Please use this identifier to cite or link to this item:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/66754Full metadata record
| ???org.dspace.app.webui.jsptag.ItemTag.dcfield??? | Value | Language |
|---|---|---|
| dc.contributor.advisor | 陸天堯(Tien-Yau Luh) | |
| dc.contributor.author | Chung-Shian Yeh | en |
| dc.contributor.author | 葉重賢 | zh_TW |
| dc.date.accessioned | 2021-06-17T00:55:39Z | - |
| dc.date.available | 2011-10-21 | |
| dc.date.copyright | 2011-10-21 | |
| dc.date.issued | 2011 | |
| dc.date.submitted | 2011-09-23 | |
| dc.identifier.citation | 1. Ivin, K. J.; Mol, J. C. Olefin Metathesis and Metathesis Polymerization, Academic Press, San Diego, CA, 1997, Chap 1-2.
2. Truett, W. L.; Johnson, D. R.; Robinson, I. M.; Montague, B. A. J. Am. Chem. Soc. 1960, 82, 2337-2340. 3. Schrock, R. R.; Murdzek, J. S.; Bazan, G. C.; Robbins, J.; Dimare, M.; O’Regan, M. J. Am. Chem. Soc. 1990, 112, 3875-3886. 4. Schrock, R. R. Acc. Chem. Res. 1990, 23, 158-165. 5. Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707-4713. 6. Schwab, P.; France, M. B.; Ziller, J. W.; Grubbs, R. H. Angew. Chem., Int. Ed. Engl. 1995, 34, 2039-2041 7. Trnka, T. M.; Grubbs, R. H. Acc. Chem. Res. 2001, 34, 18-29. 8. Weskamp, T.; Schattenmann, W. C.; Spiegler, M.; Herrmann, W. A. Angew. Chem. Int. Ed. 1998, 37, 2490-2493. 9. Weskamp., T.; Kohl, F. J.; Hieringer, W.; Gleich, D.; Herrmann, W. A. Angew. Chem. Int. Ed. 1999, 38, 2416-2419. 10. Scholl, M.; Trnka,T. M.; Morgan, J. P.; Grubbs, R. H. Tetrahedron Lett. 1999, 40, 2247-2250. 11. Huang, J.; Stevenes, E. D.; Nolan, S. P.; Peterson, J. L. J. Am. Chem. Soc. 1999, 121, 2675-2678. 12. Watkins, D. M.; Fox, M. A.; Macromolecules 1995, 28, 4939-4959. 13. Watkins, D. M.; Fox, M. A.; J. Am. Chem. Soc. 1996, 118, 4344-4353. 14. Fossum, R. D.; Fox, M. A. J. Am. Chem. Soc. 1997, 119, 1197-1207. 15. Watkins, D. M.; Fox, M. A.; J. Am. Chem. Soc. 1994, 116, 6441-6442. 16. Liu, Z.-C.; Chen, C.-H; Wang, H.-W.; Huang, Y.-C.; Kao, M.-J.; Lim, T.-S.; Luh, T. L. Chem. Asian J. 2010, 5, 1425-1438. 17. Maughon, B. R.; Weck, M.; Mohr, B.; Grubbs, R. H. Macromolecules 1997, 30, 257-265. 18. Weck, M.; Mohr, B.; Maughon, B. R.; Grubbs, R. H. Macromolecules 1997, 30, 6430-6437. 19. Sattigeri, J. A.; Shiau, C.-W. Hsu, C. C.; Yeh, F.-F.; Liou, S.; Jin, B. -H.; Luh, T.-Y. J. Am. Chem. Soc.1999, 121, 1607-1608. 20. Park, K. H.; Twieg, R. J.; Rohdes, L. F.; Shick, R. A.; Yankelevich, D.; , Knoesen, A. Macromolecules. 2004, 37, 5163-5178. 21. Delaude L. Demonceau, A. Noels, A. F. Macromolecules. 2003, 36, 1446-1456. 