請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/80164完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 駱尚廉(Shang-Lien Lo) | |
| dc.contributor.author | Yu-Hsin Cheng | en |
| dc.contributor.author | 鄭郁欣 | zh_TW |
| dc.date.accessioned | 2022-11-23T09:29:35Z | - |
| dc.date.available | 2021-08-06 | |
| dc.date.available | 2022-11-23T09:29:35Z | - |
| dc.date.copyright | 2021-08-06 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-07-05 | |
| dc.identifier.citation | Abe, I., Hayashi, K., Hirashima, T. and Kitagawa, M. 1982. Relationship between the Freundlich Adsorption Constants K and 1/N for Hydrophobic Adsorption. Journal of the American Chemical Society 104(23), 6452-6453. Al-Ghouti, M.A., Al-Degs, Y.S., Issa, A.A., Al Bakain, R.Z. and Khraisheh, M.A. 2017. Mechanistic and Adsorption Equilibrium Studies of Dibenzothiophene-Rich-Diesel on Mno2-Loaded-Activated Carbon: Surface Characterization. Environmental Progress Sustainable Energy 36(3), 903-913. Alothman, Z.A. 2012. A Review: Fundamental Aspects of Silicate Mesoporous Materials. Materials 5(12), 2874-2902. Braeken, L., Bettens, B., Boussu, K., Van der Meeren, P., Cocquyt, J., Vermant, J. and Van der Bruggen, B. 2006. Transport Mechanisms of Dissolved Organic Compounds in Aqueous Solution During Nanofiltration. J. Membr. Sci. 279(1-2), 311-319. Brendel, S., Fetter, E., Staude, C., Vierke, L. and Biegel-Engler, A. 2018. Short-Chain Perfluoroalkyl Acids: Environmental Concerns and a Regulatory Strategy under Reach. Environ. Sci Eur. 30, 11. Cai, M.H., Zhao, Z., Yin, Z.G., Ahrens, L., Huang, P., Cai, M.G., Yang, H.Z., He, J.F., Sturm, R., Ebinghaus, R. and Xie, Z.Y. 2012. Occurrence of Perfluoroalkyl Compounds in Surface Waters from the North Pacific to the Arctic Ocean. Environmental Science Technology 46(2), 661-668. Campbell, T.Y., Vecitis, C.D., Mader, B.T. and Hoffmann, M.R. 2009. Perfluorinated Surfactant Chain-Length Effects on Sonochemical Kinetics. J. Phys. Chem. A 113(36), 9834-9842. Carey, J.H., Lawrence, J., Tosine, H.M. 1976. Photodechlorination of Pcb's in the Presence of Titanium Dioxide in Aqueous Suspensions. Bulletin of Environmental Contamination and Toxicology 16(6), 697-701. Caturla, F., Molinasabio, M. and Rodriguezreinoso, F. 1991. Preparation of Activated Carbon by Chemical Activation with Zncl2. Carbon 29(7), 999-1007. Chen, J., Zhang, P.Y. and Liu, J. 2007. Photodegradation of Perfluorooctanoic Acid by 185 Nm Vacuum Ultraviolet Light. J. Environ. Sci. 19(4), 387-390. Dauchy, X., Boiteux, V., Bach, C., Rosin, C. and Munoz, J.F. 2017. Per- and Polyfluoroalkyl Substances in Firefighting Foam Concentrates and Water Samples Collected near Sites Impacted by the Use of These Foams. Chemosphere 183, 53-61. Ding, G.H. and Peijnenburg, W. 2013. Physicochemical Properties and Aquatic Toxicity of Poly- and Perfluorinated Compounds. Crit. Rev. Environ. Sci. Technol. 