請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/66470完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 徐治平(Jyh-Ping Hsu) | |
| dc.contributor.author | I-Fan Ko | en |
| dc.contributor.author | 柯逸凡 | zh_TW |
| dc.date.accessioned | 2021-06-17T00:37:25Z | - |
| dc.date.available | 2013-02-16 | |
| dc.date.copyright | 2012-02-16 | |
| dc.date.issued | 2012 | |
| dc.date.submitted | 2012-02-01 | |
| dc.identifier.citation | (1) Shugai, A. A.; Carnie, S. L. “Electrophoretic motion of a spherical particle with a thick double layer in bounded flows”, J. Colloid Interface Sci. 1999, 213, 298-315.
(2) Ebel, J. P.; Anderson, J. L.; Prieve, D.C. “Diffusiophoresis of latex particles in electrolyte gradients”, Langmuir 1988, 4, 396-406. (3) Tu, H.J.; Keh, H. J. “Particle interactions in diffusiophoresis and electrophoresis of colloidal spheres with thin but polarized double layers”, Colloid Interface Sci. 2000, 231, 265-282. (4) Deryaguin, B. V.; Dukhin, S. S.; Korotkova, A. A. “Influence of nature of electrolytes in latex on the process of film formation by ionic deposition”, Colloidal J. USSR 1978, 40, 531-536. (5) Dukhin, S. S.; Malkin, E. S.; Dukhin, A. S. “Noninertial electrophoretic and diffusiophoretic drift of particles in nonuniform, alternating electric-fields”, Colloid J. USSR. 1979, 41, 734-739. (6) Hsu, J. P.; Hsu, W. L.; Chen, Z. S. “Boundary effect on diffusiophoresis: spherical particle in a spherical cavity”, Langmuir 2009, 25, 1772-1784. (7) Dvornichenko, G. L.; Nizhnik, Y. V.; Slavikovskii, T. V. “Diffusiophoretic deposition of polymeric dispersions with the goal of obtaining protective coatings on metals”, Colloid J. Russ. Acad. Sci. 1993, 55, 36-39. (8) Zoulalian, A.; Albiol, T. “Evaluation of aerosol deposition by thermophoresis and diffusion phoresis during flow through a cylinder-Applications to project tuba diffusiophoresis”, Can. J. Chem. Eng. 1998, 76, 799-805. (9) Munoz-Cobo, J. L.; Pena, J.; Herranz, L. E.; Perez-Navarro, A. ”Steam condensation on finned tubes, in the presence of non-condensable gases and aerosols: Influence of impaction, diffusiophoresis and settling on aerosol deposition”, Nuclear Eng. Design 2005, 235, 1225-1237. (10) Hidy, G. M.; Brock, J. R. “Lung deposition of aerosols. A footnote on the role of diffusiophoresis”, Environ. Sci. Technol. 1969 , 3, 563-570. (11) Voyutskii, S. S.; Markin, Y. I.; Gorchakova, V. M.; Gul, V. E. “Adhesion of high polymers to metals .4. The temperature dependence and the activation energy of adhesion”, Zhurnal Fiz. Khimii. 1963, 37, 2027-2032. (12) Korotkova, A. A.; Deryagin, B. V. “Role of diffusiophoresis in the mechanism of film formation from rubber latexes by ion deposition”, Colloid J. USSR. 1991, 53, 719-722. (13) Goldsmith, P.; Delafield, H. J.; Cox, L. C. “The role of diffusiophoresis in the scavenging of radioactive particles from the atmosphere”, Quar. J. Roy. Meteo. Soc. 1963, 89, 43-49. (14) Abecassis, B.; Cottin-Bizonne, C.; Ybert, C.; Ajdari, A.; Bocquet, L. “Boosting migration of large particles by solute contrasts”, Nat. Mater. 2008, 7, 785-789. (15) Staffeld, P. O.; Quinn, J. A. “Diffusion-induced banding of colloid particles via diffusiophoresis : 1. Electrolytes”, Colloid Interface Sci. 1989, 130, 69-87. (16) Anderson, J. L.; Lowell, M. E.; Prieve, D. C. ”Motion of a particle generated by chemical gradients. 1. Non-electrolytes”, J. Fluid Mech. 1982, 117, 107-121. (17) Staffeld, P. O.; Quinn, J. A. “Diffusion-induced banding of colloid particles via diffusiophoresis. 