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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 謝國煌 | |
dc.contributor.author | Hung-Chia Chou | en |
dc.contributor.author | 周泓佳 | zh_TW |
dc.date.accessioned | 2021-06-17T00:12:36Z | - |
dc.date.available | 2022-12-31 | |
dc.date.copyright | 2012-07-26 | |
dc.date.issued | 2012 | |
dc.date.submitted | 2012-07-11 | |
dc.identifier.citation | 1. Amass, W., A. Amass, and B. Tighe, A review of biodegradable polymers: Uses, current developments in the synthesis and characterization of biodegradable polyesters, blends of biodegradable polymers and recent advances in biodegradation studies. Polymer International, 1998. 47(2): p. 89-144.
2. Gross, R.A. and B. Kalra, Biodegradable polymers for the environment. Science, 2002. 297(5582): p. 803-807. 3. Vink, E.T.H., et al., Applications of life cycle assessment to NatureWorks (TM) polylactide (PLA) production. Polymer Degradation and Stability, 2003. 80(3): p. 403-419. 4. Bastioli, C. and Rapra Technology Limited., Handbook of biodegradable polymers2005, Shrewsbury: Rapra Technology. xviii, 534 p. 5. Standard Specification for Compostable Plastics, in ASTM Designation D6400-042004, American Society for Testing and Materials: West Conshohocken, Pennsylvania, United States. 6. Okada, M., Chemical syntheses of biodegradable polymers. Progress in Polymer Science, 2002. 27(1): p. 87-133. 7. Ray, S.S. and M. Bousmina, Biodegradable polymers and their layered silicate nano composites: In greening the 21st century materials world. Progress in Materials Science, 2005. 50(8): p. 962-1079. 8. Reddy, C.S.K., et al., Polyhydroxyalkanoates: an overview. Bioresource Technology, 2003. 87(2): p. 137-146. 9. Albertsson, A.C. and S. Karlsson, Degradable Polymers for the Future. Acta Polymerica, 1995. 46(2): p. 114-123. 10. Seppala, J.V., A.O. Helminen, and H. Korhonen, Degradable polyesters through chain linking for packaging and biomedical applications. Macromolecular Bioscience, 2004. 4(3): p. 208-217. 11. Chandra, R. and R. Rustgi, Biodegradable polymers. Progress in Polymer Science, 1998. 23(7): p. 1273-1335. 12. Averous, L. and N. Boquillon, Biocomposites based on plasticized starch: thermal and mechanical behaviours. Carbohydrate Polymers, 2004. 56(2): p. 111-122. 13. Lim, L.T., R. Auras, and M. Rubino, Processing technologies for poly(lactic acid). Progress in Polymer Science, 2008. 33(8): p. 820-852. 14. Averous, L., Biodegradable multiphase systems based on plasticized starch: A review. Journal of Macromolecular Science-Polymer Reviews, 2004. C44(3): p. 231-274. 15. Mohee, R., et al., Biodegradability of biodegradable/degradable plastic materials under aerobic and anaerobic conditions. Waste Management, 2008. 28(9): p. 1624-1629. 16. Drimal, P., J. Hoffmann, and M. Druzbik, Evaluating the aerobic biodegradability of plastics in soil environments through GC and IR analysis of gaseous phase. Polymer Testing, 2007. 26(6): p. 729-741. 17. Standard Practice for Evaluating and Reporting Environmental Performance of Biobased Products, in ASTM Designation D7075-042004, American Society for Testing and Materials: West Conshohocken, Pennsylvania, United States. 18. Standard Test Method for Determining Aerobic Biodegradation of Plastic Materials Under Controlled Composting Conditions. Incorporating Thermophilic Temperatures, in ASTM Designation D5338-112011, American Society for Testing and Materials: West Conshohocken, Pennsylvania, United States. 