請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/64368
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 徐善慧(Shan-hui Hsu) | |
dc.contributor.author | Ting-Yen Chi | en |
dc.contributor.author | 紀廷諺 | zh_TW |
dc.date.accessioned | 2021-06-16T17:43:12Z | - |
dc.date.available | 2017-08-17 | |
dc.date.copyright | 2012-08-17 | |
dc.date.issued | 2012 | |
dc.date.submitted | 2012-08-14 | |
dc.identifier.citation | [1] C. Hepburn, Polyurethane Elastomer, Applied Science Publishers, London and New York, 1982
[2] V.R. Sastri, Plastics in Medical Devices, Elsevier Inc., 2010 [3] D.K. Chattopadhyay and K.V.S.N. Raju, Structural Engineering of Polyurethane Coatings for High Performance Applications, Progress in Polymer Science, Vol.32, 2007, p352-418 [4] O. Bayer, Das Di-Isocganat-Poluadditionsverfahren(Polyurethane), Angewandte Chemie, Vol.9, 1947, p257-272 [5] K.M. Zia, H.N. Bhatti, and I.A. Bhatti, Methods for Polyurethane and Polyurethane composites, Recycling and Recovery: A Review, Reactive and Functional Polymers, Vol.67, 2007, p675-692 [6] New Forecasts for Polypropylene, Polystyrene and Polyurethane, Gobi International, 2002 [7] J.H. Saunders and K.C. Frisch, Polyurethane: Chemistry and Technology Part I. Chemistry, Interscience Publishers, New York, 1977 [8] 蘇呈封,含PEG主鏈及側鏈之熱塑型聚胺酯彈性體合成與物性之研究,國立台灣大學,高分子科學與工程學研究所,碩士論文,2005 [9] M.P. Stevens, Polymer Chemistry: An Introduction, Oxford, New York, 1999 [10] J.M. Raquez, M. Deleglise, M.F. Lacrampe, and P. Krawczak, Thermosetting (Bio)materials Derived from Renewable Resources: A Critical Review, Progress in Polymer Science, Vol.35, 2010, p487-509 [11] L.G. Wade Jr., Organic Chemistry, Pearson Prentice Hall, New Jersey, 2006 [12] R.S. Bezwada, Absorbable Polyurethanes, Biomaterials, Chapter 7, 2010, p137-158 [13] T.M. Schmitt, Polymers | Polyurethanes, Encyclopedia of Analytical Science, 2005, p266-272 [14] J.V. Koleske, Elastomers, Polyurethanes, Encyclopedia of Materials: Science and Technology, 2001, p2472 [15] L.W. McKeen, Thermoplastic Elastomers, The Effect of Creep and Other Time Related Factors on Plastics and Elastomers, 2009, p297-307 [16] L.W. McKeen, Thermoplastic Elastomers, Fatigue and Tribological Properties of Plastics and Elastomers, 2010, p245-247 [17] B. Klesczewski, Encyclopedia of Materials: Science and Technology, 2001, p7632-7634 [18] M. Szycher, Szycher’s Handbook of Polyurethanes, 1999 [19] H.C. Beachell and I.L. Chang, Photodegradation of Urethane Model Systems, Journal of Polymer Science: PartA-1, Vol.10, 1972, 503-520 [20] H.C. Beachell, Pyrolysis of N-[β-(N’’-Phenylcarbamyl)ethyl]-N,N’-diphenylurea. Synthesis and Properties of the Decomposition Product, 2-Phenylimino-3-phenyloxazolidine and Its Analogs, Journal of Organic Chemistry, Vol.37, No.3, 1972 [21] K. Schwetlick, J. Stumpe, and R. Noack, Properties of Excited Singlet States of N-arylurethanes, Tetrahedron, Vol.35, 1979, p63-68 [22] C.E. Hoyle and K.J. Kim, Photolysis of Aromatic Diisocyanate-Based Polyurethanes in Solution, Journal of Polymer Science: Part A, Vol.24, 1986, p1879-1894 [23] C.E. Hoyle, H. Shah, and K. Moussa, Photolysis of Methylene 4,4’-Diphentldiisocyanate-Based Polyurethane Ureas and Polyureas, Polymer Durability, 1996 [24] K. Frisch, et al. In Advances in Urethane Science and Technology, 1971, p49 [25] J.W.C. Van Bogart, A. Lilaonitkul, and S.L. Cooper, Morphology and Properties of Segmented Copolymers, Multiphase polymers, 1979, p3-30 [26] 余家豪,脂肪族聚胺酯反應動力學之研究及發泡體合成,國立台灣大學,化學工程研究所,碩士論文,2006 [27] 潘仕榮等人, 聚六亞甲基碳酸酯聚胺酯脲的製備與性能評價, 生物醫學工程臨床, Vol.9, 2005, p189-193 [28] 蘇訓永,無溶劑型水性聚氨基甲酸酯之研究,國立宜蘭大學,化學工程與材料工程研究所,碩士論文,2009 [29] 高有志,生醫級聚碳酸酯型聚胺酯之微相分離性質研究,國立中興大學,化學工程研究所,碩士論文,2002 [30] J.J. Burdeniuc, and A.Z. Kamzelski, Blowing Compositions Containing Hydroxyl and Surface Active Groups for the Production of Polyurethane Foams, European patent, 1702913, 2006 [31] S. Roy, and K.K. Majumdar, Preparation of Organo-tin Catalyst Useful for Preparation of Polyurethanes, Indian patent, 194604, 2004 [32] J.W. Britain, and P.G. Gemeinhardt, Catalysis of the Isocyanate-Hydroxyl Reaction, Journal of Applied Polymer Science, Vol.4, 1960, p207-211 [33] R.W. Lenz, Chapter 7, Organic Chemistry of Synthetic High Polymers, New York, 1967 [34] P.A. Gunatillake, and G.F. Meijs, Polyurethanes in Biomedical Engineering, Encyclopedia of Materials: Science and Technology, 2001 [35] P. Vermette, H.J. Griesser, G. Laroche, and R. Guidoin, Biomedical Applications of Polyurethanes, 2001 [36] A. Takahara, R.W. Hergenrother, A.J. Coury, and S.L. Cooper, Effect of Soft Segment Chemistry on the Biostability of Segmented Polyurethanes. II. In vitro Hydrolytic Degradation and Lipid Sorption, Journal of Biomedical Materials Research, Vol.26, 1992, p801-818 [37] M.C. Tanzi, D. Mantovani, P. Petrini, R. Guidoin, and G. Laroche, Chemical Stability of Polyether Urethanes versus Polycarbonate Urethanes, Journal of Biomedical Materials