請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/59824完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 彭旭明(Shie-Ming Peng) | |
| dc.contributor.author | Chung-Han Yu | en |
| dc.contributor.author | 尤崇翰 | zh_TW |
| dc.date.accessioned | 2021-06-16T09:39:52Z | - |
| dc.date.available | 2020-02-16 | |
| dc.date.copyright | 2017-02-16 | |
| dc.date.issued | 2017 | |
| dc.date.submitted | 2017-02-08 | |
| dc.identifier.citation | [1] a) K. Onitsuka, Y. Ajioka, Y. Matsushima, S. Takahashi, Organometallics 2001, 20, 3274-3282; b) H. Lebel, J.-F. Marcoux, C. Molinaro, A. B. Charette, Chem. Rev. 2003, 103, 977-1050; c) M. B. Smith, J. March, in March's Advanced Organic Chemistry, John Wiley & Sons, Inc., 2006, pp. 136-233.
[2] H. Flack, Acta Crystallogr., Sect. A: Found. Crystallogr. 2009, 65, 371-389. [3] D. P. Rillema, D. S. Jones, J. Chem. Soc., Chem. Commun. 1979, 849-851. [4] a) T. S. Piper, J. Am. Chem. Soc. 1961, 83, 3908-3909; b) C. Piguet, G. Bernardinelli, G. Hopfgartner, Chem. Rev. 1997, 97, 2005-2062. [5] R. Wing, H. Drew, T. Takano, C. Broka, S. Tanaka, K. Itakura, R. E. Dickerson, Nature 1980, 287, 755-758. [6] Linus Pauling, Robert B. Corey, H. R. Branson, P. Natl. Acad. Sci. USA 1951, 37, 205-211. [7] X.-M. Chen, G.-F. Liu, Chem. Eur. J. 2002, 8, 4811-4817. [8] a) R. D. Gillard, D. J. Shepherd, D. A. Tarr, J. Chem. Soc., Dalton Trans. 1976, 594-599; b) J. J. Jodry, J. Lacour, Chem. Eur. J. 2000, 6, 4297-4304; c) J. Lacour, D. Moraleda, Chem. Commun. 2009, 7073-7089; d) Y. Haketa, Y. Bando, K. Takaishi, M. Uchiyama, A. Muranaka, M. Naito, H. Shibaguchi, T. Kawai, H. Maeda, Angew. Chem. Int. Ed. 2012, 51, 7967-7971. [9] a) L. Ducasse, F. Castet, A. Fritsch, I. Huc, T. Buffeteau, J. Phys. Chem. A 2007, 111, 5092-5098; b) C. Li, G.-T. Wang, H.-P. Yi, X.-K. Jiang, Z.-T. Li, R.-X. Wang, Organic Letters 2007, 9, 1797-1800; c) M. Kudo, T. Hanashima, A. Muranaka, H. Sato, M. Uchiyama, I. Azumaya, T. Hirano, H. Kagechika, A. Tanatani, J. Org. Chem. 2009, 74, 8154-8163; d) A. M. Kendhale, L. Poniman, Z. Dong, K. Laxmi-Reddy, B. Kauffmann, Y. Ferrand, I. Huc, J. Org. Chem. 2010, 76, 195-200; e) S. J. Dawson, Á. Mészáros, L. Pethő, C. Colombo, M. Csékei, A. Kotschy, I. Huc, Eur. J. Org. Chem. 2014, 2014, 4265-4275. [10] K. Kamikawa, K. Fukumoto, K. Yoshihara, M. Furusyo, M. Uemura, S. Takemoto, H. Matsuzaka, Chem. Commun. 2009, 1201-1203. [11] a) L. Yan, Z. Wang, M.-T. Chen, N. Wu, J. Lan, X. Gao, J. You, H.-M. Gau, C.-T. Chen, Chem. Eur. J. 2008, 14, 11601-11609; b) J. Bunzen, T. Bruhn, G. Bringmann, A. Lützen, J. Am. Chem. Soc. 2009, 131, 3621-3630; c) P. Guo, Dalton Trans. 2011, 40, 1716-1721; d) B. R. Groves, D. I. Arbuckle, E. Essoun, T. L. Lundrigan, R. Wang, M. A. S. Aquino, Inorg. Chem. 2013, 52, 11563-11572; e) M.-S. Seo, K. Kim, H. Kim, Chem. Commun. 2013, 49, 11623-11625. [12] C. Dolain, H. Jiang, J.-M. Léger, P. Guionneau, I. Huc, J. Am. Chem. Soc. 2005, 127, 12943-12951. [13] H. Ito, M. Ikeda, T. Hasegawa, Y. Furusho, E. Yashima, J. Am. Chem. Soc. 2011, 133, 3419-3432. [14] J. K. Bera, K. R. Dunbar, Angew. Chem. Int. Ed. 2002, 41, 4453-4457. [15] a) L.