19. Standard Specification for Labeling of End Items that Incorporate Plastics and Polymers as Coatings or Additives with Paper and Other Substrates Designed to be Aerobically Composted in Municipal or Industrial Facilities, in ASTM Designation D6868-112011, American Society for Testing and Materials: West Conshohocken, Pennsylvania, United States. 20. Standard Test Method for Determining Aerobic Biodegradation in Soil of Plastic Materials or Residual Plastic Materials After Composting, in ASTM Designation D5988-032003, American Society for Testing and Materials: West Conshohocken, Pennsylvania, United States. 21. Standard Test Method for Determining Anaerobic Biodegradation of Plastic Materials Under High-Solids Anaerobic-Digestion Conditions, in ASTM Designation D5511-112011, American Society for Testing and Materials: West Conshohocken, Pennsylvania, United States. 22. Standard Test Method for Determining Anaerobic Biodegradation of Plastic Materials Under Accelerated Landfill Conditions, in ASTM Designation D5526-942011, American Society for Testing and Materials: West Conshohocken, Pennsylvania, United States. 23. Standard Test Method for Determining the Anaerobic Biodegradation of Plastic Materials in the Presence of Municipal Sewage Sludge, in ASTM Designation D5210-922007, American Society for Testing and Materials: West Conshohocken, Pennsylvania, United States. 24. Standard Specification for Non-Floating Biodegradable Plastics in the Marine Environment, in ASTM Designation D7081-052005, American Society for Testing and Materials: West Conshohocken, Pennsylvania, United States. 25. Sawada, H., ISO standard activities in standardization of biodegradability of plastics - development of test methods and definitions. Polymer Degradation and Stability, 1998. 59(1-3): p. 365-370. 26. Khemani, K.C., C. Scholz, and American Chemical Society. Division of Polymer Chemistry., Degradable polymers and materials : principles and practice. ACS symposium series2006, Washington, DC: American Chemical Society : Distributed by Oxford University Press. xiii, 442 p. 27. Vink, E.T.H., et al., The sustainability of NatureWorks (TM) polylactide polymers and Ingeo (TM) polylactide fibers(a): an update of the future. Macromolecular Bioscience, 2004. 4(6): p. 551-564. 28. Bordes, P., E. Pollet, and L. Averous, Nano-biocomposites: Biodegradable polyester/nanoclay systems. Progress in Polymer Science, 2009. 34(2): p. 125-155. 29. Auras, R., B. Harte, and S. Selke, An overview of polylactides as packaging materials. Macromolecular Bioscience, 2004. 4(9): p. 835-864. 30. Drumright, R.E., P.R. Gruber, and D.E. Henton, Polylactic acid technology. Advanced Materials, 2000. 12(23): p. 1841-1846. 31. Ajioka, M., et al., Basic Properties of Polylactic Acid Produced by the Direct Condensation Polymerization of Lactic-Acid. Bulletin of the Chemical Society of Japan, 1995. 68(8): p. 2125-2131. 32. Patrick R. Gruber, E.S.H., Jeffrey J. Kolstad, Matthew L. Iwen, Richard D. Benson, Ronald L. Borchardt, Continuous Process for Manufacture of A Purified Lactide, 1993, Cargill, Inc.: U.S. 33. Patrick R. Gruber, E.S.H., Jeffrey J. Kolstad, Matthew L. Iwen, Richard D. Benson, Ronald L. Borchardt, Continuous Process for The Manufacture of A Purified Lactide from Esters of Lactic Acid, 1993, Cargill, Inc.: U.S. 34. Patrick R. Gruber, E.S.H., Jeffrey J. Kolstad, Matthew L. Iwen, Richard D. Benson, Ronald L. Borchardt, Continuous Process for Manufacture of Lactide Polymers with Controlled Optical Purity, 1993, Cargill, Inc.: U.S. 35. Patrick R. Gruber, E.S.H., Jeffrey J. Kolstad, Matthew L. Iwan, Richard D. Benson, Ronald L. Borchardt, Continuous Process for Manufacture of Lactide Polymers with Controlled Optical Purity, 1993, Cargill, Inc.: U.S. 36. Patrick