請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/62110
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 林江珍 | |
dc.contributor.author | Jun-Ying Ho | en |
dc.contributor.author | 何俊瑩 | zh_TW |
dc.date.accessioned | 2021-06-16T13:28:18Z | - |
dc.date.available | 2018-08-29 | |
dc.date.copyright | 2013-08-29 | |
dc.date.issued | 2013 | |
dc.date.submitted | 2013-07-22 | |
dc.identifier.citation | (1) Tiwari, V. S.; Oleg, T.; Darbha, G. K.; Hardy, W.; Singh, J. P.; Ray, P. C. Chemical Physics Letters 2007, 446, 77.
(2) Fleischmann, M.; Hendra, P. J.; McQuillan, A. J. Chemical Physics Letters 1974, 26, 163. (3) Haynes, C. L.; Van Duyne, R. P. The Journal of Physical Chemistry B 2003, 107, 7426. (4) Litorja, M.; Haynes, C. L.; Haes, A. J.; Jensen, T. R.; Van Duyne, R. P. The Journal of Physical Chemistry B 2001, 105, 6907. (5) Dick, L. A.; McFarland, A. D.; Haynes, C. L.; Van Duyne, R. P. The Journal of Physical Chemistry B 2001, 106, 853. (6) Jensen, T. R.; Duyne, R. P. V.; Johnson, S. A.; Maroni, V. A. Appl. Spectrosc. 2000, 54, 371. (7) Shafer-Peltier, K. E.; Haynes, C. L.; Glucksberg, M. R.; Van Duyne, R. P. Journal of the American Chemical Society 2002, 125, 588. (8) Yonzon, C. R.; Haynes, C. L.; Zhang, X.; Walsh, J. T.; Van Duyne, R. P. Analytical chemistry 2003, 76, 78. (9) Zhang, X.; Young, M. A.; Lyandres, O.; Van Duyne, R. P. Journal of the American Chemical Society 2005, 127, 4484. (10) Jeanmaire, D. L.; Van Duyne, R. P. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 1977, 84, 1. (11) Albrecht, M. G.; Creighton, J. A. Journal of the American Chemical Society 1977, 99, 5215. (12) Chan, G. H.; Zhao, J.; Hicks, E. M.; Schatz, G. C.; Van Duyne, R. P. Nano Letters 2007, 7, 1947. (13) Schatz, G.; Young, M.; Duyne, R. In Surface-Enhanced Raman Scattering; Kneipp, K., Moskovits, M., Kneipp, H., Eds.; Springer Berlin Heidelberg: 2006; Vol. 103, p 19. (14) Otto, A. In Light Scattering in Solids IV; Cardona, M., Guntherodt, G., Eds.; Springer Berlin Heidelberg: 1984; Vol. 54, p 289. (15) Moskovits, M. Reviews of Modern Physics 1985, 57, 783. (16) Kelly, K. L.; Coronado, E.; Zhao, L. L.; Schatz, G. C. The Journal of Physical Chemistry B 2002, 107, 668. (17) Smith, E.; Dent, G. In Modern Raman Spectroscopy – A Practical Approach; John Wiley & Sons, Ltd: 2005, p 71. (18) Belgrader, P.; Benett, W.; Hadley, D.; Richards, J.; Stratton, P.; Mariella, R.; Milanovich, F. Science 1999, 284, 449. (19) Naumann, D.; Helm, D.; Labischinski, H. Nature 1991, 351, 81. (20) Lay Jr, J. O. TrAC Trends in Analytical Chemistry 2000, 19, 507. (21) Varnum, S. M.; Warner, M. G.; Dockendorff, B.; Anheier Jr, N. C.; Lou, J.; Marks, J. D.; Smith, L. A.; Feldhaus, M. J.; Grate, J. W.; Bruckner-Lea, C. J. Analytica Chimica Acta 2006, 570, 137. (22) Kempf, V. A. J.; Mandle, T.; Schumacher, U.; Schafer, A.; Autenrieth, I. B. International Journal of Medical Microbiology 2005, 295, 47. (23) Su, X.