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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/81369完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 李克強(Keh-Chyang Lee) | |
| dc.contributor.author | Yong-Jing Jian | en |
| dc.contributor.author | 簡詠靜 | zh_TW |
| dc.date.accessioned | 2022-11-24T03:46:00Z | - |
| dc.date.available | 2021-07-23 | |
| dc.date.available | 2022-11-24T03:46:00Z | - |
| dc.date.copyright | 2021-07-23 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-07-07 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/81369 | - |
| dc.description.abstract | "本論文主要探討介電液滴於系統中的介電泳運動現象。傳統常見的電動力學現象為電泳，在此我們應用一種新穎且具有發展潛力的技術「介電泳」(Dielectrophoresis, DEP)，其原理為利用非均勻電場驅使介電質於電解質溶液中運動，在極小距離下產生極大的電場，能準確的分離粒子，再加上近年來微奈米科技蓬勃發展，更帶動介電泳的快速發展。 在真實介電泳系統中存在著許多非傳統硬球型態的粒子，無法再以單純的硬球來模擬，為了突破傳統設限，使用了液滴模型比擬為生物粒子，如DNA、RNA等等。將介電泳應用於生化方面時，更利用介電泳的不均勻電場操作，讓生物粒子免於受高壓電影響而死亡，亦達成分離或捕捉的目的。 液滴模型比起一般硬球模型多了黏度項可以調控，高黏度時能夠回到一般硬球型態，低黏度時則是能比擬為氣泡型態，另外，也讓液滴受Maxwell stress影響泳動表現，使研究的液滴模型越接近真實粒子。 本文的研究目標是決定粒子行為的關鍵因子：dipole coefficient，其代表粒子在介質中的有效極化程度，探討頻率、電雙層厚度、粒子表面帶電量、介電常數等等參數對粒子的介電泳行為之影響變化。" | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-24T03:46:00Z (GMT). No. of bitstreams: 1 U0001-0607202112380900.pdf: 4773381 bytes, checksum: 1ab52fcccfd343f4e341bcaac4bf5161 (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | 致謝 I 摘要 III Abstract IV 目錄 V 圖目錄 VIII 表目錄 XI 第一章 緒論 1 1.1. 膠體粒子與電雙層 1 1.1.1. 膠體簡介 1 1.1.2. 電雙層理論 4 1.2. 液滴(liquid droplet)暨微乳液(microemulsion)系統 7 1.2.1. 液滴暨微乳液系統介紹 7 1.2.2. 液滴暨微乳液系統之應用 9 1.2.3. 液滴變形理論 10 1.3. 介電泳概論 11 1.3.1. 介電質與極化現象 12 1.3.2. 介電泳原理 15 1.4. 介電泳應用 21 1.5. 介電泳力與偶極矩 27 1.5.1. 介電泳作用力 27 1.5.2. 有效偶極矩與dipole coefficient 29 1.6. 文獻回顧−介電泳及極化效應 31 1.7. 低頻∕高頻區間−電雙層動態平衡 38 1.8. 研究目的與論文架構 42 第二章 理論分析 43 2.1. 系統描述 43 2.2. 物理問題分析與基本假設 44 2.3. 電動力學方程組 45 2.3.1. 電位方程式 45 2.3.2. 離子守恆式 46 2.3.3. 流場方程式 47 2.4. 平衡態與擾動態 49 2.4.1. 平衡態 50 2.4.2. 擾動態 51 2.5. 邊界條件 56 2.5.1. 平衡態邊界條件 56 2.5.2. 擾動態邊界條件 57 2.6. 系統變數前處理 61 2.6.1. 無因次分析與平衡電位求解 61 2.6.2. 擾動態變數線性化 63 2.6.3. 擾動態變數一維化 63 2.7. 粒子受力與電泳動度計算 68 2.7.1. 粒子受力計算 68 2.7.2. 振盪電泳速度計算 70 2.7.3. 介電泳速度計算 72 2.8. 偶極矩強度計算 74 第三章 數值方法 75 3.1. 正交配位法 75 3.2. 空間映射 79 3.3. 牛頓(Newton-Raphson)迭代法 80 3.4. 擾動態多變數聯立解 82 第四章 結果與討論 83 4.1. 系統參數設定 83 4.2. 準確性比對 85 4.3. 表面電位之影響 88 4.4. 液滴黏度比值影響 98 4.5. 介電常數影響 112 第五章 結論 118 參考文獻 120 符號說明 127 附錄 130 A. 有效偶極矩與CM factor關係式推導 130 B. 平均(time-average)介電泳力推導 134 C. 無窮大系統計算方法 136 D. 擾動電位球面邊界條件推導 139 E. 外部流場於液滴表面邊界條件推導 140 F. 介電泳泳動度(μDEP)推導 143 | |
| dc.language.iso | zh-TW | |
| dc.subject | 電雙層極化效應 | zh_TW |
| dc.subject | 介電泳 | zh_TW |
| dc.subject | 介電質 | zh_TW |
| dc.subject | 交流電場 | zh_TW |
| dc.subject | 電動力學 | zh_TW |
| dc.subject | 介電液滴 | zh_TW |
| dc.subject | 有效偶極矩 | zh_TW |
| dc.subject | 介電泳泳動度 | zh_TW |
| dc.subject | dielectrophoresis (DEP) | en |
| dc.subject | AC electric field | en |
| dc.subject | dielectric material | en |
| dc.subject | double layer polarization | en |
| dc.subject | DEP mobility | en |
| dc.subject | effective dipole moment | en |
| dc.subject | dielectric liquid droplet | en |
| dc.subject | electrokinetics | en |
| dc.title | 介電液滴之介電泳現象探討 | zh_TW |
| dc.title | Dielectrophoresis of a dielectric fluid droplet | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳賢燁(Hsin-Tsai Liu),游佳欣(Chih-Yang Tseng) | |
| dc.subject.keyword | 介電泳,介電質,交流電場,電動力學,介電液滴,有效偶極矩,介電泳泳動度,電雙層極化效應, | zh_TW |
| dc.subject.keyword | dielectrophoresis (DEP),dielectric material,AC electric field,electrokinetics,dielectric liquid droplet,effective dipole moment,DEP mobility,double layer polarization, | en |
| dc.relation.page | 146 | |
| dc.identifier.doi | 10.6342/NTU202101294 | |
| dc.rights.note | 同意授權(限校園內公開) | |
| dc.date.accepted | 2021-07-07 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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| U0001-0607202112380900.pdf 授權僅限NTU校內IP使用（校園外請利用VPN校外連線服務） | 4.66 MB | Adobe PDF |
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