請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/7212完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 周必泰(Pi-Tai Chou) | |
| dc.contributor.author | Yu-Kai Hu | en |
| dc.contributor.author | 胡育愷 | zh_TW |
| dc.date.accessioned | 2021-05-19T17:40:16Z | - |
| dc.date.available | 2024-08-20 | |
| dc.date.available | 2021-05-19T17:40:16Z | - |
| dc.date.copyright | 2019-08-20 | |
| dc.date.issued | 2019 | |
| dc.date.submitted | 2019-08-12 | |
| dc.identifier.citation | 1. Kojima, A.; Teshima, K.; Shirai, Y.; Miyasaka, T., Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells. Journal of the American Chemical Society 2009, 6050-6051.
2. Bi, D.; Yi, C.; Luo, J.; Décoppet, J.-D.; Zhang, F.; Zakeeruddin, Shaik M.; Li, X.; Hagfeldt, A.; Grätzel, M., Polymer-templated nucleation and crystal growth of perovskite films for solar cells with efficiency greater than 21%. Nature Energy 2016, 16142. 3. Zhao, D.; Wang, C.; Song, Z.; Yu, Y.; Chen, C.; Zhao, X.; Zhu, K.; Yan, Y., Four-Terminal All-Perovskite Tandem Solar Cells Achieving Power Conversion Efficiencies Exceeding 23%. ACS Energy Letters 2018, 305-306. 4. Era, M.; Morimoto, S.; Tsutsui, T.; Saito, S., Organic‐inorganic heterostructure electroluminescent device using a layered perovskite semiconductor (C6H5C2H4NH3)2PbI4. Applied Physics Letters 1994, 676-678. 5. Tan, Z.-K.; Moghaddam, R. S.; Lai, M. L.; Docampo, P.; Higler, R.; Deschler, F.; Price, M.; Sadhanala, A.; Pazos, L. M.; Credgington, D.; Hanusch, F.; Bein, T.; Snaith, H. J.; Friend, R. H., Bright light-emitting diodes based on organometal halide perovskite. Nature Nanotechnology 2014, 687. 6. Cho, H.; Jeong, S.-H.; Park, M.-H.; Kim, Y.-H.; Wolf, C.; Lee, C.-L.; Heo, J. H.; Sadhanala, A.; Myoung, N.; Yoo, S.; Im, S. H.; Friend, R. H.; Lee, T.-W., Overcoming the electroluminescence efficiency limitations of perovskite light-emitting diodes. Science 2015, 1222. 7. Wang, N.; Cheng, L.; Ge, R.; Zhang, S.; Miao, Y.; Zou, W.; Yi, C.; Sun, Y.; Cao, Y.; Yang, R.; Wei, Y.; Guo, Q.; Ke, Y.; Yu, M.; Jin, Y.; Liu, Y.; Ding, Q.; Di, D.; Yang, L.; Xing, G.; Tian, H.; Jin, C.; Gao, F.; Friend, R. H.; Wang, J.; Huang, W., Perovskite light-emitting diodes based on solution-processed self-organized multiple quantum wells. Nature Photonics 2016, 699. 8. Dou, L.; Yang, Y.; You, J.; Hong, Z.; Chang, W.-H.; Li, G.; Yang, Y., Solution-processed hybrid perovskite photodetectors with high detectivity. Nature Communications 2014, 5404. 9. Wei, H.; Fang, Y.; Mulligan, P.; Chuirazzi, W.; Fang, H.-H.; Wang, C.; Ecker, B. R.; Gao, Y.; Loi, M. A.; Cao, L.; Huang, J., Sensitive X-ray detectors made of methylammonium lead tribromide perovskite single crystals. Nature Photonics 2016, 333. 10. Yakunin, S.; Sytnyk, M.; Kriegner, D.; Shrestha, S.; Richter, M.; Matt, G. J.; Azimi, H.; Brabec, C. J.; Stangl, J.; Kovalenko, M. V.; Heiss, W., Detection of X-ray photons by solution-processed lead halide perovskites. Nature Photonics 2015, 444. 11. Zhu, H.; Fu, Y.; Meng, F.; Wu, X.; Gong, Z.; Ding, Q.; Gustafsson, M. V.; Trinh, M. T.; Jin, S.; Zhu, X. Y., Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors. Nature Materials 2015, 636. 