請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/66803
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 王尚禮(Shan-Li Wang) | |
dc.contributor.author | Wan-Ting Liew | en |
dc.contributor.author | 廖婉婷 | zh_TW |
dc.date.accessioned | 2021-06-17T01:08:38Z | - |
dc.date.available | 2030-01-23 | |
dc.date.copyright | 2020-02-14 | |
dc.date.issued | 2019 | |
dc.date.submitted | 2020-01-31 | |
dc.identifier.citation | Adriano, D. C. (2001). Trace Elements in Terrestrial Environments Biogeochemistry, Bioavailability, and Risks of Metals. New York, NY: Springer.
Alfantazi, A., & Moskalyk, R. (2003). Processing of indium: a review. Minerals Engineering, 16(8), 687-694. doi:10.1016/S0892-6875(03)00168-7 Alloway, B. J. (2013). Heavy Metals in Soils: Trace Metals and Metalloids in Soils and their Bioavailability. Dordrecht Heidelberg New York London: Spinger. Anderson, C. J., & Welch, M. J. (1999). Radiometal-labeled agents (non-technetium) for diagnostic imaging. Chemical Reviews, 99(9), 2219-2234. Audi, G., Bersillon, O., Blachot, J., & Wapstra, A. (2003). The NUBASE evaluation of nuclear and decay properties. Nuclear Physics A, 729(1), 3-128. Bahri, Z., Rezai, B., & Kowsari, E. (2016). Selective separation of gallium from zinc using flotation: Effect of solution pH value and the separation mechanism. Minerals Engineering, 86, 104-113. doi:https://doi.org/10.1016/j.mineng.2015.12.005 Baker, A. J. M., & Proctor, J. (1990). The Influence of Cadmium, Copper, Lead, and Zinc on the Distribution and Evolution of Metallophytes in the British-Isles. Plant Syst Evol, 173(1-2), 91-108. doi:10.1007/Bf00937765 Balasoiu, C. F., Zagury, G. J., & Deschenes, L. (2001). Partitioning and speciation of chromium, copper, and arsenic in CCA-contaminated soils: influence of soil composition. Science of The Total Environment, 280(1-3), 239-255. doi:10.1016/S0048-9697(01)00833-6 Barysz, M., Leszczyński, J., & Bilewicz, A. (2004). Hydrolysis of the heavy metal cations: Relativistic effects. Physical Chemistry Chemical Physics, 6(19), 4553-4557. Benézéth, P., Diakonov, I. I., Pokrovski, G. S., Dandurand, J.-L., Schott, J., & Khodakovsky, I. L. (1997). Gallium speciation in aqueous solution. Experimental study and modelling: Part 2. Solubility of α-GaOOH in acidic solutions from 150 to 250° C and hydrolysis constants of gallium (III) to 300° C. Geochimica et Cosmochimica Acta, 61(7), 1345-1357. Bernstein, L. R. (1998). Mechanisms of therapeutic activity for gallium. Pharmacological reviews, 50(4), 665-682. Bernstein, L. R. (2005). 31Ga therapeutic gallium compounds. In M. Gielen & E. R. T. Tiekink (Eds.), Metallotherapeutic drugs and metal - based diagnostic agents: The use of metals in medicine (pp. 259-277). doi:10.1002/0470864052 Betoulle, S., Etienne, J., & Vernet, G. (2002). Acute immunotoxicity of gallium to carp (Cyprinus carpio L.). Bulletin of environmental contamination and toxicology, 68(6), 817-823. Retrieved from https://link.springer.com/content/pdf/10.1007%2Fs00128-002-0028-3.pdf Bi, X., & Westerhoff, P. (2016). Adsorption of III/V ions (In (III), Ga (III) and As (V)) onto SiO2, CeO2 and Al2O3 nanoparticles used in the semiconductor industry. Environmental Science: Nano, 3(5), 1014-1026. Blazka, M. E., Tepper, J. S., Dixon, D., Winsett, D. W., Oconnor, R. W., & Luster, M. I. (1994). Pulmonary response of fischer-344 rats to acute nose-only inhalation of indium trichloride. Environmental Research, 67(1), 68-83. doi:10.1006/enrs.1994.1065 Boros, E., Marquez, B. V., Ikotun, O. F., Lapi, S. E., & Ferreira, C. L. (2014). Coordination chemistry and ligand design in the development of metal based radiopharmaceuticals. In T. Storr (Eds.), Ligand Design in Medicinal Inorganic Chemistry (pp. 47-79). doi:10.1002/9781118697191 