22. O'Dell, R.; McConville, D. H.; Hofmeister, G. E.; Schrock, R. R. J. Am. Chem. Soc. 1994, 116, 3414-3423. 23. Lin, W.-Y.; Wang, H.-W.; Liu, Z.-C.; Xu, J.; Chen, C.-W.; Yang, Y.-C.; Huang, S.-L.; Yang, H.-C.; Luh, T.-Y. Chem. Asian J. 2007, 2, 764-774. 24. Schrock, R. R. unpublished result. 25. Zhu, L.; Luh, T. Y. unpublished result. 26. Kanis, D. R.; Ratner, M. A.; Marks, T. J. Chem. Rev. 1994, 94, 195-242. 27. Verbiest, T.; Houbrechts, S.; Kauranen, M.; Clay, K.; Persoons. A. J. Mater. Chem. 1997, 7, 2175-2189. 28. Clays, K.; Persoons, A. Phys. Rev. Lett. 1991, 66, 2980-2983. 29. Kauranen, M.; Verbiest, T.; Boutton, C.; Teerenstra, M. N.; Clays, K.; Schouten, A. J.; Nolte, R. J. M.; Persoons, A. Science. 1995, 270, 966-969. 30. Pauley, M. A.; Wang, C. H.; Chem. Phys. Lett. 1997, 280, 544-550. 31. Lin, W.-T.; Murugesh, M. G.; Sudhakar, S.; Yang H.-C.; Tai, H.-C.; Chang, C.-S.; Liu, Y.-H.; Wang, Y.; Chen, I.-W. P.; Chen, C.-H.; Luh, T.-Y. Chem. Eur. J. 2006, 12, 324 – 330. 32. Anderson , A. G.; Steckler, B. M. J. Am. Chem. Soc. 1959, 81, 4941-4946. 33. ) Wang, P.; Zhu, P.; Ye, C.; Asato, A. E.; Liu, R. S. H. J. Phys. Chem. A. 1999, 103, 7076-7082. 34. Morley, J. O. J. Am. Chem. Soc. 1988, 110, 7660-7663. 35. Ito, S.; Inabe, H.; Morita, N.; Ohta, K.; Kitamura, T.; Imafuku, K. J. Am. Chem. Soc. 2003, 125, 1669-1680. 36. Ito, S.; Ando, M.; Nomura, A.; Morita, N.; Kabuto, C.; Mukai, H.; Ohta, K.; Kawakami, J.; Yoshizawa, A.; Tajiri,A. J. Org. Chem. 2005, 70, 3939-3949. 37. Asato, A. E.; Liu, R. S. H.; Rao, V. P.; Cai, Y. M. Tetrahedron Lett. 1996, 37, 419-422. 38. Lacroix, P. G.; Malfant, I.; Iftime, G.; Razus, A. C.; Nakatani K.; Delaire, J. A. Chem. Eur. J. 2000, 6, 2599-2608. 39. Cristian, L.; Sasaki, I.; Lacroix, P. G.; Donnadieu, B.; Asselberghs, I.; Clays, K.; Razus, A. C. Chem. Mater. 2004, 16, 3543–3551. 40. Reich, L. Polym. Lett. 1964, 2, 943-946. 41. Tourillon, G.; Garnier, F. J. Eletroanal. Chem. 1982, 135, 173-178. 42. Bross, P. A.; Schöberl, U.; Daub, J. Adv. Mater. 1991, 4, 198-200. 43. Redl, F. X.; Köthe, O.; Röckl, K.; Bauer, W.; Daub, J. Macromol. Chem. Phys. 2000, 201, 2091-2100. 44. Wang, X.; Ng, J. K.-P.; Jia, P.; Lin, T.; Cho, C. M.; Xu, J.; Lu, X.; He, C. Macromolecules. 2009, 42, 5534-5544. 45. Nozoe, T.; Seto, S.; Matsumura, S.; Murase, Y. Bull. Chem. Soc. Jpn. 1962, 35, 1179-1188. 46. Nozoe, T.; Asao, T.; Susumago, H.; Ando, M. Bull. Chem. Soc. Jpn. 1974, 47, 1471–1476. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/66754 | - |
| dc.description.abstract | 我們設計降冰片烯與薁的2號與6號位置相連接的兩種單體，並且運用降冰片烯雙鍵經過開環歧化聚合反應製備聚合物。薁是典型多環系統的非苯環性芳香環，其特殊的共振結構導致此分子具有較大的偶極矩及非線性光學性質，故在降冰片烯高分子骨架上引入具此偶極的基團薁，藉以了解懸掛基團對高分子光物理性質之影響
