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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 呂宗昕(Chung-Hsin Lu) | |
| dc.contributor.author | Kai-Hsiang Liang | en |
| dc.contributor.author | 梁凱翔 | zh_TW |
| dc.date.accessioned | 2021-07-10T21:39:14Z | - |
| dc.date.available | 2021-07-10T21:39:14Z | - |
| dc.date.copyright | 2020-09-24 | |
| dc.date.issued | 2020 | |
| dc.date.submitted | 2020-08-12 | |
| dc.identifier.citation | [1] J. M. Tarascon and M. Armand, Nature, 414 (2001) 359. [2] Y. C. Liu, Y. Z. Zeng, Y. F. Lu, C. C Shen, and J. C. Chung, Journal of Taiwan Energy, 2 (2) (2015) 169. [3] K. M. Abraham, Electrochim. Acta, 38 (9) (1993) 1233. [4] S. Choudhury, R. Mangal, A. Agrawal, and L. A. Archer, Nat. Commun., (6) (2015) 10101. [5] D. Aurbach, E. Zinigrad, Y. Cohen, and H. Teller, Solid State Ion., 148 (2002) 405. [6] F. Ding, W. Xu, X. Chen, J. Zhang, M. H. Engelhard, Y. Zhang, B. R. Johnson, J. V. Crum, T. A. Blake, X. Liu, and J. G. Zhang, J. Electrochem. Soc., 160 (2013) A1894. [7] S. K. Jeong, H. Y. Seo, D. H. Kim, H.-K. Han, J. G. Kim, Y. B. Lee, Y. Iriyama, T. Abe, and Z. Ogumi, Electrochem. Commun., 10 (2008) 635. [8] W. Xu, J. Wang, F. Ding, X. Chen, E. Nasybulin, Y. Zhang, and J. G. Zhang, Energy Environ. Sci., 7 (2014) 513. [9] K. Xu, Chem. Rev., 104 (2004) 4303. [10] W. Li, H. Yao, K. Yan, G. Zheng, Z. Liang, Y. M. Chiang, and Y. Cui, Nat. Commun., 6 (2015) 7436. [11] K. Mizushima, P. C. Jones, P. J. Wiseman, and J.B. Goodenough, Mater. Res. Bull., 15 (1980) 783. [12] R. R. Agarwal, Activity and diffusivity of lithium intercalated in graphite (1982). [13] K. Ozawa, Solid State Ion., 69 (1994) 212. [14] J. B. Goodenough and K. S. Park, J. Am. Chem. Soc., 135 (4) (2013) 1167. [15] L. X. Yuan, Z. H. Wang, W. X. Zhang, X. L. Hu, J. T. Chen, Y. H. Huang, and J. B. Goodenough, Energy Environ. Sci., 4 (2) (2011) 269. [16] J.B. Goodenough and Y. Kim, Chem. Mater., 22 (3) (2010) 587. [17] G. P. Gholam Abbas Nazri, Lithium Batteries: Science and Technology, Kluwer Academic Publishers, 2003. [18] J. Zhang, Q. Kong, Z. Liu, S. Pang, L. Yue, J. Yao, X. Wang, and G. Cui, Solid State Ion., 245 (2013) 49. [19] D. Li and H. Zhou, Mater. Today, 17 (9) (2014) 451. [20] M. Winter and R. J. Brodd, Chem. Rev., 104 (2004) 4245. [21] C. Liu, Z. G. Neale, and G. Cao, Mater. Today, 17 (9) (2014) 451. [22] K. Mizushima, P. C. Jones, P. J. Wiseman, and J. B. Goodenough, Mater. Res. Bull., 15 (6) (1980) 783. [23] B. G. A. Freitas, J. M. Siqueira Jr., L. M. da Costa, G. B. Ferreira, and J. A. L. C. Resende, J. Braz. Chem. Soc., 28 (11) (2017) 2254. [24] T. Ohzuku, A. Ueda, M. Nagayama, Y. Iwakoshi, and H. Komori, Electrochim. Acta, 38 (9) (1993) 1159. [25] R. Z. Yin, Y. S. Kim, S. J. Shin, I. Jung, J. S. Kim, and