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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 陳振中 | |
dc.contributor.author | Chieh Tsao | en |
dc.contributor.author | 曹杰 | zh_TW |
dc.date.accessioned | 2021-06-17T04:51:27Z | - |
dc.date.available | 2020-08-07 | |
dc.date.copyright | 2018-08-07 | |
dc.date.issued | 2018 | |
dc.date.submitted | 2018-07-30 | |
dc.identifier.citation | (1) Mann, S. Biomineralization: Principles and Concepts in Bioinorganic Materials Chemistry; Oxford chemistry masters; Oxford University Press: New York, 2001.
(2) Weiner, S.; Dove, P. M. An Overview of Biomineralization Processes and the Problem of the Vital Effect. Rev. Mineral. Geochem. 2003, 54 (1), 1–29. (3) Rosseeva), E. V. S. (née; Cölfen, H. Mesocrystals: Structural and Morphogenetic Aspects. Chem. Soc. Rev. 2016, 45 (21), 5821–5833. (4) Sturm (née Rosseeva), E. V.; Cölfen, H. Mesocrystals: Past, Presence, Future. Crystals 2017, 7 (7), 207. (5) Seto, J.; Ma, Y.; Davis, S. A.; Meldrum, F.; Gourrier, A.; Kim, Y.-Y.; Schilde, U.; Sztucki, M.; Burghammer, M.; Maltsev, S.; et al. Structure-Property Relationships of a Biological Mesocrystal in the Adult Sea Urchin Spine. Proc. Natl. Acad. Sci. 2012, 109 (10), 3699–3704. (6) Bergström, L.; Sturm (née Rosseeva), E. V.; Salazar-Alvarez, G.; Cölfen, H. Mesocrystals in Biominerals and Colloidal Arrays. Acc. Chem. Res. 2015, 48 (5), 1391–1402. (7) Yoreo, J. J. D.; Gilbert, P. U. P. A.; Sommerdijk, N. A. J. M.; Penn, R. L.; Whitelam, S.; Joester, D.; Zhang, H.; Rimer, J. D.; Navrotsky, A.; Banfield, J. F.; et al. Crystallization by Particle Attachment in Synthetic, Biogenic, and Geologic Environments. Science 2015, 349 (6247), aaa6760. (8) Lee, J.; Yang, J.; Kwon, S. G.; Hyeon, T. Nonclassical Nucleation and Growth of Inorganic Nanoparticles. Nat. Rev. Mater. 2016, 1 (8), 16034. (9) Karthika, S.; Radhakrishnan, T. K.; Kalaichelvi, P. A Review of Classical and Nonclassical Nucleation Theories. Cryst. Growth Des. 2016, 16 (11), 6663–6681. (10) Oxtoby, D. W.; Evans, R. Nonclassical Nucleation Theory for the Gas–Liquid Transition. J. Chem. Phys. 1988, 89 (12), 7521–7530. (11) Smeets, P. J. M.; Finney, A. R.; Habraken, W. J. E. M.; Nudelman, F.; Friedrich, H.; Laven, J.; Yoreo, J. J. D.; Rodger, P. M.; Sommerdijk, N. A. J. M. A Classical View on Nonclassical Nucleation. Proc. Natl. Acad. Sci. 2017, 114 (38), E7882–E7890. (12) Addadi, L.; Raz, S.; Weiner, S. Taking Advantage of Disorder: Amorphous Calcium Carbonate and Its Roles in Biomineralization. Adv. Mater. 2003, 15 (12), 959–970. (13) Bolze, J.; Peng, B.; Dingenouts, N.; Panine, P.; Narayanan, T.; Ballauff, M. Formation and Growth of Amorphous Colloidal CaCO3 Precursor Particles as Detected by Time-Resolved SAXS. Langmuir 2002, 18 (22), 8364–8369. (14) Beniash, E.; Aizenberg, J.; Addadi, L.; Weiner, S. Amorphous Calcium Carbonate Transforms into Calcite during Sea Urchin Larval Spicule Growth. Proc. R. Soc. B Biol. Sci. 1997, 264 (1380), 461–465. (15) Politi, Y.; Metzler, R. A.; Abrecht, M.; Gilbert, B.; Wilt, F. H.; Sagi, I.; Addadi, L.; Weiner, S.; Gilbert, P. U. P. A. Transformation Mechanism of Amorphous Calcium Carbonate into Calcite in the Sea Urchin Larval Spicule. Proc. Natl. Acad. Sci. 2008, 105 (45), 17362–17366. (16) Blue, C. R.; Giuffre, A.; Mergelsberg, S.; Han, N.; De Yoreo, J. J.; Dove, P. M. Chemical and Physical Controls on the Transformation of Amorphous Calcium Carbonate into Crystalline CaCO3 Polymorphs. Geochim. Cosmochim. Acta 2017, 196, 179–196. (17) Brečević, L.; Nielsen, A. E. Solubility of Amorphous Calcium Carbonate. J. Cryst. Growth 1989, 98 (3), 504–510. (18) Cam, N.; Georgelin, T.; Jaber, M.; Lambert, J.