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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
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dc.contributor.advisor | 宋聖榮(Sheng-Rong Song) | |
dc.contributor.author | Kun-Yi Lin | en |
dc.contributor.author | 林坤誼 | zh_TW |
dc.date.accessioned | 2021-06-17T04:30:23Z | - |
dc.date.available | 2020-08-18 | |
dc.date.copyright | 2018-08-18 | |
dc.date.issued | 2018 | |
dc.date.submitted | 2018-08-13 | |
dc.identifier.citation | 林昆霖 (2013),肉眼看不見的奈米級材料及元件檢測分析就靠穿透式電子顯微鏡。國家奈米元件實驗室奈米通訊,第20期,34-38頁。
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R., Nielsen, S., Sheu, H. S., & Si, J. (2014). Gouge graphitization and dynamic fault weakening during the 2008 Mw 7.9 Wenchuan earthquake. Geology, 42(1), 47-50. doi:10.1130/g34862.1 Kušnír, I. (2000). Mineral resources of Vietnam. Acta Montanistica Slovaca, 2, 165-172. Lahfid, A., Beyssac, O., Deville, E., Negro, F., Chopin, C., & Goffé, B. (2010). Evolution of the Raman spectrum of carbonaceous material in low-grade metasediments of the Glarus Alps (Switzerland). Terra Nova, 22(5), 354-360. doi:10.1111/j.1365-3121.2010.00956.x Langford, J., Boultif, A., Auffrédic, J., & Louër, D. (1993). The use of pattern decomposition to study the combined X‐ray diffraction effects of crystallite size and stacking faults in ex‐oxalate zinc oxide. Journal of Applied Crystallography, 26(1), 22-33. Li, H. B., Wang, H., Xu, Z. Q., Si, J. L., Pei, J. L., Li, T. F., Huang, Y., Song, S. R., Kuo, L. W., Sun, Z. M., Chevalier, M. L., & Liu, D. L. (2013). Characteristics of the fault-related rocks, fault zones and the principal slip zone in the Wenchuan Earthquake Fault Scientific Drilling Project Hole-1 (WFSD-1). Tectonophysics, 584, 23-42. doi:10.1016/j.tecto.2012.08.021 Li, S. S. & Teng, M. H.(2015). Study on purification and surface modification procedures of graphite encapsulated iron nanoparticles, Hans Journal of Nanotechnology, 5(4): 63-70 Marsh, H. (1991). A tribute to Philip L. Walker. Carbon, 29(6), 703-704. McMillan, P. F. (1989). Raman Spectroscopy in Mineralogy and Geochemistry. Annual Review of Earth and Planetary Sciences, 17, 255-283. Oohashi, K., Hirose, T., Kobayashi, K., & Shimamoto, T. (2012). The occurrence of graphite-bearing fault rocks in the Atotsugawa fault system, Japan: Origins and implications for fault creep. Journal of Structural Geology, 38, 39-50. Oohashi, K., Hirose, T., & Shimamoto, T. (2011). Shear-induced graphitization of carbonaceous materials during seismic fault motion: Experiments and possible implications for fault mechanics. Journal of Structural Geology, 33(6), 1122-1134. Pei, J. L., Zhou, Z. Z., Li, H. B., Wang, H., Liu, F., Sheng, M., & Zhao, Y. (2016). New evidence of repeated earthquakes along Wenchuan earthquake fault zone. Geology in China (in Chinese), 43(1), 43-55. Pimenta, M. A., Dresselhaus, G., Dresselhaus, M. S., Cancado, L. G., Jorio, A., & Saito, R. (2007). Studying disorder in graphite-based systems by Raman spectroscopy. Phys Chem Chem Phys, 