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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 李岳聯 | |
dc.contributor.author | Pei-Ying Tsai | en |
dc.contributor.author | 蔡佩穎 | zh_TW |
dc.date.accessioned | 2021-06-17T02:38:17Z | - |
dc.date.available | 2022-08-28 | |
dc.date.copyright | 2017-08-28 | |
dc.date.issued | 2017 | |
dc.date.submitted | 2017-08-16 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/68845 | - |
dc.description.abstract | 研究中將不同比例之石墨烯(Graphene)添加至PU塗層中,再將此複合塗層塗佈於鋼底材上進行抗蝕能力與吸音能力分析。利用交流阻抗法以及鹽霧試驗量測不同石墨烯含量對抗蝕能力的影響,並搭配光學顯微鏡及掃瞄式電子顯微鏡觀察塗層微結構,最後再以落沙衝擊試驗、摩擦係數量測,以及拉拔測試、百格測試評估塗層的耐磨耗性與附著力。此外,為量測複合塗層吸音能力,以水下麥克風量測塗層在水下的吸音係數,測試頻率範圍為2K~6K Hz,此為一般潛艦常用的聲波頻段。實驗結果顯示在PU塗層中添加4 wt%及8 wt%石墨烯可以有效提升塗層抗蝕性,但隨著石墨烯含量添加,耐磨性質隨之降低,在吸音方面,添加4 wt%石墨烯有最高的吸音係數,比純PU提高約20%的吸音效果。 | zh_TW |
dc.description.abstract | In this research, different proportions of graphene were added to the PU coating, and the corrosion resistance and sound absorption ability coating were analyzed by the follow tests. The influence of the different contents of graphene coating was characterized by the Electrochemical Impedance Spectroscopy (EIS) and Salt Spray Tests (SST). The microstructure was examined by Optical Microscopy (OM) and Scanning Electron Microscopy (SEM). The falling sand abrasion test, coefficient of friction test, pull-off test and cross-cut tape test were used to evaluate the wear resistant and adhesion of the coatings. In order to characterize the sound absorption ability, we use the underwater impedance tube to measure the underwater sound absorption coefficient, and the frequency range is 2K~6K Hz. The results showed that the additions of 4wt% and 8wt% graphene in the PU coating can effectively improve the corrosion resistance. In the aspect of sound absorption, compared to the neat PU, the sound absorption coefficient increased about 20% when PU coatings combined with 4wt% graphene. | en |
dc.description.provenance | Made available in DSpace on 2021-06-17T02:38:17Z (GMT). No. of bitstreams: 1 ntu-106-R04525074-1.pdf: 6219349 bytes, checksum: 84a65220776ef8f76033274e780cb1be (MD5) Previous issue date: 2017 | en |
dc.description.tableofcontents | 致謝 i
摘要 ii Abstract iii 目錄 iv 圖目錄 vii 表目錄 x 第一章 前言 1 第二章 文獻回顧 2 2-1腐蝕的介紹與分類 2 2-1-1腐蝕的介紹 2 2-1-2腐蝕的分類 5 2-2電化學腐蝕基本理論 13 2-2-1腐蝕熱力學 13 2-2-2腐蝕動力學 14 2-3腐蝕的防治技術 16 2-3-1電化學防蝕法 16 2-3-2表面改質法 18 2-4聚氨酯塗層介紹 20 2-5石墨烯介紹 21 2-5-1石墨烯結構與性能 21 2-5-2石墨烯與高分子複合塗層 23 2-6水下吸聲材料種類與介紹 25 2-6-1水下吸聲基本原理 25 2-6-2水下吸聲材料介紹 26 2-7阻抗管吸音係數量測 28 第三章 實驗方法及步驟 30 3-1實驗儀器介紹 30 3-2材料來源及選用 32 3-3實驗流程 33 3-4塗層製作方法 35 3-5塗層表面微結構分析 36 3-5-1光學顯微鏡觀察與分析 36 3-5-2掃描式電子顯微鏡觀察與分析 37 3-6塗層抗蝕性評估 38 3-6-1交流阻抗量測 38 3-6-2鹽霧試驗量測 40 3-7塗層耐磨性評估 41 3-7-1落砂試驗 41 3-7-2摩擦係數量測 42 3-8塗層附著性評估 42 3-8-1拉拔試驗 43 3-8-2百格試驗 43 3-9塗層吸音效果量測 45 3-9-1阻抗管吸音係數量測 45 3-9-2塗層吸音性質分析 46 第四章 實驗結果與討論 48 4-1塗層表面微結構分析 48 4-1-1光學顯微鏡觀察結果與分析 48 4-1-2掃描式電子顯微鏡觀察結果與分析 49 4-2塗層抗蝕性結果分析 50 4-2-1交流阻抗結果分析 50 4-2-2鹽霧試驗結果分析 57 4-3塗層耐磨性結果分析 63 4-3-1落砂試驗結果分析 63 4-3-2摩擦係數實驗結果分析 65 4-4塗層附著性結果分析 68 4-4-1拉拔試驗結果分析 68 4-4-2百格試驗結果分析 70 4-5塗層吸音係數量測結果分析 72 第五章 結論 81 第六章 未來展望 82 參考文獻 83 | |
dc.language.iso | zh-TW | |
dc.title | 石墨烯添加量對高分子塗層抗蝕及吸音能力之影響 | zh_TW |
dc.title | Effect of graphene addition on corrosion resistance and sound absorption of polymer coatings | en |
dc.type | Thesis | |
dc.date.schoolyear | 105-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 王朝正,林招松,黃心豪 | |
dc.subject.keyword | 石墨烯,聚氨酯,吸音塗層,抗蝕,交流阻抗, | zh_TW |
dc.subject.keyword | Graphene,Polyurethane,Sound absorption coating,Anti-corrosion,EIS, | en |
dc.relation.page | 88 | |
dc.identifier.doi | 10.6342/NTU201703664 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2017-08-17 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 工程科學及海洋工程學研究所 | zh_TW |
顯示於系所單位: | 工程科學及海洋工程學系 |
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