12. Lufaso, M. W.; Woodward, P. M., Jahn-Teller distortions, cation ordering and octahedral tilting in perovskites. Acta Crystallographica Section B 2004, 10-20. 13. Glazer, A., The classification of tilted octahedra in perovskites. Acta Crystallographica Section B 1972, 3384-3392. 14. Stoumpos, C. C.; Malliakas, C. D.; Kanatzidis, M. G., Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties. Inorganic Chemistry 2013, 9019-9038. 15. Krishnamoorthy, T.; Ding, H.; Yan, C.; Leong, W. L.; Baikie, T.; Zhang, Z.; Sherburne, M.; Li, S.; Asta, M.; Mathews, N.; Mhaisalkar, S. G., Lead-free germanium iodide perovskite materials for photovoltaic applications. Journal of Materials Chemistry A 2015, 23829-23832. 16. Yangui, A.; Pillet, S.; Bendeif, E.-E.; Lusson, A.; Triki, S.; Abid, Y.; Boukheddaden, K., Broadband Emission in a New Two-Dimensional Cd-Based Hybrid Perovskite. ACS Photonics 2018, 1599-1611. 17. Needham, G.; Willett, R.; Franzen, H. J. T. J. o. P. C., Phase transitions in crystalline models of bilayers. 1. Differential scanning calorimetric and x-ray studies of (C12H25NH3) 2MCl4 and (NH3C14H29NH3) 2MCl4 salts (M= Mn2+, Cd2+, Cu2+). The Jornal of Physical 1984, 674-680. 18. Shi, D.; Adinolfi, V.; Comin, R.; Yuan, M.; Alarousu, E.; Buin, A.; Chen, Y.; Hoogland, S.; Rothenberger, A.; Katsiev, K.; Losovyj, Y.; Zhang, X.; Dowben, P. A.; Mohammed, O. F.; Sargent, E. H.; Bakr, O. M., Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals. Science 2015, 519. 19. Saidaminov, M. I.; Abdelhady, A. L.; Murali, B.; Alarousu, E.; Burlakov, V. M.; Peng, W.; Dursun, I.; Wang, L.; He, Y.; Maculan, G.; Goriely, A.; Wu, T.; Mohammed, O. F.; Bakr, O. M., High-quality bulk hybrid perovskite single crystals within minutes by inverse temperature crystallization. Nature Communications 2015, 7586. 20. Han, Q.; Bae, S.-H.; Sun, P.; Hsieh, Y.-T.; Yang, Y.; Rim, Y. S.; Zhao, H.; Chen, Q.; Shi, W.; Li, G.; Yang, Y., Single Crystal Formamidinium Lead Iodide (FAPbI3): Insight into the Structural, Optical, and Electrical Properties. Advanced Materials 2016, 2253-2258. 21. Kieslich, G.; Sun, S.; Cheetham, A. K., Solid-state principles applied to organic–inorganic perovskites: new tricks for an old dog. Chemical Science 2014, 4712-4715. 22. Mitzi, D. B., Templating and structural engineering in organic–inorganic perovskites. Journal of the Chemical Society, Dalton Transactions 2001, 1-12. 23. Saparov, B.; Mitzi, D. B., Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design. Chemical Reviews 2016, 4558-4596. 24. Dohner, E. R.; Hoke, E. T.; Karunadasa, H. I., Self-Assembly of Broadband White-Light Emitters. Journal of the American Chemical Society 2014, 1718-1721. 25. Vargas, B.; Ramos, E.; Pérez-Gutiérrez, E.; Alonso, J. C.; Solis-Ibarra, D., A Direct Bandgap Copper–Antimony Halide Perovskite. Journal of the American Chemical Society 2017, 9116-9119. 