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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 范致豪(Chihhao Fan) | |
| dc.contributor.author | Pei-Wen Zhang | en |
| dc.contributor.author | 張沛文 | zh_TW |
| dc.date.accessioned | 2021-06-17T07:10:00Z | - |
| dc.date.available | 2024-08-05 | |
| dc.date.copyright | 2019-08-05 | |
| dc.date.issued | 2019 | |
| dc.date.submitted | 2019-07-22 | |
| dc.identifier.citation | 王一雄、陳尊賢、李達源，1995。 土壤污染學，國立空中大學印行。
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/72909 | - |
| dc.description.abstract | 本研究之土壤採自桃園市大園區竹圍段崁下小段46地號，為目前被列管之控制場址。我國食用作物農地重金屬銅之管制標準為200 mg/kg，但此場址之土壤銅濃度高達2487 mg/kg，超出食用作物農地之管制標準10倍以上，非常嚴重。本研究目的為探討化學檸檬酸及檸檬萃取液淋洗高濃度銅污染土壤之效果與機制，並評估檸檬萃取液淋洗後之土壤添加檸檬製成之堆肥穩定化後其土壤品質是否符合各項地力標準。
本研究製備之材料有檸檬萃取液及其剩餘檸檬作成之堆肥，檸檬萃取液以重量1：1之蒸餾水與檸檬煮滾後，測得檸檬酸含量約9.9 g/L。以化學檸檬酸配製濃度10 g/L做比較，將淋洗液與土壤以重量固液比1：10淋洗土壤後，得其結果為檸檬萃取液淋洗效果較好，造成此結果之因素有(1)檸檬萃取液淋洗過程中其懸浮微粒被土壤攔截，導致土壤孔隙變小，因此停留時間較久與土壤充分反應及(2)檸檬萃取液裡含有其他可螯合重金屬之成分，例如：類黃銅化合物。 本研究最終得證經檸檬萃取液淋洗後之土壤改善了使用化學檸檬酸淋洗造成土壤酸化之問題及經天然檸檸汁淋洗後添加堆肥穩定化之土壤有效降低了銅之植物有效性。結果表明，原土之pH值為4.56酸性土壤，經檸檬萃取液淋洗後pH值不但沒有下降，甚至上升至5.70，且使用天然檸檬之淋洗後添加堆肥穩定化之土壤能使pH值上升至6.29恢復成弱酸性土壤；原土重金屬銅之植物有效性為677 mg/kg，經檸檬萃取液淋洗後添加堆肥穩定化之土壤能使重金屬銅之植物有效性下降至156 mg/kg。 綜合言之，本研究證明了使用檸檬萃取液不僅能有效去除銅及其他植物不需要之重金屬，且效果比化學檸檬酸好還能改善化學檸檬酸整治造成土壤酸化之問題，且添加堆肥後更能使重金屬穩定化，不易釋出被植物吸收。因此得證結合檸檬酸淋洗法與穩定化法是一有效之整治方法。 | zh_TW |
| dc.description.abstract | The soil of this study was taken from the No. 46 subsection of Kanjiao section, Zhuwei Vil., Dayuan Dist., Taoyuan City, which is a currently listed control site. The control standard of copper for edible crop agricultural land in Taiwan is 200 mg/kg, but the copper concentration of the soil in this study is as high as 2487 mg/kg, more than 10 times of the control standard. The purpose of this study is to investigate the effect of synthetic citric acid and the extract from the lemon extract on flushing heavy metal contaminated soil and to evaluate whether the soil quality meets every soil fertility standard after flushing citric acid and adding compost stabilization.
The material prepared in this study is the lemon extract and the compost made from lemon extract of the remaining lemon. After broling the mixture of 1：1 weight ratio distilled water, the citric acid content is about 9.9 g/L. Therefore, chemical citric acid of 10 g / L concentration was used as the control group. After flushing soil with the flushing solution of 1：10 solid-liquid ratio, the result showed that the lemon extract has better flushing effect, and the factors contribute to this result are ( І ) Longer natural juice retention time (Ⅱ) Other elements(like flavonols) which can chelate heavy metal contained in lemon extract. The result proved that the soil after flushing lemon extract improve the soil acidification by flushing chemical citric acid and whether the added with compost stabilization after flushing lemon extract the soil met every soil fertility standard. The result showed that the pH of the original soil was 4.56 and the soil added with compost after flush with lemon extract could raise the pH to 6.29 and effectively drop copper plant effectiveness; the plant effectiveness of the heavy metal copper in the original soil is 677 mg/kg, and the soil with compost stabilization after flushing lemon extract can decrease the plant effectiveness of heavy metal copper to 156 mg/kg. In summary, this study proved that using lemon extract not only effectively removed heavy metal with better effect than the chemical citric acid, but also improve the acidification of soil through chemical citric acid addition. Moreover, adding compost can passivate heavy metal not to be easily released. Therefore, the combination of citric acid flushing method and stabilization method is an effective remediation method. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T07:10:00Z (GMT). No. of bitstreams: 1 ntu-108-R06622011-1.pdf: 5015715 bytes, checksum: 600ef3cefc7a45c7cca2ff1cbe2ed28c (MD5) Previous issue date: 2019 | en |
| dc.description.tableofcontents | 口試委員會審定書 I
誌謝 II 摘要 III ABSTRACT IV 目錄 VI 圖目錄 XI 表目錄 XIII 第一章 前言 1 1.1 研究動機 1 1.2 研究目的 2 1.3研究架構 3 第二章 文獻回顧 5 2.1 農地污染 5 2.1.1 全國農地污染概況 5 2.1.2 桃園農地重金屬污染 7 2.2 重金屬污染 10 2.2.1 農地重金屬污染來源 10 2.2.2 重金屬在土壤中之鍵結型態與特性 10 2.2.3 重金屬在土壤中的傳輸與移動 13 2.2.4重金屬對生物及作物的風險與傷害 17 2.3 重金屬污染土壤復育技術 20 2.3.1重金屬污染土壤復育技術概述 21 2.3.2復育技術比較 24 2.4檸檬 27 2.4.1廢棄檸檬概況 27 2.4.2檸檬 27 2.4.3化學檸檬酸的製造 28 2.4.4檸檬酸去除銅的機制 28 2.5堆肥 29 2.5.1堆肥化之控制條件 29 2.5.2堆肥之穩定化作用 31 2.5.3堆肥之吸附模型 32 2.5.4國內外相關研究 33 第三章 實驗材料與方法 34 3.1實驗設備與藥品 34 3.1.1實驗設備 34 3.1.2化學藥品 35 3.1.3實驗器材 37 3.2 供試土壤之採集與土壤基本性質分析 38 3.2.1土壤採樣方法 38 3.2.2土壤風乾水分 38 3.2.3 pH值 39 3.2.4電導度 39 3.2.5質地 40 3.2.6有機質-重鉻酸鉀氧化法 41 3.2.7重金屬 42 3.3檸檬汁製作與分析 43 3.3.1檸檬汁製作方法 43 3.3.2檸檬萃取液pH測定 44 3.3.3檸檬酸含量測定 44 3.3.4檸檬類黃酮定性分析 45 3.3.5 總黃酮含量(TFC) 46 3.4堆肥製作與分析 47 3.4.1堆肥製作流程 47 3.4.2堆肥品質分析 49 3.4.3堆肥吸附實驗 51 3.5 土柱淋洗實驗 52 3.5.1淋洗方式 52 3.5.2固液比 54 3.5.3檸檬萃取液淋洗與分析 54 3.5.4時間稽延反應 57 3.6穩定化實驗與分析 58 3.6.1穩定化實驗 58 3.6.2重金屬型態序列萃取 58 3.7土壤品質 61 3.7.1植物有效性 61 3.7.2種子試驗 62 第四章 結果與討論 63 4.1 土壤基本性質 63 4.2材料分析與表徵 64 4.2.1檸檬萃取液 64 4.2.2檸檬堆肥 66 4.3檸檬萃取液淋洗(預實驗) 73 4.3.1淋洗方式 73 4.3.2固液比 74 4.4檸檬萃取液與化學檸檬酸淋洗之比較 75 4.4.1淋出液重金屬濃度之變化 75 4.4.2淋出液pH之變化 80 4.4.3 Itrax分析重金屬遷移 81 4.5堆肥吸附機制 85 4.5.1影響堆肥吸附之因素 85 4.5.2堆肥吸附機制 86 4.6檸檬酸淋洗法及結合檸檬酸淋洗法與穩定化法之比較 87 4.6.1淋洗後土壤型態之改變 87 4.6.2淋洗後穩定化土壤型態之改變 90 4.7 土壤品質 93 4.7.1基本性質 93 4.7.2重金屬 96 4.7.3發芽率 99 第五章 結論與建議 105 5.1 結論 105 5.2 建議 107 參考文獻 108 附錄一 品質管制 119 附錄二 實驗數據 120 附錄三 口試委員意見回覆 123 | |
| dc.language.iso | zh-TW | |
| dc.subject | 堆肥 | zh_TW |
| dc.subject | 淋洗 | zh_TW |
| dc.subject | 土壤品質 | zh_TW |
| dc.subject | 重金屬 | zh_TW |
| dc.subject | 檸檬 | zh_TW |
| dc.subject | 穩定化 | zh_TW |
| dc.subject | soil quality | en |
| dc.subject | heavy metals | en |
| dc.subject | flushing | en |
| dc.subject | stabilization | en |
| dc.subject | lemon | en |
| dc.subject | compost | en |
| dc.title | 應用廢棄檸檬於土壤淋洗法與穩定化法進行銅污染農地整治之研究 | zh_TW |
| dc.title | Remediation of copper-contaminated farmland using waste lemon integrated with soil flushing and stabilization | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 107-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.coadvisor | 張尊國(Tsun-Kuo Chang) | |
| dc.contributor.oralexamcommittee | 石?岡(Po-Kang Shih),江莉琦(Li-Chi Chiang) | |
| dc.subject.keyword | 重金屬,淋洗,穩定化,檸檬,堆肥,土壤品質, | zh_TW |
| dc.subject.keyword | heavy metals,flushing,stabilization,lemon,compost,soil quality, | en |
| dc.relation.page | 125 | |
| dc.identifier.doi | 10.6342/NTU201901018 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2019-07-22 | |
| dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
| dc.contributor.author-dept | 生物環境系統工程學研究所 | zh_TW |
| 顯示於系所單位： | 生物環境系統工程學系 | |
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