S. K. Jeong, J. Electrochem. Soc., 153 (3) (2012) A253. [26] 胡國榮, 杜柯, 彭忠東, “鋰離子電池正極材料-原理、性能與生產工藝”, 化學工程出版社 (2017). [27] A. K. Padhi, K. S. Nanjundaswamy, and J. B. Goodenough, J. Electrochem. Soc., 144 (4) (1997) 1188. [28] A. K. Padhi, K. S. Nanjundaswamy, C. Masquelier, S. Okada, and J. B. Goodenough, J. Electrochem. Soc., 144 (5) (1997) 1609. [29] A. Deb, U. Bergmann, E. J. Cairnsa, and S. P. Cramerd, J. Synchrotron Rad., 11 (2004) 497. [30] J. Molenda, W. Ojczyk, K. Świerczek, W. Zając, F.Krok, J. Dygas, and R. S. Liu, Solid State Ion., 177 (2006) 2617. [31] C. H. Lu, W. Y. Li, T. Subburaj, C. Y. Ou, and P. S. Kumar, Ceram. Int., 45 (2019) 12218. [32] C. H. Lu, T. Subburaj, H. T. Chiou, S. Som, C. Y. Ou, P. S. Kumar, and S. Balaji, Ionics, (2019). [33] H. Sun and K. Zhao, J. Phys. Chem. C, 121 (2017) 6002. [34] K. M. Shaju, G. V. S. Rao, and B. V. R. Chowdari, Electrochim. Acta, 48 (2002) 145. [35] J. Guo, L. F. Jiao, H. T. Yuan, H. X. Li, M. Zhang, and Y. M. Wang, Electrochim. Acta, 51 (2006) 3731. [36] C. H. Lu and B. J. Shen, J. Alloys Compd., 497 (2010) 159. [37] C. H. Lu and Y. K. Lin, J. Power Sources, 189 (2009) 40. [38] S. W. Woo, S. T. Myung, H. Bang, D. W. Kim, and Y. K. Sun, Electrochim. Acta, 54 (2009) 3851. [39] X. Xiong, Z. Wang, X. Yin, H. Guo, and X. Li, Mater. Lett., 110 (2013) 4. [40] I. Umegaki, S. Kawauchi, H. Sawada, H. Nozaki, Y. Higuchi, K. Miwa, Y. Kondo, M. Månsson, M. Telling, F. C. Coomer, S. P. Cottrell, T. Sasaki, T. Kobayashi, and J. Sugiyama, Phys. Chem. Chem. Phys., 19 (2017) 19058. [41] J. Luo, C. E. Wu, L. Y. Su, S. S. Huang, C. C Fang, Y. S. Wu, J. Chou, and N. L. Wu, J. Power Sources, 406 (2018) 63. [42] P. Yu, B. N. Popov, J. A. Ritter, and R. E. White, J. Electrochem. Soc., 146 (1999) 8. [43] M. Zhang, T. Zhang, Y. Ma, and Y. Chen, Energy Storage Mater., 4 (2016) 1. [44] B. Liang, Y. Liu, and Y. Xu, J. Power Sources, 267 (2014) 469. [45] J. W. Choi and D. Aurbach, Nat. Rev. Mater., 1 (2016) 16013. [46] N. Liu , W. Li, M. Pasta, and Y. Cui , Front. Physiol., 9 (2014) 323. [47] D. J. Lee, H. Lee, M. H. Ryou, G. B. Han, J. N. Lee, J. Song, J. Choi, K. Y. Cho, Y. M. Lee, and J. K. Park, ACS Appl. Mater. Interfaces, 5 (2013) 12005. [48] H. Wu, G. Chan, J. W. Choi, I. Ryu, Y. Yao, M. T. McDowell, S. W. Lee, A. Jackson, Y. Yang, L. Hu, and Y. Cui, Nat. Nanotechnol., 7 (2012) 310. [49] Y. Chen, S. Zeng, J. Qian, Y. Wang, Y. Cao, H. Yang, and X. Ai, ACS Appl. Mater. Interfaces, 6 (2014) 3508. [50] D. S. Jung, T. H. Hwang, S. B. Park, and J. W. Choi, Nano Lett., 13 (2013) 2092. [51] H. K. Liu, Z. P. Guo, J. Z. Wang, and K. Konstantinov, J. Mater. Chem., 20 (2010) 10055. [52] I. Kovalenko, B. Zdyrko, A. Magasinski, B. Hertzberg, Z. Milicev, R. Burtovyy, I. Luzinov, and G. Yushin, Science, 