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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳浩銘(Hao Ming Chen) | |
| dc.contributor.author | Yu-Ping Huang | en |
| dc.contributor.author | 黃宇屏 | zh_TW |
| dc.date.accessioned | 2021-06-17T02:20:21Z | - |
| dc.date.available | 2025-08-17 | |
| dc.date.copyright | 2020-08-24 | |
| dc.date.issued | 2020 | |
| dc.date.submitted | 2020-08-18 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/68416 | - |
| dc.description.abstract | 近年來能源議題已成為熱門研究主題，如何從自然界中有效獲取並儲存各種再生能源將會成為舒緩能源需求的關鍵。以太陽能為例，日光通過光電效應以光子撞擊太陽能板放出光電子，使得光能得以轉化為電能的形式，然而，電能的長途運輸不是那麼容易，這時需要再將電能轉化為更方便運輸的形式。透過電解反應以電能驅動溶液進行化學反應使我們得以在陰極、陽極獲得對應之產物，其中電解水便是一種能有效將電能儲存成化學鍵鍵能的手段。在電解水的過程中得到的陰極產物，氫氣，具有高能量密度且燃燒無汙染的優勢，藉由開發出優秀的陰極與陽極端電催化劑便能降低電解水過程中的能量損耗進而提高能量轉化效率。
本研究藉由尿素水解反應將含釕、鈷之前驅物合成在導電碳布上，再以管爐在氬氣環境下進行磷化反應合成一系列磷化釕鈷之碳布元件。藉由添加鈷金屬進入磷化釕後，相較於純的磷化釕無論是在酸性還是鹼性下催化都得到顯著的性能提升，尤其是在酸性電解液中，鈷的添加改善了磷化釕材料過電位較鹼性電解液高出許多的缺點，將本材料在酸性電解液中的過電位降低至鉑催化劑的催化活性，以及維持鹼性溶液中磷化釕的塔菲爾斜率與過電位，並且在全酸鹼值範圍都擁能保持相當優異的催化能力。此外為了瞭解電催化劑在施加電壓在水溶液中進行電催化反應時的結構以及原子區域結構，本研究除了基本的材料鑑定之外也輔以臨場X光吸收光譜與X光繞射實驗監控催化劑在真實催化條件下之材料結構變化，連結電化學量測中觀察到的現象，說明如何藉由添加鈷金屬調控釕基催化劑的催化活性。 | zh_TW |
| dc.description.abstract | Energy issues have attracted increasing attention in recent years due to the global warming and climate change. To avoid deterioration of greenhouse effect, clean energy sources should be developed to replace fossil fuels. Among numerous techniques which are able to extract energy from the nature, conversion of solar energy to electricity via photoelectric effect is a feasible method to utilize the energy from sunlight. However, delivery and storage of obtained electricity from sunlight may be challenging. To store electricity in another form, conversion of energy to chemical bonding through water electrolysis provides zero-pollution and high energy density fuel. The energy conversion efficiency can be enhanced by lowering the overpotential of anodic and cathodic catalysts. In this work the ruthenium-based catalysts were synthesized on carbon cloth by a two-step process: urea hydrolysis chemical bath deposition followed by chemical vapor deposition using phosphine (PH3) gas. With the addition of cobalt cation, enhancement on catalytic activity is observed especially in acidic media. Numerous techniques including in situ XAS, XRD are applied to monitor the genuine behaviors of materials under reaction conditions. Hence, the reaction mechanism can be unraveled. Our catalyst exhibits extremely small overpotential at 10 mA cm-2 of current density (3 mV in 0.5 M H2SO4 solution; 4 mV in 1.0 M KOH solution; 30 mV in 1.0 M PBS solution). Besides, the catalyst possesses high stability of electrocatalytic activity and material structure in catalytic process. These performances outperform all the other HER electrocatalysts, including benchmark of HER, Pt/C. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T02:20:21Z (GMT). No. of bitstreams: 1 U0001-1708202014173000.pdf: 24520203 bytes, checksum: 5899bb1bce9322414d41bde9082834ba (MD5) Previous issue date: 2020 | en |
