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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 劉懷勝(Hwai-Shen Liu) | |
| dc.contributor.author | Wei-Ya Huang | en |
| dc.contributor.author | 黃微雅 | zh_TW |
| dc.date.accessioned | 2021-07-10T21:45:28Z | - |
| dc.date.available | 2021-07-10T21:45:28Z | - |
| dc.date.copyright | 2020-07-08 | |
| dc.date.issued | 2020 | |
| dc.date.submitted | 2020-07-02 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/77070 | - |
| dc.description.abstract | 隨著工業迅速發展,對於環境負荷日趨沉重,溫室效應已是目前迫切須改善的問題,目前已有許多文獻利用單乙醇胺(MEA)、MDEA、PZ等醇胺類吸收劑進行化學吸收二氧化碳之研究,其特點為吸收容量大且反應速率快,但面臨的缺點大致有以下幾點: (1)廢氣煙道中的SO2、NO2及O2易引起醇胺降解;(2)吸收劑再生所需的能耗大;(3)高黏度;(4)所需的設備體積大。 本研究利用旋轉填充床的高質傳特性,以氫氧化鈉及氫氧化鈣溶液為吸收劑,進行化學吸收二氧化碳之實驗,另一方面,藉由連續添加氫氧化鈣於原體系,使其產生苛化作用(Caustification)以進行吸收劑再生與副產物碳酸鈣的分離程序,並且將化學再生後的吸收劑重複進行吸收程序,為一循環系統;文中將探討操作溫度、氣液流量、吸收劑之濃度等變數對於吸收百分比、表徵總括氣膜質傳係數(KGa)以及經長時間操作後對整體系統之效益影響。 實驗結果顯示,當氫氧化鈉水溶液中含有氫氧化鈣時,由於兩個鹼的協同作用能有效提升其與CO2反應之效益,使吸收效果提升,再者,藉由於原體系中之碳酸化作用(碳酸鈣沉澱),能夠呈現理想的程序特性,包含: (1)氫氧化鈉能於原體系中再生;(2)能使吸收劑維持高鹼性利於CO2捕獲;(3)簡易的副產物碳酸鈣與吸收劑分離程序。 除此之外,實驗經過數小時的連續操作後仍可維持其吸收效益,同時能夠容易地將副產物碳酸鈣收集並且再利用,此程序實現了對環境友善,低耗水以及能有效捕捉二氧化碳的概念。 | zh_TW |
| dc.description.abstract | Global warming has become a widespread concern in recent years, especially CO2 emission. Although several absorbents and processes have been proposed for carbon dioxide capture, the critics remains in the absorption efficiency and economical feasibility. Alkanolamines such as monothanolamine (MEA), methyldiethanolamine (MDEA), piperazine (PZ) have been the well accepted absorbents over the years for CO2 capture process. However, there are several drawbacks associated with these processes, including (1) amine degradation by SO2, NO2 and O2 in the flue gases requiring absorbent makeup, (2) high energy demand of absorbent regeneration, (3) high viscosity, and (4) large equipment size. In this study, a rotating packed bed (RPB) that could dramatically improve mass transfer efficiency and, leading to high reaction rate between absorbent and CO2 should be considered. Also, a very inexpensive absorbent which is sodium hydroxide together with calcium hydroxide in aqueous solution was proposed. On the other hand, a continuous CO2 capture process by calcium hydroxide addition was demonstrated, in which the absorbent, aqueous sodium hydroxide, was in-situ regenerated and almost completely reused. The gas flow rate, liquid flow rate, rotating speed and the concentration of the absorbent were taken into consideration as operating variables to observe the influence on absorption percentage, apparent overall volumertric mass transfer coefficient (KGa) and the efficiency of the process. According to experimental results, high absorption efficiency was noted due to a synergic effect from these two alkalines. Moreover, in-situ carbonation (precipitation of calcium carbonate) presented some very desired process traits including (1) easy/in-situ regeneration of sodium hydroxide, (2) stabilizing pH suitable for CO2 capture, (3) easy storage and separation of final product. Furthermore, the promising CO2 capture process could keep high absorption efficiency and pH value even after serveral hours operation. Meanwhile, calcium carbonate could be easily collected as a by-product of commercial value. Thus, this process achieved the concepts of eco-friendly, low water consumption, and zero waste together with effective carbon dioxide capture. | en |
