請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/79076
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 吳乃立(Nae-Lih Wu) | |
dc.contributor.author | Chang-En Wu | en |
dc.contributor.author | 吳昌恩 | zh_TW |
dc.date.accessioned | 2021-07-11T15:42:01Z | - |
dc.date.available | 2023-08-23 | |
dc.date.copyright | 2018-08-23 | |
dc.date.issued | 2018 | |
dc.date.submitted | 2018-08-12 | |
dc.identifier.citation | 1. R. Yazami and P. Touzain, 'A reversible graphite-lithium negative electrode for electrochemical generators', Journal of Power Sources, 9, 365-371 (1983)
2. R. a. Fong, 'Studies of Lithium Intercalation into Carbons Using Nonaqueous Electrochemical Cells', Journal of The Electrochemical Society, 137, 2009 (1990) 3. J. Luo, C.-C. Fang, and N.-L. Wu, 'High Polarity Poly(vinylidene difluoride) Thin Coating for Dendrite-Free and High-Performance Lithium Metal Anodes', Advanced Energy Materials, 8, 1701482 (2018) 4. G. Zheng, S. W. Lee, Z. Liang, H. W. Lee, K. Yan, H. Yao, H. Wang, W. Li, S. Chu, and Y. Cui, 'Interconnected hollow carbon nanospheres for stable lithium metal anodes', Nat Nanotechnol, 9, 618-23 (2014) 5. N. Mahmood, T. Tang, and Y. Hou, 'Nanostructured Anode Materials for Lithium Ion Batteries: Progress, Challenge and Perspective', Advanced Energy Materials, 6, 1600374 (2016) 6. J. M. Tarascon and M. Armand, 'Issues and challenges facing rechargeable lithium batteries', Nature, 414, 359-67 (2001) 7. R. Liu, J. Duay, and S. B. Lee, 'Heterogeneous nanostructured electrode materials for electrochemical energy storage', Chem Commun (Camb), 47, 1384-404 (2011) 8. A. K. Padhi, 'Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries', Journal of The Electrochemical Society, 144, 1188 (1997) 9. F. Wang, R. Robert, N. A. Chernova, N. Pereira, F. Omenya, F. Badway, X. Hua, M. Ruotolo, R. Zhang, L. Wu, V. Volkov, D. Su, B. Key, M. S. Whittingham, C. P. Grey, G. G. Amatucci, Y. Zhu, and J. Graetz, 'Conversion reaction mechanisms in lithium ion batteries: study of the binary metal fluoride electrodes', J Am Chem Soc, 133, 18828-36 (2011) 10. P. G. Bruce, S. A. Freunberger, L. J. Hardwick, and J. M. Tarascon, 'Li-O2 and Li-S batteries with high energy storage', Nat Mater, 11, 19-29 (2011) 11. Y. X. Yin, S. Xin, Y. G. Guo, and L. J. Wan, 'Lithium-sulfur batteries: electrochemistry, materials, and prospects', Angew Chem Int Ed Engl, 52, 13186-200 (2013) 12. X. He, J. Ren, L. Wang, W. Pu, C. Jiang, and C. Wan, 'Expansion and shrinkage of the sulfur composite electrode in rechargeable lithium batteries', Journal of Power Sources, 190, 154-156 (2009) 13. M. D. Bhatt and C. O'Dwyer, 'Recent progress in theoretical and computational investigations of Li-ion battery materials and electrolytes', Phys Chem Chem Phys, 17, 4799-844 (2015) 14. N. Nitta, F. Wu, J. T. Lee, and G. Yushin, 'Li-ion battery materials: present and future', Materials Today, 18, 252-264 (2015) 15. Z. Li, J. Huang, B. Yann Liaw, V. Metzler, and J. Zhang, 'A review of lithium deposition in lithium-ion and lithium metal secondary batteries', Journal of Power Sources, 254, 168-182 (2014) 16. Y. P. Wu, E. Rahm, and R. Holze, 'Carbon anode materials for lithium ion batteries', Journal of Power Sources, 114, 228-236 (2003) 17. Y. Tang, L. Yang, Z. Qiu, and J. Huang, 'Template-free synthesis of mesoporous spinel lithium titanate microspheres and their application in high-rate lithium