2. Non-electrolytes”, J. Colloid Interface Sci. 1989, 130, 88-100. (18) Prieve, D. C. CIT Eng. News 1982, 2, 5. (19) Dukhin, S. S.; Deryaguin, B. V. Surface and Colloid Science, Vol. 7; Wiley: New York, 1974 (20) Prieve, D. C.; Anderson, J. L.; Ebel, J. P.; Lowell, M. E. “Motion of a particle generated by chemical gradients. 2. Electrolytes”, J. Fluid Mech. 1984, 148, 247-269. (21) Malkin, E. S.; Dukhin A. S. “Interaction of dispersed particles in an electric-field and linear concentration polarization of the double-layer”, Colloidal J. USSR. 1982, 44, 801-810. (22) Prieve, D. C.; Roman, R. “Diffusiophoresis of a rigid sphere through a viscous electrolyte solution”, J. Chem. Soc. Faraday Trans. II 1987, 83, 1287-1306. (23) Pawar, Y.; Solomentsev, Y. E.; Anderson, J. L. “Polarization effects on diffusiophoresis in electrolyte gradients”, J. Colloid Interface Sci. 1993, 155, 488-498. (24) Keh, H. J.; Li, Y. L. “Diffusiophoresis in a suspension of charge-regulating colloidal spheres”, Langmuir 2007, 23, 1061-1072. (25) Keh, H. J.; Jan, J. S. “Boundary effects on diffusiophoresis and electrophoresis: motion of a colloidal sphere normal to a plane wall”, J. Colloid Interface Sci. 1996, 183, 458-475. (26) Lou, J.; He, Y.Y.; Lee, E. ”Diffusiophoresis of concentrated suspensions of spherical particles with identical ionic diffusion velocities”, J. Colloid Interface Sci. 2006, 299, 443-451. (27) Hsu, J. P.; Lou, J.; He, Y. Y.; Lee, E. “Diffusiophoresis of concentrated suspensions of spherical particles with distinct ionic diffusion velocities”, J. Phys. Chem. B 2007, 111, 2533-2539. (28) Lou, J.; Lee, E. “Diffusiophoresis of a spherical particle normal to a plane”, Phys. Chem. C 2008, 112, 2584-2592. (29) Lou, J.; Lee, E. “Diffusiophoresis of a spherical particle normal to a plane”, Phys. Chem. C 2008, 112, 2584-2592. (30) Malkin, E. S.; Dukhin, A. S. “Aperiodic electrodiffusiophoresis” Colloidal J. USSR. 1982, 44, 224-233. (31) Ma, H. C.; Keh, H. J. “Diffusioosmosis of electrolyte solutions in a fine capillary slit”, J. Colloid Interface Sci. 2006, 298, 476-486. (32) Keh, H. J.; Hsu, Y. S. “Diffusiophoresis of a colloidal sphere in nonelectrolyte gradients in a circular cylindrical pore”, Chem. Eng. Sci. 2006, 61, 3550-3563. (33) Keh, H. J.; Ma, H. C. “Diffusioosmosis of electrolyte solutions in a fine capillary tube”, Langmuir 2007, 23, 2879-2886. (34) Chang, Y. C.; Keh, H. J. “Diffusiophoresis and electrophoresis of a charged sphere perpendicular to two plane walls”, J. Colloid Interface Sci. 2008, 322, 634-653. (35) Hsu, J. P.; Luu, X. C.; Hsu, W. L. “Diffusiophoresis of an ellipsoid along the axis of a cylindrical pore”, J. Phys. Chem. B, 2010, 114, 598-606. (36) Joo, S. W.; Lee, S.Y.; Liu. J.; Qian, S.; “Diffusiophoresis of an elongated cylindrical nanoparticle along the axis of a nanopore”, ChemPhysChem 2010, 11, 3281-3288. (37) Lee, S. Y.; Yalcin, S. E.; Joo, S. W.; Baysal, O.; Qian, S. “Diffusiophoretic motion of a charged spherical particle in a nanopore”, J. Phys. Chem. B 2010, 114, 6437-6446. (38) Hsu, J. P.; Hsu, W. L.; Ku, M. H.; Chen Z. S.; Tseng, S. “Diffusiophoresis of a sphere along the axis of a cylindrical pore”, J. Colloid Interface Sci. 2010, 342, 598-606. (39) Hsu, J. P.; Luu, X. C.; Hsu, W. L. “Diffusiophoresis of an ellipsoid along the axis of a cylindrical pore”, J. Phys. Chem. B, 2010, 114, 598-606. (40) Joo, S. W.; Lee, S.Y.; Liu. J.; Qian, S.; “Diffusiophoresis of an elongated cylindrical nanoparticle along the axis of a nanopore”, ChemPhysChem 2010, 11, 