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  1. NTU Theses and Dissertations Repository
  2. 工學院
  3. 化學工程學系
請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/66832
完整後設資料紀錄
DC 欄位值語言
dc.contributor.advisor陳誠亮(Cheng-Liang Chen)
dc.contributor.authorNaomi Sawakien
dc.contributor.author澤木直美zh_TW
dc.date.accessioned2021-06-17T01:09:08Z-
dc.date.available2020-02-04
dc.date.copyright2020-02-04
dc.date.issued2020
dc.date.submitted2020-01-20
dc.identifier.citation[1] Gasset, F., Luck, M., Landis, M., Reig, P., and Shiao, T., Aqueduct global maps 2.1 constructing decision-relevant global water risk indicators. World Resource Institute, Working Paper Aug, 5, 2015.
[2] Luo, T., Young, R., and Reig, P., Aqueduct projected water stress country rankings. World Resource Institute, Technical Note Aug, 19, 2015.
[3] Kurihara, M. and Takeuchi, H., SWRO-PRO system in “mega-ton water system” for energy reduction and low environmental impact. Water 2018, 10, 48.
[4] MENA Development Report: Renewable Energy and Desalination - An Emerging and Solution to Close and the Water and Gap in the Middle and East and North Africa. The World Bank, 2012.
[5] Millero, F. J., Feistel, R., Wright, D. G., and McDougall, T. J., The composition of standard seawater and the definition of the reference-composition salinity scale. Deep-Sea Research I, 2008, 55, 50–72.
[6] Stover, R. L., Seawater reverse osmosis with isobaric energy recovery devices. Desalination, 2007, 203, 168–175.
[7] Comparitive membrane replacement guide chart for 8 inch elements. LENNTECH.
[8] Competitive Membrane Comparison Guide NEW. LENNTECH.
[9] Water Global Practice Technocal Parer: The Role of Desalination in an Increasingly Water-Scarce World. World Bank Group, 2019.
[10] Chou, S., Wang, R., and Fane, A. G., Robust and high performance hollow fiber membranes for energy harvesting from salinity gradients by pressure retarded osmosis. Journal of Membrane Science 2013, 448, 44–54.
[11] Chou, S., Wang, R., Shi, L., She, Q., Tang, C., and Fane, A. G., Thin-film composite hollow fiber membranes for pressure retarded osmosis (PRO) process with high power density. Journal of Membrane Science 2012, 389, 25–33.
[12] Electricity information with 2017 data. International Energy Agency, IV.7–IV.8, 2018.
[13] International statistics for water services 2018. IWA Statistics and Economics, 2018.
[14] The United and Nations World Water Development Report - Water for a Sustainable World.TheUnitedNationsEducational, ScientificandCulturalOrganization, 2015.
[15] Voutchkov, N., Energy use for membrane seawater desalination – current status and trends. Desalination 2018, 431, 2–14.
[16] Avlonitis, S., Kouroumbas, K., and Vlachakis, N., Energy consumption and membrane replacement cost for seawater RO desalination plants. Desalination, 2003, 157, No. 1-3, 151–158.
[17] Leob, S., Production of energy from concentrated brines by pressure-retarded osmosis. Journal of Membrane Science, 1976, 1, 49–63.
[18] Chung, T.-S., Luo, L., Wan, C. F., Cui, Y., and Amy, G., What is next for forward osmosis (FO) and pressure retarded osmosis (PRO). Separation and Purification Technology 2015, 156, 856–860.
[19] Sakai, H., Ueyama, T., Irie, M., Matsuyama, K., Tanioka, A., Saito, K., andKumano, A., Energy recovery by PRO in sea water desalination plant. Desalination 2016, 389, 52–57.
[20] Chen, Y., Loh, C. H., Zhang, L., Setiawan, L., She, Q., Fang, W., Hu, X., and Wang, R., Module scale-up and performance evaluation of thin film composite hollow fiber membranes for pressure retarded osmosis. Journal of Membrane Science 2018, 548, 398–407.