ion batteries', Journal of Materials Chemistry, 19, 5980 (2009) 18. M. He, K. Kravchyk, M. Walter, and M. V. Kovalenko, 'Monodisperse antimony nanocrystals for high-rate Li-ion and Na-ion battery anodes: nano versus bulk', Nano Lett, 14, 1255-62 (2014) 19. H. X. Dang, K. C. Klavetter, M. L. Meyerson, A. Heller, and C. B. Mullins, 'Tin microparticles for a lithium ion battery anode with enhanced cycling stability and efficiency derived from Se-doping', Journal of Materials Chemistry A, 3, 13500-13506 (2015) 20. M. R. Palacin, 'Recent advances in rechargeable battery materials: a chemist's perspective', Chem Soc Rev, 38, 2565-75 (2009) 21. Y. M. Liu, G. N. B, J. L. Esbenshade, and A. A. Gewirth, 'Characterization of the Cathode Electrolyte Interface in Lithium Ion Batteries by Desorption Electrospray Ionization Mass Spectrometry', Anal Chem, 88, 7171-7 (2016) 22. P. Verma, P. Maire, and P. Novák, 'A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries', Electrochimica Acta, 55, 6332-6341 (2010) 23. F. S. Li, Y. S. Wu, J. Chou, M. Winter, and N. L. Wu, 'A mechanically robust and highly ion-conductive polymer-blend coating for high-power and long-life lithium-ion battery anodes', Adv Mater, 27, 130-7 (2015) 24. V. A. Agubra and J. W. Fergus, 'The formation and stability of the solid electrolyte interface on the graphite anode', Journal of Power Sources, 268, 153-162 (2014) 25. S. J. An, J. Li, C. Daniel, D. Mohanty, S. Nagpure, and D. L. Wood, 'The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling', Carbon, 105, 52-76 (2016) 26. E. Peled, 'Advanced Model for Solid Electrolyte Interphase Electrodes in Liquid and Polymer Electrolytes', Journal of The Electrochemical Society, 144, L208 (1997) 27. X. Yu and A. Manthiram, 'Electrode–electrolyte interfaces in lithium-based batteries', Energy & Environmental Science, 11, 527-543 (2018) 28. K. Edström, M. Herstedt, and D. P. Abraham, 'A new look at the solid electrolyte interphase on graphite anodes in Li-ion batteries', Journal of Power Sources, 153, 380-384 (2006) 29. M. Nie, D. Chalasani, D. P. Abraham, Y. Chen, A. Bose, and B. L. Lucht, 'Lithium Ion Battery Graphite Solid Electrolyte Interphase Revealed by Microscopy and Spectroscopy', The Journal of Physical Chemistry C, 117, 1257-1267 (2013) 30. S. S. Zhang, K. Xu, and T. R. Jow, 'EIS study on the formation of solid electrolyte interface in Li-ion battery', Electrochimica Acta, 51, 1636-1640 (2006) 31. M. Nie, D. P. Abraham, Y. Chen, A. Bose, and B. L. Lucht, 'Silicon Solid Electrolyte Interphase (SEI) of Lithium Ion Battery Characterized by Microscopy and Spectroscopy', The Journal of Physical Chemistry C, 117, 13403-13412 (2013) 32. M. Gauthier, T. J. Carney, A. Grimaud, L. Giordano, N. Pour, H. H. Chang, D. P. Fenning, S. F. Lux, O. Paschos, C. Bauer, F. Maglia, S. Lupart, P. Lamp, and Y. Shao-Horn, 'Electrode-electrolyte interface in Li-ion batteries: current understanding and new insights', J Phys Chem Lett, 6, 4653-72 (2015) 33. F. Yao, D. T. Pham, and Y. H. Lee, 'Carbon-Based Materials for Lithium-Ion Batteries, Electrochemical Capacitors, and Their Hybrid Devices', ChemSusChem, 8, 2284-311 (2015) 34. Y.-N. Jo, M.-S. Park, E.-Y. Lee, J.-G. Kim, K.-J. Hong, S.-I. Lee, H. Y. Jeong, G. H. Ryu, Z. Lee, and Y.-J. Kim, 'Increasing reversible capacity of soft carbon anode by phosphoric acid treatment', Electrochimica Acta, 146, 630-637 (2014) 35. Y. Li, L. Mu, Y.