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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 張慕傑(Mu-Chieh Chang) | |
| dc.contributor.author | Yen-Hsiang Huang | en |
| dc.contributor.author | 黃彥翔 | zh_TW |
| dc.date.accessioned | 2022-11-25T03:04:17Z | - |
| dc.date.available | 2023-07-31 | |
| dc.date.copyright | 2021-08-18 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-08-02 | |
| dc.identifier.citation | 1. Lewis, N. S.; Nocera, D. G., Powering the planet: Chemical challenges in solar energy utilization. Proceedings of the National Academy of Sciences 2006, 103 (43), 15729-15735. 2. Jia, H. P.; Quadrelli, E. A., Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen. Chem. Soc. Rev. 2014, 43 (2), 547-564 3. Rafiqul, I.; Weber, C.; Lehmann, B.; Voss, A., Energy efficiency improvements in ammonia production—perspectives and uncertainties. Energy 2005, 30 (13), 2487-2504. 4. Kirova-Yordanova, Z., Exergy analysis of industrial ammonia synthesis. Energy 2004, 29, 2373-2384. 5. Egi, A.; Tanaka, H.; Konomi, A.; Nishibayashi, Y.; Yoshizawa, K., Nitrogen Fixation Catalyzed by Dinitrogen‐Bridged Dimolybdenum Complexes Bearing PCP‐ and PNP‐Type Pincer Ligands: A Shortcut Pathway Deduced from Free Energy Profiles. European Journal of Inorganic Chemistry 2020, 2020 (15-16), 1490-1498. 6. Niu, X.; Sun, D.; Shi, L.; Bai, X.; Li, Q.; Li, X. A.; Wang, J., A new nitrogen fixation strategy: the direct formation of *N2− excited state on metal-free photocatalyst. Journal of Materials Chemistry A 2021, 9 (10), 6214-6222. 7. Berman-Frank, I.; Quigg, A.; Finkel, Z. V.; Irwin, A. J.; Haramaty, L., Nitrogen-fixation strategies and Fe requirements in cyanobacteria. Limnology and Oceanography 2007, 52 (5), 2260-2269. 8. Imayoshi, R.; Nakajima, K.; Takaya, J.; Iwasawa, N.; Nishibayashi, Y., Synthesis and Reactivity of Iron- and Cobalt-Dinitrogen Complexes Bearing PSiP-Type Pincer Ligands toward Nitrogen Fixation. European Journal of Inorganic Chemistry 2017, 2017 (32), 3769-3778. 9. Li, M.; Gupta, S. K.; Dechert, S.; Demeshko, S.; Meyer, F., Merging Pincer Motifs and Potential Metal–Metal Cooperativity in Cobalt Dinitrogen Chemistry: Efficient Catalytic Silylation of N 2 to N(SiMe 3 ) 3. Angewandte Chemie International Edition 2021, 60 (26), 14480-14487. 10. Roux, Y.; Duboc, C.; Gennari, M., Molecular Catalysts for N 2 Reduction: State of the Art, Mechanism, and Challenges. ChemPhysChem 2017, 18 (19), 2606-2617. 11. Moulton, C. J.; Shaw, B. L., Transition metal–carbon bonds. Part XLII. Complexes of nickel, palladium, platinum, rhodium and iridium with the tridentate ligand 2,6-bis[(di-t-butylphosphino)methyl]phenyl. J. Chem. Soc., Dalton Trans. 1976, (11), 1020-1024. 12. Salem, H.; Ben-David, Y.; Shimon, L. J. W.; Milstein, D., Exclusive C−C Activation and an Apparent α-H Elimination with a Rhodium Phosphinite Pincer Complex. Organometallics 2006, 25 (9), 2292-2300. 13. Ullah, H.; Mousavi, B.; Younus, H. A.; Khattak, Z. A. K.; Chaemchuen, S.; Suleman, S.; Verpoort, F., Chemical fixation of carbon dioxide catalyzed via cobalt (III) ONO pincer ligated complexes. Communications Chemistry 2019, 2 (1). 