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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 林江珍(Jiang-Jen Lin) | |
dc.contributor.author | Yong-Hsiang Peng | en |
dc.contributor.author | 彭永翔 | zh_TW |
dc.date.accessioned | 2021-06-16T13:19:44Z | - |
dc.date.available | 2018-08-08 | |
dc.date.copyright | 2013-08-08 | |
dc.date.issued | 2012 | |
dc.date.submitted | 2013-07-26 | |
dc.identifier.citation | 1. (a) Stout, S. A.; Komarneni, S., Synthesis of Na-2-mica from talc and kaolinite: characterization and Sr2+ uptake. Journal of Materials Chemistry 2003, 13 (2), 377-381; (b) Kodama, T.; Higuchi, T.; Shimizu, T.; Shimizu, K.-i.; Komarneni, S.; Hoffbauer, W.; Schneider, H., Synthesis of Na-2-mica from metakaolin and its cation exchange properties. Journal of Materials Chemistry 2001, 11 (8), 2072-2077.
2. Lin, J. J.; Chu, C. C.; Chiang, M. L.; Tsai, W. C., First isolation of individual silicate platelets from clay exfoliation and their unique self-assembly into fibrous arrays. The journal of physical chemistry. B 2006, 110 (37), 18115-20. 3. Chiu, C.-W.; Lin, J.-J., Self-assembly behavior of polymer-assisted clays. Progress in Polymer Science 2012, 37 (3), 406-444. 4. Lai, Y.-H.; Chiu, C.-W.; Chen, J.-G.; Wang, C.-C.; Lin, J.-J.; Lin, K.-F.; Ho, K.-C., Enhancing the performance of dye-sensitized solar cells by incorporating nanosilicate platelets in gel electrolyte. Solar Energy Materials and Solar Cells 2009, 93 (10), 1860-1864. 5. (a) Hayward, R. C.; Pochan, D. J., Tailored Assemblies of Block Copolymers in Solution: It Is All about the Process. Macromolecules 2010, 43 (8), 3577-3584; (b) Bates, F. S., Block Copolymer Thermodynamics: theory_experiment. Annu. Rev.Phys.Chem 1990, 41 (41), 525-57. 6. Marras, S. I.; Tsimpliaraki, A.; Zuburtikudis, I.; Panayiotou, C., Thermal and colloidal behavior of amine-treated clays: the role of amphiphilic organic cation concentration. Journal of colloid and interface science 2007, 315 (2), 520-7. 7. Mahadevaiah, N.; Venkataramani, B.; Jai Prakash, B. S., Restrictive Entry of Aqueous Molybdate Species into Surfactant Modified MontmorilloniteA Breakthrough Curve Study. Chemistry of Materials 2007, 19 (18), 4606-4612. 8. Vaia, R. A.; Teukolsky, R. K.; Giannelis, E. P., Interlayer Structure and Molecular Environment of Alkylammonium Layered Silicates. Chemistry of Materials 1994, 6 (7), 1017-1022. 9. Hotta, S.; Paul, D. R., Nanocomposites formed from linear low density polyethylene and organoclays. Polymer 2004, 45 (22), 7639-7654. 10. Zeng, C.; Lee, L. J., Poly(methyl methacrylate) and Polystyrene/Clay Nanocomposites Prepared by in-Situ Polymerization. Macromolecules 2001, 34 (12), 4098-4103. 11. Fu, X.; Qutubuddin, S., Polymer–clay nanocomposites: exfoliation of organophilic montmorillonite nanolayers in polystyrene. Polymer 2001, 42 (2), 807-813. 12. Fu, X.; Qutubuddin, S., Synthesis of polystyrene–clay nanocomposites. Materials Letters 2000, 42 (1–2), 12-15. 13. Imai, Y.; Nishimura, S.; Abe, E.; Tateyama, H.; Abiko, A.; Yamaguchi, A.; Aoyama, T.; Taguchi, H., High-Modulus Poly(ethylene terephthalate)/Expandable Fluorine Mica Nanocomposites with a Novel Reactive Compatibilizer. Chemistry of Materials 2002, 14 (2), 477-479. 14. Chang, J.-H.; Jang, T.-G.; Ihn, K. J.; Lee, W.-K.; Sur, G. S., Poly(vinyl alcohol) nanocomposites with different clays: Pristine clays and organoclays. Journal of Applied Polymer Science 2003, 90 (12), 3208-3214. 