-S. Hu, H. Li, L. Chen, and X. Huang, 'Pitch-derived amorphous carbon as high performance anode for sodium-ion batteries', Energy Storage Materials, 2, 139-145 (2016) 36. J. R. Dahn, T. Zheng, Y. Liu, and J. S. Xue, 'Mechanisms for Lithium Insertion in Carbonaceous Materials', Science, 270, 590-593 (1995) 37. J. R. Dahn, W. Xing, and Y. Gao, 'The “falling cards model” for the structure of microporous carbons', Carbon, 35, 825-830 (1997) 38. Z. L. Yu, S. Xin, Y. You, L. Yu, Y. Lin, D. W. Xu, C. Qiao, Z. H. Huang, N. Yang, S. H. Yu, and J. B. Goodenough, 'Ion-Catalyzed Synthesis of Microporous Hard Carbon Embedded with Expanded Nanographite for Enhanced Lithium/Sodium Storage', J Am Chem Soc, 138, 14915-14922 (2016) 39. K. Omichi, G. Ramos-Sanchez, R. Rao, N. Pierce, G. Chen, P. B. Balbuena, and A. R. Harutyunyan, 'Origin of Excess Irreversible Capacity in Lithium-Ion Batteries Based on Carbon Nanostructures', Journal of The Electrochemical Society, 162, A2106-A2115 (2015) 40. Y. Nishi, 'Lithium ion secondary batteries; past 10 years and the future', Journal of Power Sources, 100, 101-106 (2001) 41. H. Azuma, H. Imoto, S. i. Yamada, and K. Sekai, 'Advanced carbon anode materials for lithium ion cells', Journal of Power Sources, 81-82, 1-7 (1999) 42. W. Luo, Z. Jian, Z. Xing, W. Wang, C. Bommier, M. M. Lerner, and X. Ji, 'Electrochemically Expandable Soft Carbon as Anodes for Na-Ion Batteries', ACS Cent Sci, 1, 516-22 (2015) 43. Z. Jian, C. Bommier, L. Luo, Z. Li, W. Wang, C. Wang, P. A. Greaney, and X. Ji, 'Insights on the Mechanism of Na-Ion Storage in Soft Carbon Anode', Chemistry of Materials, 29, 2314-2320 (2017) 44. B. Zhang, C. M. Ghimbeu, C. Laberty, C. Vix-Guterl, and J.-M. Tarascon, 'Correlation Between Microstructure and Na Storage Behavior in Hard Carbon', Advanced Energy Materials, 6, 1501588 (2016) 45. E. Irisarri, A. Ponrouch, and M. R. Palacin, 'Review—Hard Carbon Negative Electrode Materials for Sodium-Ion Batteries', Journal of The Electrochemical Society, 162, A2476-A2482 (2015) 46. S. Komaba, W. Murata, T. Ishikawa, N. Yabuuchi, T. Ozeki, T. Nakayama, A. Ogata, K. Gotoh, and K. Fujiwara, 'Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries', Advanced Functional Materials, 21, 3859-3867 (2011) 47. X. X. Wang, J. N. Wang, H. Chang, and Y. F. Zhang, 'Preparation of Short Carbon Nanotubes and Application as an Electrode Material in Li-Ion Batteries', Advanced Functional Materials, 17, 3613-3618 (2007) 48. D. Pan, S. Wang, B. Zhao, M. Wu, H. Zhang, Y. Wang, and Z. Jiao, 'Li Storage Properties of Disordered Graphene Nanosheets', Chemistry of Materials, 21, 3136-3142 (2009) 49. P. Sood, K. C. Kim, and S. S. Jang, 'Electrochemical and electronic properties of nitrogen doped fullerene and its derivatives for lithium-ion battery applications', Journal of Energy Chemistry, 27, 528-534 (2018) 50. M. Zeilinger, D. Benson, U. Häussermann, and T. F. Fässler, 'Single Crystal Growth and Thermodynamic Stability of Li17Si4', Chemistry of Materials, 25, 1960-1967 (2013) 51. S. Zhang, M. He, C.