-F.; Benzerara, K. In Vitro Synthesis of Amorphous Mg-, Ca-, Sr- and Ba-Carbonates: What Do We Learn about Intracellular Calcification by Cyanobacteria? Geochim. Cosmochim. Acta 2015, 161, 36–49. (19) Faatz, M.; Gröhn, F.; Wegner, G. Amorphous Calcium Carbonate: Synthesis and Potential Intermediate in Biomineralization. Adv. Mater. 2004, 16 (12), 996–1000. (20) Gong, Y. U. T.; Killian, C. E.; Olson, I. C.; Appathurai, N. P.; Amasino, A. L.; Martin, M. C.; Holt, L. J.; Wilt, F. H.; Gilbert, P. U. P. A. Phase Transitions in Biogenic Amorphous Calcium Carbonate. Proc. Natl. Acad. Sci. U. S. A. 2012, 109 (16), 6088–6093. (21) Ihli, J.; Wong, W. C.; Noel, E. H.; Kim, Y.-Y.; Kulak, A. N.; Christenson, H. K.; Duer, M. J.; Meldrum, F. C. Dehydration and Crystallization of Amorphous Calcium Carbonate in Solution and in Air. Nat. Commun. 2014, 5, 3169. (22) Ihli, J.; Kulak, A. N.; Meldrum, F. C. Freeze-Drying Yields Stable and Pure Amorphous Calcium Carbonate (ACC). Chem. Commun. 2013, 49 (30), 3134–3136. (23) Khouzani, M. F.; Chevrier, D. M.; Güttlein, P.; Hauser, K.; Zhang, P.; Hedin, N.; Gebauer, D. Disordered Amorphous Calcium Carbonate from Direct Precipitation. CrystEngComm 2015, 17 (26), 4842–4849. (24) Koga, N.; Nakagoe, Y.; Tanaka, H. Crystallization of Amorphous Calcium Carbonate. Thermochim. Acta 1998, 318 (1), 239–244. (25) Michel, F. M.; MacDonald, J.; Feng, J.; Phillips, B. L.; Ehm, L.; Tarabrella, C.; Parise, J. B.; Reeder, R. J. Structural Characteristics of Synthetic Amorphous Calcium Carbonate. Chem. Mater. 2008, 20 (14), 4720–4728. (26) Nebel, H.; Neumann, M.; Mayer, C.; Epple, M. On the Structure of Amorphous Calcium Carbonate—A Detailed Study by Solid-State NMR Spectroscopy. Inorg. Chem. 2008, 47 (17), 7874–7879. (27) Huang, S.-C.; Naka, K.; Chujo, Y. A Carbonate Controlled-Addition Method for Amorphous Calcium Carbonate Spheres Stabilized by Poly(Acrylic Acid)S. Langmuir 2007, 23 (24), 12086–12095. (28) Ma, Y.; Feng, Q. A Crucial Process: Organic Matrix and Magnesium Ion Control of Amorphous Calcium Carbonate Crystallization on β-Chitin Film. CrystEngComm 2014, 17 (1), 32–39. (29) Wang, D.; Wallace, A. F.; De Yoreo, J. J.; Dove, P. M. Carboxylated Molecules Regulate Magnesium Content of Amorphous Calcium Carbonates during Calcification. Proc. Natl. Acad. Sci. U. S. A. 2009, 106 (51), 21511–21516. (30) Tobler, D. J.; Rodriguez-Blanco, J. D.; Dideriksen, K.; Bovet, N.; Sand, K. K.; Stipp, S. L. S. Citrate Effects on Amorphous Calcium Carbonate (ACC) Structure, Stability, and Crystallization. Adv. Funct. Mater. 2015, 25 (20), 3081–3090. (31) Murai, K.; Kinoshita, T.; Nagata, K.; Higuchi, M. Mineralization of Calcium Carbonate on Multifunctional Peptide Assembly Acting as Mineral Source Supplier and Template. Langmuir ACS J. Surf. Colloids 2016, 32 (36), 9351–9359. (32) Song, R.-Q.; Cölfen, H. Additive Controlled Crystallization. CrystEngComm 2011, 13 (5), 1249–1276. (33) Gower, L. B. Biomimetic Model Systems for Investigating the Amorphous Precursor Pathway and Its Role in Biomineralization. Chem. Rev. 2008, 108 (11), 4551–4627. (34) Shen, Y.; Xie, A.; Chen, Z.; Xu, W.; Yao, H.; Li, S.; Huang, L.; Wu, Z.; Kong, X. Controlled Synthesis of Calcium Carbonate Nanocrystals with Multi-Morphologies in Different Bicontinuous Microemulsions. Mater. Sci. Eng. A 2007, 443 (1), 95–100. (35) Feoktistova, N.; Rose, J.; Prokopović, V. Z.; Vikulina, A. S.; Skirtach, A.; Volodkin, D. Controlling the Vaterite CaCO3 Crystal Pores. Design of Tailor-Made Polymer Based Microcapsules by Hard Templating. Langmuir 2016, 32 (17), 4229–4238. (36) Lei, M.; Li, P. G.; Sun, Z. B.; Tang, W. H. Effects of Organic Additives on the Morphology of Calcium Carbonate Particles in the Presence of CTAB. Mater. Lett. 2006, 60 (9), 1261–1264. (37) Xiao, J.; Yang, S. Hollow Calcite Crystals with Complex Morphologies Formed from Amorphous Precursors and Regulated by Surfactant Micellar Structures. CrystEngComm 2010, 12 (10), 3296–3304. (38) Kang, S. H.; Hirasawa, I.; Kim, W.