請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/72174
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 戴子安(Chi-An Dai) | |
dc.contributor.author | Zhao-Hua Zheng | en |
dc.contributor.author | 鄭昭華 | zh_TW |
dc.date.accessioned | 2021-06-17T06:27:09Z | - |
dc.date.available | 2028-12-31 | |
dc.date.copyright | 2018-08-23 | |
dc.date.issued | 2018 | |
dc.date.submitted | 2018-08-17 | |
dc.identifier.citation | 1. Zhang, P., M. Morris, and D. Doshi, Materials development for lowering rolling resistance of tires. Rubber Chemistry and Technology, 2016. 89(1): p. 79-116.
2. Mihara, S., Reactive processing of silica-reinforced tire rubber: new insight into the time-and temperature-dependence of silica rubber interaction. 2009. 3. Wang, M.-J., Effect of polymer-filler and filler-filler interactions on dynamic properties of filled vulcanizates. Rubber Chemistry and Technology, 1998. 71(3): p. 520-589. 4. Medalia, A.I., Heat generation in elastomer compounds: causes and effects. Rubber chemistry and technology, 1991. 64(3): p. 481-492. 5. Dannenberg, E., The effects of surface chemical interactions on the properties of filler-reinforced rubbers. Rubber Chemistry and Technology, 1975. 48(3): p. 410-444. 6. Peng, C.C., et al., “Smart” silica‐rubber nanocomposites in virtue of hydrogen bonding interaction. Polymers for advanced technologies, 2005. 16(11‐12): p. 770-782. 7. Meera, A., et al., Nonlinear viscoelastic behavior of silica-filled natural rubber nanocomposites. The Journal of Physical Chemistry C, 2009. 113(42): p. 17997-18002. 8. Stockelhuber, K., et al., Impact of filler surface modification on large scale mechanics of styrene butadiene/silica rubber composites. Macromolecules, 2011. 44(11): p. 4366-4381. 9. Yatsuyanagi, F., et al., Effects of surface chemistry of silica particles on the mechanical properties of silica filled styrene–butadiene rubber systems. Polymer journal, 2002. 34(5): p. 332. 10. Luginsland, H.-D., J. Frohlich, and A. Wehmeier, Influence of different silanes on the reinforcement of silica-filled rubber compounds. Rubber chemistry and technology, 2002. 75(4): p. 563-579. 11. Raghunath, R., D. Juhre, and M. Klüppel, A physically motivated model for filled elastomers including strain rate and amplitude dependency in finite viscoelasticity. International Journal of Plasticity, 2016. 78: p. 223-241. 12. Fu, S.-Y., et al., Effects of particle size, particle/matrix interface adhesion and particle loading on mechanical properties of particulate–polymer composites. Composites Part B: Engineering, 2008. 39(6): p. 933-961. 13. Yamaguchi, D., et al., Hierarchically Self-Organized Dissipative Structures of Filler Particles in Poly (styrene-ran-butadiene) Rubbers. Macromolecules, 2017. 50(19): p. 7739-7759. 14. Koga, T., et al., New insight into hierarchical structures of carbon black dispersed in polymer matrices: a combined small-angle scattering study. Macromolecules, 2008. 41(2): p. 453-464. 15. Baeza, G.P., et al., Effect of grafting on rheology and structure of a simplified industrial nanocomposite silica/SBR. Macromolecules, 2013. 46(16): p. 6621-6633. 16. Yuasa, T., T. Tominaga, and T. Sone, Analysis of Filler Aggregation in Compouns Using Small-angle X-ray Scattering: Effect of Functional Group Introduced into Polymer-ends of Solution-polymerized SBR. Nippon Gomu Kyokaishi, 2013(8): p. 249-255. 17. Baeza, G.P., et al., Multiscale filler structure in simplified industrial nanocomposite silica/SBR systems studied by SAXS and TEM. Macromolecules, 2012. 46(1): p. 317-329. 18. Mihara, S., et al., Ultra small-angle X-ray scattering study of flocculation in silica-filled rubber. Rubber chemistry and technology, 2014. 87(2): p. 348-359. 