-C. Su, and Z. Zhang, 'Advanced electrolyte/additive for lithium-ion batteries with silicon anode', Current Opinion in Chemical Engineering, 13, 24-35 (2016) 52. X. H. Liu, L. Zhong, S. Huang, S. X. Mao, T. Zhu, and J. Y. Huang, 'Size-dependent fracture of silicon nanoparticles during lithiation', ACS Nano, 6, 1522-31 (2012) 53. H. Wu and Y. Cui, 'Designing nanostructured Si anodes for high energy lithium ion batteries', Nano Today, 7, 414-429 (2012) 54. H. Li, 'The crystal structural evolution of nano-Si anode caused by lithium insertion and extraction at room temperature', Solid State Ionics, 135, 181-191 (2000) 55. J. P. Maranchi, A. F. Hepp, and P. N. Kumta, 'High Capacity, Reversible Silicon Thin-Film Anodes for Lithium-Ion Batteries', Electrochemical and Solid-State Letters, 6, A198 (2003) 56. L. F. Cui, L. Hu, J. W. Choi, and Y. Cui, 'Light-weight free-standing carbon nanotube-silicon films for anodes of lithium ion batteries', ACS Nano, 4, 3671-8 (2010) 57. S. Suresh, Z. P. Wu, S. F. Bartolucci, S. Basu, R. Mukherjee, T. Gupta, P. Hundekar, Y. Shi, T. M. Lu, and N. Koratkar, 'Protecting Silicon Film Anodes in Lithium-Ion Batteries Using an Atomically Thin Graphene Drape', ACS Nano, 11, 5051-5061 (2017) 58. R. Yi, F. Dai, M. L. Gordin, S. Chen, and D. Wang, 'Micro-sized Si-C Composite with Interconnected Nanoscale Building Blocks as High-Performance Anodes for Practical Application in Lithium-Ion Batteries', Advanced Energy Materials, 3, 295-300 (2013) 59. Z. Lu, N. Liu, H. W. Lee, J. Zhao, W. Li, Y. Li, and Y. Cui, 'Nonfilling carbon coating of porous silicon micrometer-sized particles for high-performance lithium battery anodes', ACS Nano, 9, 2540-7 (2015) 60. X. Li, M. Gu, S. Hu, R. Kennard, P. Yan, X. Chen, C. Wang, M. J. Sailor, J. G. Zhang, and J. Liu, 'Mesoporous silicon sponge as an anti-pulverization structure for high-performance lithium-ion battery anodes', Nat Commun, 5, 4105 (2014) 61. S. Choi, T. W. Kwon, A. Coskun, and J. W. Choi, 'Highly elastic binders integrating polyrotaxanes for silicon microparticle anodes in lithium ion batteries', Science, 357, 279-283 (2017) 62. T. W. Kwon, Y. K. Jeong, E. Deniz, S. Y. AlQaradawi, J. W. Choi, and A. Coskun, 'Dynamic Cross-Linking of Polymeric Binders Based on Host-Guest Interactions for Silicon Anodes in Lithium Ion Batteries', ACS Nano, 9, 11317-24 (2015) 63. T. M. Higgins, S. H. Park, P. J. King, C. J. Zhang, N. McEvoy, N. C. Berner, D. Daly, A. Shmeliov, U. Khan, G. Duesberg, V. Nicolosi, and J. N. Coleman, 'A Commercial Conducting Polymer as Both Binder and Conductive Additive for Silicon Nanoparticle-Based Lithium-Ion Battery Negative Electrodes', ACS Nano, 10, 3702-13 (2016) 64. C. Wang, H. Wu, Z. Chen, M. T. McDowell, Y. Cui, and Z. Bao, 'Self-healing chemistry enables the stable operation of silicon microparticle anodes for high-energy lithium-ion batteries', Nat Chem, 5, 1042-8 (2013) 65. M. H. Ryou, J. Kim, I. Lee, S. Kim, Y. K. Jeong, S. Hong, J. H. Ryu, T. S. Kim, J. K. Park, H. Lee, and J. W. Choi, 'Mussel-inspired adhesive binders for high-performance silicon nanoparticle anodes in lithium-ion batteries', Adv Mater, 25, 1571-6 (2013) 66. H. Wu, G. Yu, L. Pan, N. Liu, M. T. McDowell, Z. Bao, and Y. Cui, 'Stable Li-ion battery anodes by in-situ polymerization of conducting hydrogel to conformally coat silicon nanoparticles', Nat Commun, 4, 1943 (2013) 67. B. Koo, H. Kim, Y. Cho, K. T. Lee, N. S. Choi, and J. Cho, 'A highly cross-linked polymeric binder for high-performance silicon negative electrodes in lithium ion batteries', Angew Chem Int Ed Engl, 51, 8762-7 (2012) 68. M. G. Jeong, H. L. Du, M. Islam, J. K. Lee, Y. K. Sun, and H. G. Jung, 'Self-Rearrangement of Silicon Nanoparticles Embedded in Micro-Carbon Sphere Framework for High-Energy and Long-Life Lithium-Ion Batteries', Nano Lett, 17, 5600-5606 (2017) 69. N. Kim, S. Chae, J. Ma, M. Ko, and J. Cho, 'Fast-charging high-energy lithium-ion batteries via implantation of amorphous silicon nanolayer in edge-plane activated graphite anodes', Nature Communications, 8, 812 (2017) 70. P. Goethel and R. Yang, 'Mechanism of graphite hydrogenation catalyzed by nickel', Journal of Catalysis, 108, 356-363 (1987) 71. M. Ko, S. Chae, J. Ma, N. Kim, H.