-S.; Choi, C. K. Morphological Control of Calcium Carbonate Crystallized in Reverse Micelle System with Anionic Surfactants SDS and AOT. J. Colloid Interface Sci. 2005, 288 (2), 496–502. (39) Oaki, Y.; Kajiyama, S.; Nishimura, T.; Imai, H.; Kato, T. Nanosegregated Amorphous Composites of Calcium Carbonate and an Organic Polymer. Adv. Mater. 2008, 20 (19), 3633–3637. (40) Yao, Y.; Dong, W.; Zhu, S.; Yu, X.; Yan, D. Novel Morphology of Calcium Carbonate Controlled by Poly(l-Lysine). Langmuir 2009, 25 (22), 13238–13243. (41) Rao, A.; Vásquez-Quitral, P.; Fernández, M. S.; Berg, J. K.; Sánchez, M.; Drechsler, M.; Neira-Carrillo, A.; Arias, J. L.; Gebauer, D.; Cölfen, H. PH-Dependent Schemes of Calcium Carbonate Formation in the Presence of Alginates. Cryst. Growth Des. 2016, 16 (3), 1349–1359. (42) Xu, A.-W.; Dong, W.-F.; Antonietti, M.; Cölfen, H. Polymorph Switching of Calcium Carbonate Crystals by Polymer‐Controlled Crystallization. Adv. Funct. Mater. 2008, 18 (8), 1307–1313. (43) Szcześ, A.; Sternik, D. Properties of Calcium Carbonate Precipitated in the Presence of DPPC Liposomes Modified with the Phospholipase A2. J. Therm. Anal. Calorim. 2016, 123 (3), 2357–2365. (44) Xu, A.-W.; Yu, Q.; Dong, W.-F.; Antonietti, M.; Cölfen, H. Stable Amorphous CaCO3 Microparticles with Hollow Spherical Superstructures Stabilized by Phytic Acid. Adv. Mater. 2005, 17 (18), 2217–2221. (45) Kim, Y.-Y.; Semsarilar, M.; Carloni, J. D.; Cho, K. R.; Kulak, A. N.; Polishchuk, I.; Hendley, C. T.; Smeets, P. J. M.; Fielding, L. A.; Pokroy, B.; et al. Structure and Properties of Nanocomposites Formed by the Occlusion of Block Copolymer Worms and Vesicles Within Calcite Crystals. Adv. Funct. Mater. 2016, 26 (9), 1382–1392. (46) Zhu, Y.; Liu, Y.; Ruan, Q.; Zeng, Y.; Xiao, J.; Liu, Z.; Cheng, L.; Xu, F.; Zhang, L. Superstructures and Mineralization of Laminated Vaterite Mesocrystals via Mesoscale Transformation and Self-Assembly. J. Phys. Chem. C 2009, 113 (16), 6584–6588. (47) Peng, C.; Zhao, Q.; Gao, C. Sustained Delivery of Doxorubicin by Porous CaCO3 and Chitosan/Alginate Multilayers-Coated CaCO3 Microparticles. Colloids Surf. Physicochem. Eng. Asp. 2010, 353 (2), 132–139. (48) Yefimova, S. L.; Bespalova, I. I.; Grygorova, G. V.; Sorokin, A. V.; Mateychenko, P. V.; Cui, X. Q.; Malyukin, Y. V. Synthesis and Characterization of Mesoporous CaCO3@PSS Microspheres as a Depot System for Sustained Methylene Blue Delivering. Microporous Mesoporous Mater. 2016, 236, 120–128. (49) Lu, C.; Qi, L.; Cong, H.; Wang, X.; Yang, J.; Yang, L.; Zhang, D.; Ma, J.; Cao, W. Synthesis of Calcite Single Crystals with Porous Surface by Templating of Polymer Latex Particles. Chem. Mater. 2005, 17 (20), 5218–5224. (50) Li, T.; Hao, L.; Du, C.; Wang, Y. Synthesis of Magnesium-Doped Calcium Carbonate Microcapsules through Yeast-Regulated Mineralization. Mater. Lett. 2017, 193, 38–41. (51) Kitano, Y.; Hood, D. W. The Influence of Organic Material on the Polymorphic Crystallization of Calcium Carbonate. Geochim. Cosmochim. Acta 1965, 29 (1), 29–41. (52) Pouget, E. M.; Bomans, P. H. H.; Goos, J. A. C. M.; Frederik, P. M.; With, G. de; Sommerdijk, N. A. J. M. The Initial Stages of Template-Controlled CaCO3 Formation Revealed by Cryo-TEM. Science 2009, 323 (5920), 1455–1458. (53) Loste, E.; Wilson, R. M.; Seshadri, R.; Meldrum, F. C. The Role of Magnesium in Stabilising Amorphous Calcium Carbonate and Controlling Calcite Morphologies. J. Cryst. Growth 2003, 254 (1), 206–218. (54) Davis, K. J.; Dove, P. M.; Yoreo, J. J. D. The Role of Mg2+ as an Impurity in Calcite Growth. Science 2000, 290 (5494), 1134–1137. (55) Rodriguez-Blanco, J. D.; Shaw, S.; Bots, P.; Roncal-Herrero, T.; Benning, L. G. The Role of PH and Mg on the Stability and Crystallization of Amorphous Calcium Carbonate. J. Alloys Compd. 