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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 陳建彰 | |
dc.contributor.author | Chen-Yu Liao | en |
dc.contributor.author | 廖振宇 | zh_TW |
dc.date.accessioned | 2021-06-17T01:25:06Z | - |
dc.date.available | 2017-08-20 | |
dc.date.copyright | 2017-08-20 | |
dc.date.issued | 2017 | |
dc.date.submitted | 2017-08-08 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/67252 | - |
dc.description.abstract | 本論文主要研究聚苯胺/還原氧化石墨烯複合材料經爐管不同熱處理溫度後於超級電容的電極上之可行性,希望透過導電高分子與碳基材料兩種不同的電容機制來提升電容表現,並以此種組合彌補各別材料之優缺點,並探討溫度對聚苯胺/還原氧化石墨烯複合材料的熱解反應與鍵結變化。首先,使用網印法進行電極的快速成膜,接著以爐管對電極進行熱處理,溫布分別為100、200、300 oC與未處理,最後搭配凝膠態電解液製作出可撓性超級電容。在循環伏安法掃描速率2 mV/s下,電位窗口為0~0.8 V,低溫100 oC的熱處理後就能有效讓比電容值從88.55 mF/cm2提升至102.73 mF/cm2,然而隨後卻隨著熱處理溫度提升至200、300 oC時,比電容值開始下降,其中的原因為聚苯胺在200 oC之後會發生熱解反應的關係,其可透過熱重分析與鍵結分析中得知,也因為聚苯胺的熱解反應而導致其在超電容機制中貢獻的法拉第反應開始消失,最終電容值因此下降。而低溫100 oC熱處理之電容在撓曲下依舊有不錯的表現,比電容值可維持90.7 %,在1000次充放電後電容維持率為88.25 % ,顯示出聚苯胺/還原氧化石墨烯複合材料低溫熱處理下有著良好的可撓性。 | zh_TW |
dc.description.abstract | We investigate polyaniline (PANI)/reduced graphene oxide (rGO) composite supercapacitor post-annealed at various temperatures. Pastes containing PANI and rGO are first screen-printed onto carbon cloth. Following which the sample was annealed at 100, 200, and 300 °C for 10 min. Thermogravimetric analysis indicates the decomposition of PANI as the annealing temperature increased to 200 and 300 °C, the pseudocapacitance contributed by PANI decreases, and the capacitance values therefore decreased. 100 °C×10 min annealing can increase the areal capacitance from 88.55 mF/cm2 to 102.73 mF/cm2. Under bending with a bending radius of 0.55 cm, the capacitance retention rate is 90.7 %. After 1000 cycle CV stability test, the capacitance retention rate is 88.25 %. | en |
dc.description.provenance | Made available in DSpace on 2021-06-17T01:25:06Z (GMT). No. of bitstreams: 1 ntu-106-R04543057-1.pdf: 7464126 bytes, checksum: d2ee444b435322468b1f510d610169c7 (MD5) Previous issue date: 2017 | en |
dc.description.tableofcontents | 致謝 II
摘要 IV ABSTRACT V 總目錄 VI 表目錄 IX 圖目錄 XI 第一章 緒論 1 1.1前言 1 1.2研究動機 3 1.3論文大綱 4 第二章 理論基礎與文獻回顧 5 2.1超級電容介紹 5 2.1.1超級電容簡介 5 2.1.2超級電容的儲能機制 7 2.1.3超級電容之電極材料 9 2.1.4電解液的種類 17 2.2石墨烯 19 2.3聚苯胺 24 2.4石墨烯/聚苯胺文獻回顧 27 第三章 實驗方法與流程 31 3.1實驗藥品與量測儀器 31 3.2實驗規劃 34 3.3實驗流程 35 3.3.1基板清洗 35 3.3.2製備網印漿料 35 3.3.3製備聚苯胺/石墨烯電極於碳布上 35 3.3.4製備凝膠態電解液 36 3.3.5製備二極、三極系統的超級電容 36 3.4製程儀器與原理 40 3.4.1迴旋濃縮機(Rotary evaporator) 40 3.4.2網版印刷機 42 3.5量測儀器與原理 44 3.5.1掃描式電子顯微鏡 44 3.5.2熱重分析儀 46 3.5.3 X射線光電子能譜儀 48 3.5.4電化學阻抗分析儀 49 第四章 實驗結果與討論 55 4.1電極水接觸角測試 55 4.2聚苯胺/還原氧化石墨烯複合材料之熱重分析 57 4.3聚苯胺/石墨烯複合材料薄膜之表面型態 62 4.4 XPS 65 4.5聚苯胺/石墨烯複合材料薄膜電極之三極法測試 69 4.6聚苯胺/還原氧化石墨烯複合材料超級電容之電性分析 72 4.6.1聚苯胺/還原氧化石墨烯複合材料超級電容之循環伏安法測試 72 4.6.2聚苯胺/還原氧化石墨烯複合材料超級電容之恆電流測試 79 4.6.3聚苯胺/還原氧化石墨烯複合材料超級電容之穩定性測試 83 4.6.4聚苯胺/還原氧化石墨烯複合材料超級電容之阻抗分析測試 85 4.7聚苯胺/還原氧化石墨烯複合材料超級電容之撓曲測試 91 4.8充電後超電容點亮發光二極體測試 98 第五章 結論與未來展望 100 第六章 附錄 101 6.1摘要 101 6.2常壓電漿(Atmospheric pressure plasma, APP)之理論基礎 102 6.2.1電漿簡介 102 6.2.2電漿組成 102 6.2.3電漿生成 103 6.2.4電漿碰撞 104 6.2.5常壓電漿種類 107 6.3實驗方法與實驗儀器 112 6.3.1實驗方法 112 6.3.2實驗儀器-大氣電漿(Atmospheric pressure plasma jet, APPJ) 112 6.4實驗結果與討論 116 6.4.1常壓電漿操作下之基板溫度 116 6.4.2 SEM試片形態觀察 116 6.4.3循環伏安法(Cyclic voltammetry) 117 6.4.4恆電流充放電(Galvanostatic charging/discharging) 118 6.4.5功率密度、能量密度 118 6.4.6穩定性測試 120 6.4.7發光二極體啟動測試 120 參考文獻 121 | |
dc.language.iso | zh-TW | |
dc.title | 軟性聚苯胺/石墨烯奈米複合材料超級電容 | zh_TW |
dc.title | Flexible polyaniline/graphene nanocomposite supercapacitor | en |
dc.type | Thesis | |
dc.date.schoolyear | 105-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 陳奕君,張世航,莊嘉揚 | |
dc.subject.keyword | 聚苯胺,還原氧化石墨烯,爐管,可撓性,超級電容, | zh_TW |
dc.subject.keyword | polyaniline,reduced graphene oxide,screen printing,annealing temperature,supercapacitor,flexible electronics, | en |
dc.relation.page | 130 | |
dc.identifier.doi | 10.6342/NTU201702693 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2017-08-08 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 應用力學研究所 | zh_TW |
顯示於系所單位: | 應用力學研究所 |
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