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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 方煒(Wei Fang) | |
| dc.contributor.author | Shih-Jey Ding | en |
| dc.contributor.author | 丁世杰 | zh_TW |
| dc.date.accessioned | 2021-06-16T10:15:03Z | - |
| dc.date.available | 2018-09-06 | |
| dc.date.copyright | 2013-09-06 | |
| dc.date.issued | 2013 | |
| dc.date.submitted | 2013-08-19 | |
| dc.identifier.citation | 1. 方煒，陳林祈，張明毅，康世緯，莊啟佑。2009。電解水技術應用於動植物抑菌消毒之回顧與展望。生機論文研討會。
2. 王奕程。2008。自製無隔膜電解水應用於抑制蝴蝶蘭主要病原菌。碩士論文。臺北：國立臺灣大學生物產業機電工程學研究所。 3. 徐菁輿。2005。製備電解強酸水及電解次氯酸水與其殺菌效果之探討。碩士論文。臺北：國立臺灣大學生物產業機電工程學研究所。 4. 康世緯。2010。多用途電解滅菌自動化系統之研發與應用。碩士論文。臺北：國立臺灣大學生物產業機電工程學研究所。 5. 康世緯，陳翔瀚，方煒。2010。電流式自由氯濃度感測器之開發。生機論文研討會。 6. 陳翔瀚。2011。兩段式脈衝安培法應用於自由氯感測。碩士論文。臺北：國立台灣大學生物產業機電工程學研究所。 7. 林其民。2012。泛用型電流式自由氯感測系統之開發。碩士論文。臺北：國立台灣大學生物產業機電工程學研究所。 8. 林立欣。2012。無隔膜電解產製弱酸性次氯酸水之研究。碩士論文。臺北：國立台灣大學生物產業機電工程學研究所。 9. 陳瑞和。1991。感測器。初版，257-280。台北：全華。 10. 鍾佩如。2010。低鹽無隔膜電解水設備之研製。碩士論文。臺北：國立台灣大學生物產業機電工程學研究所。 11. Al-Haq, M.I., J. Sugiyama, and S. Isobe. 2005. Applications of electrolyzed water in agriculture & food industries. Food Science and Technology Research 11(2): 135-150. 12. Bard A.J., and L. R. Faulkner. 2001. Electrochemical methods. Fundamentals and applications 2rd ed., P. 226-236. New York: John Wiley and Sons, Inc. 13. Barrette, W. C. J., D. M. Hannum, W. D. Wheeler, and J. K. Hurst. 1989. General mechanism for the bacterial toxicityT of hypochilorous acid abolition of ATP production. Biochemistry 28 (23): 9172-9178. 14. Berg A. V. D., Milena K. H., Bart H. V. D. S. and Nico F. D. R. 1992. Analytica Chimica Acta 269 :75-82 15. Campo, F. J. D., O. Ordeig, and F. J. Muňoz. 2005. Improved free chlorine amperometric sensor chip for drinking water applications. Analytica Chimica Acta 554 (1-2): 98-104. 16. Carter, M. T., and R. A. Osteryoung. 2006. Pulse Voltammetry. New York: Wiley. 17. Cui, X., Y. Shang, Z. Shi, H. Xin and W. Cao. 2009. Physicochemical properties and bactericidal efficiency of neutral and acidic electrolyzed water under different storage conditions. Journal of Food Engineering 91 (4): 582-586. 18. Eggins, B. R. 2002. Chemical sensors and biosensors. England:John Wiley and Sons, Inc. 19. EPA. 1983. Methods for Chemical Analysis of Water, and Wastes, Method 120.1. Washington, D.C.: EPA Environmental Protection Agency. Available at: www.epa.gov. Accessed 7 May 2012. 20. Guentzel, J., K. Liang Lam, M. A. Callan, S. A. Emmons and V. L. Dunham. 2008. Reduction of bacteria on spinach, lettuce, and surfaces in food service areas using neutral electrolyzed oxidizing water. Food Microbiology 25 (1): 36-41. 21. Harp, D. L. 2002. Current technology of chlorine analysis for water and wastewater, Hach Company, USA. 22. Huang, Y. R., H. S. Hsieh, S. Y. Lin, S. J. Lin, Y. C. Hung and D. F. Hwang. 2006. Application of electrolyzed oxidizing water on the reduction of bacterial contamination for seafood. Food control 17 (12): 987-993. 23. Huang, Y., Y. Hung, S. Hsu, Y. Huang, and D. Hwang. 2008. Application of electrolyzed water in the food industry. Food Control 19 (4): 329-345. 24. Izumi, H. 1999. Electrolyzed water as a disinfectant for fresh-cut vegetables. Journal of Food Science 64 (3): 536-539. 25. Jin, J., Y. Suzuki, N. Ishikawa, and T. Takeuchi. 2004. A miniaturized FIA system for the determination of residual chlorine in environmental water samples. Analytical Sciences 20 (1): 205-207. 26. Kishioka, S. Y., T. Kosugi and A. Yamada. 2004. Electrochemical determination of a free chlorine residual using cathodic potential-step chronocoulometry. Electroanalysis 17(8): 724-726. 27. Kissinger, P. T., and W. R. Heineman. 1983. Cyclic voltammetry. Journal of Chemical Education 60 (9): 702-706. 