Research, Vol.36, 1997, p550-559 [38] C.D. Capone, Biostability of a Non-Ether Polyurethane, Journal of Biomaterials Applications, Vol.7, 1992, p108-129 [39] A.B. Mathur, T.O. Collier, W.J. Kao, M. Wiggins, M.A. Shubert, A. Hiltner, and J.M. Anderson, In vivo Biocompatibility and Biostability of Modified Polyurethanes, Journal of Biomedical Materials Research, Vol.36, 1997, p246-257 [40] D. Mizumoto, C. Nojiri, Y. Inomata, M. Onishi, M. Waki, T. Kido, T, Sugitama, K. Senshu, K. Uchida, K. Sakai, and T. Akutsu, Comparative Blood Compatibility of Polyether vs Polycarbonate Urethanes by Epifluorescent Video Microscopy, ASAIO Journal, Vol.43, 1997, M500-M504 [41] E.M. Christenson, M. Dadsetan, M. Wiggins, J.M. Anderson, and A. Hiltner, Poly(carbonate urethane) and Poly(ether urethane) Biodegradation: In vivo Studies, Journal of Biomedical Materials Applications, Vol.69, 2004, p407-416 [42] A.M. Reed, J. Potter, and M. Szycher, A Solution Grade Biostable Polyurethane Elastomer: ChronoFlexAR, Journal of Biomaterials Applications, Vol.8, 1994, p210-236 [43] M.W. King, Z. Zhang, P. Ukpab, D. Murphy, and R. Guidoin, Quantitative Analysis of the Surface Morphology and Texile Structure of the Polyurethane Vascugraft Arterial Prosthesis Using Image and Statistical Analysis, Biomaterials, Vol.15, 1994, p621-627 [44] F. Huang, Y. Marois, R. Roy, M. Julien, and R. Guidoin, Cellular Reaction to the Vascugradt Polyesterurethane Vascular Prosthesis: in vivo Studies in Rats, Biomaterials, Vio.13, 1992, p209-216 [45] R. Guidoin, M. Sigot, M. King, and M. Sigot-Luizard, Biocompatibility of the Vascugraft Evaluation of a Novel Polyester Urethane Vascular Substitute by an Organotypic Culture Technique, Biomaterials, Vol.13, 1992, p281-288 [46] R.W. Hergenrother, S.L. Cooper, Improved Materials for Blood-Contacting Applications: Blends of Sulphonated and Non-Sulphonated Polyurethanes, Journal of Materials Science: Materials in Medicine, Vol.3, 1992, p313-321 [47] T.G. Grasel, and S.L. Cooper, Properties and Biological Interactions of Polyurethane Anionomers: Effect of Sulfonate Incorporation, Journal of Biomedical Materials Research, Vol.23, p311-338 [48] 林自長,聚碳酸酯型聚胺酯生醫材料合成與其生物相容性之研究,國立中興大學,化學工程研究所,碩士論文,2000 [49] S.h. Hsu, and Z.C. Lin, Biocompatibility and Biostability of a Series of Poly(carbonate)urethanes, Colloids and Surfaces B: Biointerfaces, Vol.36, 2004, p1-12 [50] S.h. Hsu, and Y.C. Kao, Biocompatibility of Poly(carbonate urethane)s with Various Degrees of Nanophase Separation, Macromolecular Bioscience, Vol.5, 2005, p246-253 [51] S.h. Hsu, and Y.C. Kao, Cell Attachment and Proliferation on Poly(carbonate urethanes) with Various Degrees of Nanophase Separation, Macromolecular Bioscience, Vol.4, 2004, p891-900 [52] S.h. Hsu, Y.C. Kao, and Z.C. Lin, Enhanced Biocompatibility in Biostable Poly(carbonate)urethane, Macromolecular Bioscience, Vol.4, 2004, p464-470 [53] S.B. Wang, H.T. Zhu, and G.Q. Lu, Preparation, Characterization, and Catalytic Properties of Clay-Based Nickel Catalysts for Methane Reforming, Journal of Colloid and Interface Science, Vol.204, 1998, p128-134 [54] G. Kahr, and F.T. Madsen, Determination of the Cation Exchange Capacity and the Surface Area of Betonite, Illite and Kaolinite by Methylene Blue Adsorption, Applied Clay Science, Vol.9, 1995, p327-336 [55] F. Bergaya, and M. Vayer, CEC of Clays: Measurement by Adsorption of a Copper Ethylenediamine Complex, Applied Clay Science, Vol.12, 1997, p275-280 [56] D-J. Voorn, Polymer/Platelet Nanocomposite Particles: Encapsulation of Platelets by Physical and Chemical Approaches, 2006 [57] C.R. Tseng, J.Y. Wu, H.Y. Lee, and F.C. Chang, Preparation and Crystallization Behavior of Syndiotactic Polystyrene-Clay Nanocomposites, Polymer, Vol.42, 2001, p10063-10070 [58] E.P. Giannelis, Polymer Layered Silicate Nanocomposites, Advanced Materials, Vol.8, 1996, p29-35 [59] J.J. Lin, C.C. Chu, M.L. Chiang, and W.C. Tsai, First Isolation of Individual Silicate Platelets from Clay Exfoliation and Their Unique Self-Assembly into Fibrous Arrays, Journal of Physical Chemistry B, Vol.110, 2006, p18115-18120 [60] C.W. Chiu, C.C. Chu, W.T. Cheng, and J.J. Lin, Exfoliation of Semectite Clays by Branched Polyamines Consisting of Multiple Ionic Sites, European Polymer Journal, Vol.44, 2008, p628-636 [61] C.C. Chou, and J.J. Lin, One-Step Exfoliation of Montmorillonite via Phase Inversion of Amphiphilic Copolymer Emulsion, Macromolecules, Vol.38, 2005, p230-233 [62] J.J. Lin, and Y.M. Chen, Amphiphilic Properties of Poly(oxyalkylene)amine-Intercalated Semectite Aluminosilicates, Langmuir, Vol.20, 2004, p4261-4264 [63] J.J. Lin, C.C. Chu, C.C. Chou, and F.S. Shieu, Self-Assembled Nanofibers from Random Silicate Platelets, Advanced Materials, Vol.17, 2005, p301-304 [64] P.R. Li, J.C. Wei, Y.F. Chiu, H.L. Su, F.C. Peng, and J.J. Lin, Evaluation on Cytotoxicity and Genotoxicity of the Exfoliated Silicate