R. Gruber, E.S.H., Jeffrey J. Kolstad, Matthew L. Iwen, Richard D. Benson, Ronald L. Borchardt, Continuous Process for Manufacture of Lactide Polymers with Controlled Optical Purity, 1992, Cargill, Inc.: U.S. 37. Patrick R. Gruber, E.S.H., Jeffrey J. Kolstad, Matthew L. Iwen, Richard D. Benson, Ronald L. Borchardt, Continuous process for manufacture of lactide polymers with controlled optical purity, 1999, Cargill, Inc.: U.S. 38. Patrick R. Gruber, J.J.K., Christopher M. Ryan, Eric S. Hall, Robin S. Eichen Conn, Melt-stable Amorphous Lactide Polymer Film and Process for Manufacturing Thereof, 1996, Cargill, Inc.: U.S. 39. Dorgan, J.R., et al., Melt rheology of variable L-content poly(lactic acid). Journal of Rheology, 2005. 49(3): p. 607-619. 40. Urayama, H., S.I. Moon, and Y. Kimura, Microstructure and thermal properties of polylactides with different L- and D-unit sequences: Importance of the helical nature of the L-sequenced segments. Macromolecular Materials and Engineering, 2003. 288(2): p. 137-143. 41. Anderson, K.S., K.M. Schreck, and M.A. Hillmyer, Toughening polylactide. Polymer Reviews, 2008. 48(1): p. 85-108. 42. Garlotta, D., A literature review of poly(lactic acid). Journal of Polymers and the Environment, 2001. 9(2): p. 63-84. 43. Auras, R., Poly(lactic acid) : synthesis, structures, properties, processing, and applications/ edited by Rafael Auras ... [et al.]. Wiley series on polymer engineering and technology2010, Hoboken, N.J.: Wiley. xxiii, 499 p. 44. Tsuji, H., Degradation of poly (lactide)--based biodegradable materials2008, New York: Nova Science Publishers. 76 p. 45. Tokiwa, Y. and B.P. Calabia, Biodegradability and biodegradation of poly(lactide). Applied Microbiology and Biotechnology, 2006. 72(2): p. 244-251. 46. Bayer, O., *Das Di-Isocyanat-Polyadditionsverfahren (Polyurethane). Angewandte Chemie, 1947. 59(9): p. 257-272. 47. Chen, K.S., et al., Soft- and hard-segment phase segregation of polyester-based polyurethane. Journal of Polymer Research-Taiwan, 2001. 8(2): p. 99-109. 48. Abouzahr, S. and G.L. Wilkes, Structure Property Studies of Polyester-Based and Polyether-Based Mdi-Bd Segmented Polyurethanes - Effect of One-Stage Vs 2-Stage Polymerization Conditions. Journal of Applied Polymer Science, 1984. 29(9): p. 2695-2711. 49. Woods, G. and ICI Polyurethanes (Firm), The ICI Polyurethanes book. 2nd ed1990, Chichester ; New York: Published jointly by ICI Polyurethanes and Wiley. 364 p. 50. Clemitson, I., Castable polyurethane elastomers2008, Boca Raton: CRC Press. 250 p. 51. Król, P., Linear polyurethanes : synthesis methods, chemical structures, properties and applications2008, Leiden ; Boston: VSP. xviii, 256 p. 52. Skarja, G.A. and K.A. Woodhouse, Structure-property relationships of degradable polyurethane elastomers containing an amino acid-based chain extender. Journal of Applied Polymer Science, 2000. 75(12): p. 1522-1534. 53. Xiu, Y.Y., et al., Morphology-Property Relationship of Segmented Polyurethaneurea - Influences of Soft-Segment Structure and Molecular-Weight. Journal of Applied Polymer Science, 1993. 48(5): p. 867-869. 54. Lligadas, G., et al., Poly(ether urethane) networks from renewable resources as candidate biomaterials: Synthesis and characterization. Biomacromolecules, 2007. 8(2): p. 686-692. 55. Cho, J.W., et al., Improved mechanical properties of shape-memory polyurethane block copolymers through the control of the soft-segment arrangement. Journal of Applied Polymer Science, 2004. 93(5): p. 2410-2415. 56. Pandya, M.V., D.D. Deshpande, and D.G. Hundiwale, Thermal-Behavior of Cast Polyurethane Elastomers. Journal of Applied Polymer Science, 1988. 