[21] Chae, S. H., Seo, J., Kim, J., Kim, Y. M., and Kim, J. H., A simulation study with a new performance index for pressure-retarded osmosis processes hybridized with seawater reverse osmosis and membrane distillation. Desalination 2018, 444, 118–128.
[22] Vince, F., Marechal, F., Aoustin, E., and Bréant, P., Multi-objective optimization of RO desalination plants. Desalination 2008, 222, 96–118.
[23] Choi, Y., Shin, Y., Cho, H., Jang, Y., Hwang, T.-M., and Lee, S., Economic evaluation of the reverse osmosis and pressure retarded osmosis hybrid desalination process. Desalination and Water Treatment 2016, 57, 26680–26691.
[24] Malek, A., Hawlader, M., and Ho, J., Design and economics of RO seawater desalination. Desalination, 1996, 105, 245–261.
[25] Achilli, A., Cath, T. Y., and Childress, A. E., Power generation with pressure retarded osmosis: An experimental and theoretical investigation. Journal of Membrane Science 2009, 343, 42–52.
[26] Han, G., Zhang, S., Li, X., and Chung, T.-S., High performance thin film composite pressure retarded osmosis (PRO) membranes for renewable salinity-gradient energy generation. Journal of Membrane Science 2013, 440, 108–121.
[27] Wang, R., Shi, L., Tang, C. Y., Chou, S., Qiu, C., and Fane, A. G., Characterization of novel forward osmosis hollow fiber membranes. Journal of Membrane Science 2010, 355, 158–167.
[28] Wan, C. F. and Chung, T.-S., Osmotic power generation by pressure retarded osmosis using seawater brine as the draw solution and wastewater retentate as the feed. Journal of Membrane Science 2015, 479, 148–158.
[29] Aggidis, G., Luchinskaya, E., Rothschild, R., and Howard, D., The costs of small-scale hydro power production: Impact on the development of existing potential. Renewable Energy 2010, 35, 2632–2638.
[30] Avgar, I., A simulation study with a new performance index for pressure-retarded osmosis processes hybridized with seawater reverse osmosis and membrane distillation. The Knesset Research and Information Center 2018.
[31] Retail energy price data. Global Petrol Prices, 2019. https://www.globalpetrolprices.com/ [Accessed: 24 December 2019].
[32] Water prices. PUB Singapore’s National Water Agency, 2018. https://www.pub.gov.sg/watersupply/waterprice [Accessed: 24 December 2019].
dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/66832-
dc.description.abstract逆滲透(RO)已廣泛應用在海水淡化技術來生產飲用水。儘管在過去幾十年中開發了壓力交換器(PXs)等能量回收設備(ERD),並且膜技術得到了顯著改進,但RO仍然是生產飲用水最耗能的替代方法。
本文提供為多階段逆滲透和壓力延遲滲透(PRO)混合程序之能耗分析與成本評估。首先,根據第一原理建立單段、兩段、多階段RO-PX模型。於特定假設之下,發現多階段RO-PX的最佳段比率為x=1,並且兩段程序顯示出一定的能源效率改善。其次,將PRO模型添加到多階段RO-PX模型中,討論了三種多階段混合過程;一個不帶直接給水流量(混合程序A),一個帶直接給水流量(混合程序B),一個帶直接給水流量與渦輪機(混合程序C)。接著由MATLAB 2018b進行所有模擬,並基於標準化比能耗(NSEC)評估效能。
添加PX在NSECmin上有重大改進。單段RO-PX的NSECmin=1.88,與無PX的過程相比,此值小59 %。當忽略廢水泵時,與RO-PX程序相比,添加PRO還可以降低NSECmin。
RO階段的增加也有助於降低能耗;但是,它的影響僅在最初的幾階段才明顯,最終達到極限。與單段過程相比,兩段操作顯示NSECmin有一定的改進。因此,基於兩段RO對混合程序進行成本評估,並將其與兩段RO-PX進行比較。當電價設置為0.10 US$/kWh時,所有混合程序之總水價(TWP)都會變高。然而,當廢水預處理被忽略時,混合程序在不同的電價下顯示出一定的優勢。在低電價地區,RO-PX相較於有添加PRO之混合程序更具競爭力,而在高電價地區,混合程序A與混合程序C則較具競爭力。其中混合程序C對電價不敏感,因此在電價高且水價低的地區也具競爭力。廢水預處理、廢水泵以及PRO膜之發展是實際操作一步開發的關鍵。
zh_TW
dc.description.abstractReverse osmosis (RO) has been widely applied as major seawater desalination technology to produce potable water. Despite the development of energy recovery devices (ERDs) such as pressure exchangers (PXs) and dramatic improvements in membrane technology over the last few decades, RO remains to be the most energy intensive alternative to produce potable water.