Nanoclay, Applied Materials and Interfaces, Vol.2, 2010, p1608-1613 [65] J.J. Lin, C.C. Chu, M.L. Chiang, and W.C. Tsai, Manipulating Assemblies of High-Aspect-Ratio Clays and Fatty Amine Salts to Form Surfaces Exhibiting a Lotus Effect, Advanced Materials, Vol.18, 2006, p3248-3252 [66] M.C. Wang, J.J. Lin, H.J. Tseng, and S.h. Hsu, Characterization, Antimicrobial Activities and Biocompatibility of Organically Modified Clays and Their Nanocomposites with Polyurethane, Applied Material Interfaces, Vol.4, 2012, p338-350 [67] Y.w. Teow, P.V. Asharani, M. Prakash Hande, and S. Valiyaceettil, Health Impact and Safety of Engineered Nanomaterials, Chemical Communication, Vol.47, 2011, p7025-7038 [68] A. Travan, C. Pelillo, I. Donati, E. Marsich, M. Benincasa, T. Scarpa, S. Semeraro, G. Turco, R. Gennaro, and S. Paoletti, Non-cytotoxic Silver Nanoparticle-Polysaccharide Nanocomposites with Antimicrobial Activity, Biomacromolecules, Vol.10, 2009, p1429-1435 [69] S.h. Hsu, H.J. Tseng, H.S. Hung, M.C. Wang, C.H. Hung, P.R. Li, and J.J. Lin, Antimicrobial Activities and Cellular Responses to Natural Silicate Clays and Derivatives Modified by Cationic Alkylamine salts, Applied Material Interfaces, Vol.1, 2009, p2556-2564 [70] V.K. Sharma, R.A. Yngard, and Y. Lin, Silver Nanoparticles: Green Synthesis and Their Antimicrobial Activities, Advances in Colloid and Interface Science, Vol.145, 2009, p83-96 [71] S. Yang, W. Cai, G. Liu, H. Zeng, and P. Liu, Optical Study of Redox Behavior of Silicon Nanoparticles Induced by Laser Ablation in Liquid, Journal of Physical Chemistry C, Vol.113, 2009, p6480-6484 [72] K. Wegner, B. Walker, S. Tsantilis, and S.E. Pratsinis, Design of Metal Nanoparticle Synthesis by Vapor Flow Condensation, Chemical Engineering Science, Vol.57, 2002, p1753-1762 [73] K.K. Caswell, C.M. Bender, and C.J. Murphy, Seedless, Surfactantless Wet Chemical Synthesis of Silver Nanowires, Nano Letters, Vol.3, 2003, p667-669 [74] Z.S. Pillai, and P.V. Kamat, Whar Factors Control the Size and Shape of Silver Nanoparticles in the Citrate Ion Reduction Method? , Journal of Physical Chemistry B, Vol.108, 2004, p945-951 [75] K.S. Chou, and C.Y. Ren, Synthesis of Nanosized Silver Particles by Chemical Reduction Method, Materials Chemistry and Physics, Vol.64, 2000, p241-246 [76] Y. Sun, B. Mayers, T. Herricks, and Y. Xia, Polyol Synthesis of Uniform Silver Nanowires: A Plausible Growth Mechanism and the Supporting Evidence, Nano Letters, Vol.3, 2003, p955-960 [77] Y. Sun, and Y. Xia, Shape-Controlled Synthesis of Gold and Silver Nanoparticles, Science, Vol.298, 2002, p2176-2179 [78] D.H. Chen, and Y.W. Huang, Spontaneous Formation of Ag Nanoparticles, in Dimethylacetamide Solution of Poly(ethylene glycol), Journal of Colloid and Interface Science, Vol.255, 2002, p299-302 [79] X. Wang, H. Itoh, K. Naka, and Y. Chujo, Tetrathiafulvalene-Assisted Formation of Silver Dendritic Nanostructures in Acetonitrile, Langmuir, Vol.19, 2003, p6242-6346 [80] C. Johans, J. Clohessy, S. Fantini, K. Kontturi, and V.J. Cunnane, Electrosynthesis of Polyphenylpyrrole Coated Silver Particles at a Liquid-Liquid Interface, Electrochemistry Communications, Vol.4, 2002, p227-230 [81] Y. Zhang, F. Chen, J. Zhuang, Y. Tanf, D. Wang, Y. Wang, A. Dong, and N. Ren, Synthesis of Silver Nanoparticles via Electrochemical Reduction on Compact Zeolite Film Modified Electrodes, Chemical Communication, 2002, p2814-2815 [82] H. Ma, B. Yin, S. Wang, Y. Jiao, W. Pan, S. Huang, S. Chen, and F. Meng, Synthesis of Silver and Gold Nanoparticles by a Novel Electrochemical Method, ChemPhysChem, Vol.5, 2004, p68-75 [83] Y. Zhou, S.H. Yu, C.Y. Wang, X.G. Li, Y.R. Zhu, and Z.Y. Chen, A Novel Ultraviolet Irradiation Photoreduction Technique for the Preparation of Single-Crystal Ag Nanorods and Ag Dendrites, Advanced Materials, Vol.11, 1999, p850-852 [84] Y. Socol, O. Abramson, A. Gedanken, Y. Meshorer, L. Berenstein, and A. Zaban, Suspensive Electrode Formation in Pulsed Sonoelectrochemical Synthesis of Silver Nanoparticles, Langmuir, Vol.18, p4736-4740 [85] D.G. Shchukin, I.L. Radtchenko, and G.B. Sukhorukov, Photoinduced Reduction of Silver inside Microscale Polyelectrolyte Capsules, ChemPhysChem, Vol.4, 2003, p1101-1103 [86] R. Jin, Y.C. Cao, E. Hao, G.S. Metraux, G.C. Schatz, and C.A. Mirkin, Controlling Anisotropic Nanoparticle Growth through Plasmon Excitation, Nature, Vol.425, 2003, p487-490 [87] F.K. Liu, Y.C. Chang, F.H. Ko, and T.C. Chu, Microwave Assisted Synthesis of Silver Nanorod, Abstract 135, 204th Meeting, The Electrochemical Society, 2003 [88] S. Komarneni, D. Li, B. Newalkar, H. Katsuki, and A.S. Bhalla, Microwave-Polyol Process for Pt and Ag Nanoparticles, Langmuir, Vol.18, 2002, p5959-5962 [89] H. Yin, T. Yamamoto, Y. Wada, and S. Yanagida, Large-Scale and Size-Controlled Synthesis of Silver Nanoparticles under Microwave Irradiation, Materials Chemistry and Physics, Vol.83, 