35(7): p. 1803-1815. 57. Darby, R.T. and A.M. Kaplan, Fungal Susceptibility of Polyurethanes. Applied Microbiology, 1968. 16(6): p. 900-&. 58. Kim, Y.D. and S.C. Kim, Effect of chemical structure on the biodegradation of polyurethanes under composting conditions. Polymer Degradation and Stability, 1998. 62(2): p. 343-352. 59. Griesser, H.J., Degradation of Polyurethanes in Biomedical Applications - a Review. Polymer Degradation and Stability, 1991. 33(3): p. 329-354. 60. Rutkowska, M., et al., Degradation of polyurethanes in sea water. Polymer Degradation and Stability, 2002. 76(2): p. 233-239. 61. Utracki, L.A., et al., Multiphase polymers : blends and ionomers. ACS symposium series,1989, Washington, DC: American Chemical Society. x, 517 p. 62. Utracki, L.A., Polymer blends handbook2002, Dordrecht ; Boston: Kluwer Academic Publishers. 63. Mikitaev, A.K., M.K. Ligidov, and G.E. Zaikov, Polymers, polymer blends, polymer composites, and filled polymers : synthesis, properties, and applications2006, New York: Nova Science Publishers. x, 222 p. 64. Freed, K.F. and N. Clarke, Phase behavior of polymer blends. Advances in polymer science,2005, Berlin ; New York: Springer. x, 199 p. 65. Litmanovich, A.D., N.A. Plate, and Y.V. Kudryavtsev, Reactions in polymer blends: interchain effects and theoretical problems. Progress in Polymer Science, 2002. 27(5): p. 915-970. 66. Ho, R.M., C.H. Wu, and A.C. Su, Morphology of Plastic Rubber Blends. Polymer Engineering and Science, 1990. 30(9): p. 511-518. 67. Barlow, J.W. and D.R. Paul, Polymer Blends and Alloys - a Review of Selected Considerations. Polymer Engineering and Science, 1981. 21(15): p. 985-996. 68. Lipatov, I.U.S. and A.E. Nesterov, Thermodynamics of polymer blends. Polymer thermodynamics library1997, Lancaster, PA: Technomic Pub. xiii, 450 p. 69. Wang, Y.B. and M.A. Hillmyer, Polyethylene-poly(L-lactide) diblock copolymers: Synthesis and compatibilization of poly(L-lactide)/polyethylene blends. Journal of Polymer Science Part a-Polymer Chemistry, 2001. 39(16): p. 2755-2766. 70. Anderson, K.S., S.H. Lim, and M.A. Hillmyer, Toughening of polylactide by melt blending with linear low-density polyethylene. Journal of Applied Polymer Science, 2003. 89(14): p. 3757-3768. 71. Reddy, N., D. Nama, and Y.Q. Yang, Polylactic acid/polypropylene polyblend fibers for better resistance to degradation. Polymer Degradation and Stability, 2008. 93(1): p. 233-241. 72. Anderson, K.S. and M.A. Hillmyer, The influence of block copolymer microstructure on the toughness of compatibilized polylactide/polyethylene blends. Polymer, 2004. 45(26): p. 8809-8823. 73. Biresaw, G. and C. Carriere, Compatibility and mechanical properties of blends of polystyrene with biodegradable polyesters. Composites Part a-Applied Science and Manufacturing, 2004. 35(3): p. 313-320. 74. Biresaw, G. and C.J. Carriere, Interfacial tension of poly(lactic acid)/polystyrene blends. Journal of Polymer Science Part B-Polymer Physics, 2002. 40(19): p. 2248-2258. 75. Felker, F.C. and G. Biresaw, Rheology and morphology of extruded blends of polystyrene with biodegradable polyesters. Journal of Biobased Materials and Bioenergy, 2007. 1(3): p. 401-408. 76. Mohamed, A., S.H. Gordon, and G. Biresaw, Poly(lactic acid)/polystyrene bioblends characterized by thermogravimetric analysis, differential scanning calorimetry, and photoacoustic infrared spectroscopy. Journal of Applied Polymer Science, 2007. 106(3): p. 1689-1696. 77. Sarazin, P. and B.D. Favis, Morphology control in co-continuous poly(L-lactide)/polystyrene blends: A route towards highly structured and interconnected porosity in poly(L-lactide) materials. Biomacromolecules, 2003. 