28. Koseki, S., K. Yoshida, K. Yoshinori, I. Seiichiro and I. Kazuhiko. 2004. Effect of mild heat pre-treatment with alkaline electrolyzed water on the efficacy of acidic electrolyzed water against Escherichia coli O157:H7 and Salmonella on Lettuce. Food Microbiology 21 (5): 559-566. 29. Kodera, F., S. Kishioka, M. Umeda, and A. Yamada. 2004. Electrochemical detection of free chlorine using anodic current. Japanese Journal of Applied Physics 43 (7A): 913-914. 30. Kodera, F., M. Umeda, and A. Yamada, 2005. Determination of free chlorine based on anodic voltammetry using platinum, gold, and glassy carbon electrodes. Anal. Chim. Acta. 547 (1-2): 293-298. 31. Lilley, M. D., J. B. Story, and R. W. Raible. 1969. The chronoamperometric determination of dissolved oxygen using membrane electrodes. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 23 (3): 425-429. 32. McPherson, L.L. 1993. Understanding ORP’s role in the disinfection process. Water Engineering & Management. 140 (11): 29-31. 33. Mehta, A., H. Shekhar, S. H. Hyun, S. Hong and H.J. Cho, 2006. A micromachined electrochemical sensor for free chlorine monitoring in drinking water. Water Science and Technology 53 (4-5): 403-410. 34. Murata, M., T. A. Ivandini, M. Shibata, S. Nomura, A. Fujishima and Y. Einaga. 2008. Electrochemical detection of free chlorine at highly boron-doped dimond electrodes. Journal of Electroanalytical Chemistry 612: 29-36. 35. Nakajima, N., T. Nakano, F. Harada, H. Taniguchi, I. Yokoyama, J. Hirose, E. Daikoku and K. Sano. 2004. Evaluation of disinfective potential of reactivated free chlorine in pooled tap water by electrolysis. Journal of microbiological methods 57 (2): 163-173. 36. Okumura, A., A. Hirabayashi, Y. Sasaki, and R. Miyake. 2001. Simple miniaturized amperometric flow cell for monitoring residual chlorine in tap water. Analytical sciences. 17 (9): 1113-1115. 37. Ordeiga, O., R. Mas, J. Gonzalo, F. J. D. Campo, F. J. Munoz and C. D. Haro. 2005. Continuous detection of hypochlorous acid/hypochlorite for water quality monitoring and control. Electroanalysis. 17(18): 1641-1648. 38. Park, H., Y. C. Hung and R. E. Brackett. 2002. Antimicrobial effect of electrolyzed water for inactivating campylobacter jejuni during poultry washing. International Journal of Food Microbiology 72 (1-2): 77-83. 39. Pathiratne, K. A. S., S. S. Skandaraja and E. M. C. M. Jayasena. 2008. Linear sweep voltammetric determination of free chlorine in waters using graphite working electrodes. Journal of the National Science Foundation of Sri Lanka. 36(1): 25-31 40. Saputro, S., K. Takehara, K. Yoshimura, S. Matsuoka and Narsito. 2010. Differential pulse voltammetric determination of free chlorine for water disinfection process. Electroanalysis. 22 (23): 2765-2768. 41. Su, Y. C., C. Liu, and Y. C. Hung. 2007. Electrolyzed water: principles and applications. In 'New Biocides Development Conference', 309-322. Zhu, P., ed. Washington, DC: American Chemical Society. 42. Tsaousis, A. N., and C. O. Huber. 1985. Flow-injection amperometric determination of chlorine as a gold electrode. Analytica Chimica Acta. 178: 319-323. 43. White, G.C. 2010. White's handbook of chlorination and Alternative Disinfectants. 5th ed., 176-177. New Jersey: John Wiley and Sons, Inc. 44. K. Nagashima, H. Furui, M. Ejiri, and N. Nakano. 2002. Bunseki Kagaku 51 1175 | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/60297 | - |
| dc.description.abstract | 本研究旨在探討學長開發之泛用型自由氯感測器是否對於不同電解液會有不同的感測結果，並且開發一套適用於半連續式電解水機之自由氯感測系統，以利於使用者瞭解所使用電解水之自由氯濃度。
本研究探討三種不同電解液對於自由氯感測之電流響應的不同，第一種電解液為使用次氯酸鈉與0.1M NaCl不經電解而調配出來，第二種為電解0.1M KCl，第三種為電解0.1M NaCl。 本研究成功開發一套半連續式電解水機專用型自由氯感測系統，此系統可因應使用之電解質 (KCl或NaCl)，即時監測電解水之自由氯濃度。系統監測包括溫度，酸鹼度及自由氯三個子系統。溫度系統用以校正酸鹼值，酸鹼值系統用以校正自由氯濃度。此設備之自由氯量測範圍為 20~300 mg/L，酸鹼值之適用範圍為7~10，可選擇濃度為50 ppm及200 ppm。目前已將本系統安裝至半連續式電解水機上，而電解水機目前安裝於本校生農學院完全人工光型植物工廠內。 | zh_TW |