不論是單體或者聚合物在紫外-可見光光譜中，皆可以觀察到薁分子與對胺苯甲酸酯典型的吸收。將所得到的聚合物水解，經由核磁共振光譜可鑑定出聚合物的立體化學結構為全反式雙鍵全同向且全同立體排列。 利用超瑞利散射實驗，隨著聚合物分子量的增加，非線性光學性質也會隨之增加，此現象說明了降冰片烯的剛性骨架使發光團朝著同一方向的排列。 | zh_TW |
| dc.description.abstract | The azulene-appended polynorbornenes were synthesized. Herein, two monomers with different azulene moieties were designed and the polymers were synthesized through ring opening metathesis polymerization (ROMP). The azulenes are bicyclic non-benzenoid aromatics which exhibit strong dipole moments and significant nonlinear optical properties.
The intrinsic absorption from azulene and aminobezoate was observed, the | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T00:55:39Z (GMT). No. of bitstreams: 1 ntu-100-R98223115-1.pdf: 13246449 bytes, checksum: 4406bb1eb9a79e022c8c3afe9db60164 (MD5) Previous issue date: 2011 | en |
| dc.description.tableofcontents | 中文摘要…………………………………………………………………………......I
英文摘要……………………………………………………………………………..II 章節目錄……………………………………………………………………………..III 圖目錄……………………………………………………………………………......IV 表目錄………………………………………………………………………………VI 第一章 緒論…………………………………………………………………………1 第二章 結果與討論………………………………………………………………20 2-1具降冰片烯股架懸掛薁之衍生高分子………………………………….20 2-1-1 單體與高分子之合成………………………………………………20 2-2 降冰片烯股架懸掛薁單體及聚合物的結構分析…………………………...25 2-2-1 利用NMR分析聚合物之結構分析…………………………………..21 2-2-2 單體、聚合物紫外-可見光光譜之分析………………………………31 2-3 單體、聚合物非線性光學 (nonlinear optics) 之分析………………………43 第三章 結論…………………………………………………………………………45 第四章 實驗部分……………………………………………………………………46 4.1 實驗之一般敘述……………………………………………………………...46 4.2 實驗步驟……………………………………………………………………...49 第五章 參考文獻……………………………………………………………………62 附件一 GPC 數據…………………………………………………………………..66 附件二 end group 分析數據………………………………………………………..68 附錄…………………………………………………………………………………..70 部分化合物之1H NMR光譜與13C NMR光譜 | |
| dc.language.iso | zh-TW | |
| dc.subject | 降冰片烯高分子 | zh_TW |
| dc.subject | 薁 | zh_TW |
| dc.subject | azulene | en |
| dc.subject | nonlinear optical | en |
| dc.subject | HRS | en |
| dc.title | 以薁為懸掛基團之單股降冰片烯高分子 | zh_TW |
| dc.title | Polynorbornenes Appended with Azulenes | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 100-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 葉名倉(Ming-Chung Yeh),汪根欉(Ken-Tsung Wong) | |
| dc.subject.keyword | 薁,降冰片烯高分子, | zh_TW |
| dc.subject.keyword | azulene,nonlinear optical,HRS, | en |
| dc.relation.page | 99 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2011-09-23 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| Appears in Collections: | 化學系 | |
Files in This Item:
| File | Size | Format | |
|---|---|---|---|
| ntu-100-1.pdf Restricted Access | 12.94 MB | Adobe PDF |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.