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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 楊申語 | |
dc.contributor.author | Cheng-Wei Lin | en |
dc.contributor.author | 林政緯 | zh_TW |
dc.date.accessioned | 2021-06-16T23:45:18Z | - |
dc.date.available | 2015-07-30 | |
dc.date.copyright | 2012-07-30 | |
dc.date.issued | 2012 | |
dc.date.submitted | 2012-07-24 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/65475 | - |
dc.description.abstract | 具表面微結構玻璃應用日廣,玻璃表面因具有微結構增加其功能例如疏水、抗反射等,目前於玻璃表面製作微結構之技術,如雷射雕刻、表面蝕刻等製程皆屬耗時、複雜且成本昂貴。複製成型可快速製造表面微結構,其中以微熱壓成型最常用,但長時間於加熱與冷卻,以及批量製程,仍無法達到快速量產。本研究提出以滾輪壓印製程複製微結構於玻璃表面,藉由滾輪壓印製程中,加熱與冷卻分開的製程特色,以及可連續熱滾壓達到連續複製的製程特色。
本研究首先組裝滾輪壓印機台,結合高週波與紅外線快速升溫設備,快速滾壓微米與奈米結構於玻璃表面。本研究並提出滾壓玻璃製程中提升微結構轉寫率之方法,並量測微結構之轉寫率印證。奈米結構複製使用自製之陽極氧化鋁(AAO)模板,複製奈米柱狀陣列結構於Soda-lime玻璃表面,並量測抗反射效果,其反射率在光波長300~800 nm下由8~25%下降為0.8~2.5%,證實表面具奈米柱狀結構之玻璃具有抗反射效果。最後並以雙重滾輪熱壓,同時奈米柱狀結構與弧形微米結構壓印於Soda-lime玻璃表面上,成功製作出微奈米複合結構,表面具微奈米複合結構之疏水接觸角量測為114°,相較於原始平面玻璃之接觸角僅有20°,成功製造微奈米複合結構之表面疏水性玻璃。 | zh_TW |
dc.description.abstract | Glass substrate with micro/nano structures on the surface have many applications and become popular recently. There are many properties such as hydrophobicity and anti-reflection associated with glasses with micro/nano structures on the surface. Traditional fabrication method such as laser machining, wet/dry etching are time consuming and expensive. Replica molding methods can fabricate surface micro/nano stuctures with fast speed. Among them, micro hot embossing is the most commonly used method. However, the long heating/cooling cycle and the batch-mode production prevent it from being used in mass production. In this research, a novel roller imprinting method is proposed to fabricate micro/nano structures on the surface of glass substrates. During the roller imprinting process, heating and cooling were preformed separately and the fabrication of micro/nano structures were carried out continuously.
In this research, a roller imprinting facility, with induction and infrared heaters, is designed and implemented to fabricate micro/nano structures on the surface of glass substrates. Methods to increase transcription rate was investigated in this research. Nano pillars are fabricated on the surface of soda-lime glass substrate with the mold of anodic aluminum oxide. The optical performance of anti-reflection are measured. Reflection rate was reduced from 8~25% to 0.8~2.5% in the range of wavelength between 300~800 nm. It proved that glass substrate with nano pillars on the surface have anti-reflective effect. Finally, by intergrated procedure; both micro and nano structures were fabricated on the surface of soda-lime glass and hybrid micro/nano structures were fabricated successfully. The contact angle of the surface with micro/nano structures was 114°, much higher than 20° in bare glass. This study demonstrated the potential of fabricating micro/nano structures using roller hot embossing. | en |