26. Nazarenko, O.; Kotyrba, M. R.; Yakunin, S.; Aebli, M.; Rainò, G.; Benin, B. M.; Wörle, M.; Kovalenko, M. V., Guanidinium-Formamidinium Lead Iodide: A Layered Perovskite-Related Compound with Red Luminescence at Room Temperature. Journal of the American Chemical Society 2018, 3850-3853. 27. Mao, L.; Wu, Y.; Stoumpos, C. C.; Wasielewski, M. R.; Kanatzidis, M. G., White-Light Emission and Structural Distortion in New Corrugated Two-Dimensional Lead Bromide Perovskites. Journal of the American Chemical Society 2017, 5210-5215. 28. Guan, J.; Tang, Z.; M. Guloy, A., α-[NH3(CH2)5NH3]SnI4: a new layered perovskite structure. Chemical Communications 1999, 1833-1834. 29. Dou, L.; Wong, A. B.; Yu, Y.; Lai, M.; Kornienko, N.; Eaton, S. W.; Fu, A.; Bischak, C. G.; Ma, J.; Ding, T.; Ginsberg, N. S.; Wang, L.-W.; Alivisatos, A. P.; Yang, P., Atomically thin two-dimensional organic-inorganic hybrid perovskites. Science 2015, 1518. 30. Mitzi, D. B.; Dimitrakopoulos, C. D.; Kosbar, L. L., Structurally Tailored Organic−Inorganic Perovskites: Optical Properties and Solution-Processed Channel Materials for Thin-Film Transistors. Chemistry of Materials 2001, 3728-3740. 31. Knutson, J. L.; Martin, J. D.; Mitzi, D. B., Tuning the Band Gap in Hybrid Tin Iodide Perovskite Semiconductors Using Structural Templating. Inorganic Chemistry 2005, 4699-4705. 32. Lermer, C.; Birkhold, S. T.; Moudrakovski, I. L.; Mayer, P.; Schoop, L. M.; Schmidt-Mende, L.; Lotsch, B. V., Toward Fluorinated Spacers for MAPI-Derived Hybrid Perovskites: Synthesis, Characterization, and Phase Transitions of (FC2H4NH3)2PbCl4. Chemistry of Materials 2016, 6560-6566. 33. Thomson, R. I.; Rawson, J. M.; Goeta, A.; Probert, M. R.; Coome, J. A.; Hoang, T. K. A.; Carpenter, M. A., Elastic coupling and anelastic relaxation associated with multiple phase transitions in para-chloroanilinium tetrachlorocuprate, [p-ClC6H4NH3]2CuCl4. Materials Chemistry and Physics 2013, 34-46. 34. Pan, X.-w.; Wu, G.; Wang, M.; Chen, H.-z., Partially reversible photochromic behavior of organic-inorganic perovskites with copper(II) chloride. Journal of Zhejiang University-SCIENCE A 2009, 710-715. 35. Mostafa, M. F.; Abdel-Kader, M. M.; Arafat, S. S.; Kandeel, E. M., Thermochromic phase transitions in two aromatic tetrachlorocuprates. Physica Scripta 1991, 627-629. 36. Xu, Z.; Mitzi, D. B.; Dimitrakopoulos, C. D.; Maxcy, K. R., Semiconducting Perovskites (2-XC6H4C2H4NH3)2SnI4 (X = F, Cl, Br): Steric Interaction between the Organic and Inorganic Layers. Inorganic Chemistry 2003, 2031-2039. 37. Xu, Z.; Mitzi, D. B.; Medeiros, D. R., [(CH3)3NCH2CH2NH3]SnI4: A Layered Perovskite with Quaternary/Primary Ammonium Dications and Short Interlayer Iodine−Iodine Contacts. Inorganic Chemistry 2003, 1400-1402. 38. Du, K.-z.; Tu, Q.; Zhang, X.; Han, Q.; Liu, J.; Zauscher, S.; Mitzi, D. B., Two-Dimensional Lead(II) Halide-Based Hybrid Perovskites Templated by Acene Alkylamines: Crystal Structures, Optical Properties, and Piezoelectricity. Inorganic Chemistry 2017, 9291-9302. 39. Calabrese, J.; Jones, N. L.; Harlow, R. L.; Herron, N.; Thorn, D. L.; Wang, Y., Preparation and characterization of layered lead halide compounds. Journal of the American Chemical Society 1991, 2328-2330. 