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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/68320完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 李克強 | |
| dc.contributor.author | Hsiao-Yun Lai | en |
| dc.contributor.author | 賴筱韻 | zh_TW |
| dc.date.accessioned | 2021-06-17T02:17:34Z | - |
| dc.date.available | 2027-12-31 | |
| dc.date.copyright | 2018-02-23 | |
| dc.date.issued | 2017 | |
| dc.date.submitted | 2017-07-26 | |
| dc.identifier.citation | 1. Masliyah, J.H. and S. Bhattacharjee, Electrokinetic and Colloid Transport Phenomena. Electrokinetic and Colloid Transport Phenomena. 2005: John Wiley & Sons, Inc.
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Carrique, F., et al., Influence of cell-model boundary conditions on the conductivity and electrophoretic mobility of concentrated suspensions. Advances in colloid and interface science, 2005. 118(1): p. 43-50. 54. Carrique, F., F. Arroyo, and A. Delgado, Electrokinetics of concentrated suspensions of spherical colloidal particles: effect of a dynamic Stern layer on electrophoresis and DC conductivity. Journal of colloid and interface science, 2001. 243(2): p. 351-361. 55. He, Y.Y. and E. Lee, Electrophoresis in concentrated dispersions of charged porous spheres. Chemical Engineering Science, 2008. 63(23): p. 5719-5727. 56. Dukhin, A.S., V. Shilov, and Y. Borkovskaya, Dynamic electrophoretic mobility in concentrated dispersed systems. Cell model. Langmuir, 1999. 15(10): p. 3452-3457. 57. Lee, E., F.Y. Yen, and J.P. Hsu, Dynamic electrophoretic mobility of concentrated spherical dispersions. Journal of Physical Chemistry B, 2001. 105(30): p. 7239-7245. 58. 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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/68320 | - |
| dc.description.abstract | 本研究以假性光譜法數值模擬密集硬球在高分子溶液中的電泳行為，以單位晶格模型描述密集硬球、以均勻介質模型結合Debye-Bueche-Brinkman理論方程式描述非均相多孔系統中的流動行為，並求解電動力學方程組。
本研究的影響參數甚多，包含：電雙層厚度、表面電位、密集度、高分子溶液摩擦係數，影響效應則包含：電雙層重疊效應、極化效應、密集度，電力與流力競合關係極為複雜。 綜合而言，電雙層厚度與溶液中離子強度有關，電雙層厚度愈薄，溶液離子強度愈強，電場的梯度愈強，驅動力較強使得電泳動度愈快；當電雙層厚度愈厚，溶液離子強度愈弱，密集度成為決定電泳動度的主要參數，密集度愈高，電雙層重疊效應愈顯著，使得電泳動度愈慢。 在電雙層厚度與單位晶格半徑相同附近會有高低電位的電泳動度順序變化，來自於電雙層重疊效應與極化效應的消長；高分子溶液貢獻的摩擦也將減緩粒子電泳動度，且密集度與高分子溶液摩擦係數增加皆會抑制離子對流引起的極化效應。 本研究提供廣效亨利公式(generalized Henry formula)，以電泳動度對電雙層厚度圖形表示，針對不同濃度及不同電位之粒子在不同特性的高分子溶液中提供理論預測之電泳動度，亦探討表面調節(charge-regulation)粒子之行為。 本研究在使用高分子溶液之微流體系統(microfluidic systems)，例如生物晶片等等，有廣泛的應用潛力。 | zh_TW |
| dc.description.abstract | Electrophoretic behavior of rigid particles in polymeric electrolyte solutions, described by Debye-Bueche-Brinkman (DBB) model, is investigated theoretically in this study. Standard electrokinetic equations governing the particle motion are solved numerically with pseudo-spectral method.