This thesis provides analysis of energy efficiency and cost evaluation for multi-staged RO and pressure retarded osmosis (PRO) hybrid process. Firstly, single-, two- and multi-staged RO-PX models are built from first principles. Multi-staged RO-PX are found to have an optimum stage ratio of x = 1 under specific assumptions, and two-staged process shows certain improvement on energy efficiency. Secondly, PRO model is added to multi-staged RO-PX model and three multi-staged hybrid processes are discussed; one without direct feed flow (Hybrid A), one with direct feed flow (Hybrid B) and one with direct feed flow and a turbine (Hybrid C). Then, all simulations are conducted by MATLAB 2018b, and energy efficiencies are assessed based on normalised specific energy consumption, NSEC.
Addition of PXs has significant improvements on NSECmin. Single-staged RO-PX has NSECmin = 1.88, and this value is 59 % smaller compared to the process without PX. Addition of PRO also lowers NSECmin compared to RO-PX process when wastewater pump is neglected.
Increasing the number of RO stages also contributes to reduction in energy consumption; however, its effect is distinct only for first few stages, and it eventually reaches a limit. Two-staged operation shows a certain improvement on NSECmin compared with single-staged process. Therefore, cost evaluations for hybrid processes are conducted based on two-staged RO and they are compared with two-staged RO-PX. All hybrid process have higher total water price (TWC) when electricity price is set to 0.10 US$/kWh. However, hybrid processes show certain advantages under different electricity prices when wastewater pretreatment is wastewater pump are neglected. RO-PX is found to be the most competitive process in regions with low electricity prices, where Hybrid A and Hybrid C are more competitive in regions with high electricity prices. Hybrid C is especially attractive even in countries where water prices are low and electricity prices are high due to its insensitiveness to electricity prices. Requirement of wastewater pretreatment and wastewater pump are the keys to practical operations as well as further development of PRO membranes.
en
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Previous issue date: 2020
en
dc.description.tableofcontentsVerification letter from the Oral Examination Committee i
Acknowledgement iii
摘要 v
Abstract viii
List of Figures xiv
List of Tables xvi
Nomenclature xix
1 Introduction 1
1.1 Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.2 Literature Review . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
1.3 Motivation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
2 Single-Staged RO-PX Process 7
2.1 Basic Theory of RO . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
2.2 Fundamental Assumptions for RO . . . . . . . . . . . . . . . . . . . . . 8
2.3 NSEC min of Single-Staged RO . . . . . . . . . . . . . . . . . . . . . . . 10
2.4 Limitations for RO Operations . . . . . . . . . . . . . . . . . . . . . . . 16
2.5 Energy Efficiency of Single-Staged RO . . . . . . . . . . . . . . . . . . 18
2.6 Energy Recovery Device, ERD . . . . . . . . . . . . . . . . . . . . . . . 20
2.6.1 Types of ERDs . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
2.6.2 Efficiency of Pressure Exchanger, η px . . . . . . . . . . . . . . . 20
2.7 NSEC min of Single-Staged RO-PX . . . . . . . . . . . . . . . . . . . . . 22