14. Gutsulyak, D. V.; Piers, W. E.; Borau-Garcia, J.; Parvez, M., Activation of Water, Ammonia, and Other Small Molecules by PCcarbeneP Nickel Pincer Complexes. Journal of the American Chemical Society 2013, 135 (32), 11776-11779. 15. Kumar, A.; Daw, P.; Espinosa-Jalapa, N. A.; Leitus, G.; Shimon, L. J. W.; Ben-David, Y.; Milstein, D., CO2 activation by manganese pincer complexes through different modes of metal–ligand cooperation. Dalton Transactions 2019, 48 (39), 14580-14584. 16. Valdés, H.; Rufino-Felipe, E.; Morales-Morales, D., Pincer complexes, leading characters in C–H bond activation processes. Synthesis and catalytic applications. Journal of Organometallic Chemistry 2019, 898, 120864. 17. Van Der Boom, M. E.; Milstein, D., Cyclometalated Phosphine-Based Pincer Complexes: Mechanistic Insight in Catalysis, Coordination, and Bond Activation. Chemical Reviews 2003, 103 (5), 1759-1792. 18. Huff, C. A.; Sanford, M. S., Catalytic CO2 Hydrogenation to Formate by a Ruthenium Pincer Complex. ACS Catalysis 2013, 3 (10), 2412-2416. 19. Wodrich, M. D.; Hu, X., Natural inspirations for metal–ligand cooperative catalysis. Nature Reviews Chemistry 2018, 2 (1), 0099. 20. Cammarota, R. C.; Clouston, L. J.; Lu, C. C., Leveraging molecular metal–support interactions for H2 and N2 activation. Coordination Chemistry Reviews 2017, 334, 100-111. 21. Seefeldt, L. C.; Hoffman, B. M.; Dean, D. R., Mechanism of Mo-Dependent Nitrogenase. Annual Review of Biochemistry 2009, 78 (1), 701-722. 22. Shen, J.-R., The Structure of Photosystem II and the Mechanism of Water Oxidation in Photosynthesis. Annual Review of Plant Biology 2015, 66 (1), 23-48. 23. Lawrence, M. A. W.; Green, K.-A.; Nelson, P. N.; Lorraine, S. C., Review: Pincer ligands—Tunable, versatile and applicable. Polyhedron 2018, 143, 11-27. 24. Aydin, J.; Larsson, J. M.; Selander, N.; Szabó, K. J., Pincer Complex-Catalyzed Redox Coupling of Alkenes with Iodonium Salts via Presumed Palladium(IV) Intermediates. Organic Letters 2009, 11 (13), 2852-2854. 25. Christoffel, F.; Ward, T. R., Palladium-Catalyzed Heck Cross-Coupling Reactions in Water: A Comprehensive Review. Catalysis Letters 2018, 148 (2), 489-511. 26. Brewster, T. P.; Ou, W. C.; Tran, J. C.; Goldberg, K. I.; Hanson, S. K.; Cundari, T. R.; Heinekey, D. M., Iridium, Rhodium, and Ruthenium Catalysts for the “Aldehyde–Water Shift” Reaction. ACS Catalysis 2014, 4 (9), 3034-3038. 27. Torii, S.; Okumoto, H.; Akahoshi, F.; Kotani, T., Highly diastereoselective coupling reaction of cyclopentenol derivatives by palladium catalyst. Journal of the American Chemical Society 1989, 111 (24), 8932-8934. 28. Albers, P.; Pietsch, J.; Parker, S. F., Poisoning and deactivation of palladium catalysts. Journal of Molecular Catalysis A: Chemical 2001, 173 (1-2), 275-286. 29. Murugesan, S.; Kirchner, K., Non-precious metal complexes with an anionic PCP pincer architecture. Dalton Transactions 2016, 45 (2), 416-439. 30. Filonenko, G. A.; Van Putten, R.; Hensen, E. J. M.; Pidko, E. A., Catalytic (de)hydrogenation promoted by non-precious metals – Co, Fe and Mn: recent advances in an emerging field. Chemical Society Reviews 2018, 47 (4), 1459-1483. 