43(6), 598-678. El Qada, E.N., Allen, S.J. and Walker, G.M. 2006. Adsorption of Methylene Blue onto Activated Carbon Produced from Steam Activated Bituminous Coal: A Study of Equilibrium Adsorption Isotherm. Chem. Eng. J. 124(1-3), 103-110. Eschauzier, C., Beerendonk, E., Scholte-Veenendaal, P. and De Voogt, P. 2012. Impact of Treatment Processes on the Removal of Perfluoroalkyl Acids from the Drinking Water Production Chain. Environmental Science Technology 46(3), 1708-1715. Espan, V.A.A., Mallavarapu, M. and Naidu, R. 2015. Treatment Technologies for Aqueous Perfluorooctanesulfonate (Pfos) and Perfluorooctanoate (Pfoa): A Critical Review with an Emphasis on Field Testing. Environ. Technol. Innov. 4, 168-181. Fenton, H.J.H. 1894. Oxidation of Tartaric Acid in the Presence of Iron. Journal of the Chemical Society, Transactions 65, 899-910. Fernandez, N.A., Rodriguez-Freire, L., Keswani, M. and Sierra-Alvarez, R. 2016. Effect of Chemical Structure on the Sonochemical Degradation of Perfluoroalkyl and Polyfluoroalkyl Substances (Pfass). Environ. Sci.-Wat. Res. Technol. 2(6), 975-983. Flores, C., Ventura, F., Martin-Alonso, J. and Caixach, J. 2013. Occurrence of Perfluorooctane Sulfonate (Pfos) and Perfluorooctanoate (Pfoa) in Ne Spanish Surface Waters and Their Removal in a Drinking Water Treatment Plant That Combines Conventional and Advanced Treatments in Parallel Lines. Sci. Total Environ. 461, 618-626. Fu, X.F., Yang, H.P., Lu, G.H., Tu, Y.M. and Wu, J.M. 2015. Improved Performance of Surface Functionalized Tio2/Activated Carbon for Adsorption-Photocatalytic Reduction of Cr(Vi) in Aqueous Solution. Materials Science in Semiconductor Processing 39, 362-370. Fujii, S., Polprasert, C., Tanaka, S., Lien, N.P.H. and Qiu, Y. 2007. New Pops in the Water Environment: Distribution, Bioaccumulation and Treatment of Perfluorinated Compounds - a Review Paper. Journal of Water Supply Research and Technology-Aqua 56(5), 313-326. Gao, Z., Yang, H.P., Fu, X.F., Jin, Q., Wu, Q.S., Kang, L. and Wu, J.M. 2020. Efficient Photoreduction of Cr(Vi) on Tio2/Functionalized Activated Carbon (Tio2/Ac-Aemp): Improved Adsorption of Cr(Vi) and Induced Transfer of Electrons. Environ. Sci. Pollut. Res. 27(15), 17446-17457. Gatto, S., Sansotera, M., Persico, F., Gola, M., Pirola, C., Panzeri, W., Navarrini, W. and Bianchi, C.L. 2015. Surface Fluorination on Tio2 Catalyst Induced by Photodegradation of Perfluorooctanoic Acid. Catal. Today 241, 8-14. Glaze, W.H. 1987. Drinking-Water Treatment with Ozone. Environmental Science Technology 21(3), 224-230. Hall, K.R., Eagleton, L.C., Acrivos, A. and Vermeulen, T. 1966. Pore- and Solid-Diffusion Kinetics in Fixed-Bed Adsorption under Constant-Pattern Conditions. Industrial Engineering Chemistry Fundamentals 5(2), 212-+. Heschel, W. and Klose, E. 1995. On the Suitability of Agricultural by-Products for the Manufacture of Granular Activated Carbon. Fuel 74(12), 1786-1791. Hori, H., Hayakawa, E., Einaga, H., Kutsuna, S., Koike, K., Ibusuki, T., Kiatagawa, H. and Arakawa, R. 2004. Decomposition of Environmentally Persistent Perfluorooctanoic Acid in Water by Photochemical Approaches. Environmental Science