dc.description.provenance | Made available in DSpace on 2021-06-16T23:45:18Z (GMT). No. of bitstreams: 1 ntu-101-R99522702-1.pdf: 7515757 bytes, checksum: 14a62d3bc1139764ef1ea803f06f7acf (MD5) Previous issue date: 2012 | en |
dc.description.tableofcontents | 致謝 I
摘要 II Abstract III 目錄 IV 表目錄 VII 圖目錄 VIII 第一章 導論 1 1.1 玻璃微結構精密成型技術 1 1.2 光學玻璃介紹 2 1.3 微熱壓成型技術介紹 3 1.4 滾輪壓印成型 4 1.5 滾壓模具製作 5 1.6 陽極氧化鋁製作奈米結構模具 6 1.7 滾輪模具加熱型式 8 1.8 高分子材料微結構複製成型 9 1.9 研究動機與目標 9 1.10 論文架構 11 第二章 文獻回顧 19 2.1 微奈米壓印成型技術 19 2.2 玻璃微熱壓印成型技術 20 2.3 玻璃微結構應用 23 2.4 玻璃壓印微結構模具製作技術 24 2.5 微結構滾輪應用於微熱壓成型技術 24 2.6 微結構滾輪製作方法 26 2.7 微奈米混合結構的製作與應用文獻 27 2.8 整體回顧總結與研究創新 28 第三章 滾輪壓印微結構玻璃機台開發與設計 48 3.1 實驗目的及整體流程規劃: 48 3.2 滾輪壓印製作玻璃微結構製程簡介與設備開發 50 3.2.1 製程簡介 50 3.2.2 滾輪壓印製作玻璃微結構設計與組裝 51 3.3 滾輪式連續熱壓玻璃製程步驟與流程 52 3.4 其它耐熱材料備製 53 3.4.1 陶瓷隔熱棉 53 3.4.2 陶瓷螺絲和軸承 53 3.4.3 耐高溫軟質雲母片 53 3.5 量測設備 54 3.6 本章結論 55 第四章 滾輪壓印表面微結構玻璃製程參數探討 72 4.1 滾輪壓印測試接觸長度與連續滾壓之壓力均勻度 72 4.1.1 富士感壓軟片作用原理與步驟 72 4.1.2 滾輪接觸長度測試 72 4.1.3 滾輪連續滾動壓力均勻度 73 4.2 不同加熱單元對微結構玻璃成型影響 73 4.2.1 電熱盤加熱結果 73 4.2.2 紅外線加熱結果 74 4.2.3 高週波滾輪加熱結果 74 4.3 雙加熱單元對微結構玻璃成型影響 74 4.3.1 紅外線與電熱盤加熱結果 75 4.3.2 紅外線與高週波加熱結果 75 4.3.3 高週波與電熱盤加熱結果 75 4.3.4 電熱盤加熱與紅外線加熱對製程影響 76 4.4 滾壓結果與討論 76 4.4.1 滾輪滾壓速度之影響 76 4.4.2 微結構成型操作窗 77 4.4.3 微結構複製平均深度與複製率探討 77 4.5 不同微結構滾壓複製於玻璃表面 78 4.5.1 直V溝模具滾壓玻璃 78 4.5.2 橫V溝模具滾壓玻璃 79 4.6 本章結論 80 第五章 滾壓製程改善與不同光學玻璃表面微結構熱滾壓 96 5.1 改變模具材質與增加模具厚度 96 5.1.1 改變模具材質之微透鏡陣列結構滾壓結果 96 5.1.2 改變模具材質與增加模具厚度之微透鏡陣列結構滾壓結果 97 5.2 鍍層模具滾壓微透鏡陣列結構 97 5.2.1 純鎳模具鍍金與鍍白金抗沾黏測試 97 5.2.2 鎳鈷合金模具鍍鉻與鍍鈦抗沾黏測試 98 5.3 陶瓷黏膠增強模具強度微結構滾壓 98 5.4 低熔點光學玻璃微結構滾壓 99 5.4.1 小原光學S-FPL53光學玻璃微結構複製 99 5.4.2 首德光學PSK57Q1光學玻璃微結構複製 100 5.5 本章結論 101 第六章 滾輪壓印微奈米複合結構於光學玻璃表面應用 116 6.1 陽極氧化鋁(AAO)模具製作 116 6.2 奈米結構滾壓製程步驟與具奈米結構玻璃疏水性量測 117 6.3 奈米結構對抗反射影響 118 6.3.1 奈米結構抗反射之原理 118 6.3.2 奈米結構抗反射結果 119 6.4 微奈米複合結構製程步驟與疏水性量測 119 6.5 本章結論 121 第七章 結論與未來研究方向 129 7.1 結論 129 7.1.1 開發滾輪壓印微結構於光學玻璃表面機台 129 7.1.2 加熱設備測試成果與建立微透鏡陣列結構操作窗 129 7.1.3 V溝結構於玻璃表面不同滾壓方向結果 129 7.1.4 微結構轉寫率製程改善成果 130 7.1.4.1 改變模具材質與增加模具厚度結果 130 7.1.4.2 鍍層模具滾壓微結構改善抗沾黏提升製程轉寫率 130 7.1.5 低熔點光學玻璃微結構滾壓 130 7.1.6 微奈米複合結構製作於光學玻璃表面 131 7.1.6.1 奈米結構製作 131 7.1.6.2 微奈米複合結構製作於光學玻璃表面成果 131 7.2 未來研究方向 131 參考文獻 133 | |
dc.language.iso | zh-TW | |
dc.title | 滾輪壓印微奈米結構於光學玻璃表面製程開發研究 | zh_TW |
dc.title | Development of Micro/Nano-Structures on Optical Glass by Roller Hot Embossing | en |
dc.type | Thesis | |
dc.date.schoolyear | 100-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 宋震國,王?玟,吳煌榮 | |
dc.subject.keyword | 滾輪壓印,玻璃,微透鏡陣列,高週波,接觸角,陽極氧化鋁,微奈米複合結構, | zh_TW |
dc.subject.keyword | Roller hot embossing,Glass,Micro les array,High frequency induced,Contact angle,AAO,Micro/Nano structure, | en |
dc.relation.page | 139 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2012-07-24 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 機械工程學研究所 | zh_TW |
顯示於系所單位: | 機械工程學系 |
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