31. Ruban, A.; Hammer, B.; Stoltze, P.; Skriver, H. L.; Nørskov, J. K., Surface electronic structure and reactivity of transition and noble metals1Communication presented at the First Francqui Colloquium, Brussels, 19–20 February 1996.1. Journal of Molecular Catalysis A: Chemical 1997, 115 (3), 421-429. 32. Elkind, J. L.; Armentrout, P. B., Transition-metal hydride bond energies: first and second row. Inorganic Chemistry 1986, 25 (8), 1078-1080. 33. Bauschlicher, C. W.; Langhoff, S. R.; Partridge, H.; Barnes, L. A., Theoretical studies of the first‐ and second‐row transition‐metal methyls and their positive ions. The Journal of Chemical Physics 1989, 91 (4), 2399-2411. 34. Van Der Vlugt, J. I., Cooperative Catalysis with First‐Row Late Transition Metals. European Journal of Inorganic Chemistry 2012, 2012 (3), 363-375. 35. Alig, L.; Fritz, M.; Schneider, S., First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands. Chemical Reviews 2019, 119 (4), 2681-2751. 36. Elsby, M. R.; Baker, R. T., Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts. Chemical Society Reviews 2020, 49 (24), 8933-8987. 37. Lagaditis, P. O.; Sues, P. E.; Sonnenberg, J. F.; Wan, K. Y.; Lough, A. J.; Morris, R. H., Iron(II) Complexes Containing Unsymmetrical P–N–P′ Pincer Ligands for the Catalytic Asymmetric Hydrogenation of Ketones and Imines. Journal of the American Chemical Society 2014, 136 (4), 1367-1380. 38. Sonnenberg, J. F.; Wan, K. Y.; Sues, P. E.; Morris, R. H., Ketone Asymmetric Hydrogenation Catalyzed by P-NH-P′ Pincer Iron Catalysts: An Experimental and Computational Study. ACS Catalysis 2017, 7 (1), 316-326. 39. Fong, H.; Moret, M.-E.; Lee, Y.; Peters, J. C., Heterolytic H2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane. Organometallics 2013, 32 (10), 3053-3062. 40. Gonçalves, T. P.; Dutta, I.; Huang, K.-W., Aromaticity in catalysis: metal ligand cooperation via ligand dearomatization and rearomatization. Chemical Communications 2021, 57 (25), 3070-3082. 41. Gunanathan, C.; Milstein, D., Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis. Accounts of Chemical Research 2011, 44 (8), 588-602. 42. Zell, T.; Milstein, D., Hydrogenation and Dehydrogenation Iron Pincer Catalysts Capable of Metal–Ligand Cooperation by Aromatization/Dearomatization. Accounts of Chemical Research 2015, 48 (7), 1979-1994. 43. Milstein, D., Metal–ligand cooperation by aromatization–dearomatization as a tool in single bond activation. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 2015, 373 (2037), 20140189. 44. Khusnutdinova, J. R.; Milstein, D., Metal-Ligand Cooperation. Angewandte Chemie International Edition 2015, 54 (42), 12236-12273. 45. Zou, Y.-Q.; Chakraborty, S.; Nerush, A.; Oren, D.; Diskin-Posner, Y.; Ben-David, Y.; Milstein, D., Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal–Ligand Cooperation. ACS Catalysis 2018, 8 (9), 8014-8019. 46. Lyaskovskyy, V.; De Bruin, B., Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions. ACS Catalysis 2012, 2 (2), 270-279. 47. Ligand Design in Metal Chemistry. 2016. 