2004, p66-70 [90] L. Longenberger, and G. Millis, Formation of Metal Particles in Aqueous Solutions by Reactions of Metal Complexes with Polymers, Journal of Physical Chemistry, Vol.99, 1995, p475-478 [91] J.J. Lin, R.X. Dong, and W.C. Tsai, High Surface Clay-Supported Silver Nanohybrids, Silver Nanoparticles, InTech, 2010 [92] Q.L. Feng, J. Wu, G.Q. Chen, F.Z. Cui, T.N. Kim, and J.O. Kim, A Mechanistic Study of the Antibacterial Effect of Silver Ions on Escherichia coli and Staphylococcus aureus, Journal of Biomedical Materials Research, Vol.52, 2000, p662-668 [93] I. Sondi, and B. Salopek-Sondi, Silver Nanoparticles as Antimicrobial Agent: A Case Study on E. coli as a Model For Gram-Negative Bacteria, Journal of Colloid and Interface Science, Vol.275, 2004, p177-182 [94] C.N. Lok, C.M. Ho, R. Chen, Q.Y. He, W.Y. Yu, H.Z. Sun, Paul K.H. Tam, J.F. Chiu, and C.M. Che, Silver Nanoparticles: Partial Oxidation and Antibacterial Activities, Journal of Biological Inorganic Chemistry, Vol.12, 2007, p527-534 [95] L.F. Espinosa-Cristobal, G.A. Martinez-Castanon, R.E. Martinez-Martinez, J.P. Loyola-Rodriguez, N. Patino-Marin, J.F. Reyes-Macias, and F. Ruiz, Antibacterial Effect of Silver Nanoparticles Against Streptococcus mutans, Materials Letters, Vol.63, 2009, p2603-2606 [96] P.V. AshaRani, Grace L.K. Mun, M.P. Hande, and S. Valiyaveettil, Cytotoxicity and Genotoxicity of Silver Nanoparticles in Human Cells, ACSNano, Vol.3, 2009, p279-290 [97] M.V.D.Z. Park, A.M. Neigh, J.P. Vermeulen, L.J.J. de la Fonteyne, H.W. Verharen, J.J, Briede, H. van Loveren, and W.H. de Jong, The Effect of Particle size on the Cytotoxicity, Inflammation, Developmental Toxicity and Genotoxicity of Silver Nanoparticles, Biomaterials, Vol. 32, 2011, p9810-9817 [98] F. Matinez-Gutierrez, E.P. Thi, J.M. Silverman, C.C. de Oliveira, S.L. Svensson, A.V. Hoek, E.M. Sanchez, N.E. Reiner, E.C. Gaynor, E.L.G. Pryzdial, E.M. Conway, E. Orrantia, F. Ruiz, Y. Av-Gay, and H. Bach, Antibacterial activity, Inflammatory Response, Coagulation and Cytotoxicity Effects of Silver Nanoparticles, Nanomedicine: Nanotechnology, Biology, and Medicine, 2011, in Progress [99] M. Es-Souni, H. Fischer-Brandies, and M. Es-Souni, Versatile Nanocomposite Coatings with Tunable Cell Adhesion and Bactericidity, Advanced Functional Materials, Vol.18, 2008, p3179-3188 [100] N. Aihara, K. Torigoe, and K. Esumi, Preparation and Characterization of Gold and Silver Nanoparticles in Layered Laponite Suspensions, Langmuir, Vol.14, 1998, p4945-4949 [101] J. Lie, J.B. Kee, D.H. Kim, Y. Kim, Preparation of High Concentration of Silver Colloidal Nanoparticles in Layerded Laponite Sol, Colloids and Surfaces A: Physicochem. Eng. Aspects, Vol.302, 2007, p276-279 [102] S. Papp, R. Patakfalvi, and I. Dekany, Metal Nanoparticle Formation on Layer Silicate Lamellae, Colloid Polymer Science, Vol.286, 2008, p3-14 [103] R.X. Dong, C.C. Chou, and J.J. Lin, Synthesis of Immobilized Silver Nanoparticles on Ionic Silicate Clay and Observed Low-Temperature Melting, Journal of Materials Chemistry, Vol.19, 2009, p2184-2188 [104] P. Praus, M. Turicova, and M. Klementova, Preparation of Silver-Montmorillonite Nanocomposites by Reduction with Formaldehyde and Borohydride, Journal of Brazilian Chemical Society, Vol.20, 2009, p1351-1357 [105] P. Praus, M. Turicova, and M. Valaskova, Study of Silver Adsorption on Montmorillonite, Journal of Brazilian Chemical Society, Vol.19, 2008, p549-556 [106] H. Wang, X. Qiao, J. Chen, and S. Ding, Preparation of Silver Nanoparticles by Chemical Reduction Method, Colloids and Surfaces A: Physicochem. Eng. Aspects, Vol.256, 2005, p111-115 [107] X. Ding, R. Xu, H. Liu, W. Shi, S. Liu, and Y. Li, Hyperbranced Polymer-Assisted Hydrothermal In situ Synthesis of Submicrometer Silver Tubes, Crystal Growth and Design, Vol.8, 2008, p2982-2985 [108] H. Dong, K.S. Moon, and C.P. Wong, Molecular Dynamics Study of Nanosilver Particles for Low-Temperature Lead-Free Interconnect Applications, Journal of Electronic Materials, Vol.34, 2005, p40-45 [109] H.L. Su, C.C. Chou, D.J. Hung, S.H. Lin, I.C. Pao, J.H. Lin, F.L. Huang, R.X. Dong, and J.J. Lin, The Disruption of Bacterial Membrane Integrity through ROS Generation Induced by Nanohybrids of Silver and Clay, Biomaterials, Vol.30, 2009, p5979-5987 [110] M. Alexandre, and P. Dubois, Polymer-Layered Silicate Nanocomposites: Preparation, Properties and Used of a New Class of Materials, Materials Science and Engineering, Vol.28, 2000, p1-63 [111] R. A. Vaia, H. Ishii, and E.P. Giannelis, Synthesis and Properties of Two-Dimensional Nanostructures by Direct Intercalation of Polymer Melts in Layered Silicates, Chemical Materials, Vol.5, 1993, p1694-1696 [112] T. Lan, P.D. Kaviratna, and T.J. Pinnavaia, Mechanism of Clay Tactoid Exfoliation in Epoxy-Clay Nanocomposites, Chemical Materials, Vol.7, 1995, p2144-2150 [113] D. Yebassa, S. Balakrishnan, E. Feresenbet, D. Raghavan, P.R. Start, and