40. Mitzi, D. B.; Wang, S.; Feild, C. A.; Chess, C. A.; Guloy, A. M., Conducting Layered Organic-inorganic Halides Containing <110>-Oriented Perovskite Sheets. Science 1995, 1473. 41. Stoumpos, C. C.; Soe, C. M. M.; Tsai, H.; Nie, W.; Blancon, J.-C.; Cao, D. H.; Liu, F.; Traoré, B.; Katan, C.; Even, J.; Mohite, A. D.; Kanatzidis, M. G., High Members of the 2D Ruddlesden-Popper Halide Perovskites: Synthesis, Optical Properties, and Solar Cells of (CH3(CH2)3NH3)2(CH3NH3)4Pb5I16. Chem 2017, 427-440. 42. Stoumpos, C. C.; Cao, D. H.; Clark, D. J.; Young, J.; Rondinelli, J. M.; Jang, J. I.; Hupp, J. T.; Kanatzidis, M. G., Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors. Chemistry of Materials 2016, 2852-2867. 43. Dolzhenko, Y. I.; Inabe, T.; Maruyama, Y., In Situ X-Ray Observation on the Intercalation of Weak Interaction Molecules into Perovskite-Type Layered Crystals (C9H19NH3)2PbI4 and (C10H21NH3)2CdCl4. Bulletin of the Chemical Society of Japan 1986, 563-567. 44. Papavassiliou, G. C.; Koutselas, J. B.; Lagouvardos, D. J., Notizen: Preparation and Characterization of (C6H5CH2CH2NH3)2SnI4 and (C6H5CH2CH2NH3)2SnBr4. In Zeitschrift für Naturforschung B, 1993; 1013. 45. Mitzi, D. B., Synthesis, Crystal Structure, and Optical and Thermal Properties of (C4H9NH3)2MI4 (M = Ge, Sn, Pb). Chemistry of Materials 1996, 791-800. 46. Cortecchia, D.; Dewi, H. A.; Yin, J.; Bruno, A.; Chen, S.; Baikie, T.; Boix, P. P.; Grätzel, M.; Mhaisalkar, S.; Soci, C.; Mathews, N., Lead-Free MA2CuClxBr4–x Hybrid Perovskites. Inorganic Chemistry 2016, 1044-1052. 47. Arend, H.; Tichy, K.; Baberschke, K.; Rys, F., Chloride perovskite layer compounds of [NH3-(CH2)n-NH3]MnCl4 formula. Solid State Communications 1976, 999-1003. 48. Han, J.; Nishihara, S.; Inoue, K.; Kurmoo, M., On the Nature of the Structural and Magnetic Phase Transitions in the Layered Perovskite-Like (CH3NH3)2[FeIICl4]. Inorganic Chemistry 2014, 2068-2075. 49. Mitzi, D. B.; Liang, K., Preparation and Properties of (C4H9NH3)2EuI4: A Luminescent Organic−Inorganic Perovskite with a Divalent Rare-Earth Metal Halide Framework. Chemistry of Materials 1997, 2990-2995. 50. Mitzi, D. B., Organic−Inorganic Perovskites Containing Trivalent Metal Halide Layers: The Templating Influence of the Organic Cation Layer. Inorganic Chemistry 2000, 6107-6113. 51. Castro-Castro, L. M.; Guloy, A. M., Organic-Based Layered Perovskites of Mixed-Valent Gold(I)/Gold(III) Iodides. Angewandte Chemie International Edition 2003, 2771-2774. 52. Connor, B. A.; Leppert, L.; Smith, M. D.; Neaton, J. B.; Karunadasa, H. I., Layered Halide Double Perovskites: Dimensional Reduction of Cs2AgBiBr6. Journal of the American Chemical Society 2018, 5235-5240. 53. Kitazawa, N., Excitons in two-dimensional layered perovskite compounds: (C6H5C2H4NH3)2Pb(Br,I)4 and (C6H5C2H4NH3)2Pb(Cl,Br)4. Materials Science and Engineering: B 1997, 233-238. 54. Kitazawa, N., Optical Absorption and Photoluminescence Properties of Pb(I, Br)-Based Two-Dimensional Layered Perovskite. Japanese Journal of Applied Physics 1997, 2272-2276. 