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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/69687完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 謝馬利歐(Mario Hofmann) | |
| dc.contributor.author | Yi-Chun Chin | en |
| dc.contributor.author | 秦逸群 | zh_TW |
| dc.date.accessioned | 2021-06-17T03:23:50Z | - |
| dc.date.available | 2023-06-13 | |
| dc.date.copyright | 2018-06-13 | |
| dc.date.issued | 2018 | |
| dc.date.submitted | 2018-06-08 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/69687 | - |
| dc.description.abstract | 力學削切方法從3維材料得到2維材料已有不少文獻回報，因其簡易及可大量生產等優點而獲得重視。然而如何從削切所得之2維材料再進一步做成勻質薄膜乃至應用在電子元件上仍未完整了解。此篇論文將會研究純石墨烯在水-大氣介面上的成膜機置、構型及其電子元件特性。借由Langmuir-Blodgett (L-B)方法，我們發現一種全新且不可逆的緊密排列石墨烯薄膜。此外，我們也觀測到於高擠壓下，此固相膜會產生週期性的側潰現象。這些特殊之物理表現使我們發現一些新的製成手法。轉印於矽基板和玻璃後之光學、電子及原子力顯微鏡量測，證明此法有辦法達到大面積、勻質、輕薄等優異之特性，使其有未來應用於電子元件之可適性。 | zh_TW |
| dc.description.abstract | Exfoliation of 3-dimensional bulk to 2-dimensional material has been reported for years, and it is easily achieved to mass production. However, creating uniform thin films from exfoliated 2-dimensional material is one of the biggest challenges to utilizing it in many applications, such as transparent conducting film (TCF). In this thesis we study the behavior of pristine graphene films on the water-air interface through Langmuir-Blodgett method. We identify a novel morphological solid phase where graphene flakes form continuous and irreversibly connected films that are surprisingly stable. Under higher mechanical compression, those closely packed graphene films buckle with a periodic shape, but they are elastic enough to restore back to the irreversible films. Some fabrication techniques are discovered with these special behaviors. Upon transfer, we characterize its quality by optical microscope, SEM and AFM measurements. The data show that Langmuir-Blodgett graphene film is thin and uniform, and suitable for large scale electronics applications. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T03:23:50Z (GMT). No. of bitstreams: 1 ntu-107-R05222022-1.pdf: 32856287 bytes, checksum: f3eb48dd1e964886fb025008059928c5 (MD5) Previous issue date: 2018 | en |
| dc.description.tableofcontents | 口試委員會審定書 i
摘要 ii Abstract iii List of Figures vii List of Tables ix 1 Introduction 1 1.1 Graphene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.2 Transparent conducting thin film . . . . . . . . . . . . . . . . . . . . . . 2 1.3 Graphene fabrication techniques . . . . . . . . . . . . . . . . . . . . . . 3 1.4 Graphene flake deposition methods . . . . . . . . . . . . . . . . . . . . . 5 1.4.1 Spray coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 1.4.2 Casting and spin coating . . . . . . . . . . . . . . . . . . . . . . 6 1.5 Langmuir-Blodgett method . . . . . . . . . . . . . . . . . . . . . . . . . 7 1.5.1 Theoretical background . . . . . . . . . . . . . . . . . . . . . . 8 1.5.2 Subphase and insoluble molecules . . . . . . . . . . . . . . . . . 9 1.5.3 Surface tension measurement . . . . . . . . . . . . . . . . . . . 10 1.5.4 Different phases under compression . . . . . . . . . . . . . . . . 13 1.5.5 Deposition and layer controls . . . . . . . . . . . . . . . . . . . 14 2 Experimental Detail and Material Preparation 17 2.1 Graphene exfoliation . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 2.2 Centrifugation and separation . . . . . . . . . . . . . . . . . . . . . . . . 19 2.3 Graphene film preparation . . . . . . . . . . . . . . . . . . . . . . . . . 