Technology 38(22), 6118-6124. Hori, H., Nagaoka, Y., Murayama, M. and Kutsuna, S. 2008. Efficient Decomposition of Perfluorocarboxylic Acids and Alternative Fluorochemical Surfactants in Hot Water. Environmental Science Technology 42(19), 7438-7443. Hubetska, T., Kobylinska, N. and Garcia, J.R. 2020. Efficient Adsorption of Pharmaceutical Drugs from Aqueous Solution Using a Mesoporous Activated Carbon. Adsorption-Journal of the International Adsorption Society 26(2), 251-266. Jans, U. and Hoigne, J. 1998. Activated Carbon and Carbon Black Catalyzed Transformation of Aqueous Ozone into Oh-Radicals. Ozone-Sci. Eng. 20(1), 67-90. Jiang, L.Y., Cao, X., Chen, J.M., Guo, H.Q., Chen, Z. and Li, S. 2019. Removal of Chlorobenzene Using a Sequential Adsorption-Plasma Catalytic System over Ag-, Ce- and Mn-Modified Activated Carbon Catalysts. Journal of Chemical Technology and Biotechnology 94(6), 1788-1799. Kano, F., Abe, I., Kamaya, H. and Ueda, I. 2000. Fractal Model for Adsorption on Activated Carbon Surfaces: Langmuir and Freundlich Adsorption. Surface Science 467(1-3), 131-138. Kotronarou, A., Mills, G. and Hoffmann, M.R. 1991. Ultrasonic Irradiation of Para-Nitrophenol in Aqueous-Solution. J. Phys. Chem. 95(9), 3630-3638. Krafft, M.P. and Riess, J.G. 2015. Per- and Polyfluorinated Substances (Pfass): Environmental Challenges. Curr. Opin. Colloid Interface Sci. 20(3), 192-212. Lau, C., Anitole, K., Hodes, C., Lai, D., Pfahles-Hutchens, A. and Seed, J. 2007. Perfluoroalkyl Acids: A Review of Monitoring and Toxicological Findings. Toxicological Sciences 99(2), 366-394. Lau, C., Thibodeaux, J.R., Hanson, R.G., Rogers, J.M., Grey, B.E., Stanton, M.E., Butenhoff, J.L. and Stevenson, L.A. 2003. Exposure to Perfluorooctane Sulfonate During Pregnancy in Rat and Mouse. Ii: Postnatal Evaluation. Toxicological Sciences 74(2), 382-392. Lee, Y.C., Lo, S.L., Kuo, J. and Lin, Y.L. 2012. Persulfate Oxidation of Perfluorooctanoic Acid under the Temperatures of 20-40 Degrees C. Chem. Eng. J. 198, 27-32. Li, F., Duan, J., Tian, S.T., Ji, H.D., Zhu, Y.M., Wei, Z.S. and Zhao, D.Y. 2020. Short-Chain Per- and Polyfluoroalkyl Substances in Aquatic Systems: Occurrence, Impacts and Treatment. Chem. Eng. J. 380, 23. Li, L.Q., Deng, Y., Ai, J., Li, L.F., Liao, G.Y., Xu, S.W., Wang, D.S. and Zhang, W.J. 2021. Fe/Mn Loaded Sludge-Based Carbon Materials Catalyzed Oxidation for Antibiotic Degradation: Persulfate Vs H2o2 as Oxidant. Sep. Purif. Technol. 263. Li, P.P., Zhi, D., Zhang, X.X., Zhu, H.M., Li, Z.Y., Peng, Y.T., He, Y.Z., Luo, L., Rong, X.M. and Zhou, Y.Y. 2019. Research Progress on the Removal of Hazardous Perfluorochemicals: A Review. J. Environ. Manage. 