-L.; Li, Y. Biosensors and Bioelectronics 2004, 19, 563. (24) Maalouf, R.; Fournier-Wirth, C.; Coste, J.; Chebib, H.; Saikali, Y.; Vittori, O.; Errachid, A.; Cloarec, J. P.; Martelet, C.; Jaffrezic-Renault, N. Analytical chemistry 2007, 79, 4879. (25) Casadio, F.; Leona, M.; Lombardi, J. R.; Van Duyne, R. Accounts of Chemical Research 2010, 43, 782. (26) Nie, S.; Emory, S. R. Science 1997, 275, 1102. (27) Catherine, M. S.; Sailaja, V. E.; Ai Leen, K.; Jing, Z.; Lienchi, N. N.; Dennis, J. M.; Jingwu, Z.; Kenneth, B. S.; Lei, S.; Selena, C.; Robert, S.; Garry, P. N. PLoS ONE 2009, 4. (28) Ximei, Q.; Xiang-Hong, P.; Dominic, O. A.; Qiqin, Y.-G.; Georgia, Z. C.; Dong, M. S.; Lily, Y.; Andrew, N. Y.; May, D. W.; Shuming, N. Nature Biotechnology 2007, 26, 83. (29) Jarvis, R. M.; Goodacre, R. Chemical Society reviews 2008, 37, 931. (30) Wang, H. H.; Liu, C. Y.; Wu, S. B.; Liu, N. W.; Peng, C. Y.; Chan, T. H.; Hsu, C. F.; Wang, J. K.; Wang, Y. L. Advanced Materials 2006, 18, 491. (31) Liu, T. T.; Lin, Y. H.; Hung, C. S.; Liu, T. J.; Chen, Y.; Huang, Y. C.; Tsai, T. H.; Wang, H. H.; Wang, D. W.; Wang, J. K.; Wang, Y. L.; Lin, C. H. PLoS One 2009, 4, e5470. (32) Ting-Yu, L.; Kun-Tong, T.; Huai-Hsien, W.; Yu, C.; Yu-Hsuan, C.; Yuan-Chun, C.; Hsuan-Hao, C.; Chi-Hung, L.; Juen-Kai, W.; Yuh-Lin, W. Nature Communications 2011, 2, 538. (33) Liu, T. Y.; Chen, Y.; Wang, H. H.; Huang, Y. L.; Chao, Y. C.; Tsai, K. T.; Cheng, W. C.; Chuang, C. Y.; Tsai, Y. H.; Huang, C. Y.; Wang, D. W.; Lin, C. H.; Wang, J. K.; Wang, Y. L. Journal of nanoscience and nanotechnology 2012, 12, 5004. (34) Sengupta, A.; Laucks, M. L.; Davis, E. J. Applied spectroscopy 2005, 59, 1016. (35) Li, W.; Camargo, P. H. C.; Lu, X.; Xia, Y. Nano Letters 2008, 9, 485. (36) Vosgrone, T.; Meixner, A. J. Chemphyschem : a European journal of chemical physics and physical chemistry 2005, 6, 154. (37) Tao, A.; Kim, F.; Hess, C.; Goldberger, J.; He, R.; Sun, Y.; Xia, Y.; Yang, P. Nano Letters 2003, 3, 1229. (38) Chattopadhyay, S.; Lo, H.-C.; Hsu, C.-H.; Chen, L.-C.; Chen, K.-H. Chemistry of Materials 2005, 17, 553. (39) Goulet, P. J. G.; dos Santos, D. S.; Alvarez-Puebla, R. A.; Oliveira, O. N.; Aroca, R. F. Langmuir 2005, 21, 5576. (40) Lu, Y.; Liu, G. L.; Lee, L. P. Nano Lett 2005, 5, 5. (41) Kao, P.; Malvadkar, N. A.; Cetinkaya, M.; Wang, H.; Allara, D. L.; Demirel, M. C. Advanced Materials 2008, 20, 3562. (42) Michaels, A. M.; Nirmal, M.; Brus, L. E. Journal of the American Chemical Society 1999, 121, 9932. (43) Cao, Y. C.; Jin, R.; Mirkin, C. A. Science 2002, 297, 1536. (44) Kim, Y.-K.; Han, S. W.; Min, D.-H. ACS applied materials & interfaces 2012, 4, 6545. (45) Nordlander, P.; Oubre, C.; Prodan, E.; Li, K.; Stockman, M. Nano Letters 2004, 4, 899. (46) Prodan, E.; Radloff, C.; Halas, N.; Nordlander, P. Science 2003, 302, 419. (47) Davis, T.; Vernon, K.; Gomez, D. Journal of Applied Physics 2009, 106, 043502. (48) Huang, J.