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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/81607完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 李達源(Dar-Yuan Lee) | |
| dc.contributor.author | Yue-Xuan Tsai | en |
| dc.contributor.author | 蔡岳軒 | zh_TW |
| dc.date.accessioned | 2022-11-24T09:24:41Z | - |
| dc.date.available | 2022-11-24T09:24:41Z | - |
| dc.date.copyright | 2021-09-17 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-08-30 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/81607 | - |
| dc.description.abstract | 鎵和銦被廣泛地應用於半導體及光電產業，在高科技產業園區附近污染地區發現兩者共同存在於環境中。由於鎵、銦擁有相似化學性質，兩者存在於酸性土壤中會和鋁競爭吸附位置而釋出鋁，導致植物受到鋁毒害。然而，鮮少有研究探討鎵、銦共存時，鎵、銦的動態變化及植體的累積量。因此，本研究欲探討鎵和銦共存下，在不同土壤環境中的交互作用。本研究使用有效性鋁含量高的平鎮系土以及有效性鋁含量低的翁子系土為試驗土壤。利用人為方式分別於鎵處理組、銦處理組及鎵銦共處理組中添加 0、717.5、1435、2870 μmol kg-1 的氯化鎵和氯化銦。以土壤孵育實驗探討鎵、銦共存時土壤溶液中的動態變化。以水稻幼苗試驗 (50天) 探討鎵、銦對台梗 9 號幼苗生長及累積量之影響。土壤孵育之結果顯示，在鎵銦共處理組，兩試驗土壤之銦濃度與銦處理組相比有上升的趨勢，顯示鎵銦共存的情況下，土壤溶液中的鎵、銦會競爭土壤的吸附位置，鎵易被土壤吸持而銦則存留於溶液中。平鎮系土壤溶液的鋁濃度為：鎵銦共處理組 > 鎵處理組 > 銦處理組。翁子系土壤溶液的鋁濃度在三種處理組間沒有顯著差異。水稻生質量的結果顯示，翁子系水稻在 In-H、GaIn-M、以及 GaIn-H 處理下，水稻根部生長受到抑制。在三種處理下，平鎮系水稻之生長皆隨著處理濃度增加而受到抑制。翁子系水稻植體之鎵、銦濃度結果顯示，水稻對鎵、銦可能不存在競爭吸收的關係。在鎵銦共處理組，平鎮系水稻地上部之鎵、銦、鋁濃度與鎵處理組及銦處理組相比皆有下降的趨勢。本研究結果指出，當鎵、銦共存於酸性土壤中，應較注意環境中銦對植物造成的毒害，若土壤之有效鋁含量高，亦應注意鋁毒害。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-24T09:24:41Z (GMT). No. of bitstreams: 1 U0001-3008202115250500.pdf: 7594634 bytes, checksum: a03133a9d04c2b2dc514601cf3899425 (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | 摘要 i Abstract ii 目錄 iv 圖目錄 vii 表目錄 x 第一章 、緒論 1 1.1 鎵 1 1.1.1 鎵之化性、應用及污染 1 1.1.2 土壤環境中之鎵分布及動態變化 2 1.1.3 鎵對植物生長之影響 4 1.1.4 鎵對動物和人體之毒害及生長之影響 5 1.2 銦 6 1.2.1 銦之化性、應用及污染 6 1.2.2 土壤環境中銦之分布及動態變化 7 1.2.3 銦對植物生長之影響 9 1.2.4 銦對動物和人體之毒性及危害 10 1.3 鋁 11 1.3.1 鋁之化性及分布 11 1.3.2 鋁對植物生長之影響 12 1.4 鎵、銦於台灣之現況及管制標準 13 1.5 研究動機與目的 14 第二章 、材料與方法 15 2.1 試驗土壤之採集與基本特性 15 2.2 試驗土壤基本性質分析 15 2.2.1 土壤質地-比重計法 15 2.2.2 土壤pH值 16 2.2.3 土壤有機質含量 16 2.2.4 土壤有效鋁含量 17 2.2.5 土壤無定型鐵氧化物含量 