4(6): p. 1669-1679. 78. Kim, Y.F., et al., Compatibilization of immiscible poly(l-lactide) and low density polyethylene blends. Fibers and Polymers, 2004. 5(4): p. 270-274. 79. Han, J.J. and H.X. Huang, Preparation and Characterization of Biodegradable Polylactide/Thermoplastic Polyurethane Elastomer Blends. Journal of Applied Polymer Science, 2011. 120(6): p. 3217-3223. 80. Yuan, Y.M. and E. Ruckenstein, Polyurethane toughened polylactide. Polymer Bulletin, 1998. 40(4-5): p. 485-490. 81. Domb, A.J., Degradable Polymer Blends .1. Screening of Miscible Polymers. Journal of Polymer Science Part a-Polymer Chemistry, 1993. 31(8): p. 1973-1981. 82. Lopez-Rodriguez, N., et al., Crystallization, morphology, and mechanical behavior of polylactide/poly(epsilon-caprolactone) blends. Polymer Engineering and Science, 2006. 46(9): p. 1299-1308. 83. Yeh, J.T., et al., Study on the Crystallization, Miscibility, Morphology, Properties of Poly(lactic acid)/Poly(-caprolactone) Blends. Polymer-Plastics Technology and Engineering, 2009. 48(6): p. 571-578. 84. Meredith, J.C. and E.J. Amis, LCST phase separation in biodegradable polymer blends: poly(D,L-lactide) and poly(epsilon-caprolactone). Macromolecular Chemistry and Physics, 2000. 201(6): p. 733-739. 85. Hu, Y., et al., Aging of poly(lactide)/poly(ethylene glycol) blends. Part 2. Poly(lactide) with high stereoregularity. Polymer, 2003. 44(19): p. 5711-5720. 86. Cai, Q., J.Z. Bei, and S.G. Wang, In vitro study on the drug release behavior from polylactide-based blend matrices. Polymers for Advanced Technologies, 2002. 13(7): p. 534-540. 87. Sheth, M., et al., Biodegradable polymer blends of poly(lactic acid) and poly(ethylene glycol). Journal of Applied Polymer Science, 1997. 66(8): p. 1495-1505. 88. Baiardo, M., et al., Thermal and mechanical properties of plasticized poly(L-lactic acid). Journal of Applied Polymer Science, 2003. 90(7): p. 1731-1738. 89. Hu, Y., et al., Aging of poly(lactide)/poly(ethylene glycol) blends. Part 1. Poly(lactide) with low stereoregularity. Polymer, 2003. 44(19): p. 5701-5710. 90. Gaikwad, A.N., et al., Two calorimetric glass transitions in miscible blends containing poly(ethylene oxide). Macromolecules, 2008. 41(7): p. 2502-2508. 91. Park, J.W. and S.S. Im, Phase behavior and morphology in blends of poly(L-lactic acid) and poly(butylene succinate). Journal of Applied Polymer Science, 2002. 86(3): p. 647-655. 92. Yokohara, T. and M. Yamaguchi, Structure and properties for biomass-based polyester blends of PLA and PBS. European Polymer Journal, 2008. 44(3): p. 677-685. 93. Shibata, M., Y. Inoue, and M. Miyoshi, Mechanical properties, morphology, and crystallization behavior of blends of poly(L-lactide) with poly(butylene succinate-co-L-lactate) and poly(butylene succinate). Polymer, 2006. 47(10): p. 3557-3564. 94. Chen, G.X., et al., Compatibilization-like effect of reactive organoclay on the poly(L-lactide)/poly(butylene succinate) blends. Polymer, 2005. 46(25): p. 11829-11836. 95. Wang, R.Y., et al., Toughening Modification of PLLA/PBS Blends via In Situ Compatibilization. Polymer Engineering and Science, 2009. 49(1): p. 26-33. 96. Li, Y.J. and H. Shimizu, Toughening of polylactide by melt blending with a biodegradable poly(ether)urethane elastomer. Macromolecular Bioscience, 2007. 7(7): p. 921-928. 97. Feng, F. and L. Ye, Morphologies and Mechanical Properties of Polylactide/Thermoplastic Polyurethane Elastomer Blends. Journal of Applied Polymer Science, 2011. 119(5): p. 2778-2783. 