48. Luca, O. R.; Konezny, S. J.; Blakemore, J. D.; Colosi, D. M.; Saha, S.; Brudvig, G. W.; Batista, V. S.; Crabtree, R. H., A tridentate Ni pincer for aqueous electrocatalytic hydrogen production. New Journal of Chemistry 2012, 36 (5), 1149. 49. Manuel, T. D.; Rohde, J.-U., Reaction of a Redox-Active Ligand Complex of Nickel with Dioxygen Probes Ligand-Radical Character. Journal of the American Chemical Society 2009, 131 (43), 15582-15583. 50. Yang, Z.-Y.; Danyal, K.; Seefeldt, L. C., Mechanism of Mo-Dependent Nitrogenase. Humana Press: 2011; pp 9-29. 51. Samanta, S.; Demesko, S.; Dechert, S.; Meyer, F., A Two-in-one Pincer Ligand and its Diiron(II) Complex Showing Spin State Switching in Solution through Reversible Ligand Exchange. Angewandte Chemie International Edition 2014, n/a-n/a. 52. Campos, J., Bimetallic cooperation across the periodic table. Nature Reviews Chemistry 2020, 4, 696-702. 53. Xiong, N.; Zhang, G.; Sun, X.; Zeng, R., Metal‐Metal Cooperation in Dinucleating Complexes Involving Late Transition Metals Directed towards Organic Catalysis. Chinese Journal of Chemistry 2020, 38 (2), 185-201. 54. Cammarota, R. C.; Lu, C. C., Tuning Nickel with Lewis Acidic Group 13 Metalloligands for Catalytic Olefin Hydrogenation. Journal of the American Chemical Society 2015, 137 (39), 12486-12489. 55. Dutta, I.; De, S.; Yadav, S.; Mondol, R.; Bera, J. K., Aerobic oxidative coupling of alcohols and amines towards imine formation by a dicopper(I,I) catalyst. Journal of Organometallic Chemistry 2017, 849-850, 117-124. 56. Kounalis, E.; Lutz, M.; Broere, D. L. J., Cooperative H 2 Activation on Dicopper(I) Facilitated by Reversible Dearomatization of an “Expanded PNNP Pincer” Ligand. Chemistry – A European Journal 2019, 25 (58), 13280-13284. 57. Desnoyer, A. N.; Nicolay, A.; Rios, P.; Ziegler, M. S.; Tilley, T. D., Bimetallics in a Nutshell: Complexes Supported by Chelating Naphthyridine-Based Ligands. Accounts of Chemical Research 2020, 53 (9), 1944-1956. 58. Schenck, T. G.; Downes, J. M.; Milne, C. R. C.; Mackenzie, P. B.; Boucher, T. G.; Whelan, J.; Bosnich, B., Bimetallic reactivity. Synthesis of bimetallic complexes containing a bis(phosphino)pyrazole ligand. Inorganic Chemistry 1985, 24 (15), 2334-2337. 59. Berners-Price, S. J.; Johnson, R. K.; Mirabelli, C. K.; Faucette, L. F.; McCabe, F. L.; Sadler, P. J., Copper(I) complexes with bidentate tertiary phosphine ligands: solution chemistry and antitumor activity. Inorganic Chemistry 1987, 26 (20), 3383-3387. 60. Vreeken, V.; Broere, D. L. J.; Jans, A. C. H.; Lankelma, M.; Reek, J. N. H.; Siegler, M. A.; Van Der Vlugt, J. I., Well-Defined Dinuclear Gold Complexes for Preorganization-Induced Selective Dual Gold Catalysis. Angewandte Chemie International Edition 2016, 55 (34), 10042-10046. 61. Casas, J. M.; Forniés, J.; Fuertes, S.; Martín, A.; Sicilia, V., New Mono- and Polynuclear Alkynyl Complexes Containing Phenylacetylide as Terminal or Bridging Ligand. X-ray Structures of the Compounds NBu4[Pt(CH2C6H4P(o-tolyl)2-κC,P)(C⋮CPh)2], [Pt(CH2C6H4P(o-tolyl)2-κC,P)(C⋮CPh)(CO)], [{Pt(CH2C6H4P(o-tolyl)2-κC,P)(μ-C. Organometallics 2007, 26 (7), 1674-1685. 