2012, 536 (Suppl.1), S477–S479. (56) Helman, Y.; Natale, F.; Sherrell, R. M.; LaVigne, M.; Starovoytov, V.; Gorbunov, M. Y.; Falkowski, P. G. Extracellular Matrix Production and Calcium Carbonate Precipitation by Coral Cells in Vitro. Proc. Natl. Acad. Sci. U. S. A. 2008, 105 (1), 54–58. (57) Qi, L.; Li, J.; Ma, J. Biomimetic Morphogenesis of Calcium Carbonate in Mixed Solutions of Surfactants and Double-Hydrophilic Block Copolymers. Adv. Mater. 2002, 14 (4), 300–303. (58) Liang, X.; Xiang, J.; Zhang, F.; Xing, L.; Song, B.; Chen, S. Fabrication of Hierarchical CaCO3 Mesoporous Spheres: Particle-Mediated Self-Organization Induced by Biphase Interfaces and SAMs. Langmuir 2010, 26 (8), 5882–5888. (59) Tester, C. C.; Brock, R. E.; Wu, C.-H.; Krejci, M. R.; Weigand, S.; Joester, D. In Vitro Synthesis and Stabilization of Amorphous Calcium Carbonate (ACC) Nanoparticles within Liposomes. CrystEngComm 2011, 13 (12), 3975–3978. (60) Wang, R. Z.; Addadi, L.; Weiner, S. Design Strategies of Sea Urchin Teeth: Structure, Composition and Micromechanical Relations to Function. Philos. Trans. R. Soc. Lond. B Biol. Sci. 1997, 352 (1352), 469–480. (61) Killian, C. E.; Metzler, R. A.; Gong, Y. U. T.; Olson, I. C.; Aizenberg, J.; Politi, Y.; Wilt, F. H.; Scholl, A.; Young, A.; Doran, A.; et al. Mechanism of Calcite Co-Orientation in the Sea Urchin Tooth. J. Am. Chem. Soc. 2009, 131 (51), 18404–18409. (62) E. A. Minchin. M.A. Materials for a Monograph of the Ascons-I On the Origin and Growth of the Triradiate and Quadriradiate Spicules in the Family Clathrinide. 1898, 40, 469. (63) Herman E. US603226A, April 26, 1898. (64) Levi‐Kalisman Y.; Raz S.; Weiner S.; Addadi L.; Sagi I. Structural Differences Between Biogenic Amorphous Calcium Carbonate Phases Using X‐ray Absorption Spectroscopy. Adv. Funct. Mater. 2002, 12 (1), 43–48. (65) Konrad, F.; Gallien, F.; Gerard, D. E.; Dietzel, M. Transformation of Amorphous Calcium Carbonate in Air. Cryst. Growth Des. 2016, 16 (11), 6310–6317. (66) Wolf, S. E.; Leiterer, J.; Pipich, V.; Barrea, R.; Emmerling, F.; Tremel, W. Strong Stabilization of Amorphous Calcium Carbonate Emulsion by Ovalbumin: Gaining Insight into the Mechanism of ‘Polymer-Induced Liquid Precursor’ Processes. J. Am. Chem. Soc. 2011, 133 (32), 12642–12649. (67) Homeijer, S. J.; Barrett, R. A.; Gower, L. B. Polymer-Induced Liquid-Precursor (PILP) Process in the Non-Calcium Based Systems of Barium and Strontium Carbonate. Cryst. Growth Des. 2010, 10 (3), 1040–1052. (68) Wolf, S. L. P.; Jähme, K.; Gebauer, D. Synergy of Mg2+ and Poly(Aspartic Acid) in Additive-Controlled Calcium Carbonate Precipitation. CrystEngComm 2015, 17 (36), 6857–6862. (69) Rodriguez-Navarro, C.; Kudłacz, K.; Cizer, Ö.; Ruiz-Agudo, E. Formation of Amorphous Calcium Carbonate and Its Transformation into Mesostructured Calcite. CrystEngComm 2015, 17 (1), 58–72. (70) Gebauer, D.; Völkel, A.; Cölfen, H. Stable Prenucleation Calcium Carbonate Clusters. Science 2008, 322 (5909), 1819–1822. (71) Gebauer, D.; Gunawidjaja, P. N.; Ko, J. Y. P.; Bacsik, Z.; Aziz, B.; Liu, L.; Hu, Y.; Bergström, L.; Tai, C.-W.; Sham, T.-K.; et al. Proto-Calcite and Proto-Vaterite in Amorphous Calcium Carbonates. Angew. Chem. Int. Ed. 2010, 49 (47), 8889–8891. (72) Farhadi-Khouzani, M.; Chevrier, D. M.; Zhang, P.; Hedin, N.; Gebauer, D. Water as the Key to Proto-Aragonite Amorphous CaCO3. Angew. Chem. Int. Ed. 2016, 55 (28), 8117–8120. (73) Gebauer, D.; Cölfen, H. Prenucleation Clusters and Non-Classical Nucleation. Nano Today 2011, 6 (6), 564–584. (74) Gebauer, D.; Kellermeier, M.; Gale, J. D.; Bergström, L.; Cölfen, H. Pre-Nucleation Clusters as Solute Precursors in Crystallisation. Chem. Soc. Rev. 2014, 43 (7), 2348–2371. (75) Purgstaller, B.; Konrad, F.; Dietzel, M.; Immenhauser, A.; Mavromatis, V. Control of Mg2+/Ca2+ Activity Ratio on the Formation of Crystalline Carbonate Minerals via an Amorphous Precursor. Cryst. Growth Des. 2017, 17 (3), 1069–1078. (76) Demichelis, R.; Raiteri, P.; Gale, J. D.; Quigley, D.; Gebauer, D. Stable Prenucleation Mineral Clusters Are Liquid-like Ionic Polymers. Nat. Commun. 