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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱勝賢 | zh_TW |
| dc.contributor.advisor | Sheng-Hsien Chiu | en |
| dc.contributor.author | 薛方喆 | zh_TW |
| dc.contributor.author | Fang-Che Hsueh | en |
| dc.date.accessioned | 2021-07-10T21:58:20Z | - |
| dc.date.available | 2024-07-24 | - |
| dc.date.copyright | 2019-07-26 | - |
| dc.date.issued | 2019 | - |
| dc.date.submitted | 2002-01-01 | - |
| dc.identifier.citation | 1.Lehn, J. M. Supramolecular Chemistry: Concepts and Perspectives; VCH, 1995.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/77364 | - |
| dc.description.abstract | 透過適當的設計，二胺與二醛分子所形成的亞胺大環可”夾鎖”到具有適當辨識系統的啞鈴型分子上，將其亞胺鍵還原並把所得之二級胺甲基化以後，便可分離得到穩定的車輪烷分子。利用車輪烷上內鎖大環在立體上所提供的保護，可使啞鈴型分子上具高反應性官能基得到穩定性的提升。 | zh_TW |
| dc.description.abstract | Through proper design, an imino macrocycle generated from a diamine and a dialdehyde can “clip” onto a dumbbell-shaped guest to generate the corresponding imino rotaxane, which can then be transformed to stable rotaxane via reduction and methylation. We hope to use the interlocked macrocycles of the rotaxane to provide the necessary steric protection for increasing the stability of the highly reactive functionalities on the dumbbell-shaped units. | en |
| dc.description.provenance | Made available in DSpace on 2021-07-10T21:58:20Z (GMT). No. of bitstreams: 1 ntu-108-R06223103-1.pdf: 6877322 bytes, checksum: 2d5a19d1195ad10fbe8abd78b3c3f862 (MD5) Previous issue date: 2019 | en |
| dc.description.tableofcontents | 目錄
中文摘要 i Abstract ii 目錄 iii 圖目錄 iv 流程目錄 vi 第一章、導論 1 1.1 前言 1 1.2 車輪烷 2 1.3 車輪烷合成方法 2 1.3.1 機率統計法 (statistical approach) 2 1.3.2 模板導引合成法 (template-directed synthesis) 3 1.4 氮異環碳烯 (N-hetero cyclic carbene) 6 1.5 氮異環碳烯金屬錯合物的合成 9 1.6 氮異環碳烯金屬錯合物的催化應用 10 第二章、結果與討論 11 2.1 研究動機 11 2.2合成咪唑鹽啞鈴型分子 14 2.3 以夾鎖法合成咪唑鹽車輪烷 16 2.4合成氮異環碳烯車輪烷 20 2.5氮異環碳烯車輪烷的穩定性 25 2.6 結論 27 第三章、實驗部分 28 第四章、參考文獻 51 第五章、附錄 54 | - |
| dc.language.iso | zh_TW | - |
| dc.subject | 車輪烷 | zh_TW |
| dc.subject | 內鎖分子 | zh_TW |
| dc.subject | 氮異環碳烯 | zh_TW |
| dc.subject | NHC carbene | en |
| dc.subject | rotaxane | en |
| dc.subject | interlocked molecule | en |
| dc.title | 利用車輪烷結構穩定具高反應性的分子 | zh_TW |
| dc.title | Stabilizing Highly Reactive Chemical Species by Forming Their Interlocked Rotaxanes | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 107-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 陳平;徐秀福;賴建成 | zh_TW |
| dc.contributor.oralexamcommittee | Ping Cheng;Hsiu-Fu Hsu;Chien-Chen Lai | en |
| dc.subject.keyword | 內鎖分子,車輪烷,氮異環碳烯, | zh_TW |
| dc.subject.keyword | interlocked molecule,rotaxane,NHC carbene, | en |
| dc.relation.page | 54 | - |
| dc.identifier.doi | 10.6342/NTU201901667 | - |
| dc.rights.note | 未授權 | - |
| dc.date.accepted | 2019-07-19 | - |
| dc.contributor.author-college | 理學院 | - |
| dc.contributor.author-dept | 化學系 | - |
| 顯示於系所單位： | 化學系 | |
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