9(11), 1276-1291. doi:10.1039/b613962k Rahl, J., Anderson, K., Brandon, M., & Fassoulas, C. (2005). Raman spectroscopic carbonaceous material thermometry of low-grade metamorphic rocks: Calibration and application to tectonic exhumation in Crete, Greece. Earth and Planetary Science Letters, 240(2), 339-354. doi:10.1016/j.epsl.2005.09.055 Ross, J. V., & Bustin, R. M. (1990). The role of strain-Energy in creep graphitization of anthracite. Nature, 343(6253), 58-60. Rouzaud, J.N., & Oberlin, A. (1989). Structure, microtexture, and optical properties of anthracene and saccharose-based carbons. Carbon, 27(4), 517-529. Sheppard, R. G., Mathes, D. M., & Bray, D. J. (2001). Properties and characteristics of graphite for industrial applications. Poco Graphite, 5-7. Shi, H., Barker, J., Saidi, M. Y., & Koksbang, R. (1996). Structure and lithium intercalation properties of synthetic and natural graphite. Journal of the Electrochemical Society, 143(11), 3466-3472. Togo, T., Shimamoto, T., Ma, S. L., Wen, X. Z., & He, H. L. (2011). Internal structure of Longmenshan fault zone at Hongkou outcrop, Sichuan, China, that caused the 2008 Wenchuan earthquake. Earthquake Science, 24(3), 249-265. doi:10.1007/s11589-011-0789-z Tuinstra, F., & Koenig, J. L. (1970). Raman Spectrum of Graphite. 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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/70532 | - |
dc.description.abstract | 由碳質物轉變而成的石墨化現象是一個受溫度大幅影響的過程,且其反應被認為是不可逆的,能夠記錄岩石中石墨形成時的最高溫度。因此,這是一種能夠廣泛用於決定地層中變質作用發生時之峰值溫度的溫度計。石墨在不同變質地區的最高變質溫度是以石榴子石-黑雲母、鐵-鎂元素分配地質溫度計以及磷灰石核飛跡溫度計來進行估算。結果顯示峰值溫度與拉曼光譜中之三個拉曼光譜帶參數G band(Graphite band)、D1 band(Defect band 1)與D2 band(Defect band 2)之間呈線性關係。除了變質區域外,近幾年對於2008年汶川地震的研究中顯示,石墨化作用能夠在地震斷層的滑移帶出現(Togo et al., 2011),指示石墨可能不僅只在傳統的變質條件下形成。
本研究以非晶質碳質物作為原始材料,並在400°C至900°C的溫度範圍內通氮氣進行處理,實驗時間為2至6小時。每個實驗分別以改變溫度和實驗時間進行處理來避免偏差,並以拉曼光譜、X光繞射與穿透式電子顯微來分析非晶質碳質物之石墨化過程。實驗結果顯示,當非晶質碳質物在經過2小時處理後,隨著溫度的升高,拉曼光譜的R1比例(D1 / G)與溫度之間存在線性關係,然而當回到室溫後,高溫處理過程無法完整記錄在碳質物中。X光繞射資料顯示石墨晶格面(100)和晶格面(101)在處理之後出現峰值,表示天然的石墨化從晶格面(100)和晶格面(101)這兩種結構開始產生,而不是從人造石墨的特徵晶格面(002)結構面開始。因此本研究顯示石墨化現象可能無法記錄最高溫度,並且一部分石墨化現象在冷卻後是可逆的。 | zh_TW |
dc.description.abstract | Graphitization, the conversion of carbonaceous material to graphite, is considered to be an irreversible process that is independent of pressure but strongly dependent on temperature and records the highest temperature of graphite genesis. Therefore, it is often used as a geothermometer to determine the peak temperature of metamorphism in the strata. The highest temperatures achieved in different metamorphic areas were mainly estimated by the results of garnet-biotite Fe-Mg partitioning geothermometer, and apatite fission track thermometers. Studies show that the peak temperature has a linear relationship with Raman bands:G band(Graphite band)、D1 band(Defect band 1)and D2 band(Defect band 2). Graphitization has been reported in slip zones of seismic faulting, e.g. the 2008 Wenchuan earthquake, insinuating that graphite may form outside of traditional metamorphic conditions.