-W. Lee, Y. Cui, and J. Cho, 'Scalable synthesis of silicon-nanolayer-embedded graphite for high-energy lithium-ion batteries', Nature Energy, 1, 16113 (2016) 72. Q. Xu, J.-Y. Li, J.-K. Sun, Y.-X. Yin, L.-J. Wan, and Y.-G. Guo, 'Watermelon-Inspired Si/C Microspheres with Hierarchical Buffer Structures for Densely Compacted Lithium-Ion Battery Anodes', Advanced Energy Materials, 7, 1601481 (2017) 73. K. Feng, M. Li, W. Liu, A. G. Kashkooli, X. Xiao, M. Cai, and Z. Chen, 'Silicon-Based Anodes for Lithium-Ion Batteries: From Fundamentals to Practical Applications', Small, 14, (2018) 74. X. Su, Q. Wu, J. Li, X. Xiao, A. Lott, W. Lu, B. W. Sheldon, and J. Wu, 'Silicon-Based Nanomaterials for Lithium-Ion Batteries: A Review', Advanced Energy Materials, 4, 1300882 (2014) 75. T. Shen, X.-h. Xia, D. Xie, Z.-j. Yao, Y. Zhong, J.-y. Zhan, D.-h. Wang, J.-b. Wu, X.-l. Wang, and J.-p. Tu, 'Encapsulating silicon nanoparticles into mesoporous carbon forming pomegranate-structured microspheres as a high-performance anode for lithium ion batteries', Journal of Materials Chemistry A, 5, 11197-11203 (2017) 76. X. Li, P. Yan, X. Xiao, J. H. Woo, C. Wang, J. Liu, and J.-G. Zhang, 'Design of porous Si/C–graphite electrodes with long cycle stability and controlled swelling', Energy & Environmental Science, 10, 1427-1434 (2017) 77. N.-S. Choi, K. H. Yew, K. Y. Lee, M. Sung, H. Kim, and S.-S. Kim, 'Effect of fluoroethylene carbonate additive on interfacial properties of silicon thin-film electrode', Journal of Power Sources, 161, 1254-1259 (2006) 78. S. Dalavi, P. Guduru, and B. L. Lucht, 'Performance Enhancing Electrolyte Additives for Lithium Ion Batteries with Silicon Anodes', Journal of The Electrochemical Society, 159, A642 (2012) 79. T. Feng, Y. Xu, Z. Zhang, X. Du, X. Sun, L. Xiong, R. Rodriguez, and R. Holze, 'Low-Cost Al2O3 Coating Layer As a Preformed SEI on Natural Graphite Powder To Improve Coulombic Efficiency and High-Rate Cycling Stability of Lithium-Ion Batteries', ACS Appl Mater Interfaces, 8, 6512-9 (2016) 80. S. H. Park, H. J. Kim, J. Lee, Y. K. Jeong, J. W. Choi, and H. Lee, 'Mussel-Inspired Polydopamine Coating for Enhanced Thermal Stability and Rate Performance of Graphite Anodes in Li-Ion Batteries', ACS Appl Mater Interfaces, 8, 13973-81 (2016) 81. F. S. Li, Y. S. Wu, J. Chou, and N. L. Wu, 'A dimensionally stable and fast-discharging graphite-silicon composite Li-ion battery anode enabled by electrostatically self-assembled multifunctional polymer-blend coating', Chem Commun (Camb), 51, 8429-31 (2015) 82. W. Luo, X. Hu, Y. Sun, and Y. Huang, 'Electrospinning of carbon-coated MoO2 nanofibers with enhanced lithium-storage properties', Phys Chem Chem Phys, 13, 16735-40 (2011) 83. Z. Liu, S. Han, C. Xu, Y. Luo, N. Peng, C. Qin, M. Zhou, W. Wang, L. Chen, and S. Okada, 'In situ crosslinked PVA–PEI polymer binder for long-cycle silicon anodes in Li-ion batteries', RSC Advances, 6, 68371-68378 (2016) 84. H.