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| ???org.dspace.app.webui.jsptag.ItemTag.dcfield??? | Value | Language |
|---|---|---|
| dc.contributor.advisor | 黃心豪 | |
| dc.contributor.author | Yao-Ting Huang | en |
| dc.contributor.author | 黃耀霆 | zh_TW |
| dc.date.accessioned | 2021-06-17T06:08:42Z | - |
| dc.date.available | 2020-01-07 | |
| dc.date.copyright | 2019-01-07 | |
| dc.date.issued | 2018 | |
| dc.date.submitted | 2018-12-19 | |
| dc.identifier.citation | [1] 林宜慶，2009，〈超級電容器技術發展與應用趨勢分析〉，彰化：財團法人車輛研究測試中心。
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[47] 黃進益譯，1998，《電化學的原理及應用》，台北：高立圖書。譯自 : Principles and applications of electrochemistry [48] W. Gu, M. Sevilla, A. Magasinski, A. B. Fuertes, and G. Yushin, 'Sulfur-containing activated carbons with greatly reduced content of bottle neck pores for double-layer capacitors: a case study for pseudocapacitance detection,' Energy & Environmental Science, vol. 6, p. 2465, 2013. [49] S. Ban, J. Zhang, L. Zhang, K. Tsay, D. Song, and X. Zou, 'Charging and discharging electrochemical supercapacitors in the presence of both parallel leakage process and electrochemical decomposition of solvent,' Electrochimica Acta, vol. 90, pp. 542-549, 2013. [50] P. Kurzweil, 'Electrochemical Double-layer Capacitors,' University of Applied Sciences, pp. 345-407, 2015. [51] M. Lu, F. Beguin, and E. Frackowiak, Supercapacitors: Materials, Systems, and Applications. Germany: WILEY-VCH, 2013. [52] C. Lei, F. Markoulidis, Z. Ashitaka, and C. 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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/71754 | - |
| dc.description.abstract | 本研究成功開發出一套儲能複合材料的標準化製程，其中以活化碳纖維電極、PVdF膠體電解質(gel polymer electrolyte)，製作超級電容，並透過氟碳樹脂與環氧樹脂兩步驟的封裝方式將超級電容嵌入至玻璃纖維複合材料中，達到能同時承受負載與儲能的結構超級電容複合材料。此外，本研究首先針對碳纖維電極的活化方法與PVdF膠體電解質進行了研究，接著進行碳纖維電容器的製備與與封裝，利用恆電流充放電、循環伏安法及交流阻抗法來分析相關的電學性質，結果顯示在10 mA/g電流密度充放電下，具有167 mF/g的電容值及實際能量密度140 J/kg，相比於封裝前分別提升了約20%與30%，這是由於灌注時的真空壓力所影響。以拉伸試驗探討將超級電容器嵌入至玻璃纖維複合材料前後的力學性質，嵌入後平均應力仍有350.1 MPa，楊氏模數為14 GPa。為了解多功能儲能複合材料電學性質隨拉伸負載的變化，建立兩種負載變化的情形，觀察與分析電學性質。研究結果表明，兩種情形下，多功能儲能複合材料隨拉伸負載增加，相比於未受任何負載前，能量密度最大的變化率約為10%與12%，這是由於伯松比的效應，當材料受軸向拉伸時軸向伸長，側向收縮，使內部電容器受擠壓，電極距離改變，電性提升。而在玻璃纖維複合材料失效破壞前，超級電容器仍正常運作。最後將封裝後的成品置於空氣中，觀察十四天之間的衰變情形，儲能表現仍保有約96%。 | zh_TW |
| dc.description.abstract | This study demonstrates a standardized process to fabricate embedded multifunctional energy storage composites. Using Activated carbon fiber electrodes and PVdF-based gel electrolyte as building materials for supercapacitors. Two-step packaging method is used to fabricate glass-fiber reinforced polymer (GFRP) composites that can make it simultaneously bear mechanical loadings and store energy. Carbon fabric with three different activation methods and PVdF-based gel electrolyte are characterized by an electrochemical test. In addition, the electrochemical properties of the multifunctional energy storage composites are determined by galvanostatic charge-discharge (GCD), cyclic voltammetry and AC impedance method (EIS). The result shows that specific capacitance and energy density of supercapacitor with GFRP have 142 mF/g and 15.7 Wkg^(-1) provide 20% and 30% enhancement performance than a bare cell, respectively. The mechanical properties of the supercapacitor embedding of GFRP are investigated by tensile test; the result shows the average stress of 350.1 MPa and Young’s modulus of 14 GPa. Furthermore, to understand the electrical properties of multifunctional energy storage composites with external load changes, two different situations were also established. With the tensile load increase, the supercapacitor energy density is increased by around 10%, and the structural supercapacitor undergoing cyclic tensile is still functioning normally before the GFRP failure load. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T06:08:42Z (GMT). No. of bitstreams: 1 ntu-107-R05525078-1.pdf: 5284950 bytes, checksum: 6a5c79b1b80bf556f0ed6156b9f9f9a6 (MD5) Previous issue date: 2018 | en |
| dc.description.tableofcontents | 誌謝 i
中文摘要 ii 英文摘要 iii 目錄 iv 圖目錄 vii 表目錄 xi 第一章 簡介 1 1.1 動機 1 1.2 研究背景 1 1.3 研究目的 2 1.4 重要性與貢獻 3 1.5 名詞對照與符號說明 4 1.5.1 英文專有名詞與中文翻譯對照 4 1.5.2 符號說明表 7 第二章 文獻探討 11 2.1多功能儲能複合材料 11 2.1.1沿革 11 2.1.2碳纖維電容複合材料 11 2.1.3碳纖維超級電容複合材料 13 2.1.4碳纖維電池複合材料 18 2.2超級電容器 20 2.2.1概述 20 2.2.2超級電容器原理與分類 21 2.3碳電極超級電容器探討 25 2.3.1活性碳(Activated carbons) 25 2.3.2奈米碳管(Carbon nanotubes) 26 2.3.3複合碳材料(Carbon-based composites) 27 2.4碳纖維電極活化碳討 27 2.5高分子聚合物電解質 31 2.5.1概述 31 2.5.2固態聚合物電解質(Solid polymer electrolytes) 32 2.5.3膠體聚合物電解質(Gel polymer electrolyte) 33 第三章 研究方法 37 3.1研究流程 37 3.2實驗方法 39 3.2.1電化學檢測方法 39 3.2.2碳纖維電極表面處理與比表面積分析 51 3.2.3膠體電解質 54 3.2.4超級電容器製程與封裝 56 3.2.5多功能儲能複合材料性能檢測 60 3.2.6超級電容器壽命檢測 63 3.3實驗儀器與設備 63 3.4實驗藥品 66 第四章 研究結果 67 4.1碳纖維電極活化 67 4.1.1碳纖維微結構分析 67 4.1.2比電容 68 4.2PVdF膠體電解質特性 70 4.2.1濃度 70 4.2.2導電度 71 4.2.3電位窗探討 73 4.3超級電容器特性 74 4.3.1未活化碳纖維超級電容器 74 4.3.2活化碳纖維超級電容器 77 4.3.3操作電位探討 79 4.3.4封裝後性能表現 82 4.4多功能儲能複合材料特性 84 4.4.1複合材料試片 85 4.4.2儲能複合材料性能表現 87 第五章 討論 92 5.1碳纖維活化程序 92 5.2碳纖維孔徑分佈分析 92 5.3碳纖維超級電容器製程與封裝程序探討 94 5.4系統截止電位討論 98 5.5複合測試特性與破壞模式探討 99 5.6成品壽命檢測 102 5.6成品電學特性比較與分析 103 第六章 結論與未來展望 104 6.1結論 104 6.2未來展望 106 第七章 參考文獻 107 | |
| dc.language.iso | zh-TW | |
| dc.subject | 膠體電解質 | zh_TW |
| dc.subject | 超級電容 | zh_TW |
| dc.subject | 嵌入式 | zh_TW |
| dc.subject | 多功能能複合材料 | zh_TW |
| dc.subject | 活化碳纖維 | zh_TW |
| dc.subject | supercapacitor | en |
| dc.subject | activated carbon fiber | en |
| dc.subject | gel electrolyte | en |
| dc.subject | composites | en |
| dc.subject | energy storage | en |
| dc.subject | multifunctional | en |
| dc.subject | embedded | en |
| dc.title | 以活化碳纖維電極及PVdF膠體聚合物製備嵌入式多功能儲能複合材料-電化學與力學性能探討 | zh_TW |
| dc.title | Preparation of Embedded Multifunctional Energy Storage Composites with Activated Carbon Fiber Electrode and PVdF-based Gel Polymer Electrolytes ¬— on Electrochemical and Mechanical Properties | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 107-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.coadvisor | 陳洵毅(hsunyichen@ntu.edu.tw) | |
| dc.contributor.oralexamcommittee | 張豐丞,李岳聯(yuehlien@ntu.edu.tw) | |
| dc.subject.keyword | 超級電容,嵌入式,多功能能複合材料,膠體電解質,活化碳纖維, | zh_TW |
| dc.subject.keyword | supercapacitor,embedded,multifunctional,energy storage,composites,gel electrolyte,activated carbon fiber, | en |
| dc.relation.page | 109 | |
| dc.identifier.doi | 10.6342/NTU201804364 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2018-12-19 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 工程科學及海洋工程學研究所 | zh_TW |
| Appears in Collections: | 工程科學及海洋工程學系 | |
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