| dc.description.tableofcontents | 口試委員會審定書 # 誌謝 1 中文摘要 2 ABSTRACT 3 目錄 4 圖目錄 8 表目錄 18 第一章 緒論 19 1.1 能源危機與氫能源 19 1.2 氫氣製備技術 20 1.2.1 蒸汽重整 20 1.2.2 光催化水分解 21 1.2.3 電催化水分解 22 1.3 電催化析氫反應 23 1.3.1 高天然豐度過渡金屬硫族化物催化劑 26 1.3.2 高天然豐度過渡金屬磷化物催化劑 27 1.3.3 釕基催化劑 29 1.4 本研究之研究動機與目的 31 第二章 實驗步驟與儀器分析原理 34 2.1 化學藥品 34 2.2 催化劑製備流程 35 2.2.1 碳布前處理方法 35 2.2.2 鈷摻雜釕基催化劑之前驅物製備 35 2.2.3 鈷摻雜釕基催化劑製備 37 2.3 電化學分析架設與原理 39 2.3.1 電化學量測之架設 39 2.3.2 線性掃描伏安法（Linear Sweep Voltammetry, LSV） 41 2.3.3 循環伏安法（Cyclic Voltammetry, CV） 43 2.3.4 計時安培測定法（Chronoamperometry, CA） 45 2.3.5 計時電位測定法（Chronopotentiometry, CP） 45 2.3.6 電化學阻抗頻譜法（Electrochemical Impedance Spectroscopy, EIS） 46 2.4 材料分析方法與儀器原理 48 2.4.1 穿透式電子顯微鏡（Transmission Electron Microscope, TEM） 48 2.4.2 掃描式電子顯微鏡（Scanning Electron Microscope, SEM） 50 2.4.3 能量散射X光光譜（Energy-dispersive X-ray Spectroscopy, EDS） 52 2.4.4 X光繞射（X-ray Diffraction, XRD） 53 2.4.5 X光光電子能譜∕化學分析電子能譜（X-ray Photoelectron Spectroscopy / Electron Spectroscopy for Chemical Analysis, XPS/ESCA） 55 2.4.6 X光吸收光譜（X-ray Absorption Spectroscopy, XAS） 57 2.4.7 X光吸收近邊緣結構（X-ray Absorption Near Edge Structure, XANES） 60 2.4.8 延伸X光吸收細微結構（Extended X-ray Absorption Fine Structure, EXAFS） 64 第三章 研究結果與討論 65 3.1 鈷摻雜釕基催化劑之材料分析與結構鑑定 65 3.1.1 本研究使用之儀器與操作條件 65 3.1.2 掃描式電子顯微鏡影像 66 3.1.3 能量散射X光光譜分析 70 3.1.4 X光繞射圖譜分析 77 3.1.5 穿透式電子顯微鏡影像 80 3.1.6 X光吸收光譜分析 82 3.1.7 X光光電子能譜分析 87 3.1.8 電感耦合等離子體質譜法（Inductively Coupled Plasms Mass Spectrometry, ICP-MS） 93 3.2 鈷摻雜釕基催化劑之催化活性測試與電化學分析 95 3.2.1 線性掃描伏安法分析 95 3.2.2 循環伏安法分析 101 3.2.3 定電流穩定性測試 105 3.2.4 電化學阻抗頻譜分析 105 3.3 鈷摻雜釕基催化劑之臨場實驗鑑定 110 3.3.1 臨場同步輻射X光繞射圖譜分析 110 3.3.2 臨場X光吸收近邊緣結構分析 121 3.3.3 臨場延伸X光吸收細微結構分析 134 3.3.4 臨場延伸X光吸收細微結構擬合分析 148 第四章 結論 172 參考文獻 173 | |
| dc.language.iso | zh-TW | |
| dc.subject | 水分解 | zh_TW |
| dc.subject | 臨場實驗 | zh_TW |
| dc.subject | 電催化 | zh_TW |
| dc.subject | 析氫反應 | zh_TW |
| dc.subject | hydrogen evolution reaction | en |
| dc.subject | electrocatalysis | en |
| dc.subject | in situ characterization | en |
| dc.title | 鈷摻雜釕基催化劑於電催化析氫反應之研究 | zh_TW |
| dc.title | Ultra-High Performance Cobalt-doped Ruthenium-based Electrocatalyst for Hydrogen Evolution Reaction | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 108-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.advisor-orcid | 陳浩銘(0000-0002-7480-9940) | |
| dc.contributor.oralexamcommittee | 廖尉斯(Wei-Ssu Liao),張慕傑(Mu-Chieh Chang),黃志嘉(Chih Chia Huang) | |
| dc.contributor.oralexamcommittee-orcid | 廖尉斯(0000-0002-5619-4997),張慕傑(0000-0002-7270-0319),黃志嘉(0000-0002-9486-8665) | |
| dc.subject.keyword | 水分解,電催化,析氫反應,臨場實驗, | zh_TW |
| dc.subject.keyword | hydrogen evolution reaction,electrocatalysis,in situ characterization, | en |
| dc.relation.page | 176 | |
| dc.identifier.doi | 10.6342/NTU202003742 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2020-08-19 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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