15. Ho Kim, M.; Park, C. I.; Choi, W. M.; Lee, J. W.; Lim, J. G.; Park, O. O.; Kim, J. M., Synthesis and material properties of syndiotactic polystyrene/organophilic clay nanocomposites. Journal of Applied Polymer Science 2004, 92 (4), 2144-2150. 16. Ijdo, W. L.; Pinnavaia, T. J., Solid Solution Formation in Amphiphilic Organic−Inorganic Clay Heterostructures. Chemistry of Materials 1999, 11 (11), 3227-3231. 17. Maiti, P.; Yamada, K.; Okamoto, M.; Ueda, K.; Okamoto, K., New Polylactide/Layered Silicate Nanocomposites: Role of Organoclays. Chemistry of Materials 2002, 14 (11), 4654-4661. 18. Xie, W.; Xie, R.; Pan, W.-P.; Hunter, D.; Koene, B.; Tan, L.-S.; Vaia, R., Thermal Stability of Quaternary Phosphonium Modified Montmorillonites. Chemistry of Materials 2002, 14 (11), 4837-4845. 19. Lin, J.-J.; Chen, Y.-M., Amphiphilic Properties of Poly(oxyalkylene)amine-Intercalated Smectite Aluminosilicates. Langmuir : the ACS journal of surfaces and colloids 2004, 20 (10), 4261-4264. 20. Chou, C.-C.; Chang, Y.-C.; Chiang, M.-L.; Lin, J.-J., Conformational Change of Trifunctional Poly(oxypropylene)amines Intercalated within a Layered Silicate Confinement. Macromolecules 2003, 37 (2), 473-477. 21. Lin, J.-J.; Chen, I. J.; Chou, C.-C., Critical Conformational Change of Poly(oxypropylene)diamines in Layered Aluminosilicate Confinement. Macromolecular Rapid Communications 2003, 24 (8), 492-495. 22. Lin, J.-J.; Chu, C.-C.; Chiang, M.-L.; Tsai, W.-C., First Isolation of Individual Silicate Platelets from Clay Exfoliation and Their Unique Self-Assembly into Fibrous Arrays. The Journal of Physical Chemistry B 2006, 110 (37), 18115-18120. 23. Sommer, A. P.; Franke, R.-P., Biomimicry Patterning with Nanosphere Suspensions. Nano Letters 2002, 3 (5), 573-575. 24. Lin, J. J.; Chu, C. C.; Chou, C. C.; Shieu, F. S., Self-Assembled Nanofibers from Random Silicate Platelets. Advanced Materials 2005, 17 (3), 301-304. 25. Amir Parviz, B.; Ryan, D.; Whitesides, G. M., Using self-assembly for the fabrication of nano-scale electronic and photonic devices. Advanced Packaging, IEEE Transactions on 2003, 26 (3), 233-241. 26. Chowdhury, D.; Maoz, R.; Sagiv, J., Wetting Driven Self-Assembly as a New Approach to Template-Guided Fabrication of Metal Nanopatterns. Nano Letters 2007, 7 (6), 1770-1778. 27. Herranz, M. Á.; Colonna, B.; Echegoyen, L., Metal ion recognition and molecular templating in self-assembled monolayers of cyclic and acyclic polyethers. Proceedings of the National Academy of Sciences 2002, 99 (8), 5040-5047. 28. Kim, J.-H.; Rahman, M. S.; Lee, J.-S.; Park, J.-W., Liquid Crystalline Ordering in the Self-Assembled Monolayers of Tethered Rodlike Polymers. Journal of the American Chemical Society 2007, 129 (25), 7756-7757. 29. Bhargava, P.; Zheng, J. X.; Li, P.; Quirk, R. P.; Harris, F. W.; Cheng, S. Z. D., Self-Assembled Polystyrene-block-poly(ethylene oxide) Micelle Morphologies in Solution. Macromolecules 2006, 39 (14), 4880-4888. 30. Agut, W.; Brûlet, A.; Taton, D.; Lecommandoux, S., Thermoresponsive Micelles from Jeffamine-b-poly(l-glutamic acid) Double Hydrophilic Block Copolymers. Langmuir : the ACS journal of surfaces and colloids 2007, 23 (23), 11526-11533. 31. Mountrichas, G.; Pispas, S., Synthesis and pH Responsive Self-Assembly of New Double Hydrophilic Block Copolymers. Macromolecules 2006, 39 (14), 4767-4774. 