98. Lebedev, E.V., et al., Physical characterization of polyurethanes reinforced with the in situ-generated silica-polyphosphate nano-phase. Composites Science and Technology, 2006. 66(16): p. 3132-3137. 99. Cao, Q., et al., Structure and mechanical properties of thermoplastic polyurethane, based an hyperbranched polyesters. Journal of Applied Polymer Science, 2006. 102(6): p. 5266-5273. 100. Hong, H., et al., A Novel Composite Coupled Hardness with Flexibleness-Polylactic Acid Toughen with Thermoplastic Polyurethane. Journal of Applied Polymer Science, 2011. 121(2): p. 855-861. 101. Zeng, J.B., et al., Improving Flexibility of Poly(L-lactide) by Blending with Poly(L-lactic acid) Based Poly(ester-urethane): Morphology, Mechanical Properties, and Crystallization Behaviors. Industrial & Engineering Chemistry Research, 2011. 50(10): p. 6124-6131. 102. Ke, Y.C. and P. Stroeve, Polymer-layered silicate and silica nanocomposites. 1st ed2005, Amsterdam ; Boston: Elsevier. ix, 394 p. 103. Koo, J.H., Polymer nanocomposites : processing, characterization, and applications. McGraw-Hill nanoscience and technology series2006, New York: McGraw-Hill. xii, 272 p. 104. Ray, S.S., K. Okamoto, and M. Okamoto, Structure-property relationship in biodegradable poly(butylene succinate)/layered silicate nanocomposites. Macromolecules, 2003. 36(7): p. 2355-2367. 105. Nalwa, H.S., Encyclopedia of nanoscience and nanotechnology2004, Stevenson Ranch, Calif.: American Scientific Publishers. 106. Okamoto, M. and ebrary Inc., Polymer/layered silicate nanocomposites, in Rapra review reports,2003, Rapra Technology: Shrewsbury. p. 166 p. 107. Usuki, A., N. Hasegawa, and M. Kato, Polymer-clay nanocomposites. Inorganic Polymeric Nanocomposites and Membranes, 2005. 179: p. 135-195. 108. Pantoustier, N., et al., Biodegradable polyester layered silicate nanocomposites based on poly(epsilon-caprolactone). Polymer Engineering and Science, 2002. 42(9): p. 1928-1937. 109. Xu, R.J., et al., New biomedical poly(urethane urea) - Layered silicate nanocomposites. Macromolecules, 2001. 34(2): p. 337-339. 110. Chang, J.H., et al., Poly(lactic acid) nanocomposites: comparison of their properties with montmorillonite and synthetic mica(II). Polymer, 2003. 44(13): p. 3715-3720. 111. Ray, S.S. and M. Okamoto, New polylactide/layered silicate nanocomposites, 6 - Melt rheology and foam processing. Macromolecular Materials and Engineering, 2003. 288(12): p. 936-944. 112. Ray, S.S., et al., New polylactide/layered silicate nanocomposites. 1. Preparation, characterization, and properties. Macromolecules, 2002. 35(8): p. 3104-3110. 113. Ray, S.S., et al., New polylactide/layered silicate nanocomposites. 3. High-performance biodegradable materials. Chemistry of Materials, 2003. 15(7): p. 1456-1465. 114. Ray, S.S., et al., New polylactide/layered silicate nanocomposites. 5. Designing of materials with desired properties. Polymer, 2003. 44(21): p. 6633-6646. 115. Maiti, P., et al., New polylactide/layered silicate nanocomposites: Role of organoclays. Chemistry of Materials, 2002. 14(11): p. 4654-4661. 116. Ray, S.S., et al., New polylactide-layered silicate nanocomposites. 2. Concurrent improvements of material properties, biodegradability and melt rheology. Polymer, 2003. 44(3): p. 857-866. 117. Balakrishnan, H., et al., Novel toughened polylactic acid nanocomposite: Mechanical, thermal and morphological properties. Materials & Design, 2010. 31(7): p. 3289-3298. 118. Chang, J.H., Y.U. An, and G.S. Sur, Poly(lactic acid) nanocomposites with various organoclays. I. Thermomechanical properties, morphology, and gas permeability. Journal of Polymer Science Part B-Polymer Physics, 2003. 41(1): p. 94-103. 