Boughriet, A., Proix, N., Billon, G., Recourt, P., & Ouddane, B. (2007). Environmental impacts of heavy metal discharges from a smelter in Deule-canal sediments (Northern France): Concentration levels and chemical fractionation. Water Air and Soil Pollution, 180(1-4), 83-95. doi:10.1007/s11270-006-9252-5 Bradl, H. B. (2004). Adsorption of heavy metal ions on soils and soils constituents. Journal of Colloid and Interface Science, 277(1), 1-18. doi:https://doi.org/10.1016/j.jcis.2004.04.005 Brümmer, G. (1986). Heavy metal species, mobility and availability in soils. In M. Bernhard, F. E. Brinckman & P. J. Sadler (Eds.), The Importance of Chemical “Speciation” in Environmental Processes (pp. 169-192). Berlin, Heidelberg: Springer. Chang, H. F., Wang, S. L., & Yeh, K. C. (2017). Effect of gallium exposure in arabidopsis thaliana is similar to aluminum stress. Environmental Science & Technology, 51(3), 1241-1248. doi:10.1021/acs.est.6b05760 Chen, H. W. (2006). Gallium, indium, and arsenic pollution of groundwater from a semiconductor manufacturing area of Taiwan. Bulletin of Environmental Contamination and Toxicology, 77(2), 289-296. doi:10.1007/s00128-006-1062-3 Chen, J. Y., Luong, H. V. T., & Liu, J. C. (2015). Fractionation and release behaviors of metals (In, Mo, Sr) from industrial sludge. Water Research, 82, 86-93. doi:10.1016/j.watres.2015.04.011 Chinoune, K., Bentaleb, K., Bouberka, Z., Nadim, A., & Maschke, U. (2016). Adsorption of reactive dyes from aqueous solution by dirty bentonite. Applied Clay Science, 123, 64-75. doi:https://doi.org/10.1016/j.clay.2016.01.006 Christensen, J. B., Jensen, D. L., & Christensen, T. H. (1996). Effect of dissolved organic carbon on the mobility of cadmium, nickel and zinc in leachate polluted groundwater. Water Research, 30(12), 3037-3049. doi:https://doi.org/10.1016/S0043-1354(96)00091-7 Chubin, R. G., & Street, J. J. (1981). Adsorption of cadmium on soil constituents in the presence of complexing ligands. Journal of Environmental Quality, 10(2), 225-228. doi:10.2134/jeq1981.00472425001000020021x Clausén, M., Öhman, L.O., & Persson, P. (2005). Spectroscopic studies of aqueous gallium(III) and aluminum(III) citrate complexes. Journal of Inorganic Biochemistry, 99(3), 716-726. doi:https://doi.org/10.1016/j.jinorgbio.2004.12.007 Cobelo-García, A., & Filella, M. (2017). Electroanalytical techniques for the quantification of technology-critical elements in environmental samples. Current Opinion in Electrochemistry, 3(1), 78-90. doi:https://doi.org/10.1016/j.coelec.2017.06.014 Cobelo-García, A., Filella, M., Croot, P., Frazzoli, C., Du Laing, G., Ospina-Alvarez, N., Rauch, S., Salaun, P., Schäfer, J., & Zimmermann, S. (2015). COST action TD1407: network on technology-critical elements (NOTICE)-from environmental processes to human health threats. Environmental Science and Pollution Research, 22(19), 15188-15194. doi:10.1007/s11356-015-5221-0 de Matos, A. T., Fontes, M. P. F., da Costa, L. M., & Martinez, M. A. (2001). Mobility of heavy metals as related to soil chemical and mineralogical characteristics of Brazilian soils. Environmental Pollution, 111(3), 429-435. doi:10.1016/S0269-7491(00)00088-9 de Melo, B. A. G., Motta, F. L., & Santana, M. H. A. (2016). Humic acids: Structural properties and multiple functionalities for novel technological developments. Materials Science and Engineering: C, 62, 967-974. doi:https://doi.org/10.1016/j.msec.2015.12.001 Echeverría, J. C., Morera, M. T., Mazkiarán, C., & Garrido, J. J. (1998). Competitive sorption of heavy metal by soils. Isotherms and fractional factorial experiments. Environmental Pollution, 101(2), 275-284. doi:https://doi.org/10.1016/S0269-7491(98)00038-4 Fadiran, A. O., Tiruneh, A. T., & Mtshali, J. S. (2014). Assessment of mobility