334 (2011) 75. [53] P. Li, G. Zhao, X. Zheng, X. Xu, C. Yao, W. Sun, and S. X. Dou, Energy Storage Mater., 15 (2018) 422. [54] T. Kennedy, M. Brandon, F. Laffir, and K. M. Ryan, J. Power Sources, 359 (2017) 601. [55] H. Nakai, T. Kubota, A. Kita, and A. Kawashima, J. Electrochem. Soc., 158 (7) (2011) 798. [56] D. Murphy, R. Cava, S. Zahurak, and A. Santoro, Solid State Ion., 413 (1983) 9. [57] S. Ganapathy and M. Wagemaker, ACS Nano, 6 (2012) 8702. [58] H. Duan, J. Li, H. Du, S. W. Chiang, C. Xu, W. Duan, and F. Kang, J. Phys. Chem. C, 119 (2015) 5238. [59] K. Ariyoshi, R. Yamato, and T. Ohzuku, Electrochim. Acta, 51 (2005) 1125. [60] I. Belharouak, G. M. Koenig, T. Tan, H. Yumoto, N. Ota, and K. Amine, J. Electrochem. Soc., 159 (2012) A1165. [61] Y. B. He, B. Li, M. Liu, C. Zhang, W. Lv, C. Yang, J. Li, H. Du, B. Zhang, Q. H. Yang, J. K. Kim, and F. Kang, Sci. Rep., 2 (2012) 913. [62] C. H. Chen, J. T. Vaughey, A. N. Jansen, D. W. Dees, A. J. Kahaian, T. Goacher, and M. M. Thackeray, J. Electrochem. Soc., 148 (2001) A102. [63] T. Yuan, X. Yu, R. Cai, Y. K. Zhou, and Z. P. Shao, J. Power Sources, 195 (2010) 4997. [64] B. Yan, M. Li, X. Li, Z. Bai, J. Yang, D. Xiong, and D. Li, J. Mater. Chem. A, 3 (2015) 11773. [65] N. Takami, K. Hoshina, and H. Inagaki, J. Electrochem. Soc., 158 (2011) A725. [66] C. A. Zhou, X. H. Xia, Y. D. Wang, Z. J. Yao, J. B. Wu, X. L. Wang, and J. P. Tu, Small : nano micro. 14 (2018) 1704339. [67] T. Yuan, Z. Tan, C. Ma, J. Yang, Z. F. Ma, and S. Zheng, Adv. Energy Mater., 7 (2017) 1601625. [68] X. Zhang, K. Turcheniuk, J. Benson, and B. Zusmann, MRS Advances, 3 (2018) 1249. [69] Y. Xiang, P. Zhao, Z. Jin, B. Chen, H. Ming, H. Zhang, W. Zhang, G. Cao, and X. Zhu, ACS Appl. Mater. Interfaces, 10 (2018) 42258. [70] M. Odziomek, F. Chaput, F. Lerouge, A. Rutkowska, K. Świerczek, D. Carlier, M. Sitarz, and S. Parola, J. Sol-Gel Sci. Technol., 89 (2019) 225. [71] W. Meng, Y. Xua, and B. Yan, J. Alloys Compd., 732 (2018) 784. [72] M. C. Kim, S. H. Moon, S. B. Han, D. H. Kwak, J. E. Lee, E. S. Kim, S. Choi, Y. K. Shin, and K. W. Park, J. Alloys Compd., 767 (2018) 73. [73] Z. Wang, L. Sun, W. Yang, J. Yang, K. Sun, D. Chen, and X. Liu, J. Electrochem. Soc., 166 (2019) A658. [74] L. Sun, Z. Liu, Z. Wang, W. Yang, J. Yang, K. Sun, D. Chen, Y. Liu, and X. Liu, Solid State Sci., 87 (2019) 110. [75] X. Bai, W. Li, A. Wei, Q. Chang, L. Zhang ,and Z. Liu, Solid State Sci., 324 (2018) 13. [76] P. Dhaiveegan, H. Peng, M. Michalska, Y. Xiao, J. Lin, and C. Hsieh, J Solid State Electrochem., 22 (2018) 1851. [77] K. Tang, X. Mu, P. A. V. Aken, Y. Yu, and J. Maier, Adv. Energy Mater. 