17 2.2.6 土壤游離鐵鋁氧化物 17 2.2.7 試驗土壤總鎵與銦之含量 18 2.3 試驗土壤之鎵、銦添加前處理 18 2.3.1 鎵處理組土壤之製備 18 2.3.2 銦處理組土壤之製備 19 2.3.3 鎵銦共處理組土壤之製備 19 2.4 土壤浸水孵育試驗 20 2.5 水稻幼苗盆栽試驗 20 2.5.1 試驗水稻品種 20 2.5.2 水稻栽培之環境 20 2.5.3 水稻秧苗之培育 21 2.5.4 化肥施用 21 2.5.5 盆栽幼苗試驗 21 2.5.6 土壤孔隙水之採集與分析 22 2.5.7 盆栽試驗期間土壤 pH 值及 Eh 值之測定 22 2.6 以DCB溶液洗除水稻根部之鐵模 22 2.7 植體中鋁、鎵、銦含量分析 23 2.7.1 添加標準品分析 23 2.8 統計分析 23 第三章 、結果與討論 27 3.1 試驗土壤基本性質 27 3.2 土壤孵育實驗與盆栽孔隙水 29 3.2.1 土壤孵育實驗與盆栽試驗期間之土壤溶液 pH 值之變化 29 3.2.2 土壤孵育實驗與盆栽試驗期間之土壤溶液 Eh 值之變化 34 3.2.3 孵育實驗土壤溶液與盆栽試驗孔隙水之鎵濃度變化 39 3.2.4 孵育實驗土壤溶液與盆栽試驗孔隙水之銦濃度變化 45 3.2.5 孵育實驗土壤溶液與盆栽試驗孔隙水之鋁濃度變化 50 3.3 盆栽幼苗試驗 55 3.3.1 水稻幼苗於各處理組之生長情形、株高及生質量 55 3.3.2 水稻幼苗植體於鎵處理及鎵銦共處理下之鎵濃度變化 62 3.3.3 水稻幼苗地上部之鎵總累積量 64 3.3.4 水稻幼苗植體於銦處理及鎵銦共處理下之銦濃度變化 66 3.3.5 水稻幼苗地上部之銦總累積量 68 3.3.6 水稻幼苗植體於鎵處理、銦處理、以及鎵銦共處理下之鋁濃度變化 70 3.3.7 水稻幼苗地上部之鋁總累積量 74 第四章 、結論 76 第五章 、參考文獻 77 第六章 、附錄 85 | |
| dc.language.iso | zh-TW | |
| dc.subject | 水稻幼苗 | zh_TW |
| dc.subject | 新興污染物 | zh_TW |
| dc.subject | 鎵 | zh_TW |
| dc.subject | 銦 | zh_TW |
| dc.subject | 共存 | zh_TW |
| dc.subject | indium | en |
| dc.subject | rice seedlings | en |
| dc.subject | coexist | en |
| dc.subject | Emerging contaminants | en |
| dc.subject | gallium | en |
| dc.title | 探討鎵和銦兩種新興污染物共存下被酸性土壤吸持和水稻的累積 | zh_TW |
| dc.title | Gallium and Indium Retention by Acidic Soils and Accumulation by Rice Seedlings in the Coexistence of these Two Emerging Contaminants | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 鄒裕民(Hsin-Tsai Liu),莊愷瑋(Chih-Yang Tseng),許正一,許健輝 | |
| dc.subject.keyword | 新興污染物,鎵,銦,共存,水稻幼苗, | zh_TW |
| dc.subject.keyword | Emerging contaminants,gallium,indium,coexist,rice seedlings, | en |
| dc.relation.page | 94 | |
| dc.identifier.doi | 10.6342/NTU202102849 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2021-08-30 | |
| dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
| dc.contributor.author-dept | 農業化學研究所 | zh_TW |
| 顯示於系所單位： | 農業化學系 | |
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