and bioavailability of heavy metals in sewage sludge from Swaziland through speciation analysis. American Journal of Environmental Protection, 3(4), 198-208. doi:10.11648/j.ajep.20140304.14 Feng, T. L., Gurian, P. L., Healy, M. D., & Barron, A. R. (1990). Aluminum citrate: isolation and structural characterization of a stable trinuclear complex. Inorganic Chemistry, 29(3), 408-411. Filella, M., & Rodríguez-Murillo, J. C. (2017). Less-studied TCE: Are their environmental concentrations increasing due to their use in new technologies? Chemosphere, 182, 605-616. doi:https://doi.org/10.1016/j.chemosphere.2017.05.024 Gai, L. H., Wang, S. G., Gong, W. X., Liu, X. W., Gao, B. Y., & Zhang, H. Y. (2008). Influence of pH and ionic strength on Cu(II) biosorption by aerobic granular sludge and biosorption mechanism. Journal of Chemical Technology & Biotechnology, 83(6), 806-813. doi:10.1002/jctb.1869 Guetzloff, T. F., & Rice, J. A. (1994). Does humic acid form a micelle? Science of The Total Environment, 152(1), 31-35. Ha, N. N., Agusa, T., Ramu, K., Tu, N. P. C., Murata, S., Bulbule, K. A., Parthasaraty, P., Takahashi, S., Subramanian, A., & Tanabe, S. (2009). Contamination by trace elements at e-waste recycling sites in Bangalore, India. Chemosphere, 76(1), 9-15. doi:https://doi.org/10.1016/j.chemosphere.2009.02.056 Ha, N. T. H., Sakakibara, M., Sano, S., & Nhuan, M. T. (2011). Uptake of metals and metalloids by plants growing in a lead–zinc mine area, Northern Vietnam. Journal of Hazardous Materials, 186(2), 1384-1391. doi:https://doi.org/10.1016/j.jhazmat.2010.12.020 Hanay, Ö., Hasar, H., Kocer, N. N., & Aslan, S. (2008). Evaluation for agricultural usage with speciation of heavy metals in a municipal sewage sludge. Bulletin of Environmental Contamination and Toxicology, 81(1), 42-46. Retrieved from https://link.springer.com/article/10.1007%2Fs00128-008-9451-4 Hart, M. M., & Adamson, R. H. (1971). Antitumor activity and toxicity of salts of inorganic group iiia Metals - aluminum, gallium, indium, and thallium - (Walker 256 carcinosarcoma/reticulum cell sarcoma/lymphosarcoma/mammary carcinoma/leukemia). Proceedings of the National Academy of Sciences of the United States of America, 68(7), 1623-&. doi:10.1073/pnas.68.7.1623 Harter, R. D., & Naidu, R. (2001). An assessment of environmental and solution parameter impact on trace-metal sorption by oils. 65(3), 597-612. doi:10.2136/sssaj2001.653597x Hayes, K. F., Papelis, C., & Leckie, J. O. (1988). Modeling ionic strength effects on anion adsorption at hydrous oxide/solution interfaces. Journal of Colloid and Interface Science, 125(2), 717-726. Ivanova, V. Y., Chevela, V., & Bezryadin, S. (2015). Complex formation of indium (III) with citric acid in aqueous solution. Russian Chemical Bulletin, 64(8), 1842-1849. Jansen, B., Nierop, K. G. J., & Verstraten, J. M. (2003). Mobility of Fe(II), Fe(III) and Al in acidic forest soils mediated by dissolved organic matter: influence of solution pH and metal/organic carbon ratios. Geoderma, 113(3), 323-340. doi:https://doi.org/10.1016/S0016-7061(02)00368-3 Jones, M., & Bryan, N. (1998). Colloidal properties of humic substances. Advance in Colloid and Interface Science, 78, 1-48. Kabata-Pendias, A., & Mukherjee, A. B. (2007). Trace elements from soil to human: Springer Berlin Heidelberg. Kaiser, K., & Guggenberger, G. (2000). The role of DOM sorption to mineral surfaces in the preservation of organic matter in soils. Organic Geochemistry, 31(7), 711-725. doi:https://doi.org/10.1016/S0146-6380(00)00046-2 Karapanagiotis, N. K., Sterritt, R. M., & Lester, J. N. (1991). Heavy metal complexation in sludge-amended soil: The role of organic-matter in metal retention. Environ Technol, 12(12), 1107-1116. doi:10.1080/09593339109385111 