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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱勝賢(Sheng-Hsien Chiu) | |
| dc.contributor.author | Yu-Wei Lin | en |
| dc.contributor.author | 林玉薇 | zh_TW |
| dc.date.accessioned | 2021-07-10T21:41:19Z | - |
| dc.date.available | 2021-07-10T21:41:19Z | - |
| dc.date.copyright | 2020-08-10 | |
| dc.date.issued | 2020 | |
| dc.date.submitted | 2020-08-05 | |
| dc.identifier.citation | 1. (a) Lehn, J. M. Nobel Lecture, 1987. (b) Lehn, J. M. Science 1993, 260, 1762–1763. 2. Müller-Dethlefs, K.; Hobza, P. Chem. Rev. 2000, 100, 143–168. 3.(a) Ghadiri, M. R.; Granja, J. R.; Milligan, R. A.; McRee, D. E.; Khazanovich, N. Nature,1993, 366, 324–327; (b) Whitesides, G. M.; Simanek, E. E.;.Mathias, J. P.; Seto, C. T.; Chin, D.; Mammen, M.; Gordon, D. M. Acc. Chem. Res. 1995, 28, 37–44. 4. (a) Hunter, C. A.; Sanders, J. K. M. J. Am. Chem. Soc. 1990, 112, 5525–5534; (b)Hamilton, D. G.; Davies, J. E.; Prodi, L.; Sanders, J. K. M. Chem. Eur. J. 1998, 4, 608–620. 5. (a) Fujita, M.; Umemoto, K.; Yoshizawa, M.; Fujita, N.; Kusukawa, T.; Biradha, K. Chem. Commun. 2001, 509–518; (b) Kim, K. Chem. Soc. Rev. 2002, 31, 96–107. 6. (a) Neusser, H. J.; Krause, H. Chem. Rev. 1994, 94, 1829–1843; (b) Desfrancois, C.; Carles, S.; Scherann, J. P. Chem. Rev. 2000, 100, 3943–3962. 7. Naray-Szabo, G.; Ferenczy, G. G. Chem. Rev. 1995, 95, 829–847. 8. (a) Dougherty, D. A. Science 1996, 271, 163-168; (b) Ma, J. C.; Dougherty, D. A. Chem. Rev. 1997, 97, 1303–1324; (c) Gokel, G. W.; De Wall, S. L.; Meadows, E. S. Eur. J. Org. Chem. 2000, 17, 1967–1978. 9. (a) Pedersen, C. J. J. Am. Chem. Soc. 1967, 89, 2495–2496; (b) Vögtle, F.; WeberE. (Eds), Host Guest Complex Chemistry : macrocycles Springer: London, 1989; (c) Cram, D. J.; Cram, J. M. Container Molecules and Their Guests, Royal Society of Chemistry: London, 1994. 10. Atwood, J. L. Inclusion Pheomena and Molecular Recognition, Plenum Press: New York, 1988. 11. (a) Corbett, P. T.; Leclaire, J.; Vial, L; West, K. R.; Wietor J. L.; Sanders, J. K. M.; Otto, S. Chem. Rev. 2006, 106, 3652–3711; (b) Yeung, H. Y. A.; Pantos, G. D.; Sanders, J. K. M. PNAS 2009, 106, 10466–10470; (c) Belowicha, M. E.; Stoddart, J. F. Chem. Soc. Rev. 2012, 41, 2003–2024. 12. (a) Jena, N. K.; Murugan, N. A. J. Phys. Chem. C. 2013, 117, 25059–25068; (b) Ko, Y. H.; Hwang, I.; Kim, H.; Kim, Y.; Kim, K. Chem. Asian J. 2015, 10, 154–159; (c) Goujon, A.; Mariani, G.; Lang, T.; Moulin, E.; Rawiso, M.; Buhler, E.; Giuseppone, N. J. Am. Chem. Soc. 2017, 139, 4923–4928. 13. Liu Y.; Flood, A. H.; Bonvallet, P. A.; Vignon, S. A.; Northrop, B. H.; Tseng, H. R.; Jeppesen, J. O.; Huang, T. J.; Brough, B.; Baller, M.; Magonov, S.; Solares, S. D.; Goddard, W. A.; Ho, C. M.; Stoddart, J. F. J. Am. Chem. Soc. 2005, 127, 9745–9759. 14. Kudernac, T.; Ruangsupapichat, N.; Parschau, M.; Maciá, B.; Katsonis, N.; Harutyunyan,S. R.; Ernst,K. H.; Feringa, B. L. Nature 2011, 422, 759–765. 15. (a) Loeb, S. J. Chem. Soc. Rev. 2007, 36, 226–235; (b) Crowley, J. D.; Goldup, S. M.; Lee, A. L.; Leigh, D. A.; McBurney, R. T. Chem. Soc. Rev. 2009, 38, 1530–1541; (c)Chambron, J. C.; Sauvage, J. P. Sci. China Chem. 2011, 54, 2028–2031; (d) Caballero, A.; Zapata, F.; Beer, P. D. Coord. Chem. Rev. 2013, 257, 2434–2455; (e) Bruns, C. J.; Stoddart, J. F. Acc. Chem. Res. 2014, 47, 2186–2199; McGonigal, P. R. Supramolecular chemistry 2018, 30, 782–794. 