62. Collet, J. W.; Van Der Nol, E. A.; Roose, T. R.; Maes, B. U. W.; Ruijter, E.; Orru, R. V. A., Synthesis of Quinazolin-4-ones by Copper-Catalyzed Isocyanide Insertion. The Journal of Organic Chemistry 2020, 85 (11), 7378-7385. 63. Martínez-Asencio, A.; Yus, M.; Ramón, D. J., Copper(II) acetate-catalyzed one-pot conversion of aldehydes into primary amides through a Beckmann-type rearrangement. Tetrahedron 2012, 68 (21), 3948-3951. 64. Xie, M.; Han, C.; Liang, Q.; Zhang, J.; Xie, G.; Xu, H., Highly efficient sky blue electroluminescence from ligand-activated copper iodide clusters: Overcoming the limitations of cluster light-emitting diodes. Science Advances 2019, 5 (6), eaav9857. 65. Gibbons, S. K.; Hughes, R. P.; Glueck, D. S.; Royappa, A. T.; Rheingold, A. L.; Arthur, R. B.; Nicholas, A. D.; Patterson, H. H., Synthesis, Structure, and Luminescence of Copper(I) Halide Complexes of Chiral Bis(phosphines). Inorganic Chemistry 2017, 56 (21), 12809-12820. 66. Zink, D. M.; Volz, D.; Baumann, T.; Mydlak, M.; Flügge, H.; Friedrichs, J.; Nieger, M.; Bräse, S., Heteroleptic, Dinuclear Copper(I) Complexes for Application in Organic Light-Emitting Diodes. Chemistry of Materials 2013, 25 (22), 4471-4486. 67. Li, F.; Li, Y. C.; Wang, Z.; Li, J.; Nam, D.-H.; Lum, Y.; Luo, M.; Wang, X.; Ozden, A.; Hung, S.-F.; Chen, B.; Wang, Y.; Wicks, J.; Xu, Y.; Li, Y.; Gabardo, C. M.; Dinh, C.-T.; Wang, Y.; Zhuang, T.-T.; Sinton, D.; Sargent, E. H., Cooperative CO2-to-ethanol conversion via enriched intermediates at molecule–metal catalyst interfaces. Nature Catalysis 2020, 3 (1), 75-82. 68. Kuhl, K. P.; Cave, E. R.; Abram, D. N.; Jaramillo, T. F., New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces. Energy Environmental Science 2012, 5 (5), 7050. 69. Dinh, C.-T.; Burdyny, T.; Kibria, M. G.; Seifitokaldani, A.; Gabardo, C. M.; García De Arquer, F. P.; Kiani, A.; Edwards, J. P.; De Luna, P.; Bushuyev, O. S.; Zou, C.; Quintero-Bermudez, R.; Pang, Y.; Sinton, D.; Sargent, E. H., CO2electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface. Science 2018, 360 (6390), 783-787. 70. Horikoshi, R.; Funasako, Y.; Yajima, T.; Mochida, T.; Kobayashi, Y.; Kageyama, H., Copper(II) solvatochromic complexes [Cu(acac)(N^N)(ligand)]BPh4 with various axial ligands. Correlation between coordination geometries and d–d transition energies (acac=acetylacetonato, N^N=1,10-phenanthoroline, 2,2′-bipyridyl). Polyhedron 2013, 50 (1), 66-74. 71. Niu, J.; Guo, P.; Kang, J.; Li, Z.; Xu, J.; Hu, S., Copper(I)-Catalyzed Aryl Bromides To Form Intermolecular and Intramolecular Carbon−Oxygen Bonds. The Journal of Organic Chemistry 2009, 74 (14), 5075-5078. 72. Rabiee, H.; Ge, L.; Zhang, X.; Hu, S.; Li, M.; Yuan, Z., Gas diffusion electrodes (GDEs) for electrochemical reduction of carbon dioxide, carbon monoxide, and dinitrogen to value-added products: a review. Energy Environmental Science 2021, 14 (4), 1959-2008. 73. Lees, E. W.; Mowbray, B. A. W.; Salvatore, D. A.; Simpson, G. L.; Dvorak, D. J.; Ren, S.; Chau, J.; Milton, K. L.; Berlinguette, C. P., Linking gas diffusion electrode composition to CO2 reduction in a flow cell. Journal of Materials Chemistry A 2020, 8 (37), 19493-19501. 