S.D. Hudson, Chemically Functionalized Clay Vinyl Ester Nanocomposites: Effect of Processing Parameters, Journal of Polymer Science: Part A: Polymer Chemistry, Vol.42, 2004, p1310-1321 [114] R.A. Vaia, R.K. Teukolsky, and E.P. Giannelis, Interlayer Structure and Molecular Enviroment of Alkylammonium Layered Silicates, Chemical Materials, Vol.6, 1994, p1017-1022 [115] Y. Xi, R.L. Frost, H.p. He, T. Kloprogge, and T. Bostrom, Modification of Wyoming Montmorillonite Surfaces Using a Cationic Surfactant, Langmuir, Vol.21, 2005, p8675-8680 [116] R.A. Vaia, and E.P. Giannelis, Lattice Model of Polymer Melt Intercalation in Organically-Modified Layered Silicates, Macromolecules, Vol.30, 1997, p7990-7999 [117] R.A. Vaia, and E.P. Giannelis, Polymer Melt Intercalation in Organically-Modified Layered Silicates: Model Predictions and Experiment, Macromolecules, Vol.30, 1997, p8000-8009 [118] E. Zhulina, C. Singh, and A.C. Balazs, Attraction between Surfaces in a Polymer Melt Containing Telechelic Chains: Guidelines for Controlling the Surface Separation in Intercalated Polymer-Clay Composites, Langmuir, Vol.15, 1999, p3935-3943 [119] V.V. Ginzburg, and A.C. Balazs, Calculating Phase Diagrams for Nanocomposites: The Effect of Adding End-Functionalized Chains to Polymer/Clay Mixtures, Advanced Materials, Vol.12, 2000, p1805-1809 [120] V.V. Ginzburg and A.C. Balazs, Calculating Phase Diagrams of Polymer-Platelet Mixtures Using Density Functional Theory: Implications for Polymer/Clay Composites, Macromolecules, Vol.32, 1999, p5681-5688 [121] S.K. Agrawal, N. Sanabria-DeLong, G.N. Tew, and S.R. Bhatia, Nanoparticle-Reinforced Associative Network Hydrogels, Langmuir, Vol.24, 2008, p13148-13154 [122] Y.F. Lan, and J.J. Lin, Clay-Assisted Dispersion of Organic Pigments in Water, Dyes and Pigments, Vol.90, 2011, p21-27 [123] H.M. Jeong, K.H. Jang, and K.w. Cho, Properties of Waterborne Polyurethanes Based on Polycarbonate Diol Reinforced with Organophilic Clay, Journal of Macromolecular Science Part B-Physics, Vol.B42, 2003, p1249-1263 [124] J. Pavicevic, M. Spirkova, A. Strachota, K.M. Szecsenyi, N. Lazic, and J. Budinski-Simendi, The Influence of Montmorillonite and Bentonite Addition on Thermal Properties of Polyurethanes Based on Aliphatic Polycarbonate Diols, Thermochimica Acta, Vol.509, 2010, p73-80 [125] M. Spirkova, J. Pavlicevic, A. Strachota, R. Poreba, O. Bera, L. Kapralkova, J. Baldrian, M. Slouf, N. Lazic, and J. Budinski-Simendic, Novel Polycarbonate-Based Polyurethane Elastomers: Composition-Property Relationship, European Polymer Journal, Vol.47, 2011, p959-972 [126] A. Rehab, and N. Salahuddin, Nanocomposites Materials Based on Polyurethane Intercalated into Montmorillonite Clay, Materials Science and Engineering A, Vol.399, 2005, p368-376 [127] T.K. Chen, Y.I. Tien, and K.H. Wei, Synthesis and Characterization of Novel Segmented Polyurethane/Clay Nanocomposites, Polymer, Vol.41, 2000, p1345-1353 [128] J.H. Hong, E.H. Jeong, H.S. Lee, D.H. Baik, S.W. Seo, J.H. Youk, Electrospinning of Polyurethane/Organically Modified Montmorillonite Nanocomposites, Journal of Polymre Science Part B: Polymer Physics, Vol.43, 2006, p3171-3177 [129] K. Vimala, K.S. Sivudu, Y.M. Mohan, B. Sreehar, and K.M. Raju, Controlled Silver Nanoparticles Synthesis in Semi-Hydrogel Networks of Poly(acrylamide) and Carbohydrates: A Rational Methodology for Antibacterial Application, Carbohydrate Polymers, Vol.75, 2009, p463-471 [130] H. Basri, A.F. Ismail, and M. Aziz, Polyethersulfone (PES)-Silver Composite UF Membrane: Effect of Silver Loading and PVP Molecular Weight on Membrane Morphology and Antibacterial Activity, Desalination, Vol.273, 2011, p72-80 [131] I. Sawada, R. Fachrul, T. Ito, Y. Ohmukai, T. Maruyama, and H. Matsuyama, Development of a Hydrophilic Polymer Membrane Containing Silver Nanoparticles with Both Organic Antifouling and Antibacterial Properties, Journal of Membrane Science, Vol.387-388, 2012, p1-6 [132] J.W. Cho, and J.H. So, Polyurethane-Silver Fibers Prepared by Infiltration and Reduction of Silver Nitrate, Materials Letters, Vol.60, 2006, p2653-2656 [133] H.S. Hung, and S.h. Hsu, Biological Performances of Poly(ether)urethane-Silver Nanocomposites, Nanotechnology, Vol.18, 2007, p1-9 [134] C.W. Chou, S.h. Hsu, H. Chang, S.M. Tseng, and H.R. Lin, Enhanced Thermal and Mechanical Properties and Biostability of Polyurethane Containing Silver Nanoparticles, Polymer Degradation and Stability, Vol.91, 2006, p1017-1024 [135] C.W. Chou, S.h. Hsu, and P.H. Wang, Biostability and Biocompatibility of Poly(ether)urethane Contaning Gold or Silver Nanoparticles in a Porcine Model, Journal of Biomaterials Research Part A, Vol.84, 2008, p785-794 [136] H.L. Liu, S.A. Dai, K.Y. Fu, and S.h. Hsu, Antibacterial Properties of Silver Nanoparticles in Three Different Sizes and Their Nanocomposites with a New Waterborne Polyurethane, International