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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/6687完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱勝賢 | |
| dc.contributor.author | Yin-Kai Huang | en |
| dc.contributor.author | 黃胤凱 | zh_TW |
| dc.date.accessioned | 2021-05-17T09:16:19Z | - |
| dc.date.available | 2017-08-16 | |
| dc.date.available | 2021-05-17T09:16:19Z | - |
| dc.date.copyright | 2012-08-16 | |
| dc.date.issued | 2012 | |
| dc.date.submitted | 2012-08-03 | |
| dc.identifier.citation | Part I：
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/6687 | - |
| dc.description.abstract | 第一部分：
合成車輪烷有許多策略可運用，如滑套法、夾鎖法、穿透後末端膨脹法、穿透後末端封鎖法以及穿透後縮環法。我們希望套用穿透後縮環法的合成概念：先以兩個啞鈴型分子穿透一個大環，在金屬離子引導之下縮環，形成無論是以有別於以往之合成方法或其別緻有趣含有兩個小環之造型[3]車輪烷。 第二部分： 當在溶劑中存在能互相辨識鍵結之主客分子時，其互相錯合生成的準車輪烷的比例受到幾個因素影響：如對應離子的鍵結強度、溶劑極性以及濃度的高低影響。若主客分子彼此的鍵結作用力弱，則須克服許多不利的因素，排除各種干擾鍵結的來源方能合成出車輪烷，研究弱鍵結生成的車輪烷之結構，並以此來探討其可能之應用。 | zh_TW |
| dc.description.abstract | Part I：
Strategies for rotaxane synthesis such as “slippage”, “clipping”, “threading-followed-by-swelling”, “threading-followed-by-stoppering” and “threading-followed-by-shrinking” are reported. We hope to demonstrate that the “threading-followed-by-shrinking“ can also be achieved by metal-ion assisted through tandem reaction. Part II： The complexation of host and guest are influenced by the environment such as ion strength of counter-ion, polarity of solvent etc. We hoped to find suitable reaction to synthesize rotaxane in a weak hydrogen-bond system. A mild reaction was applied to interlock the macrocycle with the thread-like guest in the weak hydrogen-bond system to avoid possible interference accompanied by the reaction. Having this unique rotaxane in hand, we could study the bonding of the structure and discuss the application of the rotaxane. | en |
| dc.description.provenance | Made available in DSpace on 2021-05-17T09:16:19Z (GMT). No. of bitstreams: 1 ntu-101-R99223157-1.pdf: 3456204 bytes, checksum: 5a38527229aa40c05af8377e7c16ed8e (MD5) Previous issue date: 2012 | en |
| dc.description.tableofcontents | 目錄 iv
圖目錄 vi 表目錄 ix 流程目錄 x 第一部分 以穿透後縮環方法合成車輪烷之研究 1 壹、導論 2 1.1超分子化學簡介 2 1.2內鎖型分子 3 1.3冠醚與二級銨離子之辨識系統 5 1.4合成車輪烷的策略 8 1.5較複雜之車輪烷系統 11 貳、結果與討論 20 2.1研究動機 20 2.2大環分子的設計與合成 21 2.3大環分子與啞鈴型分子鍵結測試 25 2.4銀離子引導環合反應 27 2.5利用金屬離子模版進行縮環反應 30 參、結論 32 肆、實驗部分 33 伍、參考文獻 39 第二部分 弱鍵結系統之車輪烷合成方法與其研究 43 壹、導論 44 1.1二苄基銨離子與冠醚組成之車輪烷系統 44 1.2弱鍵結系統的車輪烷合成策略 47 1.3分子開關 51 貳、結果與討論 56 2.1研究動機 56 2.2桿狀分子的設計與合成 59 2.3尋找適當的末端封鎖反應 61 2.4利用外在添加物達成分子開關的目的 64 參、結論 75 肆、實驗部分 76 伍、參考文獻 86 附錄 89 | |
| dc.language.iso | zh-TW | |
| dc.title | 以穿透後縮環方法合成車輪烷之研究 | zh_TW |
| dc.title | A “Threading-Followed-by-Shrinking” Strategy for Rotaxane Synthesis | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 100-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 李文山,徐秀福,陳平,賴建成 | |
| dc.subject.keyword | 車輪烷,主客化學,超分子化學,非共價作用力,相反離子, | zh_TW |
| dc.subject.keyword | rotaxane,host-guest chemistry,supramolecular chemistry,non-covalent force,counter ion, | en |
| dc.relation.page | 89 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2012-08-06 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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