74. Koppenol, W. H.; Rush, J. D., Reduction potential of the carbon dioxide/carbon dioxide radical anion: a comparison with other C1 radicals. The Journal of Physical Chemistry 1987, 91 (16), 4429-4430. 75. González-Sebastián, L.; Morales-Morales, D., Cross-coupling reactions catalysed by palladium pincer complexes. A review of recent advances. Journal of Organometallic Chemistry 2019, 893, 39-51. 76. Gorelsky, S. I.; Lapointe, D.; Fagnou, K., Analysis of the Palladium-Catalyzed (Aromatic)C–H Bond Metalation–Deprotonation Mechanism Spanning the Entire Spectrum of Arenes. The Journal of Organic Chemistry 2012, 77 (1), 658-668. 77. Yang, Y.-F.; She, Y., Computational exploration of Pd-catalyzed C-H bond activation reactions. International Journal of Quantum Chemistry 2018, 118 (21), e25723. 78. Nakaoka, S.; Murakami, Y.; Kataoka, Y.; Ura, Y., Maleimide-assisted anti-Markovnikov Wacker-type oxidation of vinylarenes using molecular oxygen as a terminal oxidant. Chemical Communications 2016, 52 (2), 335-338. 79. Micksch, M.; Strassner, T., Palladium(II) Complexes with Chelating Biscarbene Ligands in the Catalytic Suzuki-Miyaura Cross-Coupling Reaction. European Journal of Inorganic Chemistry 2012, 2012 (35), 5872-5880. 80. Deolka, S.; Rivada-Wheelaghan, O.; Aristizábal, S. L.; Fayzullin, R. R.; Pal, S.; Nozaki, K.; Khaskin, E.; Khusnutdinova, J. R., Metal–metal cooperative bond activation by heterobimetallic alkyl, aryl, and acetylide PtII/CuI complexes. Chemical Science 2020, 11 (21), 5494-5502. 81. Richardson, B. G.; Jain, A. D.; Potteti, H. R.; Lazzara, P. R.; David, B. P.; Tamatam, C. R.; Choma, E.; Skowron, K.; Dye, K.; Siddiqui, Z.; Wang, Y.-T.; Krunic, A.; Reddy, S. P.; Moore, T. W., Replacement of a Naphthalene Scaffold in Kelch-like ECH-Associated Protein 1 (KEAP1)/Nuclear Factor (Erythroid-derived 2)-like 2 (NRF2) Inhibitors. Journal of Medicinal Chemistry 2018, 61 (17), 8029-8047. 82. Angurell, I.; Puig, E.; Rossell, O.; Seco, M.; Gómez-Sal, P.; Martín, A., Bifunctional N–P ligands as building blocks for construction of multilayered metallodendrimers. Journal of Organometallic Chemistry 2012, 716, 120-128. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/81817 | - |
| dc.description.abstract | 鑒於自然的永續發展，將環境中小分子活化並利用或儲存，一直是科學上的重大議題。然而，過程中面臨的問題，例如過高的活化能以及多電子與質子轉移過程，都使反應效率受限。故其中催化劑的設計就扮演了重要的角色。 別於以往以金屬原子為反應中心且配位基不參與反應之錯合物，本篇論文同時引入了金屬-配位基協同作用(metal-ligand cooperation)及金屬-金屬協同作用(metal-metal cooperation)。藉由多金屬之構型可預期錯合物具備多電子轉移能力；同時配位基具備可活化之質子，可藉由該質子的轉移改變錯合物之反應性，以利錯合物在較溫和之環境下反應。基於上述概念，在設計結構上使用了phathalazine作為有機骨架，並以具備酸性質子的磷基側臂，合成多金屬錯合物。 在完成配位基的合成與鑑定後，將配位基分別與具不同陰離子之銅一價鹽類反應，可分別得到具不同陰離子且不同構型之雙銅錯合物，該類錯合物於大氣下展現了良好的穩定性。經過結構鑑定後，以循環伏安法測量其氧化還原電位，並以紫外-可見光光譜法測量其光物理性質，探討其應用於發光材料的可能性；同時也將此系列雙銅錯合物應用於耦合反應催化以及二氧化碳的電催化還原反應。除此之外，也討論了銅二價鹽類的金屬錯合反應，與其產物鑑定。 同時，鑑於鈀金屬的高催化活性，本篇論文也利用了PdCl2與配位基進行錯合。以X光繞射晶體法鑑定產物後將此三核心鈀錯合物應用於催化Suzuki耦合反應，以比較與其他鈀催化劑之反應性差異。