Journal of Nanomedicine, Vol.5, 2010, p1017-1028 [137] S.h. Hsu, H.J. Tseng, and Y.C. Lin, The Biocompatibility and Antibacterial Properties of Waterborne Polyurethane-Silver Nanocomposites, Biomaterials, Vol.31, 2010, p6796-6808 [138] B. Chu, and B.S. Hsiao, Small-angle X-ray Scattering of Polymers, Chemical Reviews, Vol.11, 2001, p1727-1761 [139] 廖巍博,以小角度散射法決定高分子微結構,國立成功大學,化學工程研究所,碩士論文,2001 [140] 陳信龍、鄭有舜,小角度X光散射在高分子奈米結構解析之應用,科儀新知第二十九卷第二期,2007 [141] Y.S. Sun, U.S. Jeng, Y.S. Huang, K.S. Liang, T.L. Lin, and C.S. Tsao, Complementary SAXS and SANS for Structural Characteristics of a Polyurethane Elastomer of Low Hard-segment Content, Physica B, 2006, p650-652 [142] R.S. Waletzko, LaShanda T.J. Korley, B.D. Pate, E.L. Thomas, and P.T. Hammond, Role of Increased Crystallinity in Deformation-Induced Structure of Segmented Thermoplastic Polyurethane Elastomers with PEO and PEO-PPO-PEO Soft Segments and HDI Hard Segments, Macromolecules, Vol.42, 2009, p2041-2053 [143] J.T. Koberstein, and T.P. Russell, Simultaneous SAXS-DSC Study of Multiple Endothermic Behavior in Polyether-Based Polyurethane Block Copolymers, Macromolecules, Vol.19, 1986, p714-720 [144] H.L. Su, S.H. Lin, J.C. Wei, I.C. Pao, S.H. Chiao, C.C. Huang, S.Z. Lin, and J.J. Lin, Novel Nanohybrids of Silver Particles on Clay Platelets for Inhibiting Silver-Resistant Bacteria , PLoS One, Vol.6, 2011, e21125 [145] 李星達,奈米矽片銀及其高分子複合材料之抗菌與生物相容性研究,國立中興大學,化學工程研究所,碩士論文,2011 [146] K.K.Y. Wong, S.O.F. Cheung, L. Huang, J. Niu, C. Tao, C.M. Ho, C.M. Che, and P.K.H. Tam, Further Evidence of the Anti-inflammatory Effects of Silver Nanoparticles, ChemMedChem, Vol.4, 2009, p1129-1135 [147] J.C. Wei, Y.T. Yen, H.L. Su, and J.J. Lin, Inhibition of Bacterial Growth by the Exfoliated Clays and Observation of Physical Capturing Mechanism, The Journal of Physical Chemistry C, Vol.115, 2011, p18770-18775 [148] X.Y. Xie, J.H. Li, Y.P. Zhong, C.S. He, and C.R. Fan, 聚碳酸酯聚胺酯彈性體的合成與性能研究, Polymer Materials Science and Engineering, Vol.18, 2002 [149] M.D. Lelah, and S.L. Cooper, Polyurethane in Medicine, 1986 | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/64368 | - |
dc.description.abstract | 奈米銀有良好的抗菌性,但其抗菌效果及可能之細胞毒性受尺寸及分散性影響,且難以分散於疏水高分子中。本研究使用有機改質奈米矽片銀,為蒙脫土脫層之奈米矽片表面以界面活性劑改質,再以此複合物作為載體將銀離子還原其中而製備。具有分散在有機相的能力。本研究先評估有機改質奈米矽片銀的生物相容性及抗菌性,發現在總濃度10 ppm時對大腸桿菌有良好殺菌效果,且無顯著之細胞毒性或免疫反應。本研究隨即合成不同軟硬鏈節比例的聚碳酸酯型聚胺酯,並於篩選其性質後,使用高低軟鏈節比例之聚碳酸酯型聚胺酯進一步混摻有機改質奈米矽片銀形成奈米複合材料,發現軟硬鏈節比例會影響矽片銀在混摻後的效果如物化性質及微相分離程度的變化,而小角度X光數據分析也顯示此一微結構變化的趨勢。在奈米複合材料的生物相容性及抗菌性方面,混摻含75 ppm銀濃度之有機改質奈米矽片銀可大幅改善聚碳酸酯型聚胺酯的抗菌性,無顯著之免疫反應,且細胞相容性及生物穩定性較商用生醫級聚醚型聚胺酯為佳。 | zh_TW |
dc.description.abstract | Silver nanoparticles (AgNPs) are known for their excellent antimicrobial ability. The antimicrobial ability and the possible induced cytotoxicity of AgNPs depend on particle size and dispersibility. AgNPs are not readily dispersed in most hydrophobic polymers. In this study, an organically modified delaminated clay, in the form of surfactant-capped nanosilicate platelets (“NSQ”), was used to immobilize AgNPs from reduction of silver ion. The nanohybrids of AgNPs and NSQ (“AgNP/NSQ”) provided the possibility of dispersing AgNPs into hydrophobic polymers. AgNP/NSQ in aqueous solution had remarkable bactericidal effect and negligible cytotoxicity and immune response at the overall concentration of 10 ppm. To select model polymers for AgNP/NSQ doping, poly(carbonate)urethane (PCU) with different stoichiometric ratios of hard and soft segments were synthesized. The effect of doing on the physico-chemical properties and microphase separation of the PCU-AgNP/NSQ nanocomposites was determined by the hard/soft segment ratio. The change of microstructure upon doing was confirmed by small-angle X-ray scattering experiments. PCU-AgNP/NSQ nanocomposites containing 75 ppm AgNPs demonstrated superior microbiostatic ability as well as lower immune response and better endothelial cell compatibility and biodurability, compared with the commercial biomedical poly(ether)urethane, Pellethane 2363-80A. | en |
dc.description.provenance | Made available in DSpace on 2021-06-16T17:43:12Z (GMT). No. of bitstreams: 1 ntu-101-R99549014-1.pdf: 7961774 bytes, checksum: dc47a774aa6972762bc74e47355a1d9c (MD5) Previous issue date: 2012 | en |
dc.description.tableofcontents | 目錄