32. Alexandridis, P.; Yang, L., SANS Investigation of Polyether Block Copolymer Micelle Structure in Mixed Solvents of Water and Formamide, Ethanol, or Glycerol. Macromolecules 2000, 33 (15), 5574-5587. 33. Okada, A.; Usuki, A., Twenty Years of Polymer-Clay Nanocomposites. Macromolecular Materials and Engineering 2006, 291 (12), 1449-1476. 34. Böhning, M.; Goering, H.; Fritz, A.; Brzezinka, K.-W.; Turky, G.; Schönhals, A.; Schartel, B., Dielectric Study of Molecular Mobility in Poly(propylene-graft-maleic anhydride)/Clay Nanocomposites. Macromolecules 2005, 38 (7), 2764-2774. 35. Hsu, R.-S.; Chang, W.-H.; Lin, J.-J., Nanohybrids of Magnetic Iron-Oxide Particles in Hydrophobic Organoclays for Oil Recovery. ACS Applied Materials & Interfaces 2010, 2 (5), 1349-1354. 36. Lin, J.-J.; Wei, J.-C.; Juang, T.-Y.; Tsai, W.-C., Preparation of Protein−Silicate Hybrids from Polyamine Intercalation of Layered Montmorillonite. Langmuir : the ACS journal of surfaces and colloids 2006, 23 (4), 1995-1999. 37. Lin, J.-J.; Wei, J.-C.; Tsai, W.-C., Layered Confinement of Protein in Synthetic Fluorinated Mica via Stepwise Polyamine Exchange. The Journal of Physical Chemistry B 2007, 111 (34), 10275-10280. 38. Alexandre, M.; Dubois, P., Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials. Materials Science and Engineering: R: Reports 2000, 28 (1–2), 1-63. 39. Triantafyllidis, K. S.; LeBaron, P. C.; Park, I.; Pinnavaia, T. J., Epoxy−Clay Fabric Film Composites with Unprecedented Oxygen-Barrier Properties. Chemistry of Materials 2006, 18 (18), 4393-4398. 40. Zhu, J.; Morgan, A. B.; Lamelas, F. J.; Wilkie, C. A., Fire Properties of Polystyrene−Clay Nanocomposites. Chemistry of Materials 2001, 13 (10), 3774-3780. 41. Sinha Ray, S.; Yamada, K.; Okamoto, M.; Ueda, K., Polylactide-Layered Silicate Nanocomposite: A Novel Biodegradable Material. Nano Letters 2002, 2 (10), 1093-1096. 42. Kojima, Y.; Usuki, A.; Kawasumi, M.; Okada, A.; Kurauchi, T.; Kamigaito, O., Synthesis of nylon 6–clay hybrid by montmorillonite intercalated with ϵ-caprolactam. Journal of Polymer Science Part A: Polymer Chemistry 1993, 31 (4), 983-986. 43. Vaia, R. A.; Ishii, H.; Giannelis, E. P., Synthesis and properties of two-dimensional nanostructures by direct intercalation of polymer melts in layered silicates. Chemistry of Materials 1993, 5 (12), 1694-1696. 44. Azeez, A. A.; Rhee, K. Y.; Park, S. J.; Hui, D., Epoxy clay nanocomposites – processing, properties and applications: A review. Composites Part B: Engineering 2013, 45 (1), 308-320. 45. Liu, L.; Qi, Z.; Zhu, X., Studies on nylon 6/clay nanocomposites by melt-intercalation process. Journal of Applied Polymer Science 1999, 71 (7), 1133-1138. 46. Katiyar, V.; Gerds, N.; Koch, C. B.; Risbo, J.; Hansen, H. C. B.; Plackett, D., Poly l-lactide-layered double hydroxide nanocomposites via in situ polymerization of l-lactide. Polymer Degradation and Stability 2010, 95 (12), 2563-2573. 47. Akelah, A.; Moet, A., Polymer-clay nanocomposites: Free-radical grafting of polystyrene on to organophilic montmorillonite interlayers. JOURNAL OF MATERIALS SCIENCE 1996, 31 (13), 3589-3596. 48. Jin, Y.-H.; Park, H.-J.; Im, S.-S.; Kwak, S.-Y.; Kwak, S., Polyethylene/Clay Nanocomposite by In-Situ Exfoliation of Montmorillonite During Ziegler-Natta Polymerization of Ethylene. Macromolecular Rapid Communications 2002, 23 (2), 135-140. 