250, 8. Li, T.W., Jiang, Z.X., Xu, C.L., Liu, B., Liu, G.H., Wang, P.F., Li, X., Chen, W.T., Ning, C.X. and Wang, Z. 2017. Effect of Pore Structure on Shale Oil Accumulation in the Lower Third Member of the Shahejie Formation, Zhanhua Sag, Eastern China: Evidence from Gas Adsorption and Nuclear Magnetic Resonance. Marine and Petroleum Geology 88, 932-949. Lieder, P.H., York, R.G., Hakes, D.C., Chang, S.C. and Butenhoff, J.L. 2009. A Two-Generation Oral Gavage Reproduction Study with Potassium Perfluorobutanesulfonate (K+Pfbs) in Sprague Dawley Rats. Toxicology 259(1-2), 33-45. Liu, Z.M., Pan, L., Hu, F.P. and Hu, Y.Q. 2020. Advanced Landfill Leachate Biochemical Effluent Treatment Using Fe-Mn/Ac Activates O-3/Na2s2o8 Process: Process Optimization, Wastewater Quality Analysis, and Activator Characterization. Environ. Sci. Pollut. Res. 27(13), 15337-15349. Ma, J., Sui, M.H., Chen, Z.L. and Wang, L.N. 2004. Degradation of Refractory Organic Pollutants by Catalytic Ozonation - Activated Carbon and Mn-Loaded Activated Carbon as Catalysts. Ozone-Sci. Eng. 26(1), 3-10. Macon, M.B., Villanueva, L.R., Tatum-Gibbs, K., Zehr, R.D., Strynar, M.J., Stanko, J.P., White, S.S., Helfant, L. and Fenton, S.E. 2011. Prenatal Perfluorooctanoic Acid Exposure in Cd-1 Mice: Low-Dose Developmental Effects and Internal Dosimetry. Toxicological Sciences 122(1), 134-145. McKay, G., Elgeundi, M. and Nassar, M.M. 1987. Equilibrium Studies During the Removal of Dyestuffs from Aqueous-Solutions Using Bagasse Pith. Water Res. 21(12), 1513-1520. Moller, A., Ahrens, L., Surm, R., Westerveld, J., van der Wielen, F., Ebinghaus, R. and de Voogt, P. 2010. Distribution and Sources of Polyfluoroalkyl Substances (Pfas) in the River Rhine Watershed. Environmental Pollution 158(10), 3243-3250. Moriwaki, H., Takagi, Y., Tanaka, M., Tsuruho, K., Okitsu, K. and Maeda, Y. 2005. Sonochemical Decomposition of Perfluorooctane Sulfonate and Perfluorooctanoic Acid. Environmental Science Technology 39(9), 3388-3392. Naile, J.E., Khim, J.S., Hong, S., Park, J., Kwon, B.O., Ryu, J.S., Hwang, J.H., Jones, P.D. and Giesy, J.P. 2013. Distributions and Bioconcentration Characteristics of Perfluorinated Compounds in Environmental Samples Collected from the West Coast of Korea. Chemosphere 90(2), 387-394. O'Hagan, D. 2008. Understanding Organofluorine Chemistry. An Introduction to the C-F Bond. Chem. Soc. Rev. 37(2), 308-319. Ochoa-Herrera, V. and Sierra-Alvarez, R. 2008. Removal of Perfluorinated Surfactants by Sorption onto Granular Activated Carbon, Zeolite and Sludge. Chemosphere 72(10), 1588-1593. OECD, O.U.G.P.G. 2013 Synthesis Paper on Per- and Polyfluorinated Chemicals (Pfcs), Environment, Health and Safety. Persson, S., Rotander, A., Karrman, A., van Bavel, B. and Magnusson, U. 2013. Perfluoroalkyl Acids in Subarctic Wild Male Mink (Neovison Vison) in Relation to Age, Season and Geographical Area. Environ. Int. 59, 425-430. Regti, A., Laamari, M.R., Stiriba, S.E. and El Haddad, M. 2017. Use of Response Factorial Design for Process Optimization of Basic Dye Adsorption onto Activated Carbon Derived from Persea Species. Microchemical Journal 130, 129-136. Sanchez-Polo, M., von Gunten, U. and Rivera-Utrilla, J. 2005. Efficiency of Activated Carbon to Transform Ozone into Center Dot Oh Radicals: Influence of Operational Parameters. Water Res. 39(14), 3189-3198. Sansotera, M., Persico, F., Pirola, C., Navarrini, W., Di Michele, A. and Bianchi, C.L. 2014. Decomposition of Perfluorooctanoic Acid Photocatalyzed by Titanium Dioxide: Chemical Modification of the Catalyst Surface Induced by Fluoride Ions. Appl. Catal. B-Environ. 