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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 李公哲 | |
dc.contributor.author | Pei-Ya Weng | en |
dc.contributor.author | 翁珮雅 | zh_TW |
dc.date.accessioned | 2021-06-16T22:59:44Z | - |
dc.date.available | 2014-08-17 | |
dc.date.copyright | 2012-08-17 | |
dc.date.issued | 2012 | |
dc.date.submitted | 2012-08-08 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/64806 | - |
dc.description.abstract | 本研究以薄膜電晶體液晶顯示器(Thin Film Transistor Liquid Crystal Display, TFT-LCD)廢玻璃及一貫作業煉鋼轉爐石(Basic Oxygen Furnace Slag, BOF slag)為原料,經熔融均質化及燒結緻密化熱處理製成絕緣玻璃陶瓷,探討轉爐石中Fe2O3含量變化對絕緣玻璃陶瓷性質之影響。研究共分三階段,第一階段固定TFT-LCD廢玻璃與轉爐石之比例,額外添加純物質Fe2O3以分析「Fe2O3含量」-「晶相」-「機械、介電特性」之關聯性;第二階段以產出優良機械、介電特性之絕緣玻璃陶瓷為目的,以不同Fe2O3含量之轉爐石進行成分調配,評估TFT-LCD廢玻璃與轉爐石製備絕緣玻璃陶瓷之可行性;第三階段整合一、二階段之結果,研析兩階段中Fe2O3含量對絕緣玻璃陶瓷性質影響之一致性。
結果顯示,Fe2O3可作為成核劑,使晶相在較低熱處理溫度析出且形成較多晶相種類。Fe2O3添加量增加可提升機械性質,使緻密化程度增加、密度上升並增強抗折強度。然而,介電性質並未隨Fe2O3添加量增加而獲得改善。 TFT-LCD廢玻璃與轉爐石混合比例為7:3,其中轉爐石由爐前渣與爐後渣比為5:5所組成,此配比於820℃進行熱處理所得試樣具有良好之機械強度及介電性質。其密度為2.64 g/cm3、抗折強度為110 MPa、介電常數為8.8、逸散因子為0.0043、品質因子為235、介電損失因子為0.037。因此,本研究調整轉爐石之爐前/爐後渣比例以改變配比中Fe2O3含量,確實可提升絕緣玻璃陶瓷性質,同時達到減少物質及能源使用之目標。 兩階段之試驗結果顯示,Fe2O3含量變化對晶相、機械強度及介電特性造成之性質差異具有一致性,故以TFT-LCD廢玻璃及轉爐石為原料製備絕緣玻璃陶瓷,Fe2O3確為主要影響因子之一。 | zh_TW |
dc.description.abstract | The objective of this research was to use thin film liquid crystal display (TFT-LCD) waste glass and basic oxygen furnace (BOF) slag as recycled materials to produce insulating glass-ceramic by thermal treatment. In addition, the effects of Fe2O3 content in the BOF slag on the insulating glass-ceramic’s crystalline phase, mechanical, dielectric and thermal expansion properties were also experimented and discussed in details. There were three experimental stages conducted in this study. The first stage was to fix the weight ratio of TFT-LCD waste glass to BOF slag by adding pure reagent of Fe2O3 in order to analyze the relevance of Fe2O3 content to the characteristics of the products, such as crystalline phase, mechanical and dielectric properties. The second stage was to adjust the input ingredients of BOF slag which contains various Fe2O3 content to produce insulating glass-ceramic with excellent mechanical and dielectric properties. The third stage was to analyze the consistency of the effects of Fe2O3 on the production of insulating glass-ceramic from the first and second stage.
