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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 童世煌(Shih-Huang Tung) | |
| dc.contributor.author | Feng-Cheng Lin | en |
| dc.contributor.author | 林峰正 | zh_TW |
| dc.date.accessioned | 2021-06-16T22:56:53Z | - |
| dc.date.available | 2014-08-17 | |
| dc.date.copyright | 2012-08-17 | |
| dc.date.issued | 2012 | |
| dc.date.submitted | 2012-08-10 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/64646 | - |
| dc.description.abstract | 本實驗以BPO/TEMPO所形成之氮氧自由基的方式合成無規則共聚物P(S-r-BCB-r-4VP)，以此無規則共聚物熱交聯在陽極氧化鋁的奈米孔壁上，形成一層網狀交聯的奈米管，以達到孔洞改質的目的，探討嵌段式共聚物在改質後的奈米孔洞之微相分離的變化性。
以溶液潤濕法將P(S-r-BCB-r-4VP)溶液藉由毛細作用滲入陽極氧化鋁的奈米孔洞裡，待溶劑蒸發後，形成奈米管來達到孔洞改質的目的，再將嵌段式共聚物以熔融態灌入P(S-r-BCB-r-4VP)奈米管，形成外圍有一層P(S-r-BCB-r-4VP)之嵌段式共聚物奈米柱，發現在特定組成比例之無規則共聚物的孔洞改質下，可以改變嵌段式共聚物兩鏈段對於管壁的親好程度。在層狀系統，原本平行於孔壁的層狀結構將會轉變成垂直於孔壁的層狀結構，而在柱狀系統，原本平行於孔壁作排列的柱狀結構，經改質後也在形態上發現到與以往不同的螺旋狀結構。 | zh_TW |
| dc.description.abstract | A series of benzocyclobutene-functionalized random copolymers of styrene and 4-vinylpyridine were synthesized by nitroxide-mediated controlled radical polymerization. Our goal was to use these crosslinked random copolymers of P(S-r-BCB-r-4VP) as surface-modifiers to control the orientation of microdomains in lamella-forming and cylinder-forming of block copolymers in cylindrical nanopores of anodized aluminum oxide (AAO) membranes.
We introduced P(S-r-BCB-r-4VP) into the cylindrical nanopores of the AAO to form nanotubes. The block copolymers were then drawn through capillary forces from melt into P(S-r-BCB-r-4VP) nanotubes and phase separated in a confined environment where air-film interfaces are eliminated. For the compositions of random copolymers which are neutral to PS and P4VP blocks, we observed the orientation of the lamellae will change from parallel to perpendicular to the walls. For the cylinder-forming block copolymers, the morphology has changed from simple cylinders oriented parallel to the nanopores to a morphology where the cylinders form helices within the nanopores after nanopores modification. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T22:56:53Z (GMT). No. of bitstreams: 1 ntu-101-R99549024-1.pdf: 8936845 bytes, checksum: 7e82e317077b8217bac9f30509190b1d (MD5) Previous issue date: 2012 | en |
| dc.description.tableofcontents | 誌謝 I
摘要 II Abstract III 目錄 IV 圖目錄 VII 表目錄 XI 第一章 緒論 1 1-1 前言 1 1-2 研究動機 2 第二章 文獻回顧 3 2-1 高分子簡介 3 2-2 嵌段式共聚物微相分離之形態 5 2-3 嵌段式共聚物在薄膜中的微相分離形態 11 2-3.1 層狀結構Lamella 11 2-3.2 圓柱狀結構 13 2-4 無規則共聚物表面改質對嵌段式共聚物微相分離之影響 16 2-5 陽極氧化鋁模板(Anodized aluminum oxide (AAO)) 29 2-6 嵌段式共聚物奈米柱之微相分離形態 31 2-6.1 層狀形態之奈米柱 31 2-6.2 圓柱狀形態之奈米柱 33 2-6.3 球狀形態之奈米柱 35 第三章 實驗方法與儀器 42 3-1 實驗藥品 42 3-2 儀器原理 44 3-2.1 小角度X光散射儀(Small Angle X-ray Scattering，SAXS) 44 3-2.2 穿透式電子顯微鏡 (Transmission Electron Microscopy，TEM) 45 3-2.3 濺鍍機 46 3-2.4 掃瞄式電子顯微鏡 (Scanning electron microscope，SEM) 46 3-3 實驗步驟 47 3-3.1 模板法製備嵌段式共聚物奈米柱(孔洞改質前) 47 3-3.2 模板法製備P(S-r-BCB-r-4VP)奈米管 48 3-3.3 模板法製備嵌段式共聚物奈米柱(孔洞改質後) 49 3-3.4 TEM樣品之製備 50 第四章 結果與討論 51 4-1 無規則共聚物P(S-r-BCB-r-4VP)奈米管 51 4-1.1 交聯前之無規則共聚物奈米管 51 4-1.2 交聯後之無規則共聚物奈米管 53 4-1.3 瑞利不穩定現象(Rayleigh instability)之改善 57 4-2 嵌段式共聚物PS-b-P4VP奈米柱 60 4-2.1 孔洞改質前PS(20,000)-b-P4VP(17,000)奈米柱之形態 60 4-2.2 孔洞改質後PS(20,000)-b-P4VP(17,000)奈米柱之形態 65 4-3 嵌段式共聚物PS-b-PMMA奈米柱 70 4-3.1 層狀形態PS-b-PMMA奈米柱 70 4-3.1.1 孔洞改質前PS(37,000)-b-PMMA(37,000)奈米柱之形態 70 4-3.1.2 孔洞改質後PS(37,000)-b-PMMA(37,000)奈米柱之形態 72 4-3.2 柱狀形態PS-b-PMMA奈米柱 75 4-3.2.1 孔洞改質前PS(55,000)-b-PMMA(22,000)奈米柱之形態 75 4-3.2.2 孔洞改質後PS(55,000)-b-PMMA(22,000)奈米柱之形態 77 第五章 結論 81 第六章 參考文獻 82 | |
| dc.language.iso | zh-TW | |
| dc.subject | 無規則共聚物 | zh_TW |
| dc.subject | 嵌段式共聚物 | zh_TW |
| dc.subject | 微相分離方向性 | zh_TW |
| dc.subject | 表面改質 | zh_TW |
| dc.subject | 陽極氧化鋁 | zh_TW |
| dc.subject | random copolymers | en |
| dc.subject | block copolymers | en |
| dc.subject | microdomain orientation | en |
| dc.subject | surface modification | en |
| dc.subject | AAO | en |
| dc.title | 利用表面改質調控嵌段共聚物在奈米柱狀孔洞中微結構的方向性 | zh_TW |
| dc.title | Control Over the Microdomain Orientation of Block Copolymers Confined in Cylindrical Nanopores by Surface Modification | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 100-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 黃慶怡,邱文英 | |
| dc.subject.keyword | 無規則共聚物,嵌段式共聚物,微相分離方向性,表面改質,陽極氧化鋁, | zh_TW |
| dc.subject.keyword | random copolymers,block copolymers,microdomain orientation,surface modification,AAO, | en |
| dc.relation.page | 88 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2012-08-10 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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