2.8 Energy Efficiency of Single-Staged RO-PX . . . . . . . . . . . . . . . . 24
2.9 Comparison with Experimental Data . . . . . . . . . . . . . . . . . . . . 26
2.10 Process Flow Diagram of Single-Staged RO-PX . . . . . . . . . . . . . . 28
3 Multi-Staged RO-PX Process 31
3.1 NSEC min of Two-Staged RO-PX . . . . . . . . . . . . . . . . . . . . . . 31
3.2 NSEC min of n-Staged RO-PX . . . . . . . . . . . . . . . . . . . . . . . . 38
3.3 Energy Efficiency of Two-Staged RO-PX . . . . . . . . . . . . . . . . . 42
3.4 Energy Efficiency of n-Staged RO-PX . . . . . . . . . . . . . . . . . . . 45
3.5 Process Flow Diagram of Two-Staged RO-PX . . . . . . . . . . . . . . . 48
4 Hollow Fiber PRO Model 51
4.1 Basic Theory of PRO . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51
4.2 Fundamental Assumptions for PRO . . . . . . . . . . . . . . . . . . . . 53
4.3 Power Density and Recovery . . . . . . . . . . . . . . . . . . . . . . . . 55
4.4 PRO Model Validation . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
5 Multi-Staged Hybrid Process 65
5.1 NSEC min of Hybrid A . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67
5.2 NSEC min of Hybrid B . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70
5.3 NSEC min of Hybrid C . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74
5.4 Energy Efficiency of Hybrid A and Tradeoffs . . . . . . . . . . . . . . . 77
5.5 Energy Efficiency of Hybrid B and Hybrid C . . . . . . . . . . . . . . . 85
5.6 Process Flow Diagrams of Hybrid Processes . . . . . . . . . . . . . . . . 89
6 TWP and Electricity Prices 95
6.1 Total Water Price Models . . . . . . . . . . . . . . . . . . . . . . . . . . 95
6.2 TWP of Single- and Two-Staged RO-PX . . . . . . . . . . . . . . . . . . 97
6.3 TWP of Two-Staged RO based Processes . . . . . . . . . . . . . . . . . 98
6.4 Global Water Prices vs. Electricity Prices . . . . . . . . . . . . . . . . . 100
7 Conclusion 105
7.1 Summary of this dissertation . . . . . . . . . . . . . . . . . . . . . . . . 105
7.2 Future Works . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107
Bibliography 109
Appendices 113
A Theory . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113
B Stream Information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114
C Economic Evaluation . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117
dc.language.isoen
dc.subject多階段逆滲透zh_TW
dc.subject總水價zh_TW
dc.subject標準化比能耗zh_TW
dc.subject壓力交換器zh_TW
dc.subject壓力延遲滲透zh_TW
dc.subjectMulti-staged reverse osmosis (RO)en
dc.subjectPressure-retarded osmosis (PRO)en
dc.subjectPressure exchanger (PX)en
dc.subjectnormalised specific energy consumption (NSEC)en
dc.subjectTotal water price (TWP)en
dc.title多階段逆滲透及壓力延遲滲透海水淡化程序之能耗分析與成本評估zh_TW
dc.titleEnergy Analysis and Cost Evaluation for Multi-Staged Reverse Osmosis and Pressure Retarded Osmosis Desalination Processen
dc.typeThesis
dc.date.schoolyear108-1
dc.description.degree碩士
dc.contributor.oralexamcommittee莊清榮(Ching-Jung Chuang),陳榮輝(Jung-Hui Chen),吳哲夫(Jeffrey D. Ward)
dc.subject.keyword多階段逆滲透,壓力延遲滲透,壓力交換器,標準化比能耗,總水價,zh_TW
dc.subject.keywordMulti-staged reverse osmosis (RO),Pressure-retarded osmosis (PRO),Pressure exchanger (PX),normalised specific energy consumption (NSEC),Total water price (TWP),en
dc.relation.page121
dc.identifier.doi10.6342/NTU202000183
dc.rights.note有償授權
dc.date.accepted2020-01-20
dc.contributor.author-college工學院zh_TW
dc.contributor.author-dept化學工程學研究所zh_TW
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