55. Kitazawa, N., Compositional Modulation of Two-Dimensional Layered Perovskite(RNH3)2Pb(Cl,Br,I)4and Its Optical Properties. Japanese Journal of Applied Physics 1996, 6202-6207. 56. Daub, M.; Hillebrecht, H., Synthesis, Single-Crystal Structure and Characterization of (CH3NH3)2Pb(SCN)2I2. Angewandte Chemie International Edition 2015, 11016-11017. 57. Muljarov, E. A.; Tikhodeev, S. G.; Gippius, N. A.; Ishihara, T., Excitons in self-organized semiconductor/insulator superlattices: PbI-based perovskite compounds. Physical Review B 1995, 14370-14378. 58. Green, M. A.; Jiang, Y.; Soufiani, A. M.; Ho-Baillie, A., Optical Properties of Photovoltaic Organic–Inorganic Lead Halide Perovskites. The Journal of Physical Chemistry Letters 2015, 4774-4785. 59. Hong, X.; Ishihara, T.; Nurmikko, A. V., Dielectric confinement effect on excitons in lead-based layered semiconductors. Physical Review B 1992, 6961-6964. 60. Ishihara, T., Optical properties of PbI-based perovskite structures. Journal of Luminescence 1994, 269-274. 61. Lin, Q.; Armin, A.; Nagiri, R. C. R.; Burn, P. L.; Meredith, P., Electro-optics of perovskite solar cells. Nature Photonics 2014, 106. 62. Smith, M. D.; Karunadasa, H. I., White-Light Emission from Layered Halide Perovskites. Accounts of Chemical Research 2018, 619-627. 63. Smith, M. D.; Pedesseau, L.; Kepenekian, M.; Smith, I. C.; Katan, C.; Even, J.; Karunadasa, H. I., Decreasing the electronic confinement in layered perovskites through intercalation. Chemical Science 2017, 1960-1968. 64. Wood, D. L.; Tauc, J., Weak Absorption Tails in Amorphous Semiconductors. Physical Review B 1972, 3144-3151. 65. Dolgonos, A.; Mason, T. O.; Poeppelmeier, K. R., Direct optical band gap measurement in polycrystalline semiconductors: A critical look at the Tauc method. Journal of Solid State Chemistry 2016, 43-48. 66. Straus, D. B.; Kagan, C. R., Electrons, Excitons, and Phonons in Two-Dimensional Hybrid Perovskites: Connecting Structural, Optical, and Electronic Properties. The Journal of Physical Chemistry Letters 2018, 1434-1447. 67. Takagi, H.; Kunugita, H.; Ema, K., Influence of the image charge effect on excitonic energy structure in organic-inorganic multiple quantum well crystals. Physical Review B 2013, 125421. 68. Umeyama, D.; Lin, Y.; Karunadasa, H. I., Red-to-Black Piezochromism in a Compressible Pb–I–SCN Layered Perovskite. Chemistry of Materials 2016, 3241-3244. 69. Smith, I. C.; Hoke, E. T.; Solis-Ibarra, D.; McGehee, M. D.; Karunadasa, H. I., A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability. Angewandte Chemie International Edition 2014, 11232-11235. 70. Hoefler, S. F.; Trimmel, G.; Rath, T., Progress on lead-free metal halide perovskites for photovoltaic applications: a review. Monatshefte für Chemie - Chemical Monthly 2017, 795-826. 71. Shannon, R., Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallographica Section A 1976, 751-767. 72. Manser, J. S.; Christians, J. A.; Kamat, P. V., Intriguing Optoelectronic Properties of Metal Halide Perovskites. Chemical Reviews 2016, 12956-13008. 