Karn, B. (2011). Inside the radar: Select elements in nanomaterials and sustainable nanotechnology. Journal of Environmental Monitoring, 13(5), 1184-1189. doi:10.1039/c1em10049a Kim, J. I., Buckau, G., Li, G., Duschner, H., & Psarros, N. (1990). Characterization of humic and fulvic acids from Gorleben groundwater. Fresenius' Journal of Analytical Chemistry, 338(3), 245-252. Kinniburgh, D. G., Milne, C. J., Benedetti, M. F., Pinheiro, J. P., Filius, J., Koopal, L. K., & Van Riemsdijk, W. H. (1996). Metal ion binding by humic acid: application of the NICA-Donnan model. Environmental Science & Technology, 30(5), 1687-1698. Kinniburgh, D. G., van Riemsdijk, W. H., Koopal, L. K., Borkovec, M., Benedetti, M. F., & Avena, M. J. (1999). Ion binding to natural organic matter: competition, heterogeneity, stoichiometry and thermodynamic consistency. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 151(1), 147-166. doi:https://doi.org/10.1016/S0927-7757(98)00637-2 Knauer, K., Homazava, N., Junghans, M., & Werner, I. (2017). The influence of particles on bioavailability and toxicity of pesticides in surface water. Integrated Environmental Assessment and Management, 13(4), 585-600. doi:10.1002/ieam.1867 Koopal, L. K., Van Riemsdijk, W. H., & Kinniburgh, D. G. (2001). Humic matter and contaminants. General aspects and modeling metal ion binding. Pure and Applied Chemistry, 73(12), 2005-2016. doi:https://doi.org/10.1351/pac200173122005 Ladenberger, A., Demetriades, A., Reimann, C., Birke, M., Sadeghi, M., Uhlback, J., Andersson, M., Jonsson, E., & the GEMAS project team (2015). GEMAS: Indium in agricultural and grazing land soil of Europe - Its source and geochemical distribution patterns. Journal of Geochemical Exploration, 154, 61-80. doi:10.1016/j.gexplo.2014.11.020 Lead, J. R., Hamilton-Taylor, J., Peters, A., Reiner, S., & Tipping, E. (1998). Europium binding by fulvic acids. Analytica Chimica Acta, 369(1), 171-180. doi:https://doi.org/10.1016/S0003-2670(98)00230-X Licht, C., Peiro, L. T., & Villalba, G. (2015). Global substance flow analysis of gallium, germanium, and indium: Quantification of extraction, uses, and dissipative losses within their anthropogenic cycles. Journal of Industrial Ecology, 19(5), 890-903. doi:10.1111/jiec.12287 Lokanc, M., Eggert, R., & Redlinger, M. (2015). The availability of indium: The present, medium term, and long term. (NREL/SR-6A20-62409 United States 10.2172/1327212 NREL English). Retrieved from United States: https://www.osti.gov/servlets/purl/1327212 Lovik, A. N., Restrepo, E., & Muller, D. B. (2015). The global anthropogenic gallium system: Determinants of demand, supply and efficiency improvements. Environmental Science & Technology, 49(9), 5704-5712. doi:10.1021/acs.est.5b00320 Lu, F., Xiao, T., Lin, J., Ning, Z., Long, Q., Xiao, L., Huang, F., Wang, W., Xiao, Q., Lan, X., & Chen, H. (2017). Resources and extraction of gallium: A review. Hydrometallurgy, 174, 105-115. doi:https://doi.org/10.1016/j.hydromet.2017.10.010 Lukaszewski, Z., Jakubowska, M., & Zembrzuski, W. (2018). The mobility of thallium from bottom soil of the Silesian-Cracowian zinc-lead ore deposit region (Poland). Journal of Geochemical Exploration, 184, 11-16. doi:10.1016/j.gexplo.2017.10.009 Manceau, A., Marcus, M. A., & Tamura, N. (2002). Quantitative speciation of heavy metals in soils and sediments by synchrotron x-ray techniques. Reviews in Mineralogy and Geochemistry, 49(1), 341-428. Markiewiez-Patkowska, J., Hursthouse, A., & Przybyla-Kij, H. (2005). The interaction of heavy metals with urban soils: Sorption behaviour of Cd, Cu, Cr, Pb and Zn with a typical mixed brownfield deposit. Environment International, 31(4), 513-521. doi:10.1016/j.envint.2004.09.004 Matilainen, A., Gjessing, E. T., Lahtinen, T., Hed, L., Bhatnagar, A., & Sillanpää, M. (2011). An