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| ???org.dspace.app.webui.jsptag.ItemTag.dcfield??? | Value | Language |
|---|---|---|
| dc.contributor.advisor | 林逸彬(Yi-Pin Lin) | |
| dc.contributor.author | Jheng-Shin Chang | en |
| dc.contributor.author | 張正欣 | zh_TW |
| dc.date.accessioned | 2022-11-23T09:26:49Z | - |
| dc.date.available | 2021-07-23 | |
| dc.date.available | 2022-11-23T09:26:49Z | - |
| dc.date.copyright | 2021-07-23 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-07-08 | |
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Build Mater. 57, 138-143. Yang, Y., Yang, Y., Wang, Q., Huang, Q., 2010. Release of heavy metals from concrete made with cement from cement kiln co-processing of hazardous wastes in pavement scenarios. Environ. Eng. Sci. 28, 35-42. Zhang, J., Liu, J., Li, C., Jin, Y., Nie, Y., Li, J., 2009. Comparison of the fixation effects of heavy metals by cement rotary kiln co-processing and cement based solidification/stabilization. J. Hazard. Mater. 165, 1179-1185. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/80113 | - |
| dc.description.abstract | 水泥窯協同處理(co-processing)利用廢棄物替代部分的製程燃料或水泥原料，可降低生產成本減少環境負荷並處理有害廢棄物。本研究添加兩種重金屬(場址1及場址2)污染土壤，取代原料配比，以0、3、7.6和10 wt.% 製作水泥，分析其工程特性，並利用事業廢棄物毒性特性溶出程序(TCLP)、合成降水溶出程序(SPLP)、EDTA輔助TCLP (EDTA-mediated TCLP)溶出程序以及再生粒料溶出程序(RALP)檢測重金屬趨勢。 經由成分分析，污染土壤可替代水泥原料中之黏土。特性分析結果顯示當添加土壤量愈多，礦物相Ca3SiO5 (C3S)之比例有下降的趨勢，Ca2SiO4 (C2S)反之上升，使凝結時間延長且抗壓強度降低，尤其以添加高濃度之鉻污染土壤更為顯著。TCLP試驗中，添加量超過7.6%場址1的水泥粉之鉻溶出濃度超出事業廢棄物溶出標準，而添加量10%的硬固水泥之鉻溶出濃度仍符合溶出標準，添加10%場址2的水泥粉及硬固水泥之鉻溶出量皆符合標準。此外，EDTA輔助TCLP相較於TCLP有更高的鉻溶出量。RALP試驗結果顯示所有水泥皆可做為控制性低強度回填材料(CLSMs)。在本研究之添加比例下，以3 wt.% 場址1及10 wt.% 場址2污染土壤添加製作之水泥，可符合工程特性要求並兼具環境相容性。由經濟分析可知，水泥業者及污染行為人可藉由水泥窯協同處理獲得可觀的經濟效益。重金屬污染之土壤適合以水泥窯協同處理之方式進行循環利用，同時兼顧污染處理並降低傳統水泥生產之環境及經濟成本。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-23T09:26:49Z (GMT). No. of bitstreams: 1 U0001-0607202120513200.pdf: 3313994 bytes, checksum: 7a13c5fe0900f032d184bfea01d61623 (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | 摘要 I Abstract II Contents IV Content of Figures VI Content of Tables VIII Chapter 1 Introduction 1 1.1 Background 1 1.2 Research Objectives 2 Chapter 2 Literature Review 3 2.1 Heavy metal-contaminated soil 3 2.2 Co-processing of cement industry 5 2.3 Mechanism of metal immobilization by co-processing 9 2.4 Assessment of environmental compatibility 12 Chapter 3 Materials and Methods 15 3.1 Experimental design 15 3.2 Materials and chemicals 17 3.3 Microwave assisted aqua regia digestion 19 3.4 Cement manufacture 19 3.5 Performance evaluation 22 3.6 Leaching test 25 3.7 Analytical method 27 Chapter 4 Results and discussion 29 4.1 Characterization of heavy metal-contaminated soils 29 4.2 Characterization of raw materials and cement products 34 4.3 Leaching test 43 4.4 Economic analysis 49 Chapter 5 Conclusions and recommendations 51 5.1 Conclusions 51 5.2 Recommendations 52 Reference List 53 Appendix 63 | |
| dc.language.iso | en | |
| dc.subject | 經濟分析 | zh_TW |
| dc.subject | 重金屬污染土壤 | zh_TW |
| dc.subject | 水泥窯協同處理 | zh_TW |
| dc.subject | 環境相容性 | zh_TW |
| dc.subject | cement kiln | en |
| dc.subject | heavy metal-contaminated soil | en |
| dc.subject | environmental compatibility | en |
| dc.subject | co-processing | en |
| dc.title | 以水泥窯協同處理再生重金屬污染土壤生產水泥之研究 | zh_TW |
| dc.title | Reutilization of Heavy Metal Contaminated Soils for Cement Production by Cement Kiln Co-processing | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 林正芳(Hsin-Tsai Liu),席行正(Chih-Yang Tseng),廖文正 | |
| dc.subject.keyword | 重金屬污染土壤,水泥窯協同處理,環境相容性,經濟分析, | zh_TW |
| dc.subject.keyword | heavy metal-contaminated soil,cement kiln,co-processing,environmental compatibility, | en |
| dc.relation.page | 65 | |
| dc.identifier.doi | 10.6342/NTU202101310 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2021-07-08 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
| Appears in Collections: | 環境工程學研究所 | |
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| U0001-0607202120513200.pdf | 3.24 MB | Adobe PDF | View/Open |
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