3 (2013) 49. [78] X. Wu, J. Miao, W. Han, Y. S. Hu, D. Chen, J. S. Lee, J. Kim, and L. Chen, Electrochem. Commun., 25 (2012) 39. [79] C. Lin, G. Wang, S. Lin, J. Lia, and L. Lu, Chem. Commun., 51 (2015) 8970. [80] C. Yang, S. Deng, C. Lin, S. Lin, Y. Chen, J. Li, and Hui Wu, Nanoscale, 8 (2016) 18792. [81] K. J. Griffith, A. Senyshyn, and C. P. Grey, Inorg. Chem., 56 (7) (2017) 4002. [82] R. S. Roth, Prog. Solid State Chem., 13 (2) (1980) 159. [83] J. T. Han, Y. H. Huang, and J. B. Goodenough, Chem. Mater., 23 (2011) 2027. [84] R. S. Roth and L. W. Coughanour, J. Res. Natl. Bur. Stand., 55 (1955) 209. [85] K. J. Griffith, I. D. Seymour, M. A. Hope, M. M. Butala, L. K. Lamontagne, M. B. Preefer, C. P. Koçer, G. Henkelman, A. J. Morris, M. J. Cliffe, S. E. Dutton, and C. P. Grey, J. Am. Chem. Soc., 141 (2019) 16706. [86] A. D. Wadsley, Acta Crystallogr., 14 (1961) 660–664. [87] M. Gasperin, J. Solid State Chem., 53 (1984) 144. [88] S. K. E. Forghany and J. S. Anderson, J. Solid State Chem., 40 (1981) 136. [89] J. B. Goodenough and Y. Kim, J. Power Sources, 196 (2011) 6688. [90] L. Yan, X. Rui, G. Chen, W. Xu, G. Zou, and H. Luo, Nanoscale, 8 (2016) 8443. [91] S. Li, X. Cao, C. N. Schmidt, Q. Xu, E. Uchaker, Y. Pei, and G. Cao, J. Mater. Chem. A, 4 (2016) 4242. [92] L. Fei, Y. Xu, X. Wu, Y. Li, P. Xie, S. Deng, S. Smirnov, and H. Luo, Nanoscale, 5 (2013) 11102. [93] J. T. Han, D. Q. Liu, S. H. Song, Y. Kim, and J. B. Goodenough, Chem. Mater., 21 (2009) 4753. [94] M. Wei, K. Wei, M. Ichihara, and H. Zhou, Electrochem. Commun., 10 (2008) 980. [95] S. Lou, Y. Ma, X. Cheng, J. Gao, Y. Gao, P. Zuo, C. Du, and G. Yin, Chem. Commun., 51 (2015) 17293. [96] J. Gao, X. Cheng, S. Lou, Y. Ma, P. Zuo, C. Du, Y. Gao, and G. Yin, J. Alloys Compd., 728 (2017) 534. [97] B. Guo, X. Yu, X. G. Sun, M. Chi, Z. A. Qiao, J. Liu, Y. S. Hu, X. Q. Yang, J. B. Goodenough, and S. Dai, Energy Environ. Sci., 7 (2014) 2220. [98] H. X. Yu, H. Lan, L. Yan, S. S. Qian, X. Cheng, H. J. Zhu, N. B. Long, M. Shui, and J. Shu, Nano Energy, 38 (2017) 109. [99] L. Hu, L. Luo, L. Tang, C. Lin, R. Li, and Y. Chen, J. Mater. Chem. A, 6 (2018) 9799. [100] X. Wu, S. Lou, X. Cheng, C. Lin, J. Gao, Y. Ma, P. Zuo, C. Du, Y. Gao, and G. Yin, ACS Appl. Mater. Interfaces, 10 (2018) 27056. [101] X. Jiao, Q. Hao, X. Xia, D. Yao, Y. Ouyang, and W. Lei, J. Power Sources, 403 (2018) 66. [102] G. Zhu, Q. Li, and R. Che, Chem. Eur. J., 24 (2018) 12932. [103] H. Noh and W. Choi, J. Electrochem. Soc., 163 (6) (2016) A1042. [104] C. Lin, S. Yu, S. Wu, S. Lin, Z. Z. Zhu, J. Lia, and L. Lu, J. Mater. Chem. A, 3 (2015) 8627. [105] C. Yang, S. Yu, Y. Ma, C. F. Lin, Z. H. Xu, H. Zhao, S. Q. Wu, P. Zheng, Z. Z. Zhu, J. Li, and N. Wang, J. Power Sources, 360 (2017) 470. [106] X. Wen, C. Ma, C. Du, J. Liu, X. Zhang, D. Qu, and Z. Tang, Electrochim. Acta, 186 (2015) 58. [107] C. Jo, Y. Kim, J. Hwang, J. Shim, J. Chun, and