119. Ogata, N., et al., Structure and thermal/mechanical properties of poly(l-lactide)-clay blend. Journal of Polymer Science Part B-Polymer Physics, 1997. 35(2): p. 389-396. 120. Ray, S.S., et al., Biodegradable polylactide/montmorillonite nanocomposites. Journal of Nanoscience and Nanotechnology, 2003. 3(6): p. 503-510. 121. Xiao, H.W., et al., Kinetics and Crystal Structure of Poly(lactic acid) Crystallized Nonisothermally: Effect of Plasticizer and Nucleating Agent. Polymer Composites, 2010. 31(12): p. 2057-2068. 122. Li, H.B. and M.A. Huneault, Effect of nucleation and plasticization on the crystallization of poly(lactic acid). Polymer, 2007. 48(23): p. 6855-6866. 123. Battegazzore, D., S. Bocchini, and A. Frache, Crystallization kinetics of poly(lactic acid)-talc composites. Express Polymer Letters, 2011. 5(10): p. 849-858. 124. Nam, P.H., A. Fujimori, and T. Masuko, The dispersion behavior of clay particles in poly(L-lactide)/organo-modified montmorillonite hybrid systems. Journal of Applied Polymer Science, 2004. 93(6): p. 2711-2720. 125. Paul, M.A., et al., (Plasticized) polylactide/(organo-)clay nanocomposites by in situ intercalative polymerization. Macromolecular Chemistry and Physics, 2005. 206(4): p. 484-498. 126. Yang, Y. and S. Huda, Comparison of disperse dye exhaustion, color yield, and colorfastness between polylactide and poly(ethylene terephthalate). Journal of Applied Polymer Science, 2003. 90(12): p. 3285-3290. 127. Morgan, A.B. and C.A. Wilkie, Flame retardant polymer nanocomposites2007, Hoboken, N.J.: Wiley-Interscience. xix, 421 p., 8 p. of plates. 128. Xie, W., et al., Thermal degradation chemistry of alkyl quaternary ammonium montmorillonite. Chemistry of Materials, 2001. 13(9): p. 2979-2990. 129. Chigwada, G. and C.A. Wilkie, Synergy between conventional phosphorus fire retardants and organically-modified clays can lead to fire retardancy of styrenics. Polymer Degradation and Stability, 2003. 81(3): p. 551-557. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/65810 | - |
dc.description.abstract | 本高分子奈米複合材料之研究重點在於討論聚乳酸基工程塑膠材料的可行性,使聚乳酸基環保材料為一極具可能的潛力產品。此實驗研究設定在討論熱塑性聚氨酯增韌聚乳酸/蒙脫土奈米複合材料的結晶性、熱性質與機械性質。本研究的目的是為了提高此類材料的應用性及適用性,在不大幅降低其生物降解性的前提之下,使其規格達到商品化產品應用的需求。拉伸試驗和彎曲試驗的結果顯示此聚氨酯/聚乳酸高分子基材在混合10%聚氨酯、4%的滑石粉、並添加2%的改質奈米蒙托土下有最好的彈性模數和機械強度,且未大幅降低其強延展性,而耐衝擊試驗的結果則顯示相同的配方在不添加奈米蒙托土的情況下,擁有最高的耐衝擊強度33.07 J/m。硬度測試的結果與彈性模數有類似的趨勢。熱變形溫度測試結果顯現,在未經退火處理的條件下,添加無機添加物的試片仍無法提升其熱變形溫度,但在經過熱處理後,所有的試片的熱變形溫度都有顯著的提升,這可能是由於熱處理後造成結晶度提升的結果。在電子顯微鏡下觀察顯現,加入無機添加物會導致從原本的非勻相的聚乳酸/聚氨酯混摻形態有很大幅度的改變。另一方面,玻璃纖維的添加有助於明顯提高此奈米複合材料的機械強度而不影響其原本的熱性質。總言之本項研究提供一條對於以傳統製程方式製備可生物降解工程塑膠的可行途徑。 | zh_TW |
dc.description.abstract | This study of polymer nanocomposites was focused on the discussion of feasibility that PLA based plastics that can be used on automobile or furniture. This experimental research have been set on the discussion of crystallinity, mechanical and thermal properties of thermoplastic polyurethane (TPU) toughened PLA/ montmorillonite (MMT) nanocomposites, and the goal of this research is to improve their applicability and sustainability to reach the requirements of application on commercial products without much sacrifice in their biodegradability. The tensile test and flexural test showed that PLA blending with TPU in 10 wt %, talc in 4 wt%, and OMC in 2 wt% owes the highest modulus and strength without much sacrifice for elongation while the result form impact test show that the specimen of similar formula without OMC displays the highest impact resistance of 33.07 J/m. The hardness test showed similar tendency with the results of elastic modulus. The heat distortion temperature (HDT) tests showed that