20 2.3.1 Syringe pump stage . . . . . . . . . . . . . . . . . . . . . . . . . 21 2.3.2 Ultrasonication . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 2.4 Langmuir film and Langmuir-Blodgett method . . . . . . . . . . . . . . 23 2.4.1 Wilhelmy plate preparation . . . . . . . . . . . . . . . . . . . . . 24 2.4.2 Trough preparation . . . . . . . . . . . . . . . . . . . . . . . . . 26 2.4.3 Asymmetric compression . . . . . . . . . . . . . . . . . . . . . . 27 2.4.4 Isothermal measurement . . . . . . . . . . . . . . . . . . . . . . 28 2.4.5 Substrate choices . . . . . . . . . . . . . . . . . . . . . . . . . . 28 2.4.6 Langmuir-Blodgett film deposition . . . . . . . . . . . . . . . . 29 2.5 Characterization instruments . . . . . . . . . . . . . . . . . . . . . . . . 31 2.5.1 Optical microscope . . . . . . . . . . . . . . . . . . . . . . . . . 31 2.5.2 Raman spectroscopy . . . . . . . . . . . . . . . . . . . . . . . . 32 2.5.3 Scanning electron microscopy . . . . . . . . . . . . . . . . . . . 33 2.5.4 Atomic force microscopy . . . . . . . . . . . . . . . . . . . . . . 35 2.6 Sheet resistance measurement . . . . . . . . . . . . . . . . . . . . . . . 36 2.6.1 Linear four probes method . . . . . . . . . . . . . . . . . . . . . 36 2.6.2 Van der Pauw method . . . . . . . . . . . . . . . . . . . . . . . 37 3 Results and Discussion 38 3.1 Exfoliated 2-dimensional material films on water . . . . . . . . . . . . . 38 3.1.1 Selective dissolution with NMP . . . . . . . . . . . . . . . . . . 39 3.1.2 Sonicator promoted dissolution . . . . . . . . . . . . . . . . . . 41 3.2 Isothermal behavior of pristine graphene Langmuir films . . . . . . . . . 42 3.2.1 Phase transitions . . . . . . . . . . . . . . . . . . . . . . . . . . 43 3.2.2 Irreversible solid phase and surface tension locking . . . . . . . . 46 3.2.3 Ionic binding . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 3.3 Isothermal behavior of graphene/stearic acid films . . . . . . . . . . . . . 51 3.3.1 Isothermal behavior of pure stearic acid . . . . . . . . . . . . . . 52 3.3.2 Surface tension propagation . . . . . . . . . . . . . . . . . . . . 52 3.4 Film transfer and graphene quality analyzing . . . . . . . . . . . . . . . 54 3.4.1 Morphology for different phases . . . . . . . . . . . . . . . . . . 54 3.4.2 Film thickness and uniformity . . . . . . . . . . . . . . . . . . . 57 3.4.3 Sheet resistance over phases . . . . . . . . . . . . . . . . . . . . 57 4 Summary 59 Bibliography 60 | |
| dc.language.iso | zh-TW | |
| dc.subject | 石墨烯 | zh_TW |
| dc.subject | 表面張力 | zh_TW |
| dc.subject | 等溫相態 | zh_TW |
| dc.subject | L-B膜 | zh_TW |
| dc.subject | Langmuir-Blodgett | en |
| dc.subject | graphene | en |
| dc.subject | surface tension | en |
| dc.subject | isothermal phases | en |
| dc.title | 二維材料於空氣-水界面之膜強度調控研究 | zh_TW |
| dc.title | Tuning of 2D Materials’ Interactions at the Water-Air
Interface | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 106-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 謝雅萍,陳永芳,許佳振 | |
| dc.subject.keyword | L-B膜,石墨烯,表面張力,等溫相態, | zh_TW |
| dc.subject.keyword | Langmuir-Blodgett,graphene,surface tension,isothermal phases, | en |
| dc.relation.page | 66 | |
| dc.identifier.doi | 10.6342/NTU201800751 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2018-06-08 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 物理學研究所 | zh_TW |
| 顯示於系所單位： | 物理學系 | |
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