73. Song, T.-B.; Yokoyama, T.; Aramaki, S.; Kanatzidis, M. G., Performance Enhancement of Lead-Free Tin-Based Perovskite Solar Cells with Reducing Atmosphere-Assisted Dispersible Additive. ACS Energy Letters 2017, 897-903. 74. Marshall, K. P.; Walker, M.; Walton, R. I.; Hatton, R. A., Enhanced stability and efficiency in hole-transport-layer-free CsSnI3 perovskite photovoltaics. Nature Energy 2016, 16178. 75. Song, T.-B.; Yokoyama, T.; Stoumpos, C. C.; Logsdon, J.; Cao, D. H.; Wasielewski, M. R.; Aramaki, S.; Kanatzidis, M. G., Importance of Reducing Vapor Atmosphere in the Fabrication of Tin-Based Perovskite Solar Cells. Journal of the American Chemical Society 2017, 836-842. 76. Gupta, S.; Cahen, D.; Hodes, G., How SnF2 Impacts the Material Properties of Lead-Free Tin Perovskites. The Journal of Physical Chemistry C 2018, 13926-13936. 77. Qin, C.; Matsushima, T.; Fujihara, T.; Adachi, C., Multifunctional Benzoquinone Additive for Efficient and Stable Planar Perovskite Solar Cells. Advanced Materials 2017 , 1603808. 78. Li, W.; Li, J.; Li, J.; Fan, J.; Mai, Y.; Wang, L., Addictive-assisted construction of all-inorganic CsSnIBr2 mesoscopic perovskite solar cells with superior thermal stability up to 473 K. Journal of Materials Chemistry A 2016 , 17104-17110. 79. Quan, L. N.; Yuan, M.; Comin, R.; Voznyy, O.; Beauregard, E. M.; Hoogland, S.; Buin, A.; Kirmani, A. R.; Zhao, K.; Amassian, A.; Kim, D. H.; Sargent, E. H., Ligand-Stabilized Reduced-Dimensionality Perovskites. Journal of the American Chemical Society 2016, 2649-2655. 80. Sun, P.-P.; Li, Q.-S.; Yang, L.-N.; Li, Z.-S., Theoretical insights into a potential lead-free hybrid perovskite: substituting Pb2+ with Ge2+. Nanoscale 2016, 1503-1512. 81. Tang, L.-C.; Chang, Y.-C.; Huang, J.-Y.; Lee, M.-H.; Chang, C.-S., First Principles Calculations of Linear and Second-Order Optical Responses in Rhombohedrally Distorted Perovskite Ternary Halides, CsGeX3(X = Cl, Br, and I). Japanese Journal of Applied Physics 2009, 112402. 82. Chen, M.; Ju, M.-G.; Garces, H. F.; Carl, A. D.; Ono, L. K.; Hawash, Z.; Zhang, Y.; Shen, T.; Qi, Y.; Grimm, R. L.; Pacifici, D.; Zeng, X. C.; Zhou, Y.; Padture, N. P., Highly stable and efficient all-inorganic lead-free perovskite solar cells with native-oxide passivation. Nature Communications 2019 , 16. 83. Jellicoe, T. C.; Richter, J. M.; Glass, H. F. J.; Tabachnyk, M.; Brady, R.; Dutton, S. E.; Rao, A.; Friend, R. H.; Credgington, D.; Greenham, N. C.; Böhm, M. L., Synthesis and Optical Properties of Lead-Free Cesium Tin Halide Perovskite Nanocrystals. Journal of the American Chemical Society 2016, 2941-2944. 84. Weidman, M. C.; Seitz, M.; Stranks, S. D.; Tisdale, W. A., Highly Tunable Colloidal Perovskite Nanoplatelets through Variable Cation, Metal, and Halide Composition. ACS Nano 2016, 7830-7839. 85. Chen, M.-Y.; Lin, J.-T.; Hsu, C.-S.; Chang, C.-K.; Chiu, C.-W.; Chen, H. M.; Chou, P.-T., Strongly Coupled Tin-Halide Perovskites to Modulate Light Emission: Tunable 550–640 nm Light Emission (FWHM 36–80 nm) with a Quantum Yield of up to 6.4%. Advanced Materials 2018, 1706592. 