-S.; Kern, J.; Geisler, P.; Weinmann, P.; Kamp, M.; Forchel, A.; Biagioni, P.; Hecht, B. Nano letters 2010, 10, 2105. (49) Funston, A. M.; Novo, C.; Davis, T. J.; Mulvaney, P. Nano letters 2009, 9, 1651. (50) Dmitriev, A.; Hagglund, C.; Chen, S.; Fredriksson, H.; Pakizeh, T.; Kall, M.; Sutherland, D. S. Nano letters 2008, 8, 3893. (51) Tam, F.; Goodrich, G. P.; Johnson, B. R.; Halas, N. J. Nano Letters 2007, 7, 496. (52) Garcia-Vidal, F. J.; Pendry, J. B. Physical review letters 1996, 77, 1163. (53) Jahnig, F. Proceedings of the National Academy of Sciences 1979, 76, 6361. (54) Jarvis, R. M.; Goodacre, R. Analytical chemistry 2004, 76, 40. (55) Premasiri, W.; Moir, D.; Klempner, M.; Krieger, N.; Jones, G.; Ziegler, L. The Journal of Physical Chemistry B 2005, 109, 312. (56) Albrecht, M. A.; Evans, C. W.; Raston, C. L. Green Chemistry 2006, 8, 417. (57) Nel, A.; Xia, T.; Madler, L.; Li, N. Science 2006, 311, 622. (58) Vikesland, P. J.; Wigginton, K. R. Environmental Science & Technology 2010, 44, 3656. (59) Lin, J. J.; Lin, W. C.; Li, S. D.; Lin, C. Y.; Hsu, S. H. ACS applied materials & interfaces 2013, 5, 433. (60) Chu, C.-Y.; Peng, F.-C.; Chiu, Y.-F.; Lee, H.-C.; Chen, C.-W.; Wei, J.-C.; Lin, J.-J. PLoS ONE 2012, 7, e38360. (61) Wei, J.-C.; Yen, Y.-T.; Wang, Y.-T.; Hsu, S.-h.; Lin, J.-J. RSC Advances 2013. (62) Sinha Ray, S.; Okamoto, M. Progress in Polymer Science 2003, 28, 1539. (63) Alexandre, M.; Dubois, P. Materials Science and Engineering: R: Reports 2000, 28, 1. (64) Chu, C.-C.; Chiang, M.-L.; Tsai, C.-M.; Lin, J.-J. Macromolecules 2005, 38, 6240. (65) Lin, J.-J.; Chu, C.-C.; Chiang, M.-L.; Tsai, W.-C. J. Phys. Chem. B 2006, 110, 18115. (66) Li, P.-R.; Wei, J.-C.; Chiu, Y.-F.; Su, H.-L.; Peng, F.-C.; Lin, J.-J. ACS Applied Materials & Interfaces 2010, 2, 1608. (67) Carretero, M. I. Applied Clay Science 2002, 21, 155. (68) Ru, E. L.; Etchegoin, P. Principles of Surface-Enhanced Raman Spectroscopy: and related plasmonic effects; Elsevier Science, 2008. (69) Wiley, B.; Sun, Y.; Xia, Y. Accounts of Chemical Research 2007, 40, 1067. (70) Link, S.; El-Sayed, M. A. The Journal of Physical Chemistry B 1999, 103, 8410. (71) Rakich, P. T.; Popovic, M. A.; Soljacic, M.; Ippen, E. P. Nat Photon 2007, 1, 658. (72) Wang, H.; Tam, F.; Grady, N. K.; Halas, N. J. The Journal of Physical Chemistry B 2005, 109, 18218. (73) Frederix, F.; Friedt, J. M.; Choi, K. H.; Laureyn, W.; Campitelli, A.; Mondelaers, D.; Maes, G.; Borghs, G. Analytical chemistry 2003, 75, 6894. (74) Lee, K.-S.; El-Sayed, M. A. The Journal of Physical Chemistry B 2006, 110, 19220. (75) Yoon, I.; Kang, T.; Choi, W.; Kim, J.; Yoo, Y.; Joo, S. W.; Park, Q. H.; Ihee, H.; Kim, B. J Am Chem Soc 2009, 131, 758. (76) Rycenga, M.; Wang, Z.; Gordon, E.; Cobley, C. M.; Schwartz, A. G.; Lo, C. S.; Xia, Y. Angewandte Chemie International Edition 2009, 48, 9924. (77) Rycenga, M.; Cobley, C. M.; Zeng, J.; Li, W.; Moran, C. H.; Zhang, Q.; Qin, D.; Xia, Y. Chemical reviews 2011, 111, 3669. (78) Marty, F.; Rousseau, L.; Saadany, B.; Mercier, B.; Francais, O.; Mita, Y.; Bourouina, T. Microelectronics Journal 2005, 36, 673. (79) Maier, S. A. Plasmonics: Fundamentals and Applications; Springer Science+Business Media, LLC, 2007. (80) Stamplecoskie, K. G.; Scaiano, J. C.; Tiwari, V. S.; Anis, H. The Journal of Physical Chemistry C 2011, 115, 1403. (81) Myers, D. Surfaces, interfaces, and colloids; Wiley-Vch New York etc., 1999. (82) Turro, N. J.; Yekta, A. Journal of the American Chemical Society 1978, 100, 5951. (83) Chen, Y.