-K. Park, B.-S. Kong, and E.-S. Oh, 'Effect of high adhesive polyvinyl alcohol binder on the anodes of lithium ion batteries', Electrochemistry Communications, 13, 1051-1053 (2011) 85. Y. Ma, L. B. Li, G. X. Gao, X. Y. Yang, and Y. You, 'Effect of montmorillonite on the ionic conductivity and electrochemical properties of a composite solid polymer electrolyte based on polyvinylidenedifluoride/polyvinyl alcohol matrix for lithium ion batteries', Electrochimica Acta, 187, 535-542 (2016) 86. G.-M. Liao, P.-C. Li, J.-S. Lin, W.-T. Ma, B.-C. Yu, H.-Y. Li, Y.-L. Liu, C.-C. Yang, C.-M. Shih, and S. J. Lue, 'Highly conductive quasi-coaxial electrospun quaternized polyvinyl alcohol nanofibers and composite as high-performance solid electrolytes', Journal of Power Sources, 304, 136-145 (2016) 87. H. S. Mansur, C. M. Sadahira, A. N. Souza, and A. A. P. Mansur, 'FTIR spectroscopy characterization of poly (vinyl alcohol) hydrogel with different hydrolysis degree and chemically crosslinked with glutaraldehyde', Materials Science and Engineering: C, 28, 539-548 (2008) 88. Q. Li, J. Chen, L. Fan, X. Kong, and Y. Lu, 'Progress in electrolytes for rechargeable Li-based batteries and beyond', Green Energy & Environment, 1, 18-42 (2016) 89. D. Aurbach, B. Markovsky, I. Weissman, E. Levi, and Y. Ein-Eli, 'On the correlation between surface chemistry and performance of graphite negative electrodes for Li ion batteries', Electrochimica Acta, 45, 67-86 (1999) 90. K. C. S. Figueiredo, T. L. M. Alves, and C. P. Borges, 'Poly(vinyl alcohol) films crosslinked by glutaraldehyde under mild conditions', Journal of Applied Polymer Science, 111, 3074-3080 (2009) 91. H. Gao, L. Xiao, I. Plumel, G. L. Xu, Y. Ren, X. Zuo, Y. Liu, C. Schulz, H. Wiggers, K. Amine, and Z. Chen, 'Parasitic Reactions in Nanosized Silicon Anodes for Lithium-Ion Batteries', Nano Lett, 17, 1512-1519 (2017) 92. J. Ni, Y. Huang, and L. Gao, 'A high-performance hard carbon for Li-ion batteries and supercapacitors application', Journal of Power Sources, 223, 306-311 (2013) 93. S.-S. Tzeng and Y.-G. Chr, 'Evolution of microstructure and properties of phenolic resin-based carbon/carbon composites during pyrolysis', Materials Chemistry and Physics, 73, 162-169 (2002) 94. M. Winter, J. O. Besenhard, M. E. Spahr, and P. Novák, 'Insertion Electrode Materials for Rechargeable Lithium Batteries', Advanced Materials, 10, 725-763 (1998) | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/79076 | - |
dc.description.abstract | 本研究以石墨以及矽為原料,運用一系列鋰離子電池上的知識以及粉粒體的混和、乾燥等技術,搭配充放電測試以及儀器分析驗證材料之各種電化學以及物理化學特性後,合成出具商業化潛力之鋰離子電池碳矽複合負極材料。
由於我們的材料以石墨為基底,一開始我們透過研究高分子的鍍膜對於石墨電化學表現分析上做分析,一方面研究高分子鍍膜之基本方法,我們主要以聚乙烯醇PVA(Polyvinyl Alcohol)為高分子的研究對象,PVA是一個具高黏性,且溶於水可在水中形成良好分散之多羫基親水高分子,另一方面也證實石墨等碳基材料在我們的高分子改質下,不會有劣化之傾向,甚至能夠改進電極表面SEI(Solid Electrolyte Interphase)所帶來之影響,經過PC(Propylene Carbonate)的共嵌入測試更發現,該高分子分布十分均勻,可以有效在第一圈鋰化過程中阻擋PC溶劑化之鋰離子共嵌入進石墨層間,防止形成極大的不可逆電容量以及石墨結構的破壞。 接著以高分子以及石墨研究上的基礎,以小規模實驗製備碳矽複合材料,一開始先在水中分散好奈米矽,再添加入石墨以及高分子的黏著劑,本實驗同樣以聚乙烯醇為黏著劑的基底,同時加入可與聚乙烯醇做交聯反映的交聯劑,在培養皿上進行高溫乾燥,並進一步使用烘箱將水分去除並加速交聯反應的完整性,交聯過後的高分子膜可以在水中維持一定時間的穩定性而不溶解,有利於我們之後進行第二階段改質,由於此高分子膜高溫碳化後殘碳量極低,因此我們在材料外在行鍍上一層殘碳量高的酚醛樹脂,可以確保煅燒後奈米矽仍能保留在石墨表面不脫落。 經過驗證證實了該方法的可行性後,我們進一步使用較大規模的噴霧乾燥製成合成我們的碳矽複合材料,分別以球化天然石墨,KS6片狀石墨以及兩種混和使用漿料來做噴霧乾燥的碳原料,球化石墨噴霧乾燥出來的粉體會判隨著矽小球的產生,實驗顯示對於電性表現有著不好的影響,我們透過密度差的沉降方法加以分離,並得到良好之改進,而KS6石墨噴霧乾燥後產生具孔洞的的二次粒子結構,雖然有著良好的電化學表現,但是振實密度以及電極密度過低,無法進一步實際應用,因此,我們最後一部分將兩種碳材合併使用,並探討兩者比例間不同所造成的影響,最後成功製備出具高振實密度之碳矽複合材料,接著引用前面高分子鍍膜技術以及實驗室其他成員研發之PVDF電極沉浸塗布技術試圖改進材料電性表現。 | zh_TW |