overview of the methods used in the characterisation of natural organic matter (NOM) in relation to drinking water treatment. Chemosphere, 83(11), 1431-1442. doi:https://doi.org/10.1016/j.chemosphere.2011.01.018 Matzapetakis, M., Kourgiantakis, M., Dakanali, M., Raptopoulou, C., Terzis, A., Lakatos, A., Kiss, T., Banyai, I., Iordanidis, L., Mavromoustakos, T., & Salifoglou, A. (2001). Synthesis, pH-dependent structural characterization, and solution behavior of aqueous aluminum and gallium citrate complexes. Inorganic chemistry, 40(8), 1734-1744. doi: https://doi.org/10.1021/ic000461l McBride, M. (1994). Environmental chemistry of soils. New York, NY: Oxford Press. Moerlein, S. M., & Welch, M. J. (1981). The chemistry of gallium and indium as related to radiopharmaceutical production. International Journal of Nuclear Medicine and Biology, 8(4), 277-287. doi:https://doi.org/10.1016/0047-0740(81)90034-6 Naidu, R., & Harter, R. D. (1998). Effect of different organic ligands on cadmium sorption by and extractability from soils. Soil Science Society of America Journal, 62(3), 644-650. doi:10.2136/sssaj1998.03615995006200030014x Naidu, R., Kookana, R. S., Sumner, M. E., Harter, R. D., & Tiller, K. G. (1997). Cadmium sorption and transport in variable charge soils: A review. Journal of Environmental Quality, 26, 602-617. doi:10.2134/jeq1997.00472425002600030004x Newcombe, G., & Drikas, M. (1997). Adsorption of NOM onto activated carbon: Electrostatic and non-electrostatic effects. Carbon, 35(9), 1239-1250. doi:https://doi.org/10.1016/S0008-6223(97)00078-X Ogner, G., & Schnitzer, M. (1971). Chemistry of fulvic acid, a soil humic fraction, and its relation to lignin. Canadian Journal of Chemistry, 49(7), 1053-1063. Omura, M., Yamazaki, K., Tanaka, A., Hirata, M., Makita, Y., & Inoue, N. (2000). Changes in the testicular damage caused by indium arsenide and indium phosphide in hamsters during two years after intratracheal instillations. Journal of Occupational Health, 42(4), 196-204. doi:10.1539/joh.42.196 Pearson, R. G. (1963). Hard and soft acids and bases. Journal of the American Chemical Society, 85(22), 3533-3539. Poledniok, J. (2008). Speciation of scandium and gallium in soil. Chemosphere, 73(4), 572-579. doi:10.1016/j.chemosphere.2008.06.012 Poledniok, J., Kita, A., & Zerzucha, P. (2012). Spectrophotometric and inductively coupled plasma-optical emission spectroscopy determination of gallium in natural soils and soils polluted by industry: Relationships between elements. Communications in Soil Science and Plant Analysis, 43(8), 1121-1135. doi:10.1080/00103624.2012.662561 Reid, B. J., Jones, K. C., & Semple, K. T. (2000). Bioavailability of persistent organic pollutants in soils and sediments-A perspective on mechanisms, consequences and assessment. Environmental Pollution, 108(1), 103-112. doi:https://doi.org/10.1016/S0269-7491(99)00206-7 Ringering, K., Kouhail, Y., Yecheskel, Y., Dror, I., & Berkowitz, B. (2019). Mobility and retention of indium and gallium in saturated porous media. Journal of Hazardous Materials, 363, 394-400. doi:https://doi.org/10.1016/j.jhazmat.2018.09.079 Ritchie, R. J., & Raghupathi, S. S. (2008). Al-toxicity studies in yeast using gallium as an aluminum analogue. Biometals, 21(4), 379-393. Retrieved from https://link.springer.com/content/pdf/10.1007%2Fs10534-007-9127-2.pdf Santschi, P. H., Xu, C., Zhang, S., Schwehr, K. A., Lin, P., Yeager, C. M., & Kaplan, D. I. (2017). Recent advances in the detection of specific natural organic compounds as carriers for radionuclides in soil and water environments, with examples of radioiodine and plutonium. Journal of Environmental Radioactivity, 171, 226-233. doi:https://doi.org/10.1016/j.jenvrad.2017.02.023 