-M.; Hsu, R.-S.; Lin, H.-C.; Chang, S.-J.; Chen, S.-C.; Lin, J.-J. Journal of Colloid and Interface Science 2009, 334, 42. (84) Lin, J. J.; Lin, W. C.; Dong, R. X.; Hsu, S. H. Nanotechnology 2012, 23, 065102. (85) Meyer, E. E.; Rosenberg, K. J.; Israelachvili, J. Proceedings of the National Academy of Sciences 2006, 103, 15739. (86) Van Loosdrecht, M.; Lyklema, J.; Norde, W.; Schraa, G.; Zehnder, A. Applied and environmental microbiology 1987, 53, 1893. (87) Hermansson, M. Colloids and Surfaces B: Biointerfaces 1999, 14, 105. (88) Lin, J. J.; Chang, Y. C.; Cheng, I. Macromolecular rapid communications 2004, 25, 508. (89) Chou, C.-C.; Lin, J.-J. Macromolecules 2005, 38, 230. (90) Morhac, M.; Matousek, V. Applied spectroscopy 2008, 62, 91. (91) Gunnarsson, L.; Bjerneld, E.; Xu, H.; Petronis, S.; Kasemo, B.; Kall, M. Applied Physics Letters 2001, 78, 802. (92) Wei, A.; Kim, B.; Sadtler, B.; Tripp, S. L. Chemphyschem : a European journal of chemical physics and physical chemistry 2001, 2, 743. (93) Dixon, D. R.; Darveau, R. P. Journal of Dental Research 2005, 84, 584. (94) Khan, M. M.; Ista, L. K.; Lopez, G. P.; Schuler, A. J. Environ Sci Technol 2011, 45, 1055. (95) Zmantar, T.; Bettaieb, F.; Chaieb, K.; Ezzili, B.; Mora-Ponsonnet, L.; Othmane, A.; Jaffrezic, N.; Bakhrouf, A. World J Microbiol Biotechnol 2011, 27, 887. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/62110 | - |
dc.description.abstract | 本研究以具可撓性之奈米矽片 (NSP) 當作基材,使奈米銀粒子 (AgNP) 穩定地在其表面上被還原,製備成新穎之奈米矽片銀 (AgNP/NSP) 複合材料。其具有浮動性及三維熱點效應,可改善奈米粒子之穩定性、傳統陽極氧化鋁銀 (Ag/AAO) 陣列玻璃基板之空間限制和增加與微生物之接觸面積,並將其應用於表面增強拉曼散射 (SERS) 檢測技術。NSP是由層狀天然蒙脫土 (MMT) 脫層而得,其面積為100 × 100 nm2,厚度約1-5 nm。由於AgNP可吸附在幾奈米厚之NSP的上下側,相較於原始多層之AgNP/MMT (厚度約10-20 nm),此AgNP/NSP之幾何空間排列可誘發強烈的熱點效應 (z-方向),因此可廣泛地用於偵測小分子腺嘌呤 (adenine) 至微生物金黃色葡萄球菌 (S. aureus) 之SERS訊號。另外,此AgNP/NSP SERS基板具自由浮動的移動性和光學穿透性,可增加對於微生物的接觸面積及增強SERS偵測之靈敏度。
更進一步,將AgNP/NSP利用非離子型界面活性劑進行表面修飾,合成奈米銀-奈米矽片-界面活性劑 (AgNP/NSS) 複合物。先製備奈米矽片-界面活性劑 (NSS) 複合物後,在水溶液中原位 ( in-situ) 還原硝酸銀成奈米銀粒子。此界面活性劑可增強SERS基板與待測物之表面親和力,用於選擇性偵測疏水性細菌如大腸桿菌 (E. coli) 及分枝桿菌 (mycobacteria)、不規則形狀之微生物 (Fungi) 和較大型生物細胞。藉由調控界面活性劑組成比例,發現SERS偵測強度明顯提升且有一最佳化強度。 綜合疏水性、浮動基板的靈活性和三維熱點效應等特性,AgNP/NSS複合物量身定制地應用於選擇性偵測不規則形狀及疏水性微生物和較大型生物細胞,提供了一種新穎且快速無標籤的方式於特定的生物檢測。 | zh_TW |
dc.description.abstract | Novel nanohybrids of silver nanoparticle (AgNP) on nano silicate platelet (NSP) with floating and three-dimensional (3D) hot-junctions (particularly in z-direction) properties were discovered for improving the stability of free nanoparticles and the mobility of conventional Ag depositing porous anodic aluminum oxide (Ag/AAO) rigid glass-based substrate in surface-enhanced Raman scattering (SERS) detection technology. The NSP in the dimension of 100 x 100 nm2 with 1-5 nm thickness was previously synthesized from the exfoliation of natural clays such as montmorillonite (MMT). Since the AgNPs are adsorbed on both sides of few nanometer-thick NSP, the geometric arrangement of AgNP/NSP may induce strong hot-junctions (z-direction) in reference to the pristine multi-layers Ag/MMT at the thickness of ~20 nm, which can be widely used in SERS detection of small molecules (adenine from DNA) and microorganism (S. aureus). Further, AgNP/NSP SERS substrate displays free floating mobility and optical transparency (less background interference), which inherently increase the contacted surface-area between the substrate and microorganisms, thus the enhancement of SERS sensitivity.