-P. Wu, P. Field, T. Morrissey, C. Murphy, P. Nagle, B. Hathaway, C. Simmons, P. Thornton, J. Chem. Soc., Dalton Trans. 1990, 3835-3840; b) S. Aduldecha, B. Hathaway, J. Chem. Soc., Dalton Trans. 1991, 993-998. [16] a) E.-C. Yang, M.-C. Cheng, M.-S. Tsai, S.-M. Peng, J. Chem. Soc., Chem. Commun. 1994, 2377-2378; b) R. Clérac, F. A. Cotton, L. M. Daniels, K. R. Dunbar, C. A. Murillo, I. Pascual, Inorg. Chem. 2000, 39, 748-751; c) S.-M. Peng, C.-C. Wang, Y.-L. Jang, Y.-H. Chen, F.-Y. Li, C.-Y. Mou, M.-K. Leung, J. Magn. Magn. Mater. 2000, 209, 80-83; d) R. Clérac, F. A. Cotton, L. M. Daniels, K. R. Dunbar, C. A. Murillo, X. Wang, Inorg. Chem. 2001, 40, 1256-1264. [17] a) S.-J. Shieh, C.-C. Chou, G.-H. Lee, C.-C. Wang, S.-M. Peng, Angew. Chem. Int. Ed. Engl. 1997, 36, 56-59; b) C.-C. Wang, W.-C. Lo, C.-C. Chou, G.-H. Lee, J.-M. Chen, S.-M. Peng, Inorg. Chem. 1998, 37, 4059-4065; c) F. Albert Cotton, L. M. Daniels, T. Lu, C. A. Murillo, X. Wang, J. Chem. Soc., Dalton Trans. 1999, 517-518. [18] R. Clérac, F. A. Cotton, K. R. Dunbar, T. Lu, C. A. Murillo, X. Wang, Inorg. Chem. 2000, 39, 3065-3070. [19] a) D. W. Armstrong, F. A. Cotton, A. G. Petrovic, P. L. Polavarapu, M. M. Warnke, Inorg. Chem. 2007, 46, 1535-1537; b) M. M. Warnke, F. A. Cotton, D. W. Armstrong, Chirality 2007, 19, 179-183. [20] 王瑞仁，國立台灣大學化學所博士論文，2007. [21] 江志峰，國立台灣大學化學所碩士論文，2011. [22] C. Creutz, H. Taube, J. Am. Chem. Soc. 1969, 91, 3988-3989. [23] M. B. Robin, P. Day, in Adv. Inorg. Chem. Radiochem., Vol. Volume 10 (Eds.: H. J. Emeléus, A. G. Sharpe), Academic Press, 1968, pp. 247-422. [24] a) D. Gatteschi, C. Mealli, L. Sacconi, J. Am. Chem. Soc. 1973, 95, 2736-2738; b) L. Sacconi, C. Mealli, D. Gatteschi, Inorg. Chem. 1974, 13, 1985-1991; c) A. Bencini, E. Berti, A. Caneschi, D. Gatteschi, E. Giannasi, I. Invernizzi, Chem. Eur. J. 2002, 8, 3660-3670. [25] I. P.-C. Liu, M. Bénard, H. Hasanov, I. W. P. Chen, W.-H. Tseng, M.-D. Fu, M.-M. Rohmer, C.-h. Chen, G.-H. Lee, S.-M. Peng, Chem. Eur. J. 2007, 13, 8667-8677. [26] R. H. Ismayilov, W.-Z. Wang, G.-H. Lee, C.-Y. Yeh, S.-A. Hua, Y. Song, M.-M. Rohmer, M. Bénard, S.-M. Peng, Angew. Chem. Int. Ed. 2011, 50, 2045-2048. [27] 莊靜宜，國立台灣大學化學所碩士論文，2013. [28] a) R. Blessing, Acta Crystallogr., Sect. A: Found. Crystallogr. 1995, 51, 33-38; b) G. M. Sheldrick, T. R. Schneider, in Methods Enzymol., Vol. Volume 277, Academic Press, 1997, pp. 319-343. [29] J. P. Stewart, J. Mol. Model. 2007, 13, 1173-1213. [30] a) J. P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 1996, 77, 3865-3868; b) J. P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 1997, 78, 1396-1396. [31] T. H. Dunning, P. J. Hay, in Methods of Electronic Structure Theory (Ed.: H. F. Schaefer), Springer US, Boston, MA, 1977, pp. 1-27. [32] Gaussian 09, Revision