| dc.description.abstract | This study is investigate if a generic free available chlorine (FAC) monitoring system developed by the seniors have different sensing results with different electrolytes or not, and developing a free available chlorine sensing system for suitable semi-continuous electrolyzed water generating unit to help users understand the free chlorine concentration of the electrolyzed water
In this study we investigate the different of current response between three different electrolyte in sensing free available chlorine, the first electrolyte is concocted by sodium hypochlorite and 0.1M NaCl without electrolysis ,the second electrolyte is 0.1M KCl, a the third electrolyte is 0.1M NaCl. This research has developed a free chlorine sensing system for semi-continuous electrolyzed water generating, which the user can choose a different electrolyte (KCl or NaCl), can be used to real-time monitoring the concentration of free chlorine of electrolyzed water. There are three subsystems in this sensing system, including temperature, pH and free available chlorine. PH is regulated by temperature, the concentration of free chlorine is regulated by pH. This system achieved to detect FAC concentration of 20 ~ 300 mg/L in the pH range from 7 to 10.You can choose a concentration of 50 ppm and 200 ppm. Currently the system has been installed in the semi-continuous electrolyzed water generating unit. The system is now installed in the plant factory with artificial light only located in our University. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T10:15:03Z (GMT). No. of bitstreams: 1 ntu-102-R00631031-1.pdf: 1641323 bytes, checksum: e4c2dea5bd91f9ae6d93ee72fe34dbaa (MD5) Previous issue date: 2013 | en |
| dc.description.tableofcontents | 誌謝 I
摘要 II ABSTRACT III 圖目錄 VI 表目錄 VIII 第一章 前言與研究目的 1 第二章 文獻探討 3 2.1 電解水製作原理 3 2.1.1 有隔膜電解水 4 2.1.2 無隔膜電解水 5 2.2 電解水抑菌機制 6 2.2.1 酸鹼值 6 2.2.2 自由氯濃度 6 2.2.3 氧化還原電位 7 2.3 電解水之抑菌應用 7 2.4常見的自由氯感測技術 8 2.4.1 碘量滴定法 8 2.4.2 DPD比色法 8 2.4.3 DPD滴定法 10 2.5 電化學自由氯感測技術 11 2.5.1 量測還原電流之相關研究 12 2.6 電解水機介紹 15 第三章 研究方法 17 3.1 藥品與試劑 17 3.2 儀器與設備 17 3.3 比色法量測自由氯濃度 18 3.4 實驗環境與系統 19 3.4.1 三極式電極系統 19 3.4.2 工作電極之清理 19 3.5 循環伏安法 20 3.5.1電解液之比較 20 3.6 安培分析法 20 3.7具自由氯感測系統之連續式電解水機之製作 21 3.7.1電解水製備系統 21 3.7.2自由氯感測系統之製作 22 溫度感測子系統 22 酸鹼度感測子系統 25 自由氯感測子系統 26 3.7.3自由氯感測系統酸鹼值測試 28 第四章 結果與討論 30 4.1電解液之比較-安培分析法 30 4.2電解液之比較-循環伏安法 33 4.3 溫度感測子系統之製作 36 4.4酸鹼值感測子系統之製作 39 4.5自由氯感測子系統之製作 42 4.6 自由氯感測系統測試 44 4.7電解水機與感測器之測試 48 第五章 結論 53 參考文獻 55 | |
| dc.language.iso | zh-TW | |
| dc.subject | 電解液 | zh_TW |
| dc.subject | 自由氯 | zh_TW |
| dc.subject | 無隔膜電解水 | zh_TW |
| dc.subject | 半連續式電解水機 | zh_TW |
| dc.subject | electrolyte | en |
| dc.subject | electrolyzed water | en |
| dc.subject | semi-continuous electrolyzed water generating unit | en |
| dc.subject | free available chlorine | en |
| dc.title | 半連續式電解水機專用型自由氯感測系統之研究 | zh_TW |
| dc.title | Development of Free Active Chlorine Sensing System for Semi-Continuous Electrolyzed Water Generating Unit | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 101-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳林祈,黃振康 | |
| dc.subject.keyword | 自由氯,電解液,無隔膜電解水,半連續式電解水機, | zh_TW |
| dc.subject.keyword | free available chlorine,electrolyte,electrolyzed water,semi-continuous electrolyzed water generating unit, | en |
| dc.relation.page | 59 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2013-08-19 | |
| dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
| dc.contributor.author-dept | 生物產業機電工程學研究所 | zh_TW |
| 顯示於系所單位： | 生物機電工程學系 | |
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