The results indicated that Fe2O3 could act as nucleating agent to promote crystallization at lower thermal treatment temperature and stimulated the formation of a wide variety of crystal types. In addition, increase in Fe2O3 content would enhance glass-ceramic’s mechanical properties including density and flexural strength. However, dielectric properties did not improve with Fe2O3 addition. When TFT-LCD waste glass and BOF slag was blended in the ratio of 7:3 while BOF slag was prepared with pre-BOF slag and post-BOF slag in the ratio of 5:5, under heat treatment temperature of 820℃, the insulating glass-ceramic exhibited satisfactory characteristics with product density (2.64 g/cm3), bending strength (110 MPa), dielectric constant (8.8), dissipation factor (0.0043), quality factor (235), and dielectric loss factor (0.037). The final product of glass-ceramic had good mechanical strength and dielectric properties. Therefore, this research concluded that the adjustment of the pre/post BOF slag ratio would effectively improve insulating glass-ceramic properties and achieve the goal of reducing the use of additional material and energy. According to the results of first and second stage, it demonstrated that the differences of crystalline phase, mechanical and dielectric properties caused by the Fe2O3 content were consistent. Therefore, it is promising to manufacture insulating glass-ceramic from TFT-LCD waste glass and BOF slag, in which Fe2O3 would play one of the main affecting factors. | en |
dc.description.provenance | Made available in DSpace on 2021-06-16T22:59:44Z (GMT). No. of bitstreams: 1 ntu-101-R99541202-1.pdf: 6590932 bytes, checksum: 14c53bce6134c50642d541f4319ec7ac (MD5) Previous issue date: 2012 | en |
dc.description.tableofcontents | 誌謝 I
摘要 II Abstract III 目錄 V 圖目錄 IX 表目錄 XIII 第一章 前言 1 1-1研究緣起 1 1-2研究目的 5 第二章 文獻回顧 6 2-1 TFT-LCD廢玻璃 6 2-1-1 TFT-LCD產業之現況 6 2-1-2 TFT-LCD原理及製程 10 2-1-3 TFT-LCD廢玻璃來源與現況 15 2-1-4 TFT-LCD廢玻璃資源化概況 17 2-2一貫作業煉鋼爐渣─轉爐石 20 2-2-1轉爐石之種類與來源 21 2-2-2轉爐石之特性 25 2-2-3轉爐石資源化概況 29 2-3玻璃陶瓷 33 2-3-1玻璃、陶瓷與玻璃陶瓷 33 2-3-2玻璃陶瓷之製備 37 2-3-2-1玻璃之形成 37 2-3-2-2玻璃之成分 39 2-3-2-3相分離 41 2-3-2-4成核(nucleation)與晶體成長(crystal growth) 42 2-3-2-5成核劑 45 2-3-2-6結晶化熱處理 46 2-3-3玻璃陶瓷之熱學性質 48 2-3-4玻璃陶瓷之介電性質 50 2-3-4-1介電常數(dielectric constant) 50 2-3-4-2介電損失因子(dielectric loss factor) 55 2-3-4-3品質因子(quality factor,Q) 57 2-3-4-4介電強度 57 2-3-5 Fe2O3對玻璃陶瓷之影響 59 第三章 實驗方法與步驟 61 3-1實驗材料與設備 61 3-1-1實驗材料 61 3-1-2實驗設備 62 3-1-3分析儀器 63 3-2實驗方法 66 3-3實驗架構 72 第四章 結果與討論 76 4-1廢棄物基本性質分析 76 4-1-1三成分分析 76 4-1-2成分分析 77 4-1-3晶相分析 80 4-2第一階段─添加Fe2O3對絕緣玻璃陶瓷性質之影響 83 4-2-1熱差分析 84 4-2-2晶相分析 86 4-2-3機械性質分析 95 4-2-3-1密度和吸水率 95 4-2-3-2抗折強度 101 4-2-4介電性質分析 103 4-2-4-1介電常數 103 4-2-4-2逸散因子與品質因子 106 4-2-4-3介電損失因子 109 4-2-5熱學性質分析 111 4-2-6第一階段綜合討論 114 4-3第二階段─改變爐前/爐後渣比例探討製備絕緣玻璃陶瓷之可行性 115 4-3-1熱差分析 117 4-3-2晶相分析 119 4-3-3機械性質分析 127 4-3-3-1密度、吸水率及孔隙率 127 4-3-3-2抗折強度 130 4-3-4介電性質分析 133 4-3-4-1介電常數 133 4-3-4-2逸散因子與品質因子 135 4-3-4-3介電損失因子 138 4-3-5熱學性質分析 140 4-3-6第二階段綜合討論 143 4-4第三階段─Fe2O3為第二階段主要影響因子之評估 146 第五章 結論與建議 152 5-1結論 152 5-2建議 153 參考文獻 154 | |
dc.language.iso | zh-TW | |
dc.title | Fe2O3於TFT-LCD廢玻璃混合轉爐石製備絕緣玻璃陶瓷影響之研究 | zh_TW |
dc.title | Effects of Fe2O3 on Manufacturing Insulating Glass-Ceramic from TFT-LCD Waste Glass and Basic Oxygen Furnace Slag | en |
dc.type | Thesis | |
dc.date.schoolyear | 100-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 王鯤生,侯嘉洪 | |
dc.subject.keyword | TFT-LCD廢玻璃,轉爐石,絕緣玻璃陶瓷,機械性質,介電性質, | zh_TW |
dc.subject.keyword | TFT-LCD Waste Glass,Basic Oxygen Furnace Slag,Insulating Glass-Ceramic,Mechanical Properties,Dielectric Properties, | en |
dc.relation.page | 160 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2012-08-08 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
顯示於系所單位: | 環境工程學研究所 |
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