Parameters of electrokinetic interest, such as the double layer thickness, κa, the particle zeta potential, ζ, concentration, H, and the extra retardation force of the polymeric solutions, λa, are examined respectively to understand their specific impact on the particle motion. It is found that the higher the polymeric retarding force is, the lower the particle mobility. The involvement of polarization and overlapping effects of the double layer further complicates the electrophoretic behavior of the particle, which is discussed in detail. General mobility charts expressed as a function of the reciprocal of dimensionless Debye length are established for various particle zeta potential and suspension concentrations. These original charts are very useful for the prediction of particle mobility in DBB polymeric solutions. Moreover, particles with charge regulated surface are explored as well, which is often encountered in bio-colloids such as human cells. This study extends the conventional aqueous electrolyte systems to polymeric ones, which find potential applications in microfluidic operations involving polymeric solutions in particular. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T02:17:34Z (GMT). No. of bitstreams: 1 ntu-106-R03524102-1.pdf: 3187269 bytes, checksum: 8ff8b5b8c598ed109158498b8670deef (MD5) Previous issue date: 2017 | en |
| dc.description.tableofcontents | 摘要 I
Abstract II 目錄 III 圖目錄 VI 第 1 章 緒論 10 1-1 膠體懸浮液 10 1-2 電動力學現象與文獻回顧 14 1.2.1 電雙層理論 14 1.2.2 電泳理論 20 1.2.3 極化效應理論 21 1.2.4 電泳文獻回顧 23 1-3 高分子溶液簡介 29 1.3.1 高分子溶液 29 1.3.2 Debye-Bueche-Brinkman理論 32 1.3.3 高分子溶液在微流體系統之應用 36 1-4 研究目的與論文架構 40 第 2 章 理論分析 41 2-1 電動力學方程組 41 2.1.1 電位方程式 41 2.1.2 離子守恆式 43 2.1.3 流場方程式 44 2-2 平衡態與擾動態 46 2.2.1 平衡系統 46 2.2.2 擾動系統 47 2-3 粒子受力計算 49 2-4 電泳動度計算 50 第 3 章 數值方法 52 3-1 正交配位法 52 3-2 空間映射 57 3-3 牛頓(Newton-Raphson)迭代法 58 第 4 章 密集硬球在高分子溶液中之電泳現象 61 4-1 系統介紹 61 4-2 邊界條件 65 4.2.1 主控方程式 65 4.2.2 平衡態邊界條件 67 4.2.3 擾動態邊界條件 69 4.2.4 無因次一維化之主控方程式及邊界條件 71 4-3 計算之網格點 73 4-4 電雙層厚度κa之影響 74 4-5 表面電位ϕr之影響 90 4-6 密集度H之影響 94 4-7 高分子溶液摩擦係數λa之影響 98 4-8 表面調節現象 102 4-9 結論 109 參考文獻 111 符號說明 121 附錄 124 | |
| dc.language.iso | zh-TW | |
| dc.subject | 極化效應 | zh_TW |
| dc.subject | 電泳 | zh_TW |
| dc.subject | 高分子溶液 | zh_TW |
| dc.subject | 多孔介質 | zh_TW |
| dc.subject | 膠體懸浮液 | zh_TW |
| dc.subject | double layer polarization | en |
| dc.subject | electrophoresis | en |
| dc.subject | porous medium | en |
| dc.subject | colloids | en |
| dc.subject | polymeric solutions | en |
| dc.title | 密集硬球在高分子溶液中之電泳現象 | zh_TW |
| dc.title | Electrophoresis of Spherical Colloidal Particles in Polymer Solution | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 106-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 游佳欣,趙玲,朱智瑋 | |
| dc.subject.keyword | 電泳,高分子溶液,多孔介質,極化效應,膠體懸浮液, | zh_TW |
| dc.subject.keyword | electrophoresis,polymeric solutions,porous medium,double layer polarization,colloids, | en |
| dc.relation.page | 138 | |
| dc.identifier.doi | 10.6342/NTU201701985 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2017-07-26 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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