Schmidt, M. W. I., Torn, M. S., Abiven, S., Dittmar, T., Guggenberger, G., Janssens, I. A., Kleber, M., Kögel-Knabner, I., Lehmann, J., Manning, D. A. C., Nannipieri, P., Rasse, D. P., Weiner, S., & Trumbore, S. E. (2011). Persistence of soil organic matter as an ecosystem property. Nature, 478(7367), 49-56. doi:10.1038/nature10386 Schmitt, D., Taylor, H. E., Aiken, G. R., Roth, D. A., & Frimmel, F. H. (2002). Influence of natural organic matter on the adsorption of metal ions onto clay minerals. Environmental Science & Technology, 36(13), 2932-2938. doi:10.1021/es010271p Schnitzer, M. (1978). Humic substances: Chemistry and reactions. In M. Schnitzer & S. U. Khan (Eds.), Developments in soil science (Vol. 8, pp. 1-64). doi:https://doi.org/10.1016/S0166-2481(08)70016-3 Schnitzer, M., & Hansen, E. (1970). Organo-metallic interactions in soils: 8. An evaluation of methods for the determination of stability constants of metal-fulvic acid complexes. Soil Science, 109(6), 333-340. Schnitzer, M., & Skinner, S. I. M. (1966). Organo-metallic interactions in soils: 5. Stability constants of Cu++-, Fe++-, and Zn++-fulvic acid complexes. Soil Science, 102(6), 361-365. Schwarz-Schampera, U. (2014). Indium. In G. Gun (Eds.), Critical metals handbook (pp. 204-229). Oxford, UK: John Wiley & Sons. Senesi, N., & Brunetti, G. (1996). Chemical and physico-chemical parameters for quality evaluation of humic substances produced during composting. In M. Bertoldi, P. Sequi, B. Lemmes & T. Papi (Eds.), The science of composting (pp. 195-212). Dordrecht, NL: Springer. Shaheen, S. M., Tsadilas, C. D., & Rinklebe, J. (2013). A review of the distribution coefficients of trace elements in soils: Influence of sorption system, element characteristics, and soil colloidal properties. Advances in Colloid and Interface Science, 201, 43-56. Retrieved from https://www.sciencedirect.com/science/article/pii/S0001868613001206?via%3Dihub Sillanpää, M., Ncibi, M. C., Matilainen, A., & Vepsäläinen, M. (2018). Removal of natural organic matter in drinking water treatment by coagulation: A comprehensive review. Chemosphere, 190, 54-71. doi:https://doi.org/10.1016/j.chemosphere.2017.09.113 Singh, U., Uehara, G. (1998).Electrochemistry of the double layer: Principle and application to soils. In Sparks, D. L. (Eds.), Soil Physical Chemistry (pp. 1-46). New York, NY: CRC Press. Spark, K. M., Wells, J. D., & Johnson, B. B. (1997). Sorption of heavy metals by mineral-humic acid substrates. Aust J Soil Res, 35(1), 113-122. doi:10.1071/S96010 Sparks, D. L. (1998). Kinetics and mechanisms of chemical reaction at the soil mineral /water interface. In Sparks, D. L. (Eds.), Soil Physical Chemistry (pp. 135-192). New York, NY: CRC Press. Sparks, D. L. (2003). Chemistry of soil organic matter. In Sparks, D. L. (Eds.), Environmental soil chemistry (pp. 101-110). California, USA: Elsevier Science. Sposito, G. (1984). The surface chemistry of soils. New York, NY: Oxford university press. Sposito, G. (2004). The surface chemistry of natural particles. New York, NY: Oxford University Press. Sposito, G. (2008). The chemistry of soils.New York, NY: Oxford university press. Stevenson, F. (1982). Extraction, fractionation, and general chemical composition of soil organic matter. Humus chemistry. Genesis, composition, reactions, 26-54. Stevenson, F., & Fitch, A. (1986). Chemistry of complexation of metal ions with soil solution organics. Interactions of soil minerals with natural organics and microbes, (17), 29-58. doi: https://doi.org/10.2136/sssaspecpub17.c2 Stevenson, F. J. (1994). Humus chemistry: genesis, composition, reactions. Canada, CA: John Wiley & Sons. Summers, R. S., & Roberts, P. V. (1988). Activated carbon adsorption of humic substances. II. Size exclusion