16. (a) Beves, J. E.; Blight, B. A.; Campbell, C. J.; Leigh, D. A.; McBurney, R. T. Angew. Chem. Int. Ed. 2011, 50, 9260–9327; (b) Wu,Y. W.; Tung, S. T.; Lai, C. C.; Liu, Y. H.; Peng, S. M.; Chiu, S. H. Angew.Chem.Int. Ed. 2015, 54,11745–11749;(c) Au-Yeung, H. Y.; Yee, C. C.; Hung Ng, A. W.; Hu, K. Inorg. Chem. 2018, 57, 3475−3485. 17. (a) Pentecost, C. D.; Chichak, K. S.; Peters, A. J.; Cave, G. W. V.; Cantrill, S. J.; Stoddart, J. F. Angew. Chem. Int. Ed. 2007, 46, 218 –222; (b) Ponnuswamy, N.; Cougnon, F. B. L.; Pantos,̧ G. D.; Sanders, J. K. M. J. Am. Chem. Soc. 2014, 136, 8243−8251. 18. Leigh, D. A.; Pritchard, R. G.; Stephens, A. J. Nat. Chem, 2014, 6, 978–982. 19. Chichak,K. S.; Cantrill, S. J.; Pease,A. R.; Chiu, S.-H.; Cave, G. W. V.; Atwood, J. L.; Stoddart, J. F. Science 2004, 304, 1308–1312. 20. (a) Buchecker, C. O. D.; Sauvage, J.-P. Angew.Chem. Int. Ed.Engl. 1989, 28,189–192; Lukin, O.; Vögtle, F. Angew. Chem. Int. Ed. 2005, 44, 1456–1477. 21. (a) Wasserman, E. J. Am. Chem. Soc. 1960, 82, 4433-4434; (b) Wasserman, E. Sci. Am. 1962, 207, 94–102. 22. (a) Busch, D. H.; Stephenson, N. A. Coord. Chem. Rev. 1990, 100, 119–154; (b) Busch, D. H. J. Incl. Phen. 1992, 12, 389–395. 23. Beves, J. E.; Blight, B. A.; Campbell, C. J.; Leigh, D. A.; McBurney, R. T. Angew. Chem. Int. Ed. 2011, 50, 9260–9327. 24. Dietrich-Buchecker, C. O.; Sauvage, J. P.; Kintzinger, J. P. Tetrahedron Lett. 1983, 24, 5095–5098. 25. Buhleier, E.; Wehner, W.; Vögtle, F. Synthesis. 1978, 1978, 155–158. 26. Hawker, C. J.; Fréchet, J. M. J. J. Am. Chem. Soc. 1990, 112, 7638–7647. 27. (a) Kwan, C., Zhao, R., Van Hove, M.A.; Cai, Z. Leung, K. C. F. Nat. Commun. 2018, 9, 497–505; (b) Wang, X. Q.; Li, W. J.; Wang, W.; Wen, J.; Zhang, Y.; Tan, H. ; Yang, H. B. J. Am. Chem. Soc. 2019, 141, 13923−13930. 28. Wang, X. Q., Wang, W., Li, W. J.; Chen, L. J.; Yao, R.; Yin, G. Q.; Wang, Y. X.; Zhang, Y.; Huang, J.; Tan, H.; Yu, Y.; Li, X.; Xu, L.; Yang, H. B. Nat. Commun. 2018, 9, 3190–3200. 29. Tung, S.-T.; Lai, C.-C.; Liu, Y.-H.; Peng, S.-M.; Chiu, S.-H. Angew. Chem. Int. Ed. 2013, 52, 13269–13272. 30. Xu, H.-C. Department of Chemistry, College of Science National Taiwan University Master Thesis 2018. 31. Hsu, C.-J. Department of Chemistry, College of Science National Taiwan University Master Thesis 2017. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/76948 | - |
| dc.description.abstract | 本實驗室先前研究出以鈉離子為模板，使含有二乙二醇鏈的二胺分子及具備吡啶單元的大環分子正交排列，並分別與四醛或六醛的核心分子反應生成具有多個[2]交環烷分枝的異交環烷。本研究主要希望在具備吡啶單元的大環分子上導入縮醛保護基作為延伸端點，並利用上述辨識系統進一步有效率地合成樹枝狀交環烷。 | zh_TW |
| dc.description.abstract | Our laboratory had previously found that Na+ ions could template the threading of diethylene glycol-containing diamines into pyridine-containing macrocycles and resulted in the self-assembly synthesis of hetero-[2]catenane dimers and trimers when molecular cores with two and three isophthalaldehyde units were applied, respectively. By attaching acetal-protected isophthalaldehydes to the structure of pyridine-containing macrocycles, we plan to construct [2]catenane dendrimers by repeating the same self-assembly synthesis for few times. | en |
| dc.description.provenance | Made available in DSpace on 2021-07-10T21:41:19Z (GMT). No. of bitstreams: 1 U0001-0408202016543600.pdf: 4585750 bytes, checksum: 413d955b4f9815c682c1910032b2a1b7 (MD5) Previous issue date: 2020 | en |