2011, 2, 590. (77) Vekilov, P. G. The Two-Step Mechanism of Nucleation of Crystals in Solution. Nanoscale 2010, 2 (11), 2346–2357. (78) Becker, R.; Döring, W. Kinetische Behandlung Der Keimbildung in Übersättigten Dämpfen. Ann. Phys. 1935, 416 (8), 719–752. (79) Beischer, D. Kinetik Der Phasenbildung. Von Prof. Dr. M. Volmer. (Die Chemische Reaktion, Bd. 4.) 220 Seiten Mit 61 Abbildungen Und 15 Tabellen. Format 8°. Verlag Theodor Steinkopff, Dresden 1939. Preis Geb. RM 20.—, Brosch. RM 19 —. Z. Für Elektrochem. Angew. Phys. Chem. 1940, 46 (5), 327–327. (80) Lothe, J.; Pound, G. M. Reconsiderations of Nucleation Theory. J. Chem. Phys. 1962, 36 (8), 2080–2085. (81) A.J.Bradley, W.F.Cox & H.J.Goldschmidt, An X-Ray Study of the Iron-Copper-Nickel Equilibrium Diagram at Various Temperatures; J.Institute Metals, 1941, 67, 189-201. (82) Cölfen, H.; Mann, S. Higher-Order Organization by Mesoscale Self-Assembly and Transformation of Hybrid Nanostructures. Angew. Chem. Int. Ed. 2003, 42 (21), 2350–2365. (83) Zhu, G.; Yao, S.; Zhai, H.; Liu, Z.; Li, Y.; Pan, H.; Tang, R. Evolution from Classical to Non-Classical Aggregation-Based Crystal Growth of Calcite by Organic Additive Control. Langmuir 2016, 32 (35), 8999–9004. (84) Niederberger, M.; Cölfen, H. Oriented Attachment and Mesocrystals: Non-Classical Crystallization Mechanisms Based on Nanoparticle Assembly. Phys. Chem. Chem. Phys. 2006, 8 (28), 3271–3287. (85) Long, X.; Ma, Y.; Qi, L. In Vitro Synthesis of High Mg Calcite under Ambient Conditions and Its Implication for Biomineralization Process. Cryst. Growth Des. 2011, 11 (7), 2866–2873. (86) Politi, Y.; Batchelor, D. R.; Zaslansky, P.; Chmelka, B. F.; Weaver, J. C.; Sagi, I.; Weiner, S.; Addadi, L. Role of Magnesium Ion in the Stabilization of Biogenic Amorphous Calcium Carbonate: A Structure−Function Investigation. Chem. Mater. 2010, 22 (1), 161–166. (87) Raz, S.; Weiner, S.; Addadi, L. Formation of High-Magnesian Calcites via an Amorphous Precursor Phase: Possible Biological Implications. Adv. Mater. 2000, 12 (1), 38–42. (88) Berner, R. A. The Role of Magnesium in the Crystal Growth of Calcite and Aragonite from Sea Water. Geochim. Cosmochim. Acta 1975, 39 (4), 489–504. (89) Fukushi, K.; Munemoto, T.; Sakai, M.; Yagi, S. Monohydrocalcite: A Promising Remediation Material for Hazardous Anions. Sci. Technol. Adv. Mater. 2011, 12 (6). (90) Lin, C.-J.; Yang, S.-Y.; Huang, S.-J.; Chan, J. C. C. Structural Characterization of Mg-Stabilized Amorphous Calcium Carbonate by Mg-25 Solid-State NMR Spectroscopy. J. Phys. Chem. C 2015, 119 (13), 7225–7233. (91) Yang, S.-Y.; Chang, H.-H.; Lin, C.-J.; Huang, S.-J.; Chan, J. C. C. Is Mg-Stabilized Amorphous Calcium Carbonate a Homogeneous Mixture of Amorphous Magnesium Carbonate and Amorphous Calcium Carbonate? Chem. Commun. 2016, 52 (77), 11527–11530. (92) Lenders, J. J. M.; Dey, A.; Bomans, P. H. H.; Spielmann, J.; Hendrix, M. M. R. M.; de With, G.; Meldrum, F. C.; Harder, S.; Sommerdijk, N. A. J. M. High-Magnesian Calcite Mesocrystals: A Coordination Chemistry Approach. J. Am. Chem. Soc. 2012, 134 (2), 1367–1373. (93) Isa, Y.; Okazaki, M. Some Observations on the Ca2+-Binding Phospholipid from Scleractinian Coral Skeletons. Comp. Biochem. Physiol. Part B Comp. Biochem. 