J. Lee, Chem. Mater., 26 (2014) 3508. [108] G. Zhu, Q. Li, Y. Zhao, and R. Che, ACS Appl. Mater. Interfaces, 9 (2017) 41258. [109] Y. Huang, X. Li, J. Luo, K. Wang, Q. Zhang, Y. Qiu, S. Sun, S. Liu, J. Han, and Y. Huang, ACS Appl. Mater. Interfaces, 9 (2017) 8696. [110] H. Shim, E. Lim, S. Fleischmann, A. Quade, A. Tolosa, and V. Presser, Sustainable Energy Fuels, 3 (2019) 1776. [111] H. Song and Y. T. Kim, Chem. Commun., 51 (2015) 9849. [112] A.G. Ashish, P. Arunkumar, B. Babu, P. Manikandan, S. Sarang, and M. M. Shaijumon, Electrochim. Acta, 176 (2015) 285. [113] H. Li, L. Shen, G. Pang, S. Fang, H. Luo, K. Yang, and X. Zhang, Nanoscale, 7 (2015) 619. [114] H. Park, H. B. Wu ,T. Song, X. W. Lou, and U. Paik, Adv. Energy Mater., 5 (2015) 1401945. [115] C. H. Lu and H. C. Wang, J. Electrochem. Soc., 152 (6) (2005) C341. [116] F. Zhang, F. Yi, A. Gao, D. Shu, Z. Sun, J. Mao, X. Zhou, Z. Zhu, and Y. Sun, J. Alloys Compd., 819 (2020) 153018. [117] S. Chen, M. Yao, F. Wang, J. Wang, Y. Zhang, and Y. Wang, Ceram. Int., 45 (2019) 5594. [118] Y. Zhao, J. J. Zhu, J. M. Hong, N. Bian, and H. Y. Chen, Eur. J. Inorg. Chem., 20 (2004) 4072. [119] C. O. Kappe, D. Dallinger, and S. S. Murphree, Practical Microwave Synthesis for Organic Chemists, Wiley-VCH: Weinheim, 2009. [120] B. J Shen, J. S. Ma, H. C. Wu, and C. H. Lu, Mater. Lett., 62 (2008) 4075. [121] 金欽漢, 戴樹珊, 黃卡瑪, “微波化學”, 科學出版社 (1999). [122] R. Henríquez, C. Vásquez, E. Muñoz, P. Grez, F. Martín, J. R. Ramos-Barrado, and E. A. Dalchiele, Physica E Low Dimens. Syst. Nanostruct., 118 (2020) 113881. [123] N. Palaniyandy, M. A. Kebede, K. I. Ozoemena, and M. K. Mathe, Electrocatalysis, 10 (2019) 314. [124] N. Takami, K. Ise, Y. Harada, T. Iwasaki, T. Kishi, and K. Hoshina, J. Power Sources, 396 (2018) 429. [125] G. Wang, Z. Wen, L. Du, Y. E. Yang, S. Li, J. Sun, and S. Ji, J. Power Sources, 367 (2017) 106. [126] S. Lou, X. Cheng, Y. Zhao, A. Lushington, J. Gao, Q. Li, P. Zuo, B. Wang, Y. Gao, Y. Ma, C. Du, G. Yin, and X. Sun, Nano Energy, 34 (2017) 15. [127] R. Inada, R. Kumasaka, S. Inabe, T. Tojo, and Y. Sakurai, J. Electrochem. Soc., 166 (2019) A5157. [128] A. J. Bard and L. R. Faulkner, Electrochemical Methods: Fundamentals and Applications., 2001. [129] J. Luo, J. Peng, P. Zeng, W. Xiao, W. Li, Z. Wu, Y. Wang, C. Miao, G. Chen, H. Shu, and X. Wang, Electrochim. Acta, 341 (2020) 136072. [130] S. Lou, X. Cheng, J. Gao, Q. Li, L. Wang, Y. Cao, Y. Ma, P. Zuo, Y. Gao, C. Du, H. Huo, and G. Yin, Energy Storage Mater., 11 (2018) 57. [131] Y. Yuan, H. Yu, X. Cheng, R. Zheng, T. Liu, N. Peng, N. Long, M. Shui, and J. Shu, Chem. Eng. J., 374 (2019) 937. [132] T. Yamazaki, U. Mizutani, and Y. Iwama, Jpn. J. Appl. Phys., 22 (1983) 454. [133] R. Inada, T. Mori, R. Kumasaka, R. Ito, T. Tojo, and