148, 29-35. Schroder, H.F., Jose, H.J., Gebhardt, W., Moreira, R. and Pinnekamp, J. 2010. Biological Wastewater Treatment Followed by Physicochemical Treatment for the Removal of Fluorinated Surfactants. Water Sci. Technol. 61(12), 3208-3215. Schroder, H.F. and Meesters, R.J.W. 2005. Stability of Fluorinated Surfactants in Advanced Oxidation Processes - a Follow up of Degradation Products Using Flow Injection-Mass Spectrometry, Liquid Chromatography-Mass Spectrometry and Liquid Chromatography-Multiple Stage Mass Spectrometry. J. Chromatogr. A 1082(1), 110-119. Seacat, A.M., Thomford, P.J., Hansen, K.J., Olsen, G.W., Case, M.T. and Butenhoff, J.L. 2002. Subchronic Toxicity Studies on Perfluorooctanesulfonate Potassium Salt in Cynomolgus Monkeys. Toxicological Sciences 68(1), 249-264. Sing, K.S.W., Everett, D.H., Haul, R.A.W., Moscou, L., Pierotti, R.A., Rouquerol, J. and Siemieniewska, T. 1985. Reporting Physisorption Data for Gas Solid Systems with Special Reference to the Determination of Surface-Area and Porosity (Recommendations 1984). Pure and Applied Chemistry 57(4), 603-619. Son, H.Y., Kim, S.H., Shin, H.I., Bae, H.I. and Yang, J.H. 2008. Perfluorooctanoic Acid-Induced Hepatic Toxicity Following 21-Day Oral Exposure in Mice. Arch. Toxicol. 82(4), 239-246. Sun, M., Arevalo, E., Strynar, M., Lindstrom, A., Richardson, M., Kearns, B., Pickett, A., Smith, C. and Knappe, D.R.U. 2016. Legacy and Emerging Perfluoroalkyl Substances Are Important Drinking Water Contaminants in the Cape Fear River Watershed of North Carolina. Environ. Sci. Technol. Lett. 3(12), 415-419. Szymczyk, A., Labbez, C., Fievet, P., Vidonne, A., Foissy, A. and Pagetti, J. 2003. Contribution of Convection, Diffusion and Migration to Electrolyte Transport through Nanofiltration Membranes. Adv. Colloid Interface Sci. 103(1), 77-94. Tan, K.L. and Hameed, B.H. 2017. Insight into the Adsorption Kinetics Models for the Removal of Contaminants from Aqueous Solutions. Journal of the Taiwan Institute of Chemical Engineers 74, 25-48. Tang, C.Y., Fu, Q.S., Criddle, C.S. and Leckie, J.O. 2007. Effect of Flux (Transmembrane Pressure) and Membrane Properties on Fouling and Rejection of Reverse Osmosis and Nanofiltration Membranes Treating Perfluorooctane Sulfonate Containing Wastewater. Environmental Science Technology 41(6), 2008-2014. Tang, H.Q., Xiang, Q.Q., Lei, M., Yan, J.C., Zhu, L.H. and Zou, J. 2012. Efficient Degradation of Perfluorooctanoic Acid by Uv-Fenton Process. Chem. Eng. J. 184, 156-162. Trojanowicz, M., Bojanowska-Czajka, A., Bartosiewicz, I. and Kulisa, K. 2018. Advanced Oxidation/Reduction Processes Treatment for Aqueous Perfluorooctanoate (Pfoa) and Perfluorooctanesulfonate (Pfos) - a Review of Recent Advances. Chem. Eng. J. 336, 170-199. Tsai, W.T., Chen, H.P. and Hsien, W.Y. 2002. A Review of Uses, Environmental Hazards and Recovery/Recycle Technologies of Perfluorocarbons (Pfcs) Emissions from the Semiconductor Manufacturing Processes. J. Loss Prev. Process Ind. 15(2), 65-75. Tsang, W., Burgess, D.R. and Babushok, V. 1998. On the Incinerability of Highly Fluorinated Organic Compounds. Combust. Sci. Technol. 