口試委員會審定書..........................................................................................................i 誌謝.................................................................................................................................ii 中文摘要........................................................................................................................iii 英文摘要........................................................................................................................iv 第一章 文獻回顧..........................................................................................................1 1-1 聚胺基甲酸酯..................................................................................................1 1-1-1 簡介.......................................................................................................1 1-1-2 聚胺基甲酸酯合成單體.......................................................................4 1-1-3 聚胺酯生醫材料.................................................................................10 1-2 黏土與奈米矽片............................................................................................12 1-3 奈米銀............................................................................................................15 1-4 奈米複合材料................................................................................................18 1-4-1 奈米銀/黏土複合材料........................................................................19 1-4-2 高分子/黏土複合材料........................................................................20 1-4-3 高分子/奈米銀複合材料....................................................................23 1-5 小角度X光散射(small angle X-ray scattering) ...........................................24 1-6 研究目的........................................................................................................26 第二章 研究方法........................................................................................................27 2-1 研究架構........................................................................................................27 2-2 有機改質奈米矽片銀與相關樣品之物性研究............................................29 2-2-1 有機改質奈米矽片銀製備.................................................................29 2-2-2 有機改質奈米矽片有機含量測定.....................................................29 2-2-3 有機改質奈米矽片純度檢測.............................................................29 2-2-4 有機改質奈米矽片銀尺寸型態觀察.................................................30 2-2-5 有機改質奈米矽片銀與相關樣品粒徑與界面電位分析.................30 2-2-6 有機改質奈米矽片銀銀含量檢測30 2-2-7 有機改質奈米矽片銀純度檢測.........................................................30 2-3 有機改質奈米矽片銀與相關樣品之生物相容性測試................................30 2-3-1 有機改質奈米矽片銀與相關樣品之細胞毒性測試.........................30 2-3-2 有機改質奈米矽片銀與相關樣品之免疫反應測試.........................32 2-3-3 反轉錄-聚合酶連鎖反應....................................................................33 2-4 有機改質奈米矽片銀與相關樣品之抗菌測試............................................34 2-4-1 相關藥品之配製.................................................................................34 2-4-2 菌株之活化.........................................................................................35 2-4-3 抗菌測試(Antibacterial test) ..............................................................35 2-5 聚碳酸酯型聚胺酯(Poly(carbonate)urethane, PCU)的合成........................35 2-5-1 藥品前處理.........................................................................................35 2-5-2 反應步驟.............................................................................................36 2-5-3 反應後處理.........................................................................................37 2-6 不同合成比例之聚胺酯材料篩選................................................................37 2-6-1 各種聚胺酯之分子量量測.................................................................37 2-6-2 各種聚胺酯膜材之製備.....................................................................38 2-6-3 各種聚胺酯膜材之接觸角量測.........................................................38 2-6-4 各種聚胺酯厚膜之拉伸試驗.............................................................38 2-6-5 各種聚胺酯之熱性質分析.................................................................38 2-6-6 各種聚胺酯之細胞貼附增生測試.....................................................39 2-7 聚胺酯與有機改質奈米矽片銀複合材料之物性研究................................39 2-7-1 商用生醫級聚胺酯對照組之材料製備.............................................39 2-7-2 聚胺酯與有機改質奈米矽片銀複合材料製備.................................39 2-7-3 聚胺酯與有機改質奈米矽片銀複合材料之接觸角量測.................40 2-7-4 聚胺酯與有機改質奈米矽片銀複合材料之拉伸試驗.....................40 2-7-5 聚胺酯與有機改質奈米矽片銀複合材料之熱性質分析.................40 2-7-6 聚胺酯與有機改質奈米矽片銀複合材料之原子力顯微鏡表面微結構分析.................................................................................................40 2-8 聚胺酯與有機改質奈米矽片銀複合材料之小角度X光散射結構分析....41 2-9 聚胺酯與有機改質奈米矽片銀複合材料之細胞貼附增生測試................41 2-10 聚胺酯與有機改質奈米矽片銀複合材料之免疫反應測試......................41 2-11 聚胺酯與有機改質奈米矽片銀複合材料之抗菌測試..............................42 2-12 聚胺酯與有機改質奈米矽片銀複合材料之大鼠皮下植入實驗..............43 2-13 統計學分析..................................................................................................43 第三章 結果................................................................................................................44 3-1 有機改質奈米矽片銀與相關樣品之物性研究............................................44 3-1-1 有機改質奈米矽片有機含量測定.....................................................44 3-1-2 有機改質奈米矽片純度檢測.............................................................44 3-1-3 有機改質奈米矽片銀尺寸型態觀察.................................................44 3-1-4 有機改質奈米矽片銀與相關樣品粒徑與界面電位分析.................44 3-1-5 