1987, 87 (3), 507–512. (94) Huster, D.; Arnold, K.; Gawrisch, K. Strength of Ca2+ Binding to Retinal Lipid Membranes: Consequences for Lipid Organization. Biophys. J. 2000, 78 (6), 3011–3018. (95) Mao, Y.; Du, Y.; Cang, X.; Wang, J.; Chen, Z.; Yang, H.; Jiang, H. Binding Competition to the POPG Lipid Bilayer of Ca 2+ , Mg 2+ , Na + , and K + in Different Ion Mixtures and Biological Implication. J. Phys. Chem. B 2013, 117 (3), 850–858. (96) Melcrová, A.; Pokorna, S.; Pullanchery, S.; Kohagen, M.; Jurkiewicz, P.; Hof, M.; Jungwirth, P.; Cremer, P. S.; Cwiklik, L. The Complex Nature of Calcium Cation Interactions with Phospholipid Bilayers. Sci. Rep. 2016, 6 (1). (97) East, J. M.; Lee, A. G. Lipid Selectivity of the Calcium and Magnesium Ion Dependent Adenosine Triphosphatase, Studied with Fluorescence Quenching by a Brominated Phospholipid. Biochemistry (Mosc.) 1982, 21 (17), 4144–4151. (98) Membrane Lipid. Wikipedia; 2018. (99) Rietveld, H. M. A Profile Refinement Method for Nuclear and Magnetic Structures. J. Appl. Crystallogr. 1969, 2 (2), 65–71. (100) Rietveld, H. M. The Crystal Structure of Some Alkaline Earth Metal Uranates of the Type M3UO6. Acta Crystallogr. 1966, 20 (4), 508–513. (101) Rietveld, H. M. Line Profiles of Neutron Powder-Diffraction Peaks for Structure Refinement. Acta Crystallogr. 1967, 22 (1), 151–152. (102) The Rietveld Method; Young, R. A., Ed.; International Union of Crystallography monographs on crystallography; International Union of Crystallograhy ; Oxford University Press: [Chester, England] : Oxford ; New York, 1993. (103) Pawley, G. S. Unit-Cell Refinement from Powder Diffraction Scans. J. Appl. Crystallogr. 1981, 14 (6), 357–361. (104) Le Bail, A.; IUCr. The Rietveld method using an experimental profile convoluted by adjustable analytical function http://scripts.iucr.org/cgi-bin/paper?S0108767384089200 (accessed Apr 7, 2018). (105) Khattak, C. P.; Cox, D. E. Profile Analysis of X-Ray Powder Diffractometer Data: Structural Refinement of La0.75Sr0.25CrO3. J. Appl. Crystallogr. 1977, 10 (5), 405–411. (106) Langford, J. I.; Wilson, A. J. C. Scherrer after Sixty Years: A Survey and Some New Results in the Determination of Crystallite Size. J. Appl. Crystallogr. 1978, 11 (2), 102–113. (107) Cox, D. E.; Toby, B. H.; Eddy, M. M. Acquisition of Powder Diffraction Data with Synchrotron Radiation. Aust. J. Phys. 1988, 41 (2), 117–132. (108) Young, R. A.; Wiles, D. B. Profile Shape Functions in Rietveld Refinements. J. Appl. Crystallogr. 1982, 15 (4), 430–438. (109) (3) Can anyone tell me what the information of FWHW in XRD... https://www.researchgate.net/post/Can_anyone_tell_me_what_the_information_of_FWHW_in_XRD_spectra_can_tell_us (accessed Jul 2, 2018). (110) Welcome to the TOPAS documentation! — TOPAS 3.1 documentation http://topas.readthedocs.io/en/latest/ (accessed Jul 2, 2018). (111) Introduction - aims and learning outcomes | MyScope http://www.ammrf.org.au/myscope/tem/introduction/ (accessed Apr 22, 2018). (112) Williams, D. B.; Carter, C. B. Transmission Electron Microscopy: A Textbook for Materials Science, 2nd ed.; Springer US, 2009. (113) Mass, T.; Giuffre, A. J.; Sun, C.-Y.; Stifler, C. A.; Frazier, M. J.; Neder, M.; Tamura, N.; Stan, C. V.; Marcus, M. A.; Gilbert, P. U. P. A. Amorphous Calcium Carbonate Particles Form Coral Skeletons. Proc. Natl. Acad. Sci. 2017, 114 (37), E7670–E7678. (114) Nilsson, A.; Nordlund, D.; Waluyo, I.; Huang, N.; Ogasawara, H.; Kaya, S.; Bergmann, U.; Näslund, L.-Å.; Öström, H.; Wernet, P.; et al. X-Ray Absorption Spectroscopy and X-Ray Raman Scattering of Water and Ice; an Experimental View. J. Electron Spectrosc. Relat. Phenom. 