19. Teixeira, J., Small-angle scattering by fractal systems. Journal of Applied Crystallography, 1988. 21(6): p. 781-785. 20. Goerl, U., et al., Investigations into the silica/silane reaction system. Rubber chemistry and technology, 1997. 70(4): p. 608-623. 21. Ten Brinke, J., et al., Mechanistic aspects of the role of coupling agents in silica–rubber composites. Composites Science and Technology, 2003. 63(8): p. 1165-1174. 22. Blume, A., M. El-Roz, and F. Thibault-Starzyk, Infrared study of the silica/silane reaction. 11 Kautschuk Herbst Kolloqium, 2014. 23. Vilmin, F., et al., Reactivity of bis [3-(triethoxysilyl) propyl] tetrasulfide (TESPT) silane coupling agent over hydrated silica: Operando IR spectroscopy and chemometrics study. The Journal of Physical Chemistry C, 2014. 118(8): p. 4056-4071. 24. Valentin, J., et al., Characterization of the reactivity of a silica derived from acid activation of sepiolite with silane by 29Si and 13C solid-state NMR. Journal of colloid and interface science, 2006. 298(2): p. 794-804. 25. Li, Y., et al., Surface modification of silica by two-step method and properties of solution styrene butadiene rubber (SSBR) nanocomposites filled with modified silica. Composites Science and Technology, 2013. 88: p. 69-75. 26. Ha, S.-h., S.-w. Kim, and H.-k. Jeong, Investigation of Reaction Rate of Bis (triethoxysilylpropyl) tetrasulphide in Silica-Filled Compound Using Pyrolysis-Gas Chromatography/Mass Spectrometry. Asian Journal of Chemistry, 2013. 25(9). 27. Limper, A., Mixing of Rubber Compounds. 2012: p. 47-69. 28. S.N.Chakravarty, D. Editor’s Pick: Mixing And Mix Design – Advances In Mixing Technology (Part 2). [RUBBER MIXING] 2015 August 12; Available from: https://rubbermachineryworld.com/tag/rubber-mixing/. 29. Klockmann, O., Internal Mixer–a Reaction Vessel. Mixing of Rubber Compounds, 2012: p. 95-105. 30. Schuster, R., Dispersion and distribution of fillers, in Mixing of Rubber Compounds. 2012, Limper. p. 173-230. 31. Berriot, J., et al., Evidence for the shift of the glass transition near the particles in silica-filled elastomers. Macromolecules, 2002. 35(26): p. 9756-9762. 32. Sengloyluan, K., et al., Reinforcement efficiency of silica in dependence of different types of silane coupling agents in natural rubber-based tire compounds. KGK Kautschuk, Gummi, Kunststoffe, 2016. 69(5): p. 44-53. 33. Veiga, V.D.A., et al., Tire tread compounds with reduced rolling resistance and improved wet grip. Journal of Applied Polymer Science, 2017. 134(39): p. 45334. 34. Reuvekamp, L.A., et al., Effects of time and temperature on the reaction of TESPT silane coupling agent during mixing with silica filler and tire rubber. Rubber chemistry and technology, 2002. 75(2): p. 187-198. 35. Ten Brinke, J., P. Van Swaaij, and L. Reuvekamp, The influence of silane sulphur rank on processing of a silica-reinforced tyre tread compound. Kautschuk Gummi Kunststoffe, 2002. 55(5): p. 244-254. 36. Vleugels, N., et al. Influence of oligomeric resins on traction and rolling resistance of silica tire treads. in 184th Technical Meeting ACS Rubber Division. 2013. ACS Rubber Division. 37. Bassett, D., E. Boucher, and A. Zettlemoyer, Adsorption studies on hydrated and dehydrated silicas. Journal of colloid and interface science, 1968. 27(4): p. 649-658. 38. Nakayama, H., et al., Silane coupling agent bearing a photoremovable succinimidyl carbonate for patterning amines on glass and silicon surfaces with controlled surface densities. Colloids and Surfaces B: Biointerfaces, 2010. 1(76): p. 88-97. 39. Wasserman, S.R., Y.T. Tao, and G.M. Whitesides, Structure and reactivity of alkylsiloxane monolayers formed by reaction of alkyltrichlorosilanes on silicon substrates. Langmuir, 1989. 5(4): p. 1074-1087. 40. Schaefer, D., et al., Multilevel structure of reinforcing silica and carbon. Journal of Applied Crystallography, 2000. 33(3‐1): p. 587-591. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/72174 | - |