86. Lin, J.-T.; Liao, C.-C.; Hsu, C.-S.; Chen, D.-G.; Chen, H.-M.; Tsai, M.-K.; Chou, P.-T.; Chiu, C.-W., Harnessing Dielectric Confinement on Tin Perovskites to Achieve Emission Quantum Yield up to 21%. Journal of the American Chemical Society 2019, 10324-10330. 87. Koscher, B. A.; Swabeck, J. K.; Bronstein, N. D.; Alivisatos, A. P., Essentially Trap-Free CsPbBr3 Colloidal Nanocrystals by Postsynthetic Thiocyanate Surface Treatment. Journal of the American Chemical Society 2017, 6566-6569. 88. Zhang, J.; Wu, S.; Liu, T.; Zhu, Z.; Jen, A. K. Y., Boosting Photovoltaic Performance for Lead Halide Perovskites Solar Cells with BF4− Anion Substitutions. Advanced Functional Materials 2019, 1808833. 89. Ahmed, T.; Seth, S.; Samanta, A., Boosting the Photoluminescence of CsPbX3 (X = Cl, Br, I) Perovskite Nanocrystals Covering a Wide Wavelength Range by Postsynthetic Treatment with Tetrafluoroborate Salts. Chemistry of Materials 2018, 3633-3637. 90. Chen, J.; Kim, S.-G.; Park, N.-G., FA0.88Cs0.12PbI3−x(PF6)x Interlayer Formed by Ion Exchange Reaction between Perovskite and Hole Transporting Layer for Improving Photovoltaic Performance and Stability. Advanced Materials 2018, 1801948. 91. Kim, H.; Lee, Y. H.; Lyu, T.; Yoo, J. H.; Park, T.; Oh, J. H., Boosting the performance and stability of quasi-two-dimensional tin-based perovskite solar cells using the formamidinium thiocyanate additive. Journal of Materials Chemistry A 2018, 18173-18182. 92. Jeon, N. J.; Noh, J. H.; Kim, Y. C.; Yang, W. S.; Ryu, S.; Seok, S. I., Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells. Nature Materials 2014, 897. 93. Fang, H.; Jena, P., Atomic-Level Design of Water-Resistant Hybrid Perovskites for Solar Cells by Using Cluster Ions. The Journal of Physical Chemistry Letters 2017, 3726-3733. 94. Oliveira, L.; Magna, P.; Gallo, N. J. H.; Domenicucci, E. C.; Li, M. S., Coupled Pairs of Cu+OCN− in KCl Studied by Optical Absorption and Thermally Stimulated Depolarization Current. physica status solidi (b) 1992, 141-151. 95. Yang, W. S.; Noh, J. H.; Jeon, N. J.; Kim, Y. C.; Ryu, S.; Seo, J.; Seok, S. I., High-performance photovoltaic perovskite layers fabricated through intramolecular exchange. Science 2015, 1234. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/7212 | - |
| dc.description.abstract | 錫基鈣鈦礦是一種很有前景的半導體材料，且最具前瞻性的鉛替代品。根據理論和實驗，錫基鈣鈦礦表現出較窄的帶隙和與鉛類似的光電特性。然而，錫基鈣鈦礦的空氣穩定性差，阻礙了實際應用的發展。許多團隊已經做出了很多努力，例如添加額外的氯化亞錫 (SnF2) 作為補償劑或者將維度從三維降到二維鈣鈦礦以防止四價錫的產生。因此，合成了具有化學式TEA2SnI4（TEA = 噻吩基乙基銨）的新型鈣鈦礦納米板，通過將具有強化學相互作用的硫氰酸銨（NH4SCN）添加劑引入到錫基鈣鈦礦中，可以顯著提高其空氣穩定性和光致發光性能。在優化的條件下，我們的結果顯示錫基鈣鈦礦的空氣穩定性實際上得到改善。此外，光致發光量子產率（PLQY）可達22 ％。 | zh_TW |
