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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 張慕傑(Mu-Chieh Chang) | |
| dc.contributor.author | Hsin-Yu Lai | en |
| dc.contributor.author | 賴欣妤 | zh_TW |
| dc.date.accessioned | 2022-11-25T05:34:17Z | - |
| dc.date.available | 2023-07-29 | |
| dc.date.copyright | 2021-08-18 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-07-30 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/82024 | - |
| dc.description.abstract | "近年來致力於減少依賴石化燃料作為主要的能源來源，科學家們積極尋找可替代的燃料。其中，氫氣是廣為人知的能量儲存系統，且由於水是反應完後唯一可能產生的副產物，相對於其他燃料而言對環境的危害較小，常見的研究為利用質子還原反應產生氫氣，若要加速反應的進行，則催化劑的設計勢必為重要的一環。 本篇欲將金屬金屬協同作用(Metal-Metal cooperation)以及金屬配基協同作用(Metal-Ligand cooperation)兩種概念結合於單一錯合物中，因此以1,4-Phthalazine為中心骨架，以diphenylphosphine作為側臂，設計出具有pendent proton relay的螯合配基。在隔絕水氧的反應條件下與所設計之配位基進行反應，合成雙金屬鈷錯合物。藉由X-光繞射、元素分析、電子順磁共振光譜以及循環伏安法等分析儀器，確認錯合物之合成以及其結構特性之鑑定。 將合成之鈷錯合物進行質子還原之電化學實驗，由結果可發現本篇之催化劑在此反應中具有活性。而其中一雙鈷錯合物進行氧化反應後得到的結果，我們初步判定此錯合物可能具有活化水分子的潛能，而得到的另一雙銀錯合物亦值得進行後續的鑑定及應用，這也將成為日後能發展的應用方向。 " | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-25T05:34:17Z (GMT). No. of bitstreams: 1 U0001-2907202113173000.pdf: 4614807 bytes, checksum: 00c61c62ccaab53f6fae453a1b2f0715 (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | "致謝 i 摘要 ii Abstract iii Contents v List of Figures viii List of Schemes xi List of Tables xiv Chapter 1 Introduction 1 1.1 Metal-Ligand Cooperation 2 1.1.1 Pincer Ligand and Redox-Active Ligand 2 1.1.2 Pendant proton relay 8 1.2 Metal-Metal Cooperation 13 1.3 Multifunctional Catalyst 19 1.4 Motivation and Molecular Design 23 Chapter 2 Results and Discussions 25 2.1 PNNP Phthalazine Ligand Synthesis and Characterization 25 2.1.1 Ligand 1 Synthesis and Structure Characterization 25 2.1.2 Ligand 1 Deprotonation Test 33 2.1.3 Electrochemical Properties of Ligand 1 36 2.2 Mono-Cobalt Complex 2 Synthesis and Characterization 39 2.2.1 Synthesis and Structure Characterization of Mono-Cobalt Complex 2 39 2.2.2 Electrochemical Properties of Mono-cobalt complex 2 46 2.3 Di-Cobalt (II) Complexes Synthesis and Characterization 51 2.3.1 Synthesis and Structure Characterization of Fluoride Bridging Di-Cobalt Complex 3 51 2.3.2 Synthesis and Structure Characterization of Di-Cobalt Complex 4 58 2.3.3 Electrochemical Properties of Di-Cobalt Complex 3 62 2.3.4 Electrochemical Properties of Di-Cobalt Complex 4 65 2.3.5 Redox reaction of complex 3 and 4 69 2.3.6 Electron Paramagnetic Resonance Spectrum of Di-Cobalt Complex 3 and 4 80 2.4 Catalytic Reaction of the Cobalt Complexes 82 2.4.1 Ring Opening Polymerization 82 2.4.2 Coupling Reaction and Methylation Catalyzed by Cobalt Complexes 83 2.4.3 Electrochemical Proton Reduction Reaction 86 2.5 Unsymmetrical Naphthyridine Ligand Synthesis and Characterization. 91 Chapter 3 Conclusion and Future Work 96 Chapter 4 Experimental Section 98 General Information 98 Physical Measurements 98 Preparation 101 1,4-Phthalazinediamine (1a) 101 (Diphenylphosphanyl)methanol (1b) 102 N1, N4-bis((diphenylphosphanyl)methyl)phthalazine-1,4-diamine (1) 103 Co(LH2)Cl2 (2) 104 Co2(LH2)2(MeCN)2F(BF4)3 (3) 105 Co2(LH2)2(MeCN)2(ClO4)4 (4) 106 Ag2(LH2)2(BF4)2 (5) 107 Co2(LH2O)2(ACN)2(BF4)2 (6) 108 2-Amino-7-hydroxy-1,8-naphthyridine (8) 109 2-Amino-7-chloro-1,8-naphthyridine (9) 110 N-(7-chloro-1,8-naphthyridin-2-yl)acetamide (10) 111 1-acetyl-7-amino-1,8-naphthyridine (11) 112 References 114 Appendix 126 " | |
| dc.language.iso | en | |
| dc.subject | 多功能金屬錯合物 | zh_TW |
| dc.subject | 金屬-配位基協同作用 | zh_TW |
| dc.subject | 金屬-金屬協同作用 | zh_TW |
| dc.subject | 多功能配位基 | zh_TW |
| dc.subject | Metal-Ligand cooperation | en |
| dc.subject | Metal-Metal cooperation | en |
| dc.subject | pendent proton relay | en |
| dc.title | 多功能鈷金屬錯合物之合成及應用 | zh_TW |
| dc.title | Synthesis and Applications of Multifunctional Cobalt Complexes | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 王朝諺(Hsin-Tsai Liu),林雅凡(Chih-Yang Tseng) | |
| dc.subject.keyword | 金屬-配位基協同作用,金屬-金屬協同作用,多功能配位基,多功能金屬錯合物, | zh_TW |
| dc.subject.keyword | Metal-Ligand cooperation,Metal-Metal cooperation,pendent proton relay, | en |
| dc.relation.page | 147 | |
| dc.identifier.doi | 10.6342/NTU202101891 | |
| dc.rights.note | 同意授權(限校園內公開) | |
| dc.date.accepted | 2021-08-01 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| dc.date.embargo-lift | 2023-07-29 | - |
| 顯示於系所單位： | 化學系 | |
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