On the other hand, the surface modulation of AgNP/NSP with a nonionic surfactant could be applied toward a variety of microorganisms including hydrophobic microbes, irregular-shaped microorganisms and larger biological cells due to their mutual specific surface interactions. The tri-component nanohybrids, Ag-NSP-surfactant (AgNP/NSS) were synthesized by in-situ reduction of AgNO3 into AgNP in the presence of NSP-surfactant hybrids (NSS) in aqueous. Owing to the presence of surfactant, the surface tension of AgNP/NSS had been adjusted and the affinity between AgNP/NSS and microorganisms had significantly increased for selectively detecting hydrophobic bacteria such as E. coli and mycobacteria, irregular-shaped microorganisms such as fungi and larger cells. With the surfactant fraction of AgNP/NSS increased, the SERS intensity of hydrophobic bacteria had dramatically enhanced comparing to the pristine AgNP/NSP and had an optimal value. Combination of hydrophobicity, substrate floating flexibility and 3D hot-junctions, the AgNP/NSS nanohybrids were tailored for selectively detecting irregular-shaped, hydrophobic microorganisms and larger biological cells, which provided a novel rapid label-free way for specific bio-detection. | en |
dc.description.provenance | Made available in DSpace on 2021-06-16T13:28:18Z (GMT). No. of bitstreams: 1 ntu-102-R00549027-1.pdf: 5369109 bytes, checksum: 8b98126519369b1b486edb2a43fbf717 (MD5) Previous issue date: 2013 | en |
dc.description.tableofcontents | Acknowledgements…………………………………………………………..............I
中文摘要 …………………………………………………………............II Abstract …………………………………………………………..............IV Contents ………………………………………………………............VII Figure captions ……………………………………………………….............IX Table captions …………………………………………………………...........XIII Scheme captions …………………………………………………………...........XIV Chapter 1 Introduction and Literature Review…............1 1.1. Theoretical Background of Surface-Enhanced Raman Scattering(SERS)………………………………………………………....1 1.1.1. Historical Review……………………….……...…….1 1.1.2. The Electromagnetic Theory of SERS…………………2 1.1.3. The Advances of Biological Detection by SERS………3 1.1.4. Development of SERS Active Substrates……………4 1.1.5. Correlation of SERS and Gaps Effect of Plasmonic Nanostructures………………………………………….6 1.1.6. SERS signals from different types of bacteria…….……8 1.2. Nanomaterials…………………………………….…………….10 1.3. Nanoscale Silicate Platelets (NSP)……………………13 1.4. Silver Nanoparticle…….…………….………………………15 1.4.1. Silver as SERS Signals Enhancer……………………15 1.4.2. The Shape Effect of AgNPs on LSPR………………...17 1.4.3. The Size Effect of AgNPs on SERS…………………..19 1.5. Surfactant……………………………………….……………..20 1.5.1. Classification of Surfactants……………………...