dc.description.abstract | 本研究主要探討改變胎面膠(tire tread compound)混煉時之混煉參數例如混煉時間、腔體體積分率和添加順序等因素,對於胎面膠之主要填充物二氧化矽顆粒分散效果的影響以及對輪胎性質之關連。其中輪胎性質主要探討為滾動阻力(rolling resistance),濕地抓地力(wet traction),輪胎剛性(stiffness)以及潘安效應(Payne effect)。再利用超小角度X光散射(USAXS)和穿透式電子顯微鏡(TEM)之量測,分析二氧化矽之分散性質與聚集之多層次之結構(hierarchical structure)。利用測量樣品的Payne effect看二氧化矽間的作用力,並瞭解其顆粒分散狀況。本研究利用兩種混煉機進行混煉實驗,一為小型混煉試驗機,另一為大型混煉機。根據在小型混煉機的參數調控,再應用到大型混煉機上,探討其是否有一致性。並且利用py-GCMS研究二氧化矽顆粒與矽烷偶聯劑(silane coupling agent)的反應程度,並尋找適合的矽烷偶聯劑用量。藉由以上控制混煉參數和測量矽烷偶聯劑未反應程度,希望找到濕地抓地力、滾動阻力和剛性皆有提升的方法。 | zh_TW |
dc.description.abstract | In this study, the brabender mixing parameters such as mixing time, fill factor, compound adding sequence, their effect on the silica dispersion in rubber formulations and the correlation between the process/structure/property of tire tread compounds were investigated. Typically, there are several important performance parameters for high efficiency green tires, namely low rolling resistance, high wet traction, high stiffness, low wear, and low Payne effect. By using ultra small angle x-ray scattering (USAXS) and transmission electron microscope (TEM) techniques, the dispersion property and the hierarchical structure of silica nanoparticles (from silica primary particles to dimer/trimer/tetramer aggregates, to clusters consisting of assembled aggregates, to the mass fractal of the clusters) were studied. Typically, the Payne effect as measured by dynamic mechanical analysis (DMA) technique can be used to represent the extent of filler-filler interaction in tread compounds. In this study, I used two different brabender mixers; one is a lab-scale brabender and the other is a production-scale banbury mixer located at Cheng Shin Rubber Ind. Co. in Taiwan, the sponsor of the project. py-GCMS technique was also used to study the degree of unreacted TESPT, a silane coupling agent, added in the tire tread compound to improve the silica dispersibility. In addition, an optimum amount of TESPT can be obtained to improve RR, WT, as well as the stiffness of the tread compounds. | en |
dc.description.provenance | Made available in DSpace on 2021-06-17T06:27:09Z (GMT). No. of bitstreams: 1 ntu-107-R05524029-1.pdf: 6247885 bytes, checksum: a9f261ce986755b571fe3f8d40fc077d (MD5) Previous issue date: 2018 | en |
dc.description.tableofcontents | 口試委員會審定書 #
誌謝 i 摘要 ii Abstract iii 目錄 iv Chapter 1 緒論 1 Chapter 2 文獻回顧 3 Chapter 3 實驗方法與測量方式 13 Chapter 4 TESPT的反應性和性質分析 18 Chapter 5 小型混煉機:改變混煉參數提升胎面膠性能 42 5.1 混煉時間的變化 42 5.2 腔體填充分率 (fill factor) 54 5.3 矽烷偶聯劑和混煉溫度的影響 61 Chapter 6 正新大型混煉機實驗 73 6.1 改變腔體填充分率 (fill factor) 73 6.2 改變混煉添加順序 78 6.3 改變混煉時間 84 6.4 添加增黏劑 (tackifier) 96 Chapter 7 總結 109 附錄 111 參考文獻 119 | |
dc.language.iso | zh-TW | |
dc.title | 混煉製程對於二氧化矽填充橡膠系統的動態機械性質影響:混煉參數與矽烷偶聯劑反應性分析 | zh_TW |
dc.title | Effect of mixing process on the dynamic mechanical properties of silica-filled rubber system: mixing parameters and the reactivity of silane coupling agent | en |
dc.type | Thesis | |
dc.date.schoolyear | 106-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 謝之真(Chih-Chen Hsieh),邱文英(Wen-Yen Chiu),程耀毅(YAO-YI CHENG),曹正熙(Cheng-Si Tsao) | |
dc.subject.keyword | 混煉參數,TESPT反應性,胎面性質,小角度X光散射,穿透式電子顯微鏡, | zh_TW |
dc.subject.keyword | tire tread,mixing parameters,reactivity of TESPT,silica filled rubber,SAXS,TEM, | en |
dc.relation.page | 122 | |
dc.identifier.doi | 10.6342/NTU201803798 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2018-08-17 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-107-1.pdf 目前未授權公開取用 | 6.1 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。