the specimens without annealing would not much alter their HDT even adding inorganic fillers while the specimens with thermal treatment would dramatically raise the HDT, which may come from the increase of crystallinity after thermal treatment. The observation under electron microscope demonstrated that the incorporation of inorganic fillers would dramatically alter the heterogeneous morphology of PLA/TPU blending. On the other hand, the incorporation of glass fiber in these nanocomposites showed the significant enhancement of mechanical strength with no interference on their thermal behaviors. In the conclusion, this research provides a possible route to prepare biodegradable engineering plastics in traditional method. | en |
dc.description.provenance | Made available in DSpace on 2021-06-17T00:12:36Z (GMT). No. of bitstreams: 1 ntu-101-R99524015-1.pdf: 4249593 bytes, checksum: a233ff984e53735cacfed99678471965 (MD5) Previous issue date: 2012 | en |
dc.description.tableofcontents | 中文摘要 I
Abstract III Acknowledgement V Contents VII List of Figures X List of Tables XIII List of Abbreviations and Acronyms XV Chapter 1 Introduction 1 Chapter 2 Literature Review 3 2.1 Biodegradable Polymers 3 2.1.1 Development of Biodegradable Polymers 4 2.1.2 Category of Biodegradable Polymers 6 2.1.3 Testing Standard of Biodegradable Polymers 10 2.2 Polylactic Acid 13 2.2.1 Synthesis and Manufacture of Polylactic Acid 15 2.2.2 Properties of Polylactic Acid 19 2.2.3 Degradation of Polylactic Acid 22 2.3 Polyurethane 25 2.3.1 Synthesis and Manufacture of Polyurethane 28 2.3.2 Properties of Polyurethane 30 2.3.3 Degradation of Polyurethane 32 2.4 Polymer Blends and Polylactide Blends 34 2.4.1 Processing Methods of Polymer blends 35 2.4.2 Compatibility of Polymer blends 36 2.4.3 Thermodynamic Theory of Polymer Blends 38 2.4.4 Polylactide Blends 41 2.5 Montmorillonite and Polymer/clay Nanocomposite 47 2.5.1 Preparation of Polymer/clay Nanocomposites 48 2.5.2 Characterization of Polymer/clay Nanocomposites 49 2.5.3 Polylactide /clay Nanocomposites 51 Chapter 3 Methods and Materials 57 3.1 Experimental Equipments 57 3.2 Experimental Materials and Procedures 58 3.3 Preparation of TPU-blend-PLA/MMT Nanocomposites 59 3.3.1 Synthesis of Biodegradable Polyurethane 59 3.3.2 Preparation of Biodegradable Polymeric Nanocomposites 61 3.4 Characterization Techniques and Instruments 64 3.4.1 Fourier Transform Infrared Spectra 65 3.4.2 Tensile Test 65 3.4.3 Flexural Test 65 3.4.4 Impact Test 66 3.4.5 Hardness Test 66 3.4.6 Thermal Properties 66 3.4.7 Heat Distortion Temperature 67 3.4.8 Morphology 67 Chapter 4 Results and Discussion 69 4.1 Fourier Transform Infrared Spectra 69 4.2 Tensile Test 71 4.3 Flexural Test 74 4.4 Impact Test 78 4.5 Hardness Test 81 4.6 Thermal Properties 83 4.7 Heat Distortion Temperature 98 4.8 Morphology 100 Chapter 5 Conclusion 109 References 113 | |
dc.language.iso | en | |
dc.title | 生物可分解含聚乳酸奈米複合材料之開發應用於工程塑膠 | zh_TW |
dc.title | The Development of Biodegradable Polylactic Acid Nanocomposite Materials Utilized in Engineering Plastic | en |
dc.type | Thesis | |
dc.date.schoolyear | 100-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 邱文英,韓錦鈴,黃智楷 | |
dc.subject.keyword | 聚乳酸,熱塑性聚氨酯,蒙脫土,奈米複合材料,玻璃纖維,工程塑料,可降解塑料, | zh_TW |
dc.subject.keyword | Polylactide (PLA),Thermoplastic polyurethane (TPU),Montmorillonite (MMT),Nanocomposites,Glass fiber,Engineering plastics,Biodegradable plastics, | en |
dc.relation.page | 122 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2012-07-11 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
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