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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 于昌平 | |
| dc.contributor.author | Li-Hsun Huang | en |
| dc.contributor.author | 黃立勛 | zh_TW |
| dc.date.accessioned | 2021-06-17T06:00:59Z | - |
| dc.date.available | 2019-02-15 | |
| dc.date.copyright | 2019-02-15 | |
| dc.date.issued | 2019 | |
| dc.date.submitted | 2019-02-11 | |
| dc.identifier.citation | Abourached, Carole, TuncCatal, andHongLiu. 2014. “Efficacy of Single-Chamber Microbial Fuel Cells for Removal of Cadmium and Zinc with Simultaneous Electricity Production.” Water Research 51:228–33.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/71452 | - |
| dc.description.abstract | 隨著全球人口快速增加，能源的使用大幅提升，導致全球暖化的現象，因此再生能源和水資源處理技術逐年受到重視。微生物燃料電池(Microbial Fuel Cell, MFC)為一種生物電化學技術，此技術在運行時，能同時有產電和廢水處理的功能，可用於作為生質能和降解廢水中之有機質。另外，由於製造肥料所需，全球磷礦的開採量增加，又加上磷礦自然形成速度緩慢，導致磷礦資源消耗逐年加劇。近年，科學家嘗試從人類尿液中，以沉澱的方式回收一種磷的礦物進行再利用，此磷礦沉澱物為鳥糞石(struvite, NH4MgPO4·6H2O)，而沉澱反應需在鹼性環境下進行，當雙槽式MFC在運行時，其陰極槽的部分為鹼性環境，可以進行鳥糞石沉澱。因此本研究主要探討MFC處理人工尿液時，其有機質降解成效、產電效能和磷回收的效果。
本研究不同於以往文獻中使用單槽式MFC來進行尿液中的磷回收，改使用平板雙槽式MFC處理人工尿液，槽體分為陽極槽和陰極槽，兩槽中間以薄膜進行區隔。陽極進行微生物降解有機質的反應，陰極進行曝氣和鳥糞石沉澱之反應。兩槽中的電極皆使用石墨氈。本研究同時比較陰極電極改質與不同薄膜對產電效果之影響，此改質為電極進行催化塗層，使用的催化劑為鈦菁鐵(iron phthalocyanine, FePc)，薄膜則分為陽離子交換膜、陰離子交換膜和質子交換膜。本實驗在水質、產能和磷回收部分進行探討。結果顯示化學需氧量之去除率最高可達93.7%。而使用質子交換膜時可以獲得較高之電壓，並產生最高功率密度78.14 mW/m2。使用質子交換膜時，成功地在陰極槽中獲得鳥糞石沉澱。 | zh_TW |
| dc.description.abstract | The potential of two-chambers microbial fuel cells (MFCs) for treating synthetic human urine has been investigated. In the treatment, there are not only the degradation of organic matter but also the recycling of phosphate as struvite (magnesium ammonium phosphate, NH4MgPO4·6H2O). In this study, we used the flat plate MFC (FPMFC), which was made up of an anode and a cathode. The two chambers were separated by the membrane. The anode with channel, where the microorganism degrade substrate, was operated as a plug flow reactor, and the anode was inoculated with anaerobic sludge obtained from a wastewater treatment plant. The cathode without channel was continuously aerated, and the precipitation of struvite will occur with the alkaline environment in the cathode. We adopted graphite felt for the electrode and investigated supported iron phthalocyanine (FePc) as the catalyst for the oxygen reduction reaction (ORR). Cation exchange membrane, anion exchange membrane and proton exchange membrane were used in the FPMFC to test which one is good for electricity production. Organic matter can be degraded effectively by using FPMFC and the maximum removal efficiency is 93.7%. When we use the proton exchange membrane, the FPMFC have the high voltage output and the maximum power density is 78.14 mW/m2. By adding magnesium dichloride, we got the struvite in the cathode from synthetic urine. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T06:00:59Z (GMT). No. of bitstreams: 1 ntu-108-R05541121-1.pdf: 3246460 bytes, checksum: 62d6d9fe83b128bb4fd15bc128b39bb6 (MD5) Previous issue date: 2019 | en |
| dc.description.tableofcontents | 論文口試委員審定書 i
致謝 ii 摘要 iii Abstract iv 目錄 v 圖目錄 vii 表目錄 viii 第一章 緒論 1 1.1. 研究背景 1 1.2. 研究動機與目的 2 1.3. 研究架構圖 4 第二章 文獻回顧 5 2.1. 微生物燃料電池之理論和發展 5 2.1.1. 生物電化學系統之演進 5 2.1.2. 微生物燃料電池產電原理 6 2.1.3. 生物電化學系統應用 8 2.2. 微生物燃料電池組態設計 9 2.2.1. 微生物燃料電池陰極 9 2.2.2. 微生物燃料電池之構型 11 2.2.3. 微生物燃料電池之薄膜 14 2.3. 磷酸銨鎂沉澱應用於磷之回收 15 2.3.1. 磷酸銨鎂沉澱反應 15 2.3.2. 微生物燃料電池應用於磷之回收 16 第三章 材料與方法 17 3.1. 實驗藥品與設備 17 3.1.1. 實驗藥品 17 3.1.2. 實驗設備與儀器 20 3.2. 平板式微生物燃料電池系統 21 3.2.1. 平板式微生物燃料電池組態 21 3.2.2. 菌種來源與馴養 22 3.2.3. 平板式微生物燃料電池電極製備 22 3.2.4. 平板式微生物燃料電池薄膜準備 23 3.2.5. 平板式微生物燃料電池運行 24 3.3. 平板式微生物燃料電池產電能力分析 29 3.3.1. 電壓量測與紀錄 29 3.3.2. 內電阻分析 29 3.3.3. 內電阻和最大功率密度測定 33 3.3.4. 單極電位分析 33 3.4. 平板式微生物燃料電池之磷回收能力 34 3.4.1. 磷酸銨鎂沉澱試驗 34 3.4.2. 磷酸銨鎂沉澱物分析 35 3.5. 平板式微生物燃料電池之水質分析 36 3.5.1. 化學需氧量 36 3.5.2. pH值 36 3.5.3. 氨氮 36 3.5.4. 水中陰離子檢測方法─離子層析法 36 第四章 結果與討論 37 4.1. 平板式微生物燃料電池去除有機質表現 37 4.1.1. 有無塗覆催化劑去除效果比較 37 4.1.2. 不同薄膜去除效果比較 37 4.2. 平板式微生物燃料電池產電效能 41 4.2.1. 馴養期之產電狀況 41 4.2.2. 有無塗覆催化劑產電效能比較 42 4.2.2.1. 電壓大小比較 42 4.2.2.2. 最大功率密度和內電阻比較 42 4.2.2.3. 單極電位比較 42 4.2.3. 不同薄膜產電效能比較 45 4.2.3.1. 電壓大小比較 45 4.2.3.2. 最大功率密度和內電阻比較 45 4.3. 平板式微生物燃料電池之磷回收 48 4.3.1. 陽離子交換膜應用於磷回收 48 4.3.2. 質子交換膜應用於磷回收 50 4.3.3. 陰離子交換膜應用於磷回收 55 4.3.4. 磷酸銨鎂沉澱測試 55 4.3.5. 磷酸銨鎂沉澱物分析 59 第五章 結論與建議 61 5.1. 結論 61 5.2. 建議 62 參考文獻 63 | |
| dc.language.iso | zh-TW | |
| dc.title | 雙槽平板式微生物燃料電池產能和磷回收研究 | zh_TW |
| dc.title | Power Generation and Phosphate Recovery Using Two-Chambers Flat Plate Microbial Fuel Cell | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 107-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 黃郁慈,童心欣 | |
| dc.subject.keyword | 微生物燃料電池,尿液處理,磷回收,鳥糞石, | zh_TW |
| dc.subject.keyword | microbial fuel cell,membrane,urine treatment,phosphate recovery,struvite, | en |
| dc.relation.page | 69 | |
| dc.identifier.doi | 10.6342/NTU201900430 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2019-02-12 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
| 顯示於系所單位： | 環境工程學研究所 | |
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