139(1-6), 385-402. Ullah, S., Huber, S., Bignert, A. and Berger, U. 2014. Temporal Trends of Perfluoroalkane Sulfonic Acids and Their Sulfonamide-Based Precursors in Herring from the Swedish West Coast 1991-2011 Including Isomer-Specific Considerations. Environ. Int. 65, 63-72. Van de Vijver, K.I., Hoff, P., Das, K., Brasseur, S., Van Dongen, W., Esmans, E., Reijnders, P., Blust, R. and De Coen, W. 2005. Tissue Distribution of Perfluorinated Chemicals in Harbor Seals (Phoca Vitulina) from the Dutch Wadden Sea. Environmental Science Technology 39(18), 6978-6984. Van der Bruggen, B., Vandecasteele, C., Van Gestel, T., Doyen, W. and Leysen, R. 2003. A Review of Pressure-Driven Membrane Processes in Wastewater Treatment and Drinking Water Production. Environ. Prog. 22(1), 46-56. Vecitis, C.D., Park, H., Cheng, J., Mader, B.T. and Hoffmann, M.R. 2009. Treatment Technologies for Aqueous Perfluorooctanesulfonate (Pfos) and Perfluorooctanoate (Pfoa). Front. Environ. Sci. Eng. China 3(2), 129-151. von Sonntag, C. 2008. Advanced Oxidation Processes: Mechanistic Aspects. Water Sci. Technol. 58(5), 1015-1021. Wei, Z.S., Villamena, F.A. and Weavers, L.K. 2017. Kinetics and Mechanism of Ultrasonic Activation of Persulfate: An in Situ Epr Spin Trapping Study. Environmental Science Technology 51(6), 3410-3417. Xu, J.Z., Chen, L.Z., Qu, H.Q., Jiao, Y.H., Xie, J.X. and Xing, G.G. 2014. Preparation and Characterization of Activated Carbon from Reedy Grass Leaves by Chemical Activation with H3po4. Applied Surface Science 320, 674-680. Yaseen, M., Ullah, S., Ahmad, W., Subhan, S. and Subhan, F. 2021. Fabrication of Zn and Mn Loaded Activated Carbon Derived from Corn Cobs for the Adsorptive Desulfurization of Model and Real Fuel Oils. Fuel 284. Zhao, P.J., Xia, X.H., Dong, J.W., Xia, N., Jiang, X.M., Li, Y. and Zhu, Y.M. 2016. Short- and Long-Chain Perfluoroalkyl Substances in the Water, Suspended Particulate Matter, and Surface Sediment of a Turbid River. Sci. Total Environ. 568, 57-65. Zhou, Z., Liang, Y., Shi, Y.L., Xu, L. and Cai, Y.Q. 2013. Occurrence and Transport of Perfluoroalkyl Acids (Pfaas), Including Short-Chain Pfaas in Tangxun Lake, China. Environmental Science Technology 47(16), 9249-9257. 孫溏澤 (2020) 以顆粒活性碳吸附全氟丁烷磺酸及其微波再生之研究, 國立臺灣大學. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/80164 | - |