…20 1.5.2. Basic Characteristic of Surfactant……………..…….22 1.5.3. Adhesion of Surfactant on Nanomaterials and Microorganisms……………………...….………….23 1.6. Research Objectives………………………………………........26 Chapter 2 Experimental Section....................28 2.1. Materials………………………………………………………..28 2.2. Synthesis of AgNP/Clay Nanohybrids........29 2.3. Synthesis of AgNP/NSS Nanohybrids………………………30 2.4. Control Experiments Involving Synthesis of AgNP/NSP+S……31 2.5. Bacteria Growth…………………………………..……......32 2.6. Preparation of SERS Sample……………..……..……………32 2.7. Surface-Enhanced Raman Scattering (SERS) Experiments…...33 2.8. Instruments and Analysis………………..……………....33 Chapter 3 Results and Discussion…………………………………......35 3.1. Synthesis of AgNP/Clay SERS Substrate……...35 3.1.1. Synthesis of AgNP/NSP Nanohybrids………….……...35 3.1.2. Modification with Different Types of Surfactants……..38 3.1.3. Synthesis of Tri-Component AgNP/NSS Nanohybrids..39 3.1.4. Characterization of SERS Substrate………………..….42 3.2. Three-Dimensional Hot-Junctions in Floating AgNP/NSP SERS Substrate…………………………………………………..44 3.2.1. The Characteristics of AgNP/NSP…………………44 3.2.2. Tilted Sputtering of Au onto AgNP/NSP…46 3.2.3. Relationship of SERS Intensity and Inter-Particle Gaps(3-D Hot-Junctions)……………………48 3.2.4. SEM Observation of Actual Contacts between AgNP/NSP SERS Substrate and Bacteria……………..51 3.2.5. UV Adsorption Analysis…………………..…………..52 3.2.6. SERS Signals of Small Molecular……….……54 3.2.7. Brief Summary………………………………..………57 3.3. Selectively Detecting Hydrophobic Microorganisms by AgNP/NSS SERS Substrate………….…………….…………58 3.3.1. Differentiation of SERS Signals between Hydrophilic and Hydrophobic Bacteria……………..………………58 3.3.2. Correlation between SERS Intensity and Surfactant Content…………………………………………….59 3.3.3. Functionality of Surfactant toward Hydrophobic Bacteria……………..………………………………64 3.3.4. SEM Observation of Actual Contacts between SERS Substrate and Bacteria…………………………………66 3.3.5. SERS Detection of Superhydrophobic Mycobacteria….68 3.3.6. The Role of Surfactant for SERS Detection……..……70 3.3.7. Brief Summary………………………………………..73 Chapter 4 Conclusion…………………………………………………………….74 Reference……………………………………………………………………………76 Curriculum Vitae……………...............…………………………………..………….85 | |
dc.language.iso | zh-TW | |
dc.title | 奈米矽片銀/界面活性劑複合物於表面增強拉曼散射偵測之應用 | zh_TW |
dc.title | Nanohybrids of Silver Nanoparticle/Silicate Platelets/Surfactant for Surface-Enhanced Raman Scattering Detection | en |
dc.type | Thesis | |
dc.date.schoolyear | 101-2 | |
dc.description.degree | 碩士 | |
dc.contributor.coadvisor | 劉定宇 | |
dc.contributor.oralexamcommittee | 戴憲弘,謝國煌,沈永清 | |
dc.subject.keyword | 表面增強拉曼散射,奈米銀粒子,奈米矽片,界面活性劑, | zh_TW |
dc.subject.keyword | surface-enhanced Raman scattering,silver nanoparticles,nano silicate platelets,surfactants., | en |
dc.relation.page | 86 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2013-07-23 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
顯示於系所單位: | 高分子科學與工程學研究所 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-102-1.pdf 目前未授權公開取用 | 5.24 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。