| dc.description.tableofcontents | 謝辭 .................................................................................................................................. i 摘要 ................................................................................................................................. ii Abstract........................................................................................................................... iii 目錄 ................................................................................................................................ iv 圖目錄 .............................................................................................................................. v 流程目錄 ......................................................................................................................... vi 表目錄 ............................................................................................................................ vii 第一章、導論 .................................................................................................................. 1 1.1 前言.................................................................................................................... 1 1.2 內鎖分子簡介................................................................................................... 3 1.3 交環烷分子....................................................................................................... 4 1.4 樹枝狀分子....................................................................................................... 6 1.5 樹枝狀車輪烷................................................................................................... 8 第二章、結果與討論 .................................................................................................... 10 2.1 研究動機......................................................................................................... 10 2.2 交環烷前驅物之合成..................................................................................... 13 2.3 樹枝狀[2]交環烷之合成研究.......................................................................... 15 2.4 結論................................................................................................................. 19 第三章、實驗部分 ........................................................................................................ 20 第四章、參考資料 ........................................................................................................ 30 第五章、附錄 ................................................................................................................ 34 | |
| dc.language.iso | zh-TW | |
| dc.subject | 交環烷 | zh_TW |
| dc.subject | 動態自組裝 | zh_TW |
| dc.subject | 樹枝狀分子 | zh_TW |
| dc.subject | 鈉離子模板 | zh_TW |
| dc.subject | 發散合成法 | zh_TW |
| dc.subject | catenane | en |
| dc.subject | dendrimer | en |
| dc.subject | sodium ion template | en |
| dc.subject | self assembly | en |
| dc.subject | divergent | en |
| dc.title | 樹枝狀[2]交環烷的合成研究 | zh_TW |
| dc.title | The Synthesis of [2]Catenane Dendrimers | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 108-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳平(Ping Cheng),徐秀福(Hsiu-Fu Hsu),李文山(Wen-Shan Li),賴建成(Chien-Chen Lai) | |
| dc.subject.keyword | 交環烷,樹枝狀分子,鈉離子模板,動態自組裝,發散合成法, | zh_TW |
| dc.subject.keyword | catenane,dendrimer,sodium ion template,self assembly,divergent, | en |
| dc.relation.page | 52 | |
| dc.identifier.doi | 10.6342/NTU202002395 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2020-08-06 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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