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-25T03:04:17Z (GMT). No. of bitstreams: 1 U0001-3007202102265000.pdf: 5467600 bytes, checksum: 6de7f260abf8b0290bba35f2b6608998 (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | "致謝 i 摘要 ii Abstract iii List of Figures ix List of Schemes xiii List of Tables xvi List of Compounds and Crystal structures xvii Scheme of Synthetic Routes xix Chapter 1 Introduction 1 1.1 Metal-Ligand Cooperation 2 1.2 Metal-Metal Cooperation 10 1.3 Multifunctional Complex 14 1.4 Motivation and Molecular Design 16 Chapter 2 Results and Discussions 19 2.1 Ligand Synthesis and Characterization 19 2.1.1 Ligand Synthesis and Structure Characterization 19 2.1.2 Ligand Deprotonation Test 24 2.2 Di-copper Complexes Synthesis and Characterization 27 2.2.1 Synthesis and Structural Characterization of Di-copper Complex 1 27 2.2.2 Synthesis and Structural Characterization of Di-copper Complex 2 36 2.2.3 Synthesis and Characterization of Di-copper(II) complexes 48 2.3 Electrochemical Properties Measurement 54 2.3.1 Electrochemical Properties of the Ligand 54 2.3.2 Electrochemical Properties of Di-copper Complex 1I 56 2.3.2 Electrochemical Properties of Di-copper Complex 2PF6 59 2.4 Deprotonation of Di-copper(I) complexes 61 2.4.1 Deprotonation Test of Di-copper complex 1I 61 2.4.2 Deprotonation Test of Di-copper complex 2PF6 64 2.5 Application of Di-copper(I) complexes 67 2.5.1 Photo-luminescent Property 68 2.5.2 Organic Catalytic Reaction 75 2.5.3 Electrocatalytic Reaction 79 2.6 Palladium Complex 3 Synthesis and Characterization 82 2.6.1 Synthesis and Structural Characterization of Palladium Complex 3 82 2.6.2 Application of palladium complex 3 86 Chapter 3 Conclusion and Future Work 92 Chapter 4 Experimental Section 94 General Information 94 Physical Measurement 94 Preparation 98 1,4-diaminophthalazine 98 Diphenylphosphinomethanol 99 Ligand (H2L) 100 Complex 1I (H2L)Cu2I2 101 Complex 2PF6 (H2L)2Cu2(PF6)2 102 Complex 3 (HL)Pd3(DMF)Cl5 104 Reference 105 Supporting Information 114 " | |
| dc.language.iso | en | |
| dc.subject | 金屬-配位基協同作用 | zh_TW |
| dc.subject | 三金屬錯合物 | zh_TW |
| dc.subject | 金屬-金屬協同作用 | zh_TW |
| dc.subject | 多功能金屬錯合物 | zh_TW |
| dc.subject | 雙金屬錯合物 | zh_TW |
| dc.subject | bimetallic complex | en |
| dc.subject | trimetallic complex | en |
| dc.subject | multifunctional complex | en |
| dc.subject | metal-metal cooperation | en |
| dc.subject | metal-ligand cooperation | en |
| dc.title | 合成與鑑定多功能銅、鈀錯合物 | zh_TW |
| dc.title | Synthesis and Characterizations of Multifunctional Copper and Palladium Complexes | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳浩銘(Hsin-Tsai Liu),林柏亨(Chih-Yang Tseng) | |
| dc.subject.keyword | 金屬-配位基協同作用,金屬-金屬協同作用,多功能金屬錯合物,雙金屬錯合物,三金屬錯合物, | zh_TW |
| dc.subject.keyword | metal-ligand cooperation,metal-metal cooperation,multifunctional complex,bimetallic complex,trimetallic complex, | en |
| dc.relation.page | 153 | |
| dc.identifier.doi | 10.6342/NTU202101920 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2021-08-03 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| dc.date.embargo-lift | 2023-07-31 | - |
| 顯示於系所單位： | 化學系 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| U0001-3007202102265000.pdf | 5.34 MB | Adobe PDF | 檢視/開啟 |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。