and electrostatic interactions. Journal of Colloid And Interface Science, 122(2), 382-397. doi:10.1016/0021-9797(88)90373-6 Sun, C., Yue, Q., Gao, B., Mu, R., Liu, J., Zhao, Y., Yang, Z. & Xu, W. (2011). Effect of pH and shear force on flocs characteristics for humic acid removal using polyferric aluminum chloride-organic polymer dual-coagulants. Desalination, 281, 243-247. doi:https://doi.org/10.1016/j.desal.2011.07.065 Tack, F. M. G. (2010). Trace elements: General Soil Chemistry, priciples and processes. In P. S. Hooda (Eds.), Trace elements in soils (pp.13-23). United Kingdom: John, Wiley & Sons. Tanaka, A., Hirata, M., Kiyohara, Y., Nakano, M., Omae, K., Shiratani, M., & Koga, K. (2010). Review of pulmonary toxicity of indium compounds to animals and humans. Thin Solid Films, 518(11), 2934-2936. doi:10.1016/j.tsf.2009.10.123 Thurman, E. M., & Malcolm, R. L. (1981). Preparative isolation of aquatic humic substances. Environmental Science & Technology, 15(4), 463-466. Tokumaru, T., Ozaki, H., Onwona-Agyeman, S., Ofosu-Anim, J., & Watanabe, I. (2017). Determination of the extent of trace metals pollution in soils, sediments and human hair at e-waste recycling site in Ghana. Archives of environmental contamination and toxicology, 73(3), 377-390. Retrieved from https://link.springer.com/content/pdf/10.1007%2Fs00244-017-0434-5.pdf Violante, A., Cozzolino, V., Perelomov, L., Caporale, A. G., & Pigna, M. (2010). Mobility and bioavailability of heavy metals and metalloids in soil environments. Journal of Soil Science and Plant Nutrition, 10(3), 268-292. doi:10.4067/S0718-95162010000100005 Wood, S. A., & Samson, I. M. (2006). The aqueous geochemistry of gallium, germanium, indium and scandium. Ore Geology Reviews, 28(1), 57-102. doi:https://doi.org/10.1016/j.oregeorev.2003.06.002 Woodwell, G. M., Whittaker, R., Reiners, W., Likens, G. E., Delwiche, C., & Botkin, D. (1978). The biota and the world carbon budget. Science, 199(4325), 141-146. Retrieved from https://science.sciencemag.org/content/sci/199/4325/141.full.pdf Xiao, F., Yi, P., Pan, X. R., Zhang, B. J., & Lee, C. (2010). Comparative study of the effects of experimental variables on growth rates of aluminum and iron hydroxide flocs during coagulation and their structural characteristics. Desalination, 250(3), 902-907. doi:https://doi.org/10.1016/j.desal.2008.12.050 Yang, J. L. (2014). Comparative acute toxicity of gallium (III), antimony (III), indium (III), cadmium (II), and copper (II) on freshwater swamp shrimp (Macrobrachium nipponense). Biological research, 47(1). doi:10.1186/0717-6287-47-13 Young, S. D. (2013). Chemistry of heavy metals and metalloids in soils. In B. J. Alloway (Eds.), Heavy metals in soils (pp. 51-96). Dordrecht, NL: Springer. Yu. I. Tarasevich, V. V. L. y., G. M. Tel’biz. (2005). Interaction of humic and fulvic acids with nanoclusters of aluminum hydroxo cations on the surface of kaolinite according to IR spectroscopy data. Theoretical and Experimental Chemistry, 41(1), 48-52. doi:https://doi.org/10.1007/s11237-005-0021 | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/66803 | - |
dc.description.abstract | 隨著半導體、光電和能源等高科技新興產業的發展,鎵和銦及其他具有特別理化性質的元素被使用於相關製程中,並釋放至環境當中。臺灣已發現許多科技產業園區周遭地下水的鎵和銦濃度較自然背景為高,可能造成土壤污染並藉由作物進入食物鏈對人體和生態產生危害,故必須瞭解這些污染物進入土壤後的物種型態與宿命。土壤中吸附反應決定金屬離子的移動性和生物有效性,腐植酸是土壤系統中有機物質中腐植物質組成分之一,因具有各類官能基而具有與重金屬錯合的能力,在土壤環境中金屬的傳輸扮演重要的角色。為了釐清土壤中有機物質對鎵與銦的影響,本研究將以腐植酸作為吸附劑進行鎵和銦離子的吸附反應,以期探討腐植酸與鎵和銦之間的反應機制。在低 pH 值 (pH 3.0 – 6.0) 環境溶液中,腐植酸對鎵和銦皆有高吸附量,形成不具移動性且穩定的錯合物型態。隨著 pH 值的遞增,在高 pH 值環境中 (pH 8.0 以上) ,鎵是以具移動性的物種型態存在,且其含量隨著溶液中可溶性碳濃度含量的增加而上升;銦則是以不具移動性的錯合物型態,且含量隨著 pH 值的遞增而增加。其中鎵和銦分別在鹼性及中性 pH 值環境中具有最大移動性。反應時間與溶液離子強度的增加同時促進了:溶液中具可移動性的鎵,具可移動性的銦 (pH 3.0 – 6.0) 及腐植酸-銦穩定型態錯合物 (pH 7.0 – 11.0) 含量的增加。從 XANES 及 EXAFS 光譜分析數據得知,吸附實驗中鎵和銦皆無沉澱物生成,表示在有腐植酸的系統中,鎵和銦產生沉澱物之機率降到最低。 因此鎵和銦被腐植酸所吸附時,其移動性和有效性可能因此而增加,導致環境風險隨之增加。 | zh_TW |
