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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 施文彬 | |
| dc.contributor.author | Tsung-Hua Tsai | en |
| dc.contributor.author | 蔡宗樺 | zh_TW |
| dc.date.accessioned | 2021-06-16T16:30:10Z | - |
| dc.date.available | 2022-12-25 | |
| dc.date.copyright | 2013-01-16 | |
| dc.date.issued | 2012 | |
| dc.date.submitted | 2012-12-25 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/63241 | - |
| dc.description.abstract | In the field of supercapacitors, the degradation of capacitance caused from the volume change during redox was being mentioned for a long time. But there were few people studied it.
In this thesis, we used anodic aluminum oxide (AAO) as the substrate, taking advantage of the high specific surface area and synthesized polypyrrole (PPy) on it to make a supercapacitor electrode. The method which used to synthesize PPy was called indirect method. Atomic force microscope (AFM) scanning and cyclic voltammetry (CV) test were operated simultaneously to analyze the porosity change of the PPy film. The porosity of the PPy film was determined by an imaging program. Due to the hole structure of the AAO, the stress occurred within redox did not cause obvious damage on the film so the electrodes showed very good cyclic stability. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T16:30:10Z (GMT). No. of bitstreams: 1 ntu-101-R98522526-1.pdf: 3320971 bytes, checksum: 83b74f76f29cc12971e9c744d2fef537 (MD5) Previous issue date: 2012 | en |
| dc.description.tableofcontents | ABSTRACT i
CONTENTS ii LIST OF FIGURES iii LIST OF TABLES vi Chapter 1 Introduction 1 1.1 Background – Introduction of Supercapacitors 1 1.2 Introduction of PPy 3 1.3 Literatures of Degradation Tests 5 1.4 Objectives 8 Chapter 2 Experimental 9 2.1 Synthesis of PPY - Indirect Polymerizing Method 9 2.2 Polypyrrole Film with Different Thickness 12 2.3 Preparation of Electrodes for CV Test 15 2.4 Cyclic Voltammetry Test 16 2.5 CV & AFM Combo Test 19 2.6 Experimental Steps of Combo Test 19 2.6.1 Frequency sweep 19 2.6.2 AFM Scanning 20 2.6.3 Porosity Analyzing 29 Chapter 3 Conclusions and Future Work 39 REFERENCES 40 | |
| dc.language.iso | en | |
| dc.title | 利用原子力顯微鏡探討聚吡咯-陽極氧化鋁薄膜超電容之電容衰退特性 | zh_TW |
| dc.title | Study on degradation of pollypyrrole / anodic aluminum oxide supercapacitor utilizing atomic force microscopre | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 101-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 施博仁,楊龍杰 | |
| dc.subject.keyword | 聚吡,咯,陽極氧化鋁薄膜,超電容,非接觸聚合,原子力顯微鏡,衰退, | zh_TW |
| dc.subject.keyword | polypyrrole,anodic aluminum oxide,supercapacitor,indirect method,atomic force microscope,degradation, | en |
| dc.relation.page | 45 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2012-12-26 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 機械工程學研究所 | zh_TW |
| 顯示於系所單位： | 機械工程學系 | |
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