In this study, amorphous carbon samples were chosen as starting materials and treated at temperatures ranging from 400°C to 900°C for 2 to 6 hours. In each experiment, either temperature or experiment time was chosen as the control variable in order to avoid deviation. The TEM, Raman spectra analyzer, and X-ray diffraction were used to analyze the graphitization process of amorphous carbon. In-situ analyses indicate a positive correlation between temperature and Raman R1 ratio (D1/G) as the temperature increases during 2 hours of treatment. However, this correlation seems to be not preserved once annealed to room temperature. After being treated, the X-ray diffraction patterns of graphite (100) and (101) peaks are significant, suggesting that natural graphitization initiates at (100) and (101) instead of the synthetic graphite characteristic (002) peak. Graphitization, therefore, might not record the highest temperature, and a portion of graphite may be reversible after cooling. | en |
dc.description.provenance | Made available in DSpace on 2021-06-17T04:30:23Z (GMT). No. of bitstreams: 1 ntu-107-R05224111-1.pdf: 7516410 bytes, checksum: 057598e3176f35f80fcc5f3ebd5d4d9c (MD5) Previous issue date: 2018 | en |
dc.description.tableofcontents | 口試委員會審定書 i
誌謝 ii 中文摘要 iii ABSTRACT iv 目錄 vi 圖目錄 viii 表目錄 ix 第一章 緒論 - 1 - 1.1前言 - 1 - 1.2研究背景 - 2 - 1.2.1石墨化作用 - 2 - 1.2.2石墨與碳質物 - 3 - 1.3前人研究 - 4 - 1.3.1拉曼地質溫度計 - 4 - 1.3.2汶川斷層泥研究 - 6 - 1.4 研究目的 - 8 - 第二章 研究材料與方法 - 9 - 2.1研究方法總論 - 9 - 2.2研究材料 - 10 - 2.3實驗儀器與處理方法 - 13 - 2.3.1拉曼光譜分析 - 14 - 2.3.2 X光粉末繞射分析 - 17 - 2.3.3穿透式電子顯微分析 - 17 - 第三章 分析結果 - 20 - 3.1實驗條件與結果 - 20 - 3.1.1溫度對石墨化影響之模擬實驗 - 20 - 3.1.2時間對石墨化影響之模擬實驗 - 20 - 3.2拉曼光譜儀實驗結果 - 20 - 3.2.1 SMU、KLVG-BH05、LK:低度石墨化樣本 - 21 - 3.2.2 GPS:高度石墨化樣本 - 28 - 3.2.3 JL、WFSD-1:斷層泥樣本 - 31 - 3.3 XRD粉末繞射實驗結果 - 38 - 3.3.1 SMU、KLVG-BH05、LK:低度石墨化樣本 - 39 - 3.3.2 GPS、JL、WFSD-1:高度石墨化樣本與斷層泥樣本 - 45 - 3.3.3 Carbon black、graphite electrode:人造碳黑與石墨 - 51 - 3.4穿透式電子顯微實驗結果 - 52 - 3.4.1 SMU:低度石墨化樣本 - 52 - 3.4.2 JL:九龍地表斷層泥 - 54 - 3.4.3 GPS:和平石墨片岩 - 55 - 第四章 討論 - 56 - 4.1不同碳質物在加熱處理前後之石墨化現象 - 56 - 4.1.1拉曼光譜中的石墨化現象 - 56 - 4.1.2 X光繞射中的石墨化現象 - 59 - 4.1.3 穿透式電子顯微中的石墨化現象 - 63 - 4.2石墨化現象與溫度、時間的關係 - 63 - 4.3天然碳質物與人造碳質物的差異 - 64 - 4.4人造石墨中不同製程所造成的訊號差異 - 64 - 4.5不同石墨化程度之碳質物特徵比較及其隱示 - 65 - 第五章 結論 - 66 - 參考文獻 - 68 - 附錄一、拉曼光譜參數資料 - 72 - 附錄二、X光繞射參數資料 - 75 - 附錄三、ICSD、COD石墨結構參數資料 - 76 - 附錄四、EDS元素分析 - 77 - | |
dc.language.iso | zh-TW | |
dc.title | 非晶質碳質物之石墨化現象 | zh_TW |
dc.title | Graphitization of Amorphous Carbonaceous Materials | en |
dc.type | Thesis | |
dc.date.schoolyear | 106-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 劉瑩三(Ying-San Liou),郭力維(Li-Wei Kuo),江威德(Wei-Teh Jiang),黃怡禎(Eugene Huang) | |
dc.subject.keyword | 非晶質碳,碳質物拉曼光譜,X光繞射,石墨化作用,加熱模擬滑移帶, | zh_TW |
dc.subject.keyword | Amorphous carbon,Raman spectrum of carbonaceous materials (RSCM),X-ray diffraction,graphitization,heating simulation of slip zone, | en |
dc.relation.page | 79 | |
dc.identifier.doi | 10.6342/NTU201802595 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2018-08-13 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 地質科學研究所 | zh_TW |
顯示於系所單位: | 地質科學系 |
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