49. Ke, Y.; Long, C.; Qi, Z., Crystallization, properties, and crystal and nanoscale morphology of PET–clay nanocomposites. Journal of Applied Polymer Science 1999, 71 (7), 1139-1146. 50. Jan, I.-N.; Lee, T.-M.; Chiou, K.-C.; Lin, J.-J., Comparisons of Physical Properties of Intercalated and Exfoliated Clay/Epoxy Nanocomposites. Industrial & Engineering Chemistry Research 2005, 44 (7), 2086-2090. 51. Chiu, C.-W.; Cheng, W.-T.; Wang, Y.-P.; Lin, J.-J., Fine Dispersion of Hydrophobic Silicate Platelets in Anhydride-Cured Epoxy Nanocomposites. Industrial & Engineering Chemistry Research 2007, 46 (22), 7384-7388. 52. Chu, C. C.; Lin, J. J.; Shiu, C. R.; Kwan, C. C., Fine dispersion and property differentiation of nanoscale silicate platelets and spheres in epoxy nanocomposites. Polym. J. 2005, 37 (4), 239-245. 53. Lim, S.-H.; Dasari, A.; Wang, G.-T.; Yu, Z.-Z.; Mai, Y.-W.; Yuan, Q.; Liu, S.; Yong, M. S., Impact fracture behaviour of nylon 6-based ternary nanocomposites. Composites Part B: Engineering 2010, 41 (1), 67-75. 54. Timmaraju, M. V.; Gnanamoorthy, R.; Kannan, K., Influence of imbibed moisture and organoclay on tensile and indentation behavior of polyamide 66/hectorite nanocomposites. Composites Part B: Engineering 2011, 42 (3), 466-472. 55. Wang, Y.; Gao, J.; Ma, Y.; Agarwal, U. S., Study on mechanical properties, thermal stability and crystallization behavior of PET/MMT nanocomposites. Composites Part B: Engineering 2006, 37 (6), 399-407. 56. Vaia, R. A.; Giannelis, E. P., Lattice Model of Polymer Melt Intercalation in Organically-Modified Layered Silicates. Macromolecules 1997, 30 (25), 7990-7999. 57. Aranda, P.; Ruiz-Hitzky, E., Poly(ethylene oxide)-silicate intercalation materials. Chemistry of Materials 1992, 4 (6), 1395-1403. 58. Zhao, X.; Urano, K.; Ogasawara, S., Adsorption of polyethylene glycol from aqueous solution on montmorillonite clays. Colloid & Polymer Sci 1989, 267 (10), 899-906. 59. Delhom, C. D.; White-Ghoorahoo, L. A.; Pang, S. S., Development and characterization of cellulose/clay nanocomposites. Composites Part B: Engineering 2010, 41 (6), 475-481. 60. Jeon, H. G.; Jung, H. T.; Lee, S. W.; Hudson, S. D., Morphology of polymer/silicate nanocomposites High density polyethylene and a nitrile copolymer. Polymer Bulletin 1998, 41 (1), 107-113. 61. Yano, K.; Usuki, A.; Okada, A.; Kurauchi, T.; Kamigaito, O., Synthesis and properties of polyimide–clay hybrid. Journal of Polymer Science Part A: Polymer Chemistry 1993, 31 (10), 2493-2498. 62. Sinha Ray, S.; Okamoto, M., Polymer/layered silicate nanocomposites: a review from preparation to processing. Progress in Polymer Science 2003, 28 (11), 1539-1641. 63. Lingaiah, S.; Sadler, R.; Ibeh, C.; Shivakumar, K., A method of visualization of inorganic nanoparticles dispersion in nanocomposites. Composites Part B: Engineering 2008, 39 (1), 196-201. 64. Park, J. H.; Jana, S. C., Mechanism of Exfoliation of Nanoclay Particles in Epoxy−Clay Nanocomposites. Macromolecules 2003, 36 (8), 2758-2768. 65. Ha, S. R.; Rhee, K. Y.; Kim, H. C.; Kim, J. T., Fracture performance of clay/epoxy nanocomposites with clay surface-modified using 3-aminopropyltriethoxysilane. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2008, 313–314 (0), 112-115. 66. Chan, Y.-N.; Hsu, R.-S.; Lin, J.-J., Mechanism of Silicate Platelet Self-Organization during Clay-Initiated Epoxy Polymerization. The Journal of Physical Chemistry C 2010, 114 (23), 10373-10378. 