dc.description.abstract | Our research takes graphite and silicon nanoparticles as ingredients and utilizes a series of knowledge in lithium ion batteries and techniques in particular science such as mixing and drying to synthesize a silicon-carbon anode composite having the potential to commercialization. Our materials are well-studied by advanced instrument and battery tester to fully understand the physical and electrochemical property.
At the beginning, we start with the polymer surface modification and examine the effect to pristine natural graphite electrode. We choose polyvinyl alcohol (PVA) as the main character of polymer coating, which is an adhesive, water solution polymer that can form good dispersion in aqueous solution. We want to prove that the polymer coating layer did not bring any drawback and even benefit the SEI formation. Through the propylene carbonate test, we can conclude that the polymer layer is pretty uniform and able to block the co-intercalation of solvated lithium ions. In the following experiment, we firstly made a laboratory scale batch of silicon-graphite composite based on our previous results and experience. By adding well dispersed silicon particles and polymeric PVA binder together with graphite, we successfully acquired silicon-graphite composite having reasonable capacity and performance. Still, we also introduced the usage of another phenolic resin coating. The high carbon yield phenolic resin can help bind silicon particles on carbon surface. After proving the feasibility of this concept, we applied spray drying as our large scale production method. We used three kinds of carbon sources, that is, spherical natural graphite, KS6 flake graphite and both of them. For natural graphite case, silicon balls will form during the spray drying process and it’s detrimental to the electrode. We employed sedimentation method to separate the composite and silicon balls and got good improvement. For KS6 flake graphite case, porous secondary particles formed and exhibited good cycling performance and stability. However, the tap density and volumetric density for KS6 related electrode is way too low to put into real practice. For spray drying using both spherical natural graphite and KS6 flake graphite together, we can obtain composite that provides great support for silicon particles and ideal performance without further purification. Most importantly, the tap density and volumetric density can be maintained at an acceptable value. Followed by some post processing including polymer particle coating and PVDF electrode coating, the performance is expected to be improved. | en |
dc.description.provenance | Made available in DSpace on 2021-07-11T15:42:01Z (GMT). No. of bitstreams: 1 ntu-107-R05524067-1.pdf: 8929820 bytes, checksum: 1581fe36d172bcee15aebd704a3aa19d (MD5) Previous issue date: 2018 | en |
dc.description.tableofcontents | 誌謝 II