Y. Sakurai, Int J Appl Ceram Technol., 16 (2019) 264. [134] C. Yang, C. Lin, S, Lin, Y. Chen, and J. Li, J. Power Sources, 328 (2016) 336. [135] C. G. Fonstad and R. H. Rediker, J. Appl. Phys., 42 (1971) 2911. [136] J. A. Marley and R. C. Dockerty, Phys. Rev., 140 (1965) A304. [137] M. Nagasawa, S. Shionoya, and S. Makishima, J. Appl. Phys., 4 (1965) 195. [138] W. Wei, P. Du, D. Liu, H. Wang, and P. Liu, Mater. Lett., 196 (2017) 191. [139] F. Zoller, D. Bohm, T. Bein, and D. Fattakhova-Rohlfing, ChemSusChem, 12 (2019) 4140. [140] L. L. Hu, L. P. Yang, D. Zhang, X. S. Tao, C. Zeng, A. M. Cao, and L. J. Wan, Chem. Commun., 53 (2017) 11189. [141] H. Mou, W. Xiao, C. Miao, R. Li, and L. Yu, Front. Chem., 8 (2020) 141. [142] Z. Hu, X. Xu, X. Wang, K. Yu, and C. Liang, J. Alloys Compd., 835 (2020) 155446. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/76877 | - |
| dc.description.abstract | 本研究以微波輔助微乳膠法合成TiNb2O7單相粉體，並探討此製程對TiNb2O7之晶體結構、顯微形貌與電化學特性之影響。結果顯示相較於傳統固相反應法，微乳膠限制粒子生長且微波均勻加熱的特性使奈米粒子的TiNb2O7於800℃低溫下生成。MM-TNO的比表面積達較高顯示其具有較多活性點可供反應進行。恆電流間歇滴定技術與阻抗分析均顯示MM-TNO具有較低的內阻與較小的過電壓。比表面積的增加使1.4 V以下的鋰離子擴散速率提升，並減少MM-TNO的過電壓。過電壓的下降促進循環伏安測試中Nb4+/ Nb3+氧化還原對，使MM-TNO的0.1 C電容量與5 C電容量提升，且100圈後循環壽命良好。MM-TNO具有良好的贋電容性質，可藉由快速的物理吸附/脫附機制進行反應，使MM-TNO在高電流下有優秀的電容量表現。 本研究亦將無機氧化物包覆於TiNb2O7粉體上，探討包覆濃度對電化學特性的改變。樣品的繞射峰顯示為純相粉體，並無其他雜相繞射峰出現。粉體形貌為5-10 nm的粒子包覆於100-200 nm的TiNb2O7粒子外。當無機氧化物包覆濃度為適量時，可降低樣品的電荷轉移阻抗，導致0.1 C下電容量提升。當電壓區間下降至0.2-3 V時，電容量隨著無機氧化物包覆濃度增加而提升。由於超越TiNb2O7理論電容量，因此確認樣品中的無機氧化物在低電壓下發揮負極材料的特性。 | zh_TW |
| dc.description.abstract | The influence of the microwave-assisted microemulsion method process on the crystal structures, microscopic morphologies, and electrochemical properties of TiNb2O7 was discussed in the present study. The characteristics of microemulsion method were the restricted particle growth as compared with the traditional solid-state reaction method. The uniform heating effects provided by microwave reaction enabled TiNb2O7 nanoparticles to generate at a low temperature of 800°C. Both the galvanostatic intermittent titration technique and impedance analysis results show that microwave-assisted microemulsion synthesized TiNb2O7 (MM-TNO) had lower internal resistance and smaller overpotential. The promotion in the specific surface area increased the lithium ion diffusion coefficient and reduced the overpotential of MM-TNO. The decline of overpotential promoted the Nb4+/Nb3+ redox couple and increased the 0.1 C and 5 C capacity of MM-TNO. The cycle life of MM-TNO was also improved after 100 cycles. In the second part, the inorganic oxides were coated on the TiNb2O7 powders to improve the electrochemical properties. The particles with a diameter of 5-10 nm were coated on the 100-200 nm TiNb2O7 particles. The XRD diffraction peaks of the