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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳誠亮(Cheng-Liang Chen) | |
| dc.contributor.author | Yien Tien | en |
| dc.contributor.author | 田依恩 | zh_TW |
| dc.date.accessioned | 2022-11-24T03:09:37Z | - |
| dc.date.available | 2021-11-03 | |
| dc.date.available | 2022-11-24T03:09:37Z | - |
| dc.date.copyright | 2021-11-03 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-10-28 | |
| dc.identifier.citation | B. Kamm and M. Kamm, “Biorefinery – Systems,” Chem. Biochem. Eng. Q. 18, 1, 1–6 (2004). C. S. M. Pereira , V. M. T. M. Silva and A. E. Rodrigues, “Ethyl lactate as a solvent: Properties, applications and production processes – a review,” Green Chem., 13, 2658-2671 (2011). V. Dichiarante, D. Ravelli and A. Albini, “Green chemistry: state of the art through an analysis of the literature,” Green Chemistry Letters and Reviews, 3, 2, 105-113, (2010). S. Aparicio and R. Alcalde, “The green solvent ethyl lactate: an experimental and theoretical characterization,” Green Chem., 11, 65-78, (2009). “Ethyl Lactate Market - Forecast(2021 - 2026)”, IndustryARC. H. Endres and A. Siebert-Raths, Technische Biopolymere, München: Hanser-Verlag., p. 103 (2009). D. T. Vu, A. K. Kolah, N. S. Asthana, L. Peereboom, C. T. Lira and D. J. Miller, “Oligomer distribution in concentrated lactic acid solutions,” Fluid Phase Equilibria, 236, 125–135 (2005). K. Sundmacher, A. Kienle, Reactive distillation, Wiley-VCH Verlag GmbH Co. KGaA (2002). N. Asthana, A. Kolah, D. T. Vu, C.T. Lira, and D. J. Miller, “A Continuous Reactive Separation Process for Ethyl Lactate Formation,” Organic Process Research Development, 9, 599−607 (2005). N. S. Asthana, A. K. Kolah, D. T. Vu, C. T. Lira, and D. J. Miller, “A Kinetic Model for the Esterification of Lactic Acid and Its Oligomers,” Ind. Eng. Chem. Res., 45, 5251-5257 (2006). Y. Zhang, L. Ma and J. Yang, “Kinetics of esterification of lactic acid with ethanol catalyzed by cation-exchange resins,” Reactive and Functional Polymers, 61, 1, 101-114 (2004). J. Gao, X. M. Zhao, L. Y. Zhou and Z. H. Huang, “Investigation of Ethyl Lactate Reactive Distillation Process,” Chemical Engineering Research and Design, 85, 4, 525-529 (2007). D. J. Miller, N. Asthana, A. Kolah, and C. T. Lira, “Process for production of organic acid esters,” US Patent 7,652,167 (2010). S. B. Dai, H. Y. Lee and C. L. Chen, “Design and Economic Evaluation for the Production of Ethyl Lactate via Reactive Distillation Combined with Various Separation Configurations,” Ind. Eng. Chem. Res., 58, 6121−6132 (2019). Y. Y. Tsau, “Energy-efficient separation design and novel ethyl lactate production process design using reactive distillation and distillation-pervaporation configuration,” Master thesis, National Taiwan University (2020). P. Delgado, M. T. Sanz and S. Beltrán, “Isobaric vapor–liquid equilibria for the quaternary reactive system: Ethanol + water + ethyl lactate + lactic acid at 101.33 kPa,” Fluid Phase Equilibria, 255, 1, 17-23 (2007). D. T. Vu, C. T. Lira, N. S. Asthana, A. K. Kolah and D. J. Miller, “Vapor−Liquid Equilibria in the Systems Ethyl Lactate + Ethanol and Ethyl Lactate + Water,” J. Chem. Eng. Data, 51, 4, 1220–1225 (2006). R. A. Tusso-Pinzón, A. Castillo-Landero, L. G. Matallana-Pérez and A. Jiménez-Gutiérrez, “Intensified synthesis for ethyl lactate production in cluding economic, sustainability and inherent safety criteria,” Chemical Engineering and Processing - Process Intensification, 154, 108041 (2020). C. Y. Su, C. C. Yu, I. L. Chien and J. D. Ward, “Plant-Wide Economic Comparison of Lactic Acid Recovery Processes by Reactive Distillation with Different Alcohols,” Ind. Eng. Chem. Res., 52, 32, 11070–11083 (2013). J. G. Hayden and J. P. O'Connell, “A Generalized Method for Predicting Second Virial Coefficients,” Ind. Eng. Chem. Proc. Des., 14, 209-216 (1975). I. D. Gil, J. M. Gómez and G. Rodríguez, “Control of an extractive distillation process to dehydrate ethanol using glycerolas entrainer,” Computers Chemical Engineering, 39, 129-142 (2012). W. Reinders, D. Minjer, C. H. de Minjer, “Vapor-liquid equilibria in ternary systems IV. The system water-ethanol-trichlorethane,” Rec. Trav. Chim., 66, 9, 552-63 (1947). W. M. Haynes, CRC Handbook of Chemistry and Physics, 91st ed., CRC Press (2010-2011) M. J. O'Neil, P. E. Heckelman, P. H. Dobbelaar, Royal Society of Chemistry (Great Britain), K. J. Roman and C. M. Kenny, The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologicals, 15th ed., Royal Society of Chemistry: Cambridge, UK, p. 706 (2013). J. Huang, “Design and economic evaluation of hybrid separation systems for bioethanol dehydration,” Master thesis, National Taiwan University (2019). J. M. Douglas, Conceptual Design of Chemical Processes, McGraw-Hill, New York (1988). W. D. Seider, J. D. Seader, D. R. Lewin and S. Widagdo, Product and Process Design Principles: Synthesis, Analysis and Evaluation, 3rd ed., John Wiley Sons, Hoboken, NJ (2009). R. Turton, W. B. Whiting, J. A. Shaeiwitz and R. C. Bailie, Analysis, Synthesis and Design of Chemical Processes, 2nd ed., Pearson College Div (2003). W. L. Luyben, Principles and Case Studies of Simultaneous Design, John Wiley Sons, Inc. (2011). D. R. Woods, Cost Estimation for the Process Industries, McMaster University, (1983). | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/80570 | - |
| dc.description.abstract | 本研究目的是為了建立更具競爭性的商業規模的乳酸乙酯（L1E）生產製程，因為其在綠色溶劑上的有龐大的發展潛力，但售價仍無法跟傳統溶劑競爭，由前人發展的專利開始改良，採用反應蒸餾塔（RD）進行酯化反應和萃取蒸餾塔（ED）分離副產物，提供了三種不同的製程設計，並使用Aspen Plus模擬。根據模擬結果進行經濟分析，得知生產成本的競爭性，與前人研究的滲透蒸發分離組態進行比較，為了解決薄膜壽命太短而使成本提高的問題，使用工業上技術成熟的萃取蒸餾塔組態，並考慮熱整合設計進一步降低能耗。製程內包含了反應段以及蒸餾段，反應段有一支反應蒸餾塔，分離段有兩支萃取蒸餾塔，產物是99 mol%的乳酸乙酯從反應蒸餾塔流出，多的反應物乙醇和副產物的水被送到分離段進行分離。此研究主要是針對反應蒸餾塔改良，使其更加高效且節能，同時減少寡聚物的生成，達到降低成本的目的，最具競爭力設計製程經過最適化後的年總成本為221.89 kUSD，比之前的滲透蒸發混合分離系統研究降低了21%的成本。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-24T03:09:37Z (GMT). No. of bitstreams: 1 U0001-2510202110405000.pdf: 3951669 bytes, checksum: be27249f90807a3ae9b45d46ee9ce7c6 (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | 口試委員會審定書 Ⅰ 誌謝 II 中文摘要 III ABSTRACT IV CONTENTS V LIST OF FIGURES VII LIST OF TABLES X Chapter 1 Introduction 1 1.1 Review of ethyl lactate production processes 1 1.2 Literature survey 2 1.3 Research motivation 6 Chapter 2 Reaction Kinetics and Thermodynamics 7 2.1 Reaction kinetics 7 2.2 Thermodynamics 11 2.3 Extractive distillation 14 Chapter 3 Process Design 17 3.1 Pervious researches 17 3.1.1 Dai’s work14 17 3.1.2 Tsau’s work15 20 3.2 Proposed novel design 24 3.2.1 Schematic diagrams of designs 24 3.2.2 Simulation results of design A – with side draw 27 3.2.3 Simulation results of design A – with side draw and azeotropic ethanol supplement 31 3.2.4 Simulation results of design B – with bottom flow 34 3.2.5 Simulation results of design C – with thermally coupled 38 Chapter 4 Economic Analysis 43 4.1 Total annual cost (TAC) 43 4.2 Economic analysis of designed processes 44 4.2.1 Design A – with side draw 45 4.2.2 Design A – with side draw and azeotropic ethanol supplement 47 4.2.3 Design B – with bottom flow 48 4.2.4 Design C – with thermally coupled 49 Chapter 5 Optimization 51 5.1 Variables 51 5.1.1 Variables in reaction section 51 5.1.2 Variables in separation section 53 5.2 Optimization algorithm 54 5.3 Optimization result and discussion 55 5.3.1 Optimization of side draw case 55 5.3.2 Optimization of thermally coupled case 59 Chapter 6 Conclusion 68 REFERENCE 70 APPENDIX 74 | |
| dc.language.iso | en | |
| dc.subject | 最適化 | zh_TW |
| dc.subject | 乳酸乙酯 | zh_TW |
| dc.subject | 反應蒸餾 | zh_TW |
| dc.subject | 萃取蒸餾 | zh_TW |
| dc.subject | 程序設計 | zh_TW |
| dc.subject | Optimization | en |
| dc.subject | Extractive distillation | en |
| dc.subject | Reactive distillation | en |
| dc.subject | Ethyl lactate | en |
| dc.subject | Process design | en |
| dc.title | 乳酸乙酯反應蒸餾與萃取蒸餾分離製程之設計與經濟評估 | zh_TW |
| dc.title | Novel Ethyl Lactate Production Process Design using Reactive Distillation and Extractive Distillation Configuration | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.coadvisor | 李豪業(Hao-Yeh Lee) | |
| dc.contributor.oralexamcommittee | 錢義隆(Hsin-Tsai Liu),吳哲夫(Chih-Yang Tseng),李瑞元 | |
| dc.subject.keyword | 乳酸乙酯,反應蒸餾,萃取蒸餾,程序設計,最適化, | zh_TW |
| dc.subject.keyword | Ethyl lactate,Reactive distillation,Extractive distillation,Process design,Optimization, | en |
| dc.relation.page | 77 | |
| dc.identifier.doi | 10.6342/NTU202104118 | |
| dc.rights.note | 同意授權(限校園內公開) | |
| dc.date.accepted | 2021-10-29 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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