2010, 177 (2), 99–129. (115) X-Ray Absorption and X-Ray Emission Spectroscopy: Theoryand Applications; Bokhoven, J. A. van, Lamberti, C., Eds.; John Wiley & Sons, Inc: Chichester, West Sussex, 2016. (116) German, R. M.; Suri, P.; Park, S. J. Review: Liquid Phase Sintering. J. Mater. Sci. 2009, 44 (1), 1–39. (117) German, R. M. Coarsening in Sintering: Grain Shape Distribution, Grain Size Distribution, and Grain Growth Kinetics in Solid-Pore Systems. Crit. Rev. Solid State Mater. Sci. 2010, 35 (4), 263–305. (118) Kingery, W. D. Densification during Sintering in the Presence of a Liquid Phase. I. Theory. J. Appl. Phys. 1959, 30 (3), 301–306. (119) Kingery, W. D.; Narasimhan, M. D. Densification during Sintering in the Presence of a Liquid Phase. II. Experimental. J. Appl. Phys. 1959, 30 (3), 307–310. (120) Niemi, A. N.; Courtney, T. H. Settling in Solid-Liquid Systems with Specific Application to Liquid Phase Sintering. Acta Metall. 1983, 31 (9), 1393–1401. (121) EDS SEM http://www.vcbio.science.ru.nl/en/fesem/eds/ (accessed May 25, 2018). (122) Levitt, M. H. Spin Dynamics: Basics of Nuclear Magnetic Resonance; Wiley, 2001. (123) 科学网—CP----交叉极化固体核磁共振技术简介 - 朱清仁的博文 http://blog.sciencenet.cn/blog-655140-509089.html (accessed Apr 28, 2018). (124) Pitzer, K. S. Thermodynamics of Electrolytes. I. Theoretical Basis and General Equations. J. Phys. Chem. 1973, 77 (2), 268–277. (125) Pitzer, K. S.; Mayorga, G. Thermodynamics of Electrolytes. II. Activity and Osmotic Coefficients for Strong Electrolytes with One or Both Ions Univalent. J. Phys. Chem. 1973, 77 (19), 2300–2308. (126) Pitzer, K. S. Electrolyte Theory - Improvements since Debye and Hueckel. Acc. Chem. Res. 1977, 10 (10), 371–377. (127) Activity Coefficients in Electrolyte Solutions; Pytkowicz, R. M., Ed.; CRC Press: Boca Raton, 1979. (128) Merkel, B. J.; Planer-Friedrich, B. Groundwater Geochemistry: A Practical Guide to Modeling of Natural and Contaminated Aquatic Systems, 2nd ed.; Nordstrom, D. K., Ed.; Springer-Verlag: Berlin Heidelberg, 2008. (129) Goldsmith, J. R.; Graf, D. L.; Joensuu, O. I. The Occurrence of Magnesian Calcites in Nature. Geochim. Cosmochim. Acta 1955, 7 (5), 212–230. (130) Julian R. Goldsmith, Donald L. Graf with Additional Analytical Determinations by A. A. Chodos, O. I. Joensuu and L. D. McVickeR ELATION BETWEEN LATTICE CONSTANTS AND COMPOSITION OF THE Ca-Mg CARBONATES. Ther American Mineralogist. 1958, 43, 84-101. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/71070 | - |
dc.description.abstract | 高鎂含量方解石介晶普遍存在於生物礦物中,但難以用實驗合成出來。在本實驗中,通過非晶態含鎂碳酸鈣 (MgACC) 在脂質水溶液中的相轉化,成功合成出高鎂方解石介晶。利用穿透式電子顯微鏡的選定區域電子衍射圖以及暗場推斷出MgACC利用二次成核形成了介晶的結構,除了相轉化的探討,還結合其他分析技術,如SEM、TXM、NMR、HRXRD等,探討脂質在溶液中扮演的角色以及雙半球構形的生長機制,發現脂質可能與碳酸鈣有特殊的作用力,而雙半球的形成可能與液相燒結 (LPS) 機制有關。除了溶液狀態時的相轉化探討外,本研究還涉及樣品在高濕度下的相轉化,發現部分實驗條件樣品會在此環境下長出fiber的結構,可能為後續長出spicule的中間態。
本實驗第二部分利用XANES變溫實驗在高真空以及0.4 mbar水氣的環境來研究ACC相轉過程,發現環境水的是ACC相轉的關鍵,且ACC的相轉可能為相轉帶動脫水,而非脫水帶動相轉。 | zh_TW |
dc.description.abstract | Mesocrystals of high-magnesium calcites are commonly found in biominerals but are difficult to prepare in vitro under ambient conditions. In this work, mesocrystals of high-magnesium calcite were successfully synthesized through the phase transformation of magnesian amorphous calcium carbonate (Mg-ACC) in aqueous solution with lipids. From the selected area electron diffraction patterns and the dark field transmission electron microscopic images, we infer that the mesocrystals are formed via the solid-state secondary nucleation within Mg-ACC. The role of lipids in the phase transformation process was studied by 13C and 31P NMR spectroscopy. We also investigate the phase transition of ACC by X-ray absorption spectroscopy (XAS). In particular, ACC was characterized by XAS at different temperatures under either ultra high vacuum or a water atmosphere of 0.4 mbar. We found that moisture in the environment is the key for the phase transition of ACC. | en |
dc.description.provenance | Made available in DSpace on 2021-06-17T04:51:27Z (GMT). No. of bitstreams: 1 ntu-107-R05223155-1.pdf: 7243067 bytes, checksum: 9081a592ab04fffde09cefa520e0a608 (MD5) Previous issue date: 2018 | en |