samples were confirmed as pure phase powders. Diffraction peaks related to impurity phases were absent in the XRD patterns. The charge transfer resistance of the samples can be reduced with an appropriate concentration of inorganic oxide coating, leading to promotion in 0.1 C capacity. The capacity elevated with increasing inorganic oxides concentration when the voltage range changed to 0.2-3 V. The phenomenon was attributed to the promotion of theoretical capacity. | en |
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| dc.description.tableofcontents | 致謝 I 摘要 II Abstract III 目錄 V 圖目錄 VII 表目錄 X Chapter 1 緒論 1 1.1 前言 1 1.2 鋰離子電池發展背景與電池工作原理 2 1.2.1 鋰離子電池發展背景 2 1.2.2 鋰離子電池工作原理 3 1.3 鋰離子電池正極材料 6 1.3.1 LiCoO2 6 1.3.2 LiFePO4 6 1.3.3 LiNi1-x-yCoxMnyO2 7 1.4 鋰離子電池負極材料 9 1.4.1 石墨 9 1.4.2 矽基材料 9 1.4.3 Li4Ti5O12 10 1.4.4 TiNb2O7 11 1.5 鋰離子電池負極材料合成方法 14 1.5.1 固相反應法 (Solid-state reaction method) 14 1.5.2 溶膠凝膠法 (Sol-gel method) 14 1.5.3 溶劑熱法 (Solvothermal method) 15 1.5.4 微乳膠法 (Microemulsion method) 15 1.5.5 微波合成法 16 1.6 研究動機 18 Chapter 2 實驗方法 52 2.1 TiNb2O7負極材料製備 52 2.1.1 固相反應法製備TiNb2O7粉體 52 2.1.2 微波輔助微乳膠法製備TiNb2O7粉體 52 2.2 二氧化錫包覆TiNb2O7複合材料製備 53 2.3 TiNb2O7特性分析 54 Chapter 3 微波輔助微乳膠法合成TiNb2O7粉體 59 3.1 TiNb2O7粉體晶體結構分析 59 3.2 TiNb2O7粉體顯微形貌分析 60 3.3 TiNb2O7粉體電化學特性分析 61 3.3.1 TiNb2O7負極電化學特性分析 61 3.3.2 TiNb2O7負極充放電特性分析 62 Chapter 4 二氧化錫包覆之TiNb2O7複合材料 78 4.1 二氧化錫包覆TiNb2O7粉體晶體結構分析 78 4.2 二氧化錫包覆TiNb2O7粉體顯微結構分析 78 4.3 二氧化錫包覆TiNb2O7粉體電化學特性分析 79 4.3.1 二氧化錫包覆TiNb2O7之阻抗分析 79 4.3.2 二氧化錫包覆TiNb2O7之充放電特性分析 79 4.3.3 二氧化錫包覆TiNb2O7於低電壓下之充放電行為 80 Chapter 5 結論 90 參考文獻 91 | |
| dc.language.iso | zh-TW | |
| dc.subject | 微波輔助微乳膠法 | zh_TW |
| dc.subject | 鋰離子電池 | zh_TW |
| dc.subject | 負極材料 | zh_TW |
| dc.subject | TiNb2O7 | zh_TW |
| dc.subject | 無機氧化物包覆 | zh_TW |
| dc.subject | microwave-assisted microemulsion method | en |
| dc.subject | lithium ion batteries | en |
| dc.subject | anode materials | en |
| dc.subject | TiNb2O7 | en |
| dc.subject | inorganic oxides coating | en |
| dc.title | 奈米鈮鈦氧化物鋰離子電池負極材料之製備與分析 | zh_TW |
| dc.title | Preparation and Characterization of Nano-sized Titanium Niobium Oxide as Anode Materials for Lithium Ion Batteries | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 108-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳啟東(Chii-Dong Chen),溫政彥(Cheng-Yen Wen) | |
| dc.subject.keyword | 鋰離子電池,負極材料,TiNb2O7,無機氧化物包覆,微波輔助微乳膠法, | zh_TW |
| dc.subject.keyword | lithium ion batteries,anode materials,TiNb2O7,inorganic oxides coating,microwave-assisted microemulsion method, | en |
| dc.relation.page | 100 | |
| dc.identifier.doi | 10.6342/NTU202003078 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2020-08-13 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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