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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 童世煌(Shih-Huang Tung) | |
| dc.contributor.author | Chien-Han Chen | en |
| dc.contributor.author | 陳建翰 | zh_TW |
| dc.date.accessioned | 2022-11-25T05:33:11Z | - |
| dc.date.available | 2026-10-04 | |
| dc.date.copyright | 2021-10-21 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-10-05 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/81961 | - |
| dc.description.abstract | 本研究首先將單官能環氧化合物、單官能酯類化合物、微量的三級氮觸媒進行熔融混摻，鑑定環氧基與活性酯基的反應機制，並設計多種應用以解決現今環氧樹脂熱性質與介電性質不佳、過度依賴石油原料之問題，此外，同時藉由此化學合成多官能氧代氮代苯併環己烷樹脂。 為了同時提升環氧樹脂固化物的熱性質與介電性質，本篇研究選用含有甲基丙烯酸酯末端的聚氧二甲苯商品SA9000與環氧樹脂進行共聚，並將固化物進行機械性質、熱性質與介電性質分析，其固化物薄膜具有透明性與可撓曲性，並具有優異的熱性質(Tg = 218-220 oC)與介電性質(Df = 0.003)，兩者性質皆優於未改質的聚氧二甲苯雙酚SA90與環氧樹脂之共聚物。 環氧樹脂固化物現今多倚賴石油原料，而本篇研究由生質能衍生物合成了四種含有活性酯的雙官能環氧化合物，並透過FTIR、DSC分析得知四種環氧化合物皆具有自身固化特性，可透過自身固化的方式簡易達成全生質能為基底之固化物，而所得固化物皆具有優異的介電性質(Df = 0.007-0.010)。 多官能氧代氮代苯併環己烷樹脂雖有優異的機械性質，卻難以被合成，因此，本篇研究合成含有活性酯基的Bz化合物，並利用活性酯基與環氧基的反應，與兩種環氧樹脂DGEBA、HP7200合成雙官能與多官能氧代氮代苯併環己烷樹脂，透過DSC與FTIR分析，證明兩種合成的樹脂皆具有較低的固化溫度與較高的反應性，而升溫固化後，所得固化物具有優異的熱穩定性(Td5%=356-367 oC)與介電性質(Df=0.005-0.007) | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-25T05:33:11Z (GMT). No. of bitstreams: 1 U0001-2809202111253600.pdf: 6568202 bytes, checksum: 7ad8e46d2dd0edfe8970e4987582e370 (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | 中文摘要 I Abstract III 目錄 IV Scheme 目錄 VI 圖目錄 VIII 表目錄 IX 第一章 緒論 1 第二章 原理與文獻回顧 2 2.1 環氧樹脂之發展背景 2 2.2 環氧樹脂之開環機制 2 2.3 生質能衍生環氧樹脂 7 2.4 氧代氮代苯併環己烷樹脂之背景 10 第三章 實驗內容 13 3.1 實驗藥品與溶劑 13 3.2 實驗儀器與分析 16 3.3 實驗規劃 19 3.4 實驗步驟 21 3.4.1 活性酯基與環氧基反應機制鑑定 21 3.4.2 低介電與高熱穩定性環氧樹脂固化物 23 3.4.3 簡易達成全生質能為基底之環氧樹脂固化物的方法 26 3.4.3 由市售環氧樹脂合成多官能benzoxazine樹脂之方法 35 第四章 結果與討論 41 4.1 反應機制鑑定 41 4.1.1 模型反應(I)：GPE均聚反應鑑定 41 4.1.2 模型反應(II)：GPE與酯類化合物反應機制鑑定 42 4.1.3 模型反應(III)：GPE與活性酯化合物反應機制鑑定 47 4.2 低介電與高熱穩定性環氧樹脂固化物 55 4.2.1 環氧樹脂與SA9000共聚機制 55 4.2.2 環氧樹脂與SA9000共聚固化物薄膜機械性質分析 55 4.2.3 環氧樹脂與SA9000共聚固化物熱機械性質分析 56 4.2.4 環氧樹脂與SA9000共聚固化物介電性質分析 60 4.3 簡易達成全生質能為基底之環氧樹脂固化物的方法 61 4.3.1環氧單體合成與鑑定 61 4.3.2環氧單體之DSC分析 66 4.3.3固化物FTIR分析與機制鑑定 67 4.3.4固化物熱機械性質與熱穩定性分析 68 4.3.5固化物介電性質分析 73 4.4 由市售環氧樹脂合成多官能benzoxazine樹脂之方法 74 4.4.1含活性酯之Bz化合物(4-BZBP)製備 74 4.4.2多官能Bz樹脂(EBz-D、EBz-H)製備 83 4.4.3 樹脂反應性分析 88 4.4.4 固化物機械性質及熱性質分析 90 4.4.5 固化物介電性質分析 93 第五章 結論 95 第六章 參考文獻 97 第七章 研究成果列表 101 | |
| dc.language.iso | zh-TW | |
| dc.subject | 環氧樹脂 | zh_TW |
| dc.subject | 氧代氮代苯併環己烷 | zh_TW |
| dc.subject | 低介電 | zh_TW |
| dc.subject | 熱穩定性 | zh_TW |
| dc.subject | 活性酯基 | zh_TW |
| dc.subject | 生質能 | zh_TW |
| dc.subject | benzoxazine | en |
| dc.subject | epoxy | en |
| dc.subject | active-ester | en |
| dc.subject | thermal stability | en |
| dc.subject | low-dielectric | en |
| dc.subject | bio-based | en |
| dc.title | 環氧樹脂與活性酯共聚反應機制鑑定及其應用 | zh_TW |
| dc.title | Identification and application of reaction mechanism between epoxy and active-ester | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 博士 | |
| dc.contributor.coadvisor | 林慶炫(Ching-Hsuan Lin),鄭如忠(Ru-Jong Jeng) | |
| dc.contributor.oralexamcommittee | 劉英麟(Hsin-Tsai Liu),戴憲弘(Chih-Yang Tseng),蘇文炯 | |
| dc.subject.keyword | 環氧樹脂,活性酯基,熱穩定性,低介電,生質能,氧代氮代苯併環己烷, | zh_TW |
| dc.subject.keyword | epoxy,active-ester,thermal stability,low-dielectric,bio-based,benzoxazine, | en |
| dc.relation.page | 104 | |
| dc.identifier.doi | 10.6342/NTU202103424 | |
| dc.rights.note | 同意授權(限校園內公開) | |
| dc.date.accepted | 2021-10-06 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| dc.date.embargo-lift | 2026-10-04 | - |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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