| dc.description.abstract | Tin-based perivskite is a promising semiconductor material and is the most forward-looking candidates of lead alternative. According to theory and experiment, tin-based perovskite exhibits narrower band gap and comparable photoelectric properties to lead analog. However, the poor oxidative stability of tin-based perovskite has hindered the development for real application. Many groups have contributed a lot of efforts, such as adding extra SnF2 as compensator or decreasing the dimensionality form three-dimensional to two-dimensional perovskite to prevent Sn4+ generation. Hence, new tin perovskite nanoplates with chemical formula TEA2SnI4 (TEA = thienylethylammonium) is synthesized and its air stability and photoluminescence property can be significantly enhanced by introducing ammonium thiocyanate (NH4SCN) additive with strong chemical interactions to Sn2+ into 2D tin-based perovskites. Under optimized condition, our results show that the air stability of tin perovskite is actually improved. Besides, the photoluminescence quantum yield (PLQY) can reach to 22%. | en |
| dc.description.provenance | Made available in DSpace on 2021-05-19T17:40:16Z (GMT). No. of bitstreams: 1 ntu-108-R06223163-1.pdf: 3987843 bytes, checksum: 311dd8e15ac5e0739e14eecf3caa2e01 (MD5) Previous issue date: 2019 | en |
| dc.description.tableofcontents | 論文口試委員會審定書 I
誌謝 II 摘要 III ABSTRACT IV CONTENT V LIST OF FIGURES VIII LIST OF TABLES XII CHAPTER 1 PEROVSKITES INTRODUCTION 1 1.1 BACKGROUND 1 CHAPTER 2 STRUCTURE 3 2.1 THREE-DIMENSIONAL PEROVSKITES 3 2.2 TWO-DIMENSIONAL PEROVSKITES 4 2.2.1 Connectivity of the Inorganic Layer 5 2.2.2 Structural Distortions of the Inorganic Layer 7 2.2.3 Thickness of the Inorganic Layer 8 2.2.4 The A Site 8 2.2.5 The B Site 9 2.2.6 The X Site 10 CHAPTER 3 ELECTRIC CONFINEMENT 10 3.1 EXCITONS 11 3.2 DETERMINING THE BAND GAP (EG) AND EXCITON BINDING ENERGY (EB) 11 3.3 ELECTRONIC CONFINEMENT EFFECTS 13 3.3.1 Tuning Eb through the Organic Layer 16 3.3.2 Tuning Eb through the Inorganic Layer 16 CHAPTER 4 LEAD-FREE AND LOW-LEAD PEROVSKITES 18 4.1 LEAD-FREE PEROVSKITE MATERIALS 19 4.1.1 Tin (Sn)-Based Perovskites 19 4.1.2 Germanium (Ge)-Based Perovskites 21 4.1.3 Lead-Free Binary Metal Halide Perovskites 22 CHAPTER 5 EXPERIMENT 23 5.1 EXPERIMENT MOTIVATION 23 5.2 EXPERIMENTAL SECTION 25 5.2.1 Chemical 25 5.2.2 Synthesis methods 25 CHAPTER 6 RESULTS AND DISCUSSIONS 28 CHAPTER 7 CONCLUSION 58 REFERENCE 59 | |
| dc.language.iso | zh-TW | |
| dc.title | 高空氣穩定性二維類核殼結構錫鈣鈦礦光致發光材料 | zh_TW |
| dc.title | High air stability two-dimensional core shell like structure tin-based perovskite photoluminescence material | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 107-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 薛景中(Jing-Jong Shyue),蔡明剛(Ming-Kang Tsai) | |
| dc.subject.keyword | 錫基鈣鈦礦,無鉛鈣鈦礦,低維度鈣鈦礦,二維材料,發光材料, | zh_TW |
| dc.subject.keyword | Tin-based perovskites,Lead-free perovskites,Low-dimensional perovskites,Two-dimensional material,Photoluminescence material, | en |
| dc.relation.page | 75 | |
| dc.identifier.doi | 10.6342/NTU201903018 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2019-08-13 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| dc.date.embargo-lift | 2024-08-20 | - |
| 顯示於系所單位： | 化學系 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-108-1.pdf | 3.89 MB | Adobe PDF | 檢視/開啟 |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。