dc.description.tableofcontents | 國立臺灣大學(碩)博士學位論文口試委員會審定書 I
致謝 II 摘要 IV Abstract V 目錄 VI 圖目錄 XIII 表目錄 XVIII 第一章 緒論 1 1.1 生物礦化概要 1 1.2 碳酸鈣 2 1.2.1非晶態碳酸鈣 2 1.2.1A重要性 2 1.2.1B 穩定性 4 1.2.1C 結構 4 1.2.2 成核前團簇 (Prenucleation cluster, PNC) 6 1.3 生物礦化的機制 7 1.3.1 結晶理論 7 1.3.1A 古典成核理論 (Classical nucleation theory, CNT) 7 1.3.1B 旋節分解 10 1.3.1C 兩步驟成核 10 1.3.1D 非古典成核理論 11 1.3.2 熱力學及動力學 11 1.4 鎂的影響 12 1.4.1 含鎂碳酸鈣演化的機制 12 1.4.2 含鎂碳酸鈣的結構 15 1.4.2A 含鎂非晶態碳酸鈣 15 1.4.2B 含鎂方解石 16 1.5 脂質 16 1.6動機 17 第二章 理論基礎 18 2.1 X光結晶學 18 2.1.1 Rietveld analysis介紹 19 2.1.1A勞倫茲因子 (Lorentz factor, L) 20 2.1.1B偏極化因子 (Polarization factor, P) 20 2.1.1C多重因子 (Multiplicity factor) 21 2.1.1D結構因子 (Structure factor) 21 2.1.1E溫度因子 (Temperature factor) 21 2.1.1F吸收因子 (Absorption factor) 22 2.1.1G峰型函數 (Profile function) 22 2.1.1H擇優取向 (Preferred orientation) 23 2.1.2擬合的結果 23 2.1.3 粒徑 24 2.2 TEM對比 26 2.2.1質量對比 28 2.2.2繞射對比 28 2.2.3相位對比 29 2.3碳酸鈣的X光吸收光譜 29 2.3.1 XANES介紹 30 2.3.1A穿透模式 (transmission mode) 30 2-3.1B螢光模式 (fluorescence mode) 31 2-3.1C電子產率 (electron yield, EY) 31 2.3.2 碳酸鈣Ca L2,3 edge XANES原理介紹 33 2.4 液相燒結(Liquid phase sintering) 33 第三章 實驗儀器及方法 36 3.1 化學藥品 36 3.2 實驗儀器 37 3.2.1粉末X光繞射 (X-ray powder diffraction, XRD) 37 3.2.2傅立葉轉換紅外線光譜儀 (Fourier transform infrared spectroscopy, FT-IR) 38 3.2.3感應耦合電漿質譜儀 (Inductively coupled plasma mass spectroscopy, ICP-MS) 39 3.2.4光學顯微鏡 (Optical microscopy, OM) 39 3.2.5掃描式電子顯微鏡 (Scanning electron microscopy, SEM) 39 3.2.6聚焦離子束研磨 (Focused ion beam milling, FIB) 41 3.2.7穿透式電子顯微鏡 (Transmission electron microscopy, TEM) 41 3.2.8 X光能量散色光譜儀 (Energy-dispersive x-ray spectrometer, EDS) 41 3.2.9固態核磁共振光譜 (Solid-state nuclear magnetic resonance, SSNMR) 41 3.2.9A魔角旋轉(Magic Angle Spinning, MAS) 42 3.2.9B交叉極化 (Cross Polarization, CP) 43 3.2.9C Bloch decay 44 3.2.10熱重分析儀 (Thermogravimetric analysis, TGA) 45 3.2.11差示掃描量熱法 (Differential scanning calorimetry, DSC) 45 3.2.12 NSRRC穿透式X光顯微術 (Transmission X-ray microscopy, TXM) 45 3.2.13 NSRRC X光高解析度粉末繞射 (High-resolution powder X-ray diffraction, HRXRD) 46 3.2.14 NSRRC X光吸收光譜 (X-ray absorption spectroscopy, XAS) 46 3.3 實驗軟體 46 3.3.1 Phreeqc 46 3.3.2 GSAS-II 47 3.3.3 Mercury 48 3.3.4 Digital micrograph 48 3.3.5 ImageJ 48 3.3.6 Fox 48 3.4 實驗方法 48 3.4.1含鎂碳酸鈣演化探討 49 3.4.1A含有lipid含鎂碳酸鈣的製備 49 3.4.1B無lipid控制組含鎂碳酸鈣的製備 50 3.4.1C含鎂碳酸鈣的熟化 50 3.4.2 XANES實驗設計 50 3-4.2A MgACC的製備 50 3-4.2B ACC的製備 51 3-4.2C XANES圖譜擬合流程 51 3.4.3 GSAS-II流程 51 第四章 結果與討論 53 4.1 含鎂碳酸鈣水溶液中的演化 53 4.1.1 相演化以及鎂含量的探討 53 4.1.2 Mesocrystal之含鎂方解石的形成及論證 55 4.1.3脂質在系統中的角色 64 4.1.4含鎂碳酸鈣雙半球構形的探討 71 4.1.5含鎂碳酸鈣細微結構的探討 77 4.1.5A MgACC 77 4.1.5B Mg-calcite 79 4.1.6小結 81 4.2 含鎂碳酸鈣空氣中的演化 81 4.3 非晶態碳酸鈣相演化 86 4.3.1不同鎂含量MgACC的XANES光譜探討 86 4.3.2 ACC變溫XANES實驗 87 第五章 結論與未來展望 92 附錄 94 A. X光粉末繞射基本公式證明 94 A.1電子散射 94 A.2原子散射 95 A.3一塊小晶體散射 97 A.4溫度震動的影響 99 A.5小晶體散射的積分強度 101 A.6粉末樣品的積分強度 104 B. Mg-calcite的Rietveld analysis探討 106 C. Ca L2,3-edge XANES變溫實驗數據擬合結果 110 參考資料 113 | |
dc.language.iso | zh-TW | |
dc.title | 非晶態碳酸鈣相演化與含鎂方解石介晶之形成機制 | zh_TW |
dc.title | Phase evolution of amorphous calcium carbonate and the formation mechanism of Mg-calcite mesocrystals | en |
dc.type | Thesis | |
dc.date.schoolyear | 106-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 林弘萍,鄭淑芬,許益瑞 | |
dc.subject.keyword | 非晶態含鎂碳酸鈣,高鎂方解石介晶,暗場成像,液相燒結,Rietveld analysis,非晶態碳酸鈣,XANES, | zh_TW |
dc.subject.keyword | magnesian amorphous calcium carbonate,mesocrystals of high-magnesium calcites,dark field image,Rietveld analysis,amorphous calcium carbonate,XANES, | en |
dc.relation.page | 129 | |
dc.identifier.doi | 10.6342/NTU201802132 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2018-07-31 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 化學研究所 | zh_TW |
顯示於系所單位: | 化學系 |
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