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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱勝賢(Sheng-Hsien Chiu) | |
| dc.contributor.author | Chun Hung | en |
| dc.contributor.author | 洪群 | zh_TW |
| dc.date.accessioned | 2021-06-17T01:54:17Z | - |
| dc.date.available | 2022-07-27 | |
| dc.date.copyright | 2017-07-27 | |
| dc.date.issued | 2017 | |
| dc.date.submitted | 2017-07-24 | |
| dc.identifier.citation | [1] Steed, J. W.; Atwood, J. L. Supramolecular Chemistry, 2nd ed, Wiley, 2009.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/67859 | - |
| dc.description.abstract | 利用單體分子本身結構的剛性與配位金屬的方向性，我們可以在溶液中進行 [c3]與[c4]雛菊鏈的選擇性自組裝。有別於以往利用苯胺與異氰酸酯的內鎖反應，本研究希望以苯胺與醯胺化反應來合成內鎖的高階雛菊鏈，以利未來合成出複雜度更高的結構。 | zh_TW |
| dc.description.abstract | In this research, molecular daisy chains were synthesized using structure rigidity, coordination geometries and bond rotational barriers to selectively form [c3] or [c4]daisy chains. Differ from the previous work, these daisy chains were synthesized through amide formation by introducing an aldehyde- or amine-group on the stopper. This approach opens a new perspective for the synthesis of even more complicated structures. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T01:54:17Z (GMT). No. of bitstreams: 1 ntu-106-R04223157-1.pdf: 7393520 bytes, checksum: ad4db915ee16906551af9043850be5c6 (MD5) Previous issue date: 2017 | en |
| dc.description.tableofcontents | 中文摘要 i
英文摘要 ii 圖目錄 iv 流程目錄 v 第一章、導論 1 1.1 前言 1 1.2 雛菊鏈 2 第二章、結果與討論 3 2.1 研究動機 3 2.2 兩性單體的設計與合成 10 2.3 [c3]與[c4]雛菊鏈分子之合成 13 2.4 加入/移除鋅離子控制[c3]與[c4]雛菊鏈分子肌肉的行為研究 15 2.5 封鎖機基團修飾官能基之合成 22 2.6封鎖基團修飾官能基之[c3]雛菊鏈之合成 24 2.7結論 27 第三章、實驗部分 28 第四章、參考資料 45 附錄 48 | |
| dc.language.iso | zh-TW | |
| dc.title | 以醯胺鍵合成內鎖[c3]與[c4]雛菊鏈之研究 | zh_TW |
| dc.title | Interlocking [c3]- and [c4]Daisy Chain by Amidation | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 105-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 賴建成(Chien-Chen Lai),李文山(Wen-Shan Li),陳平(Richard P. Cheng),徐秀福(Hsiu-Fu Hsu) | |
| dc.subject.keyword | 醯胺鍵,內鎖,雛菊鏈, | zh_TW |
| dc.subject.keyword | Interlocking,Daisy Chain,Amidation, | en |
| dc.relation.page | 84 | |
| dc.identifier.doi | 10.6342/NTU201701789 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2017-07-24 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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