有機改質奈米矽片銀銀含量檢測.....................................................44 3-1-6 有機改質奈米矽片銀純度檢測.........................................................45 3-2 有機改質奈米矽片銀與相關樣品之生物相容性測試................................45 3-2-1 有機改質奈米矽片銀與相關樣品之細胞毒性測試.........................45 3-2-2 有機改質奈米矽片銀與相關樣品之免疫反應測試.........................47 3-3 有機改質奈米矽片銀與相關樣品之抗菌測試............................................47 3-4 不同合成比例之聚胺酯材料篩選................................................................47 3-4-1 各種聚胺酯之分子量量測.................................................................47 3-4-2 各種聚胺酯膜材之接觸角量測.........................................................48 3-4-3 各種聚胺酯厚膜之拉伸試驗.............................................................48 3-4-4 各種聚胺酯之熱性質分析.................................................................48 3-4-5 各種聚胺酯之細胞貼附增生測試.....................................................49 3-5 聚胺酯與有機改質奈米矽片銀複合材料之物性研究................................49 3-5-1 聚胺酯與有機改質奈米矽片銀複合材料之接觸角量測.................49 3-5-2 聚胺酯與有機改質奈米矽片銀複合材料之拉伸試驗.....................49 3-5-3 聚胺酯與有機改質奈米矽片銀複合材料之熱性質分析.................50 3-5-4 聚胺酯與有機改質奈米矽片銀複合材料之原子力顯微鏡表面微結構分析.................................................................................................50 3-6 聚胺酯與有機改質奈米矽片銀複合材料之小角度X光散射結構分析....51 3-7 聚胺酯與有機改質奈米矽片銀複合材料之細胞貼附增生測試................51 3-8 聚胺酯與有機改質奈米矽片銀複合材料之免疫反應測試........................52 3-9 聚胺酯與有機改質奈米矽片銀複合材料之抗菌測試................................52 3-10 聚胺酯與有機改質奈米矽片銀複合材料之大鼠皮下植入實驗..............52 第四章 討論................................................................................................................53 4-1 有機改質奈米矽片銀與相關樣品之物性研究............................................53 4-1-1 有機改質奈米矽片有機含量測定.....................................................53 4-1-2 有機改質奈米矽片純度檢測.............................................................53 4-1-3 有機改質奈米矽片銀尺寸型態觀察.................................................53 4-1-4 有機改質奈米矽片銀與相關樣品粒徑與界面電位分析.................54 4-1-5 有機改質奈米矽片銀銀含量檢測.....................................................54 4-1-6 有機改質奈米矽片銀純度檢測.........................................................55 4-2 有機改質奈米矽片銀與相關樣品之生物相容性測試................................55 4-2-1 有機改質奈米矽片銀與相關樣品之細胞毒性測試.........................55 4-2-2 有機改質奈米矽片銀與相關樣品之免疫反應測試.........................57 4-3 有機改質奈米矽片銀與相關樣品之抗菌測試............................................58 4-4 聚碳酸酯型聚胺酯的合成............................................................................58 4-5 不同合成比例之聚胺酯材料篩選................................................................59 4-5-1 各種聚胺酯之分子量量測.................................................................59 4-5-2 各種聚胺酯膜材之接觸角量測.........................................................60 4-5-3 各種聚胺酯厚膜之拉伸試驗.............................................................60 4-5-4 各種聚胺酯之熱性質分析.................................................................61 4-5-5 各種聚胺酯之細胞貼附增生測試.....................................................61 4-6 聚胺酯與有機改質奈米矽片銀複合材料之物性研究................................61 4-6-1 聚胺酯與有機改質奈米矽片銀複合材料之接觸角量測.................62 4-6-2 聚胺酯與有機改質奈米矽片銀複合材料之拉伸試驗.....................62 4-6-3 聚胺酯與有機改質奈米矽片銀複合材料之熱性質分析.................63 4-6-4 聚胺酯與有機改質奈米矽片銀複合材料之原子力顯微鏡表面微結構分析.................................................................................................64 4-7 聚胺酯與有機改質奈米矽片銀複合材料之小角度X光散射結構分析....65 4-8 聚胺酯與有機改質奈米矽片銀複合材料之細胞貼附增生測試................67 4-9 聚胺酯與有機改質奈米矽片銀複合材料之免疫反應測試........................67 4-10 聚胺酯與有機改質奈米矽片銀複合材料之抗菌測試..............................68 4-11 聚胺酯與有機改質奈米矽片銀複合材料之大鼠皮下植入實驗..............69 4-12 未來展望......................................................................................................69 第五章 結論................................................................................................................71 參考文獻........................................................................................................................72 | |
dc.language.iso | zh-TW | |
dc.title | 有機改質奈米矽片銀與聚碳酸酯型聚胺酯複合材料之抗菌性、生物相容性與微結構研究 | zh_TW |
dc.title | Evaluation of the Antimicrobial Activity, Biocompatibility and Microstructure of the Nanocomposites from Silver Nanoparticles Immobilized on Organically Modified Nano Silicate Platelets and Poly(carbonate)urethane | en |
dc.type | Thesis | |
dc.date.schoolyear | 100-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 林江珍(Jiang-Jen Lin),戴憲弘(Shenghong A. Dai),鄭有舜(U-Ser Jeng),林睿哲(Jui-Che Lin) | |
dc.subject.keyword | 奈米銀,奈米矽片,抗菌性,生物相容性,聚碳酸酯型聚胺酯,奈米複合材料,小角度X光散射, | zh_TW |
dc.subject.keyword | Silver nanoparticles,Nanosilicate platelets,Antimicrobial ability,Biocompatibility,Poly(carbonate)urethane,Nanocomposites,Small-angle X-ray scattering, | en |
dc.relation.page | 132 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2012-08-14 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
顯示於系所單位: | 高分子科學與工程學研究所 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-101-1.pdf 目前未授權公開取用 | 7.78 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。