3281-3288. (41) Lee, S. Y.; Yalcin, S. E.; Joo, S. W.; Baysal, O.; Qian, S. “Diffusiophoretic motion of a charged spherical particle in a nanopore”, J. Phys. Chem. B 2010, 114, 6437-6446. (42) Lee, S. Y.; Yalcin, S. E.; Joo, S. W.; Sharma, A.; Baysal, O.; Qian, S. “The effect of axial concentration gradient”, Microgravity Sci. 2010, 22, 329-338. (43) Yalcin, S. E.; Lee, S. Y.; Joo, S. W.; Baysal, O.; Qian, S. “Electrodiffusiophoretic motion of a charged spherical particle in a nanopore”, J. Phys. Chem. B. 2010, 114, 4082-2093. (44) O’Brien, R. W.; White, L. R. “Electrophoretic mobility of a spherical colloidal particle”, J. Chem. Soc. Faraday Trans. 2 1978. , 74, 1607-1626. (45) Happel, J.; Brenner, H. Low Reynolds Number Hydrodynamecs; Martinus Nijhoff : Boston, 1983. (46) Hsu, J. P.; Yeh, L. H. J. Chin. Inst. Chem. Eng. 2006, 37, 601 (47) Keh, H. J.; Li, Y. L. “Diffusiophoresis in a suspension of charge-regulating colloidal spheres”, Langmuir 2007, 23, 1061-1072. (48) FLEXPDE, version 2.22, PDE Solutions, Spokane Valley, WA, 2001. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/66470 | - |
| dc.description.abstract | 本論文探討一個帶電的圓柱形粒子在充滿電解質溶液且不帶電的圓柱孔道中軸向擴散泳運動，來模擬粒子在有邊界的擴散泳行為。我們著重在化學泳的影響其包含兩種不同型態的電雙層極化以及來自陰陽離子擴散係數不同造成的電泳效應。由數值模擬的結果顯示出在有孔道邊界的出現對於粒子的擴散泳行為有顯著的影響。舉例來說，在低電解質濃度的情況下，粒子將朝向低濃度端泳動。在其它的幾何形狀中，比如說，球形粒子在球形空腔中。這個現象只有在表面電位超過150 mV才會出現，然而在本論文的幾何形狀中，我們在低表面電位(25 mV)就可觀察到此現象，這說明了邊界的存在以及粒子的形狀還有帶電狀況對於擴散泳行為都有顯著的影響。 | zh_TW |
| dc.description.abstract | The presence of a boundary on the diffusiophoretic behavior of a particle is modeled by considering the diffusiophoresis of a charged, finite cylindrical particle along the axis of an uncharged cylindrical pore filled with electrolyte solution. We focus on the effect of chemiphoresis including two types of double-layer polarization and that of electrophoresis coming from the difference in the diffusivity of cations and that of anions. The results of numerical simulation reveal that the presence of the pore can have a significant influence on the diffusiophoretic behavior of the particle. For instance, under the conditions of low electrolyte concentration, the particle tends to migrate to the low concentration side. In other geometry, example, sphere in a spherical cavity. This phenomenon occurs only if the surface potential exceeds ca. 150 mV, but it can be observed even at a low surface potential (ca. 25 mV) in the present geometry. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T00:37:25Z (GMT). No. of bitstreams: 1 ntu-101-R97524044-1.pdf: 1430305 bytes, checksum: b296768604acf69a0a96ce3354c9806c (MD5) Previous issue date: 2012 | en |
| dc.description.tableofcontents | 中文摘要 I
英文摘要 II 目錄 III 圖目錄 IV 第一章 介紹 1 第二章 理論 3 第三章 結果與討論 9 程式碼驗證 9 數值模擬 9 第一部分：KCl 水溶液 10 第二部分：NaCl 水溶液 16 第四章 結論 19 參考文獻 21 圖 26 | |
| dc.language.iso | zh-TW | |
| dc.title | 邊界效應對擴散泳行為的影響:圓柱形粒子在狹窄圓柱形孔道中 | zh_TW |
| dc.title | Boundary Effect on Diffusiophoresis: A Finite Cylinder along the Axis of a Narrow Cylindrical Pore | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 100-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 張有義,曾琇瑱,劉博滔,林松華(Sung-Hwa Lin) | |
| dc.subject.keyword | 擴散泳,邊界效應,圓柱形粒子在圓柱孔道中,電雙層極化,電泳, | zh_TW |
| dc.subject.keyword | diffusiophoresis,boundary effect,cylinder in cylindrical pore,double-layer polarization,electrophoresis, | en |
| dc.relation.page | 40 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2012-02-01 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-101-1.pdf 目前未授權公開取用 | 1.4 MB | Adobe PDF |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。