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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳永芳(Yang-Fang Chen) | |
| dc.contributor.author | Jyun-De Wu | en |
| dc.contributor.author | 吳俊德 | zh_TW |
| dc.date.accessioned | 2021-06-17T01:44:30Z | - |
| dc.date.available | 2027-07-25 | |
| dc.date.copyright | 2017-07-28 | |
| dc.date.issued | 2017 | |
| dc.date.submitted | 2017-07-26 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/67693 | - |
| dc.description.abstract | 在此論文中，我將利用低成本的奈米製程技術，製作出大面積的三維手性超穎材料。首先，透過奈米球鏡微影術做出週期的金屬奈米孔洞於光阻上，以作為之後蒸鍍所需的遮罩。再依照孔洞遮罩微影術的概念，傾角斜向蒸鍍金屬及氧化層，成功把金屬層及氧化層相疊後，使其呈螺旋狀的奈米結構，此結構的手性近場會與不同手性的分子產生交互作用，得到在近紅外光波段的新圓二色性光譜，再透過此光譜分辨出分子的手性。
此外，我們也利用時域有限差分法(FDTD)來模擬計算我們的結構特性，和實驗相互驗證。最後，我們相信此技術，在未來的生化工業上，會有絕佳的應用。 | zh_TW |
| dc.description.abstract | In this study, we have demonstrated a cost effective nanofabrication method to fabricate three-dimensional (3D) chiral metamaterial arrays covering a large area. First, Nanospherical-Lens Lithography (NLL) is employed to fabricate periodic metal nanohole arrays on top of photoresist film. This sample configuration is ideal for the following angled metal or dielectric material evaporation, whose concept is very similar to Hole-Mask Lithography. Metal and dielectric materials are deposited sequentially and nanodisks stacked up in a spiral manor are successfully demonstrated. The fabricated 3D nanostructures exhibit optical chirality in the near-infrared and interact differently for chiral molecules with different handedness. The measured circular dichroism (CD) offers the possibility to distinguish chemical molecules with different handedness. Finite-difference time-domain method is also performed to confirm our experimental observation. We believe the proposed methods will very useful in future biological or chemical application. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T01:44:30Z (GMT). No. of bitstreams: 1 ntu-106-R04222005-1.pdf: 6462493 bytes, checksum: 23df01fbbb7b644072330fcc0fc9f1bb (MD5) Previous issue date: 2017 | en |
| dc.description.tableofcontents | 口試委員會審定書 #
誌謝 i 中文摘要 ii ABSTRACT iii CONTENTS iv LIST OF FIGURES vii LIST OF TABLES xvi Chapter 1 Introduction 1 Chapter 2 Theoretical background 3 2.1 Nanospheres 3 2.1.1 Self-Assembly Effect of Nanosphere 3 2.1.2 Nanospherical-Lens Lithography (NLL) 4 2.1.3 Hole-Mask Colloidal Lithography (HCL) 8 2.2 Principle of Surface Plasmon 12 2.2.1 Surface Plasmon Resonance 12 2.2.2 Localized Surface Plasmon Resonance (LSPR) 16 2.2.3 The Applications of LSPR 19 2.3 Chirality 23 2.3.1 Optical Activity 23 2.3.2 Measurement of Rotation of Polarization 24 2.3.3 Circular Dichroism (CD) 26 2.3.4 Optical Chirality (OC) 30 2.3.5 Other Applications of Chiral Metamaterials 39 2.4 Notations of Chiral Biomolecules 48 2.5 Simulation Method 51 2.5.1 Finite Difference 51 2.5.2 Finite-Difference Time-Domain Method 53 Chapter 3 Instrument 57 3.1 Fabrication Instrument 57 3.1.1 Polystyrene Sphere and Convective Self-Assembly System 57 3.1.2 Exposure System (Mercury, Xenon lamp) 59 3.1.3 E-Beam Evaporator 60 3.1.4 Plasma Etching System 61 3.2 Measurement Instrument 62 3.2.1 Scanning Electron Microscope (SEM) 62 3.2.2 Spectrophotometer 63 Chapter 4 Experimental Results and Discussion 64 4.1 Design of LH & RH Spiral Nanostructures 64 4.1.1 Fabrication of Nanostructures 64 4.1.2 Discussion by Simulation 70 4.2 Measurement of LH & RH Spiral Nanostructures 78 4.2.1 Setup of Chiral Measurement 78 4.2.2 Ag Spiral Nanostructures 79 4.2.3 Au Spiral Nanostructures 81 4.2.4 Comparison of Ag and Au Spiral Nanostructures 84 4.2.5 Comparison of Our Chiral Metamaterial and Published Papers 85 4.3 Biomolecules Sensing of Metamaterial 88 4.3.1 Analytical Method of Biomolecules Sensing 88 4.3.2 Setup of Chiral Bio-Sensing 92 4.3.3 Cysteine Sensing 93 4.3.4 Thalidomide Sensing 95 Chapter 5 Conclusion and Future Work 98 5.1.1 Conclusion 98 5.1.2 Future Work 98 REFERENCE 99 | |
| dc.language.iso | en | |
| dc.subject | 奈米球鏡微影術 | zh_TW |
| dc.subject | 手性 | zh_TW |
| dc.subject | 圓二色性 | zh_TW |
| dc.subject | 超穎材料 | zh_TW |
| dc.subject | 時域有限差分法 | zh_TW |
| dc.subject | 生物感測 | zh_TW |
| dc.subject | Nanospherical-Lens Lithography | en |
| dc.subject | Chirality | en |
| dc.subject | Metamaterial | en |
| dc.subject | Circular Dichroism | en |
| dc.subject | FDTD | en |
| dc.subject | Bio-Sensing | en |
| dc.title | 奈米球鏡微影術及孔洞遮罩微影術製作三維手性超穎材料之研究 | zh_TW |
| dc.title | Three-Dimensional Chiral Metamaterials Fabricated Using Nanospherical-Lens Lithography and Hole-Mask Lithography | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 105-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.coadvisor | 張允崇(Yun-Chorng Chang) | |
| dc.contributor.oralexamcommittee | 藍永強(Yung-Chiang Lan) | |
| dc.subject.keyword | 奈米球鏡微影術,手性,圓二色性,超穎材料,時域有限差分法,生物感測, | zh_TW |
| dc.subject.keyword | Nanospherical-Lens Lithography,Chirality,Metamaterial,Circular Dichroism,FDTD,Bio-Sensing, | en |
| dc.relation.page | 104 | |
| dc.identifier.doi | 10.6342/NTU201701961 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2017-07-27 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 應用物理研究所 | zh_TW |
| 顯示於系所單位： | 應用物理研究所 | |
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