| dc.description.abstract | "全氟化合物 (Perfluorinated chemicals, PFCs) 是一人工合成物，為良好之界面活性劑，被廣泛應用於工業與民生用品中，隨著長碳鏈PFCs之危害研究越來越多，現今許多產業逐步將短碳鏈PFCs作為長碳鏈之替代品，如全氟丁烷磺酸 (Perfluorobutanesulfonic acid, PFBS)，因其具較小之毒性與生物累積性。然而，近年來在環境與生物體中陸續測得短碳鏈PFCs之存在，歐盟於2020年將PFBS加入高度關切物質清單中，美國環保署也於2021年修訂PFBS對人體健康之安全暴露劑量，因此發展有效去除短碳鏈PFCs之方法為重要之議題。 本研究利用改質活性碳 (OAC) 去除水中之PFBS，分析改質前後活性碳之比表面積、界達電位、表面結構和組成成分與鍵結，並探討pH值、OAC量、PFBS濃度和系統溫度對去除效果之影響。研究結果顯示，初始PFBS濃度為200 ppm且pH值為3.2之水樣，控制系統溫度為25 ℃時，加入10 g/500 mL之OAC反應30分鐘，有最佳PFBS去除效果，去除率為99.412 %，吸附量為9.901 mg/g，此吸附過程符合擬一階吸附動力模式與Freundlich等溫吸附模式。上述結果說明改質過程改變了活性碳的物化性質，進一步增加了OAC的吸附能力。 此外，將吸附過後之OAC重複利用，每次吸附後都會有部分的OAC吸附位置被填滿，造成去除速度和去除率逐次降低，去除率由第1次99.412 %降至第10次66.797 %，吸附量亦由第1次9.901 mg/g減少至第10次6.689 mg/g。 最後，將OAC用以吸附其他常見之PFCs，並比較PFBS和全氟辛酸 (Perfluorooctanoic acid, PFOA)、全氟辛烷磺酸 (Perfluorooctanesulfonic acid, PFOS) 之競爭吸附關係，實驗發現PFOS最易被吸附，PFBS最不易被吸附。而將OAC應用於實廠廢水，實驗結果顯示，實廠廢水中的有機物可能會和PFBS競爭吸附或阻擋吸附位置，使得PFBS之去除效果降低。" | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-23T09:29:35Z (GMT). No. of bitstreams: 1 U0001-2806202116561500.pdf: 3803732 bytes, checksum: 513d92246e554d3b29b5facde4e4181b (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | 口試委員審定書 i 致謝 ii 摘要 iii Abstract iv 目錄 vi 圖目錄 x 表目錄 xii 第一章 前言 1 1.1 研究緣起 1 1.2 研究目的 2 1.3 研究內容 2 第二章 文獻回顧 3 2.1 全氟化合物 3 2.1.1 全氟化合物之性質 3 2.1.2 全氟化合物之危害 5 2.1.3 全氟化合物之法規 6 2.2 短碳鏈之全氟化合物 8 2.2.1 短碳鏈全氟化合物之性質與分布 8 2.2.2 全氟丁烷磺酸 11 2.3 全氟化合物之去除方法 12 2.3.1 吸附法 13 2.3.2 膜過濾法 13 2.3.3 自由基氧化法 14 2.3.4 光化學氧化法 15 2.3.5 超聲波氧化法 16 2.4 活性碳去除法 17 2.4.1 活性碳基本性質 17 2.4.2 活性碳吸附模式 19 2.4.3 改質活性碳之去除方法 22 2.4.4 活性碳結合臭氧之去除方法 26 第三章 材料與方法 28 3.1 研究內容與架構 28 3.2 實驗方法與步驟 30 3.2.1 背景實驗 30 3.2.2 操作參數實驗 31 3.2.3 OAC再利用實驗 32 3.2.4 實際應用 32 3.2.5 品質管制 33 3.3 實驗藥品與裝置 34 3.3.1 實驗藥品 34 3.3.2 實驗裝置 35 3.4 分析方法 36 3.4.1 比表面積分析儀 36 3.4.2 界達電位分析儀 37 3.4.3 掃描式電子顯微鏡 38 3.4.4 化學分析影像能譜儀 39 3.4.5 高效能離子層析儀 39 3.4.6 離子層析儀 41 第四章 結果與討論 42 4.1 背景實驗 42 4.1.1 標準添加分析 42 4.1.2 器材吸附實驗分析 43 4.1.3 控制實驗分析 44 4.2 活性碳物化性質分析 47 4.2.1 比表面積分析 47 4.2.2 界達電位分析 49 4.2.3 掃描式電子顯微鏡分析 50 4.2.4 化學分析影像能譜 52 4.3 操作參數實驗 54 4.3.1 初始pH值對吸附之影響 54 4.3.2 活性碳劑量對吸附之影響 56 4.3.3 初始PFBS濃度對吸附之影響 57 4.3.4 系統溫度對吸附之影響 58 4.4 吸附模式 59 4.4.1 吸附動力模式 59 4.4.2 等溫吸附模式 59 4.5 OAC再利用實驗 61 4.6 與其他常見活性碳之比較 62 4.7 實際應用 63 4.7.1 其他PFCs之去除效果 63 4.7.2 實廠廢水基質之去除效果 66 第五章 結論與建議 68 5.1 結論 68 5.2 建議 69 參考文獻 70 附表 77 | |
| dc.language.iso | zh-TW | |
| dc.subject | 實廠廢水 | zh_TW |
| dc.subject | 全氟丁烷磺酸 | zh_TW |
| dc.subject | 改質活性碳 | zh_TW |
| dc.subject | 吸附 | zh_TW |
| dc.subject | Realistic wastewater | en |
| dc.subject | Perfluorobutanesulfonic acid | en |
| dc.subject | Modified activated carbon | en |
| dc.subject | Adsorption | en |
| dc.title | 以摻釕和錳之活性碳去除全氟丁烷磺酸之研究 | zh_TW |
| dc.title | Removal of Perfluorobutanesulfonic Acid by Ru/Mn-loaded Activated Carbon | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 郭繼汾(Hsin-Tsai Liu),胡景堯(Chih-Yang Tseng) | |
| dc.subject.keyword | 全氟丁烷磺酸,改質活性碳,吸附,實廠廢水, | zh_TW |
| dc.subject.keyword | Perfluorobutanesulfonic acid,Modified activated carbon,Adsorption,Realistic wastewater, | en |
| dc.relation.page | 84 | |
| dc.identifier.doi | 10.6342/NTU202101174 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2021-07-06 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
| 顯示於系所單位： | 環境工程學研究所 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| U0001-2806202116561500.pdf | 3.71 MB | Adobe PDF | 檢視/開啟 |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。