Sodium carboxymethyl cellulose,Phase equilibrium,Induction time, | en |
| dc.relation.page | 142 | |
| dc.identifier.doi | 10.6342/NTU202101822 | |
| dc.rights.note | 同意授權(限校園內公開) | |
| dc.date.accepted | 2021-07-28 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| dc.date.embargo-lift | 2026-07-28 | - |
| 顯示於系所單位： | 化學工程學系 | |
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