67. Chan, Y. N.; Dai, S. H. A.; Lin, J. J., Simultaneous Occurrence of Self-Assembling Silicate Skeletons to Wormlike Microarrays and Epoxy Ring-Opening Polymerization. Macromolecules 2009, 42 (13), 4362-4365. 68. Lan, Y.-F.; Lin, J.-J., Clay-assisted dispersion of organic pigments in water. Dyes and Pigments 2011, 90 (1), 21-27. 69. Wang, K.; Chen, L.; Wu, J.; Toh, M. L.; He, C.; Yee, A. F., Epoxy Nanocomposites with Highly Exfoliated Clay: Mechanical Properties and Fracture Mechanisms. Macromolecules 2005, 38 (3), 788-800. 70. Liu; Phang, I. Y.; Shen, L.; Chow, S. Y.; Zhang, W.-D., Morphology and Mechanical Properties of Multiwalled Carbon Nanotubes Reinforced Nylon-6 Composites. Macromolecules 2004, 37 (19), 7214-7222. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/61941 | - |
dc.description.abstract | 本研究經由系統化的合成,設計開發一新型雙親性奈米黏土,使用不同聚醚胺及環氧樹脂合成之脫層劑經由離子交換得到脫層型奈米黏土,再經由反向離子交換控制奈米材料之有機無機比例,進而達到雙親性。並利用其雙親性應用於分散顏料、吸附有機溶劑及導入環氧樹脂,製備成奈米複合材料。天然的蒙脫土經由開發之脫層劑的崁入,將層間距由 12Å 脫層為無序的奈米矽片,其基本結構中長寬高的尺寸為 100 × 100 × 1 nm,並藉由穿透式電子顯微鏡 (TEM) 及 X 光繞射儀 (XRD) 得到驗證。但也由於脫層劑使混成材料轉為疏水性及黏稠不易分散及利用,利用開發出之反向離子交換反應控制有機脫層劑/無機奈米黏土之比例,並找出最佳比例為 30/70 和 50/50 具有雙親性。此奈米混成材料在 1wt% 的添加可使表面張力由 72 mN/m 下降至 41 mN/m。 此外,添加在水和甲苯共溶液中可表現出穩定之乳化現象。另外在界達電位 (zeta potential) 和粒徑分析中可以勾勒出此雙親奈米矽片之雙親機制。在應用方面,幫助 pigment 顏料之分散和吸附 20 倍重量的癸烷,並利用共沉澱法合成氧化鐵於雙親奈米黏土中,利用磁力可以吸附水中之 pigment 顏料。另一方面,將此雙親奈米矽片作為添加劑在環氧樹脂材料中,製備出不同添加含量的奈米複合材料,並從性質改變的結果應證了雙親奈米矽片在高分子良好的分散性,例如添加 0.5wt%之雙親奈米矽片,即可將鉛筆硬度從
2H 到 4H,在穿透度的部分,未改質蒙脫土和雙親奈米矽片在同樣添加量時,雙親奈米矽片有明顯較佳之透明度。 | zh_TW |
dc.description.abstract | A systematic approach of using poly(oxyalkylene)-amine-salt terminated 2,2-bis(4-hydroxyphenyl)propane. epoxy oligomers for modifying the layered silicate clays has led to organoclays with different surfactant properties. The pristine layered structure of natural clays such as sodium montmorillonite (Na+-MMT) could be organically intercalated into basal spacing from 12Å to 100Å and exfoliated to form randomized thin layer silicate platelets (ca. 1 nm thickness) , depending on the choices of the amine-oligomers. The organic modification of the ionic clays with cation exchanged capacity of 120 mequiv./100g involved the amine-salt ionic exchange reaction and accompanied by the organic incorporation into the clay layered structure as the first step. These organoclays were characterized by X-ray diffraction and shown their expanded basal spacing up to 100 Å and even into randomized platelets, and confirmed by TEM examination. Furthermore, we manipulated the organoclays fraction of hydrophobic amine-oligomers and hydrophilic randomized thin layer silicate platelets by reverse ion exchanged reaction as the second step. The cooperation of organic amine-oligomers and inorganic platelets has led to amphiphilic property in balanced organic fraction. The amphiphilic nature was further enhanced by their ability of lowering the surface tension at the water–air interface from 72 to 41 mN/m at 1 wt% of organoclay. The platelet ionic charges were analyzed by zeta potential measurement showing a pH-dependent charge species existed on the surface of the random platelets. The zeta potential of balanced organoclay was demonstrated charge reverse with pH changed, showing the interaction of nano silicate platelets and amine-oligomers can be evidenced. Since the amphiphilic organoclay synthesized, extremely stable emulsions form even the clay–amine suspension remains unflocculated in