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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱勝賢(Sheng-Hsien Chiu) | |
| dc.contributor.author | Shin-Han Tseng | en |
| dc.contributor.author | 曾信翰 | zh_TW |
| dc.date.accessioned | 2021-07-10T21:36:16Z | - |
| dc.date.available | 2021-07-10T21:36:16Z | - |
| dc.date.copyright | 2016-10-14 | |
| dc.date.issued | 2016 | |
| dc.date.submitted | 2016-07-21 | |
| dc.identifier.citation | [1] Steed, J. W.; Atwood J. L.; Supramolecular Chemistry, 2nd ed, Wiley, 2009.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/76753 | - |
| dc.description.abstract | 我們利用單元分子結構之剛硬性與金屬離子配位構形進行自組裝，專一性地合成出具功能性[c3]雛菊鏈( [c3]daisy chain )，並可藉由酸/鹼調控模擬生物肌肉”收縮 (contracted) ”和”舒張 (stretched)”的行為，有別於傳統分子肌肉線性運動，此為新穎二維分子肌肉之有機分子。 | zh_TW |
| dc.description.abstract | Daisy chain is a daisy garland where the stems are interlocked to form a chain and chaplet. A molecular daisy chain is an array of identical molecules that must be designed in a way that two complementary sites recognize each other by intermolecular rather than intramolecular. In other words, the monomer must be prevent from ‘biting its own tail’ and lead to form a cyclic or acyclic daisy chains.
Herein, we report an artificial molecular muscle based on using structure rigidity, coordination geometries and bond rotational barriers to selectively form a [c3]daisy chains that operate as molecular switches through the acid/base condition to mimic the behavior of bio-muscle. Differing from the traditional linear behavior, it’s a novel two-dimensional molecular muscle. | en |
| dc.description.provenance | Made available in DSpace on 2021-07-10T21:36:16Z (GMT). No. of bitstreams: 1 ntu-105-R03223137-1.pdf: 10684326 bytes, checksum: 42248d4825d8bd0dc6e01871dbc58ae2 (MD5) Previous issue date: 2016 | en |
| dc.description.tableofcontents | 目錄
摘要 i 英文摘要 ii 目錄 iii 圖目錄 iv 流程目錄 vi 第一章、 導論 1 1.1 前言 1 1.2雛菊鏈 2 第二章、 結果與討論 4 2.1 研究動機 4 2.2 [c3]雛菊鏈之單體分子設計 10 2.3合成雛菊鏈之單體分子流程 11 2.4單體分子自組裝之研究 13 2.5 [c3]雛菊鏈與[c4]雛菊鏈分子之合成 18 2.6酸鹼控制[c3]雛菊鍊分子肌肉的行為研究 19 2.7結論 20 第三章、 實驗部分 21 第四章、 參考文獻 28 第五章、 附錄 31 | |
| dc.language.iso | zh-TW | |
| dc.subject | 分子肌肉 | zh_TW |
| dc.subject | 配位化學 | zh_TW |
| dc.subject | 超分子化學 | zh_TW |
| dc.subject | 扭轉斥力 | zh_TW |
| dc.subject | 模板導引法 | zh_TW |
| dc.subject | 雛菊鏈 | zh_TW |
| dc.subject | coordination chemistry | en |
| dc.subject | daisy chain | en |
| dc.subject | molecular muscle | en |
| dc.subject | template-directed synthesis | en |
| dc.subject | supramolecular chemistry | en |
| dc.subject | torsional strain | en |
| dc.title | 二維分子肌肉之合成與研究 | zh_TW |
| dc.title | The Two-Dimensional Molecular Muscle
Based on a [c3]Daisy Chain | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 104-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳平(Richard P. Cheng),徐秀福(Hsiu-Fu Hsu),李文山(Wen-Shan Li),賴建成(Chien-Chen Lai) | |
| dc.subject.keyword | 超分子化學,配位化學,分子肌肉,雛菊鏈,模板導引法,扭轉斥力, | zh_TW |
| dc.subject.keyword | supramolecular chemistry,coordination chemistry,molecular muscle,daisy chain,template-directed synthesis,torsional strain, | en |
| dc.relation.page | 50 | |
| dc.identifier.doi | 10.6342/NTU201601160 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2016-07-21 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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|---|---|---|---|
| ntu-105-R03223137-1.pdf 未授權公開取用 | 10.43 MB | Adobe PDF |
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