摘要 IV Abstract VI Table of Contents VIII List of Figures XII List of Tables XX Chapter1 Introduction 1 1-1 Background 1 1-2 Motivations and Objectives 2 Chapter2 Literature Review 3 2-1 Features of Rechargeable Lithium-ion Batteries 3 2-1-1 Basic Concepts of Lithium-ion Batteries 3 2-1-2 Brief History of Lithium Ion Battery 6 2-1-3 Introduction to Cathode Materials 7 2-1-4 Introduction to Anode Materials 10 2-1-5 Solid-Electrolyte Interphase 11 2-2 Introduction to Carbon Anode Materials 15 2-2-1 Graphite 15 2-2-2 Hard Carbon and Soft Carbon 17 2-3 Introduction to Silicon Anode Materials 20 2-4 Introduction to Carbon-Silicon Composite Anode Materials 26 Chapter3 Experimental 32 3-1 Materials and Chemicals 32 3-2 Synthesis of Materials 33 3-2-1 Polymer coating on natural graphite 33 3-2-2 Hot plate drying of silicon-carbon mixture solution35 3-2-3 Spray drying of silicon-carbon mixture 37 3-2-4 Sedimentation for NSPG-H batch 38 3-2-5 Additional carbon source coating 39 3-2-6 Polyvinylidene Fluoride (PVDF) Electrode Coating 41 3-3 Material Characterizations and Analysis 43 3-3-1 Electron Microscopy 43 3-3-2 X-ray Diffraction 44 3-3-3 Thermal Analysis 45 3-3-4 Surface Area Analyses 46 3-4 Electrochemical Characterizations 46 3-4-1 Preparation of Electrodes and Cells 46 3-4-2 Charge/Discharge Test 48 3-4-3 Cyclic Voltammetry 48 3-4-4 Electrochemical Impedance Spectroscopy 49 Chapter4 Surface Modification on Natural Graphite Using Polymer 50 4-1 Introduction 50 4-2 Crosslinking Test 51 4-3 Electrochemical test of polymer coated graphite 53 4-4 Propylene Carbonate (PC) Test 56 Chapter5 Spray Drying of Natural Graphite or KS6 Flake Graphite with Silicon 60 5-1 Hot plate drying test for graphite/silicon composite 60 5-1-1 Introduction 60 5-1-2 Characterization and Electrochemical Performance 61 5-2 Spray drying of silicon-natural graphite 63 5-2-1 Introduction 63 5-2-2 Material Characterization and Process Modification 64 5-2-3 Electrochemical Performance 70 5-2-4 Volume Expansion Study and Results Comparison 74 5-3 Spray drying of silicon-KS6 flake graphite 79 5-3-1 Introduction 79 5-3-2 Material Characterization 80 5-3-3 Electrochemical Performance 82 Chapter6 Spray Drying of Silicon with both NG and KS6 as Carbon Source 88 6-1 Spray Drying Process 88 6-1-1 Introduction 88 6-1-2 Material Characterization 89 6-1-3 Electrochemical Performance 93 6-1-4 Volume Expansion Study and Results Comparison 98 6-2 Post-Processing of NKSPG 101 6-2-1 Introduction 101 6-2-2 Polymer Coating 101 6-2-3 PVDF electrode coating 104 6-3 Comparison and Discussion of Spray Dried Batches 107 6-3-1 Fading Mechanism Study from Cycling Test 107 6-3-2 Rate Capability Test 110 6-3-3 Specific Surface Area Analysis 112 6-3-4 Electrochemical Impedance Spectroscopy 113 Chapter7 Conclusions and Outlook 116 7-1 Conclusions 116 7-2 Outlook 117 Reference 119 | |
dc.language.iso | en | |
dc.title | 透過噴霧造粒技術製備奈米矽分散於碳表面之鋰離子電池碳矽複合負極材料 | zh_TW |
dc.title | Engineering Carbon Surface with Well Dispersed Silicon Nanoparticles via Spray Drying for Lithium Ion Batteries | en |
dc.type | Thesis | |
dc.date.schoolyear | 106-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 吳玉祥(Yu-Shiang Wu),吳弘俊(Hung-Chun Wu),方家振(Chia-Chen Fang) | |
dc.subject.keyword | 鋰離子電池,碳矽負極,噴霧乾燥,高分子, | zh_TW |
dc.subject.keyword | Li-ion batteries,Silicon-carbon composite,Spray drying,Polymer, | en |
dc.relation.page | 131 | |
dc.identifier.doi | 10.6342/NTU201802948 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2018-08-13 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
dc.date.embargo-lift | 2023-08-23 | - |
顯示於系所單位: | 化學工程學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-107-R05524067-1.pdf 目前未授權公開取用 | 8.72 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。