dc.description.abstract | The development of semiconductors and optoelectronics industries has resulted in the release of gallium (Ga) and indium (In) into the environment, which could pose a threat to public health. To lower the environmental risk of these emerging pollutants, it is crucial to understand their fates in the environment. In soil environments, the adsorption and desorption reactions of pollutants by soil constituents determines their mobility and bioavailability. Humic acid is one of soil colloids, which play an important role in determining metal mobility and bioavailability in soil. This study investigated the adsorption mechanism of humic acid on Ga and In ions. The adsorption experiments were carry out under several different conditions including solution pH and ionic strength. The experimental results revealed that humic acid has strong affinity for Ga and In as indicated by the high adsorption capacity of humic acid for Ga and In. Ga and In were bound to humic acid through forming a non-mobile and stable complex in low pH range (pH 3.0-6.0) solution. A mobile species of Ga-humic acid complexes formed at pH 8.0 and above. Comparatively, In was reacted with humic acid to form an immobile complex at different pHs. Meanwhile, Ga and In have the highest mobility in alkaline and neutral pH conditions, respectively. The results of X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) show that the coordination environment of Ga-humic acid complexes changed with increasing solution pH, while that of In-humic acid complexes remained the same. No precipitation occurred in either Ga or In system. Thus, the adsorption of Ga and In on humic acid may result in the increase in the mobility and availability of Ga and In, which may consequently increase their environmental risks. | en |
dc.description.provenance | Made available in DSpace on 2021-06-17T01:08:38Z (GMT). No. of bitstreams: 1 ntu-108-R05623028-1.pdf: 4553966 bytes, checksum: ccdc4f579b53c9c1cbf62b661739896a (MD5) Previous issue date: 2019 | en |
dc.description.tableofcontents | 中文摘要 i
ABSTRACT ii 目錄 iii 圖目錄 vi 表目錄 viii 第 1 章 前言 1 第 2 章 研究目的 4 第 3 章 文獻回顧 5 3.1 土壤中重金屬存在之型態與傳輸 5 3.2 土壤中重金屬的吸附反應 6 3.3 影響吸附反應的土壤因子 8 3.4 鎵、銦 9 3.4.1 鎵、銦的來源及環境背景濃度 9 3.4.2 鎵、銦的毒性 10 3.4.3 鎵、銦在土壤中的型態物種 11 3.5 有機物質 15 3.5.1 腐植酸 17 第4章 材料與方法 18 4.1 腐植酸純化 18 4.2 實驗溶液配製 19 4.2.1 背景溶液 19 4.2.2 腐植酸懸浮液 19 4.2.3 金屬母液 19 4.3 實驗方法 21 4.3.1 在不同溶液 pH 值下金屬的滴定實驗 21 4.3.2 在不同溶液 pH 值下 HA 對金屬的吸附實驗 22 4.3.3 溶液反應時間差異對 HA 吸附金屬反應之影響 23 4.3.4 溶液離子強度差異對 HA 吸附金屬反應之影響 24 4.4 化學分析 25 4.4.1 金屬定量分析 25 4.4.2 可溶性有機碳分析 26 4.4.3 同步輻射 26 第5章 實驗結果與討論 27 5.1 前置實驗-滴定實驗結果 27 5.2 金屬滴定實驗結果 30 5.3 在不同溶液 pH 值下腐植酸對金屬的吸附實驗結果 33 5.4 反應時間差異對腐植酸吸附金屬反應之影響 37 5.5 溶液離子強度差異對腐植酸吸附金屬反應之影響 38 5.6 小結 39 5.7 同步輻射分析結果 41 5.7.1 在不同溶液 pH 值下腐植酸對金屬的等溫吸附實驗 41 5.7.2 反應時間差異對腐植酸吸附金屬反應之影響 48 5.2.6 小結 55 5.8 小結 67 第6章 結論 68 參考文獻 70 附錄圖表 78 | |
dc.language.iso | zh-TW | |
dc.title | 腐植酸對三價鎵和銦之吸附作用 | zh_TW |
dc.title | Adsorption of Trivalent Gallium and Indium by Humic Acid | en |
dc.type | Thesis | |
dc.date.schoolyear | 108-1 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 許正一(Zeng-Yei Hseu),劉雨庭(Yu-Ting Liu),鄒裕民(Yu-Min Tzou) | |
dc.subject.keyword | 鎵,銦,腐植酸,吸附,X 光吸收光譜, | zh_TW |
dc.subject.keyword | Gallium,Indium,humic acid,Adsorption,X-ray Absorption Spectroscopy, | en |
dc.relation.page | 88 | |
dc.identifier.doi | 10.6342/NTU202000024 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2020-02-03 | |
dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
dc.contributor.author-dept | 農業化學研究所 | zh_TW |
顯示於系所單位: | 農業化學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-108-1.pdf 目前未授權公開取用 | 4.45 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。