| dc.description.provenance | Made available in DSpace on 2021-07-10T21:45:28Z (GMT). No. of bitstreams: 1 U0001-0207202015445400.pdf: 8433155 bytes, checksum: 1a91cb7ffc70511964d069a1f04a43eb (MD5) Previous issue date: 2020 | en |
| dc.description.tableofcontents | 摘要 I Abstract II 目錄 IV 圖目錄 VII 表目錄 XIV 第一章 緒論 1 第二章 文獻回顧 2 2-1 二氧化碳捕捉技術 2 2-1.1 物理吸收 2 2-1.2 化學吸收 3 2-1.3 物理吸附 4 2-1.4 薄膜分離 4 2-1.5 低溫冷凝 4 2-1.6 以氫氧化鈉及氫氧化鈣溶液為吸收劑捕捉二氧化碳之系統 5 2-2 旋轉填充床 10 2-2.1 旋轉填充床之構造與設計 12 2-2.2 旋轉填充床的壓降 25 2-2.3 旋轉填充床之液體流態、滯留量與滯留時間 34 2-2.4 旋轉填充床之液膜質傳係數與氣膜質傳係數 42 2-2.5 旋轉填充床中化學吸收二氧化碳 49 2-2.6 旋轉填充床之應用與發展 58 第三章 實驗設備與分析方法 69 3-1 實驗裝置 69 3-2 實驗藥品、儀器與實驗流程 71 3-2.1 實驗藥品 71 3-2.2 實驗儀器 71 3-2.3 實驗流程 72 3-3雙膜理論 (two-film theory) 75 3-4 實驗分析 80 3-4.1 吸收百分比A (absorption percentage) 80 3-4.2 表徵總括氣膜體積質傳係數(apparent overall volumetric mass transfer coefficient) 80 3-5 物性資料 83 3-5.1 二氧化碳在蔗糖溶液中的物理性質 83 第四章 實驗結果與討論 84 4-1 吸收百分比A (absorption percentage) 84 4-1.1 氣、液體進口溫度對於吸收百分比的影響 84 4-1.2 氣體流量及轉速對於吸收百分比的影響 86 4-1.3 液體流量及轉速對於吸收百分比的影響 93 4-1.4 氫氧化鈉與氫氧化鈣及蔗糖濃度對於吸收百分比的影響 99 4-1.5 與其他系統吸收百分比之比較 106 4-2 表徵總括氣膜體積質傳係數 (apparent overall volumetric mass transfer coefficient, KGa) 109 4-2.1 氣、液體進口溫度對於質傳係數的影響 109 4-2.2 氣體流量及轉速對於質傳係數的影響 111 4-2.3 液體流量對於質傳係數的影響 117 4-2.4 氫氧化鈉與氫氧化鈣及蔗糖濃度對於質傳係數的影響 123 4-2.5 與其他系統之質傳係數比較 132 4-3 循環系統-連續補充氫氧化鈣與分離碳酸鈣固體 135 4-3.1 在循環系統下-氣體流量對於吸收百分比的影響 140 4-3.2 在循環系統下-添補氫氧化鈣當量多寡對於吸收百分比的影響 143 4-3.3 在循環系統下-添補氫氧化鈣之頻率對於吸收百分比的影響 146 4-3.4 在循環系統下-不同吸收劑對於吸收百分比的影響 149 第五章 結論 152 參考文獻 155 符號說明 173 附錄A 實驗之吸收百分比、KGa數據表 178 附錄B 吸收不同濃度之二氧化碳對於吸收百分比及KGa的影響 192 附錄C 不同操作溫度下氫氧化鈉與二氧化碳之反應速率常數 193 附錄D 吸收及溶劑再生製程中所產生的碳酸鈣形貌及組成 195 附錄E 液相組成之分析 202 附錄F 二氧化碳濃度之校正檢量線 205 附錄G 實驗手法修正後之實驗數據 206 | |
| dc.language.iso | zh-TW | |
| dc.subject | 旋轉填充床 | zh_TW |
| dc.subject | 氫氧化鈣 | zh_TW |
| dc.subject | 二氧化碳捕捉 | zh_TW |
| dc.subject | 氣膜質傳係數 | zh_TW |
| dc.subject | 吸收百分比 | zh_TW |
| dc.subject | absoption percentage | en |
| dc.subject | sodium hydroxide | en |
| dc.subject | carbon dioxide capture | en |
| dc.subject | gas-side mass transfer coefficient | en |
| dc.subject | rotating packed bed | en |
| dc.subject | calcium hydroxide | en |
| dc.title | 旋轉填充床中氫氧化鈉/氫氧化鈣吸收二氧化碳之程序—原位吸收劑再生及循環 | zh_TW |
| dc.title | Carbon Dioxide Capture by Sodium Hydroxide/Calcium Hydroxide in a Rotating Packed Bed with in situ Regeneration and Recycling | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 108-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 林佳璋(Chia-Chang Lin),陳昱劭(Yu-Shao Chen),江佳穎(Chia-Ying Chiang) | |
| dc.subject.keyword | 旋轉填充床,吸收百分比,氣膜質傳係數,二氧化碳捕捉,氫氧化鈣, | zh_TW |
| dc.subject.keyword | rotating packed bed,absoption percentage,gas-side mass transfer coefficient,carbon dioxide capture,sodium hydroxide,calcium hydroxide, | en |
| dc.relation.page | 231 | |
| dc.identifier.doi | 10.6342/NTU202001269 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2020-07-03 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位: | 化學工程學系 | |
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