water/toluene biphase and assisted pigment dispersion. Moreover, amphiphilic organoclay with magnetic iron-oxide nanoparticles (FeNPs) embedded in the clay were synthesized by in situ Fe2+/Fe3+ coprecipitation. Then pigment adsorption with magnetic force in water was carried on. On the other side, as the filler, good enhancement of epoxy nanocomposites was carried, not only mechanical but also thermal property, raising pencil hardness from 2H to 4H with only 0.5 wt%. The high aspect-ratio and fine dispersion of the platelet silicates were found to be important factors in influencing the cured epoxy. | en |
dc.description.provenance | Made available in DSpace on 2021-06-16T13:19:44Z (GMT). No. of bitstreams: 1 ntu-101-R00549020-1.pdf: 5451726 bytes, checksum: 77f678e73659f523f6f39b68ce4ee054 (MD5) Previous issue date: 2012 | en |
dc.description.tableofcontents | Table of Content
謝誌-I- 摘要-II- ABSTRACT-III- List of Figures.-VII- List of Tables-XII- Chapter 1 Introduction-1- 1.1 Natural occurrences of biomaterials and clay minerals-1- 1.2 Intercalation and exfoliation of layered clays-3- 1.2.1 Intercalation with alkyl quaternary and polymeric amine-salts-4- 1.2.2 Exfoliation of the layered structure into individual platelets-6- 1.2.3 The Current Development and Application of Organic Clays-8- 1.3 Clay–polymer Nanocomposites-12- 1.3.1 Preparation of Nanocomposites-13- 1.3.2 Structure of polymer clay nanocomposites-15- 1.3.3 Epoxy clay nanocomposites-16- 1.4 Research Objectives-20- Chapter 2 Materials and Experiments-21- 2.1 Materials -21- 2.2 Experimental Section-21- 2.2.1 Preparation of amine oligomers-21- 2.2.2 Ion exchange reaction of the synthesized amine oligomers with non-swelling Na+-MMT-22- 2.2.3 Reverse Ion exchange reaction of the sodium hydroxide to extract out amine-terminated epoxy oligomer-22- 2.2.4 Preparation of pigment clay mixture solution. -23- 2.2.5 Preparation of epoxy nanocomposites-23- 2.3 Instruments and Measurements-24- Chapter 3 Results and Discussion-25- 3.1 Preparation of amphiphilic nano silicate platelets quarts-25- 3.1.1 Preparation of POP-amine/DGEBA coupled oligomers as intercalating agents-25- 3.1.2 Ionic exchanging and intercalating of Na+-MMT with the quaternary salts of POP-amine oligomers and ethylenediamine oligomers-27- 3.1.3 Mechanism of intercalation versus exfoliation and TEM evidence of exfoliation-32- 3.1.4 Control organic fraction of POP-amine derived and amphiphilic property-34- 3.1.5 Surface property of MMT with different amount POP400 derived and mechanism hypothesis by zeta potential-41- 3.2 Geometric dispersion of pigment and decane adsorption-50- 3.3 Property of epoxy/clay nanocomposites-56- Chapter 4 Conclusion-63- Chapter 5 References-64- | |
dc.language.iso | en | |
dc.title | 雙性黏土矽片製備及環氧樹脂複材應用 | zh_TW |
dc.title | Amphiphilic Clay Silicate Platelets and Epoxy Nanocomposites Applications | en |
dc.type | Thesis | |
dc.date.schoolyear | 101-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 謝國煌(Kuo-Huang Hsieh),戴憲弘(Shenghong A. Dai),沈永清 | |
dc.subject.keyword | 奈米矽片,插層脫層,雙親性,奈米複合材料, | zh_TW |
dc.subject.keyword | nano silicate platelets,intercalation, exfoliation,organoclay,amphiphilic, | en |
dc.relation.page | 68 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2013-07-26 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
顯示於系所單位: | 高分子科學與工程學研究所 |
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