E.01, G. W. T. M. J. Frisch, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, G. Scalmani, V. Barone, B. Mennucci, G. A. Petersson, H. Nakatsuji, M. Caricato, X. Li, H. P. Hratchian, A. F. Izmaylov, J. Bloino, G. Zheng, J. L. Sonnenberg, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, T. Vreven, J. A. Montgomery, Jr., J. E. Peralta, F. Ogliaro, M. Bearpark, J. J. Heyd, E. Brothers, K. N. Kudin, V. N. Staroverov, R. Kobayashi, J. Normand, K. Raghavachari, A. Rendell, J. C. Burant, S. S. Iyengar, J. Tomasi, M. Cossi, N. Rega, J. M. Millam, M. Klene, J. E. Knox, J. B. Cross, V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, R. L. Martin, K. Morokuma, V. G. Zakrzewski, G. A. Voth, P. Salvador, J. J. Dannenberg, S. Dapprich, A. D. Daniels, Ö. Farkas, J. B. Foresman, J. V. Ortiz, J. Cioslowski, and D. J. Fox, Gaussian, Inc., Wallingford CT, 2009. [33] a) C. Reichardt, W. Scheibelein, Tetrahedron Lett. 1977, 18, 2087-2090; b) G. R. Newkome, S. J. Garbis, V. K. Majestic, F. R. Fronczek, G. Chiari, J. Org. Chem. 1981, 46, 833-839. [34] X. López, M.-Y. Huang, G.-C. Huang, S.-M. Peng, F.-Y. Li, M. Bénard, M.-M. Rohmer, Inorg. Chem. 2006, 45, 9075-9084. [35] a) A. Spek, Acta Crystallogr. Sect. D 2009, 65, 148-155; b) A. Spek, Acta Crystallogr., Sect. C 2015, 71, 9-18; c) J. Noll, M. Korb, H. Lang, Acta Crystallogr. Sect. E 2016, 72, 318-321. [36] a) M.-Y. Huang, C.-Y. Yeh, G.-H. Lee, S.-M. Peng, Dalton Trans. 2006, 0, 5683-5690; b) C.-W. Yeh, I. P.-C. Liu, R.-R. Wang, C.-Y. Yeh, G.-H. Lee, S.-M. Peng, Eur. J. Inorg. Chem. 2010, 2010, 3153-3159. [37] a) L. X. Dang, J. Am. Chem. Soc. 1995, 117, 6954-6960; b) J. D. Rodriguez, J. M. Lisy, J. Am. Chem. Soc. 2011, 133, 11136-11146. [38] J. F. Berry, F. Albert Cotton, C. A. Murillo, Dalton Trans. 2003, 3015-3021. [39] S.-A. Hua, I. P.-C. Liu, H. Hasanov, G.-C. Huang, R. H. Ismayilov, C.-L. Chiu, C.-Y. Yeh, G.-H. Lee, S.-M. Peng, Dalton Trans. 2010, 39, 3890-3896. [40] S.-Y. Lai, T.-W. Lin, Y.-H. Chen, C.-C. Wang, G.-H. Lee, M.-h. Yang, M.-k. Leung, S.-M. Peng, J. Am. Chem. Soc. 1999, 121, 250-251. [41] X. López, M. Bénard, M.-M. Rohmer, Inorg. Chem. 2007, 46, 5-7. [42] T.-B. Tsao, S.-S. Lo, C.-Y. Yeh, G.-H. Lee, S.-M. Peng, Polyhedron 2007, 26, 3833-3841. [43] C.-H. Cheng, R.-D. Hung, W.-Z. Wang, S.-M. Peng, I. C. Chen, ChemPhysChem 2010, 11, 517-524. [44] H. Iida, M. Shimoyama, Y. Furusho, E. Yashima, J. Org. Chem. 2009, 75, 417-423. [45] D. E. Williams, D. J. Craycroft, J. Phys. Chem. 1987, 91, 6365-6373. [46] F. A. Cotton, C. Y. Liu, C. A. Murillo, Q. Zhao, Inorg. Chem. 2006, 45, 9493-9501. [47] J. F. Berry, F. A. Cotton, L. M. Daniels, C. A. Murillo, X. Wang, Inorg. Chem. 2003, 42, 2418-2427. [48] J. F. Berry, F. A. Cotton, P. Lei, T. Lu, C. A. Murillo, Inorg. Chem. 2003, 42, 3534-3539. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/59824 | - |
| dc.description.abstract | 近年來，立體化學的研究在各領域有許多的成果，特別在分子立體結構的排列位向之控制，其中對於螺旋結構的選擇性至今仍是相當感興趣的議題。螺旋結構因螺旋方向不同而有左旋和右旋兩種異構物，兩者互為鏡像異構物。此外，在本實驗室及Cotton實驗室致力研究的直線型多核金屬串(EMACs)是由四個多氮配基螺旋環繞著直線型金屬軸的錯合物，目前只有少部分利用物理方法成功分離出兩種立體異構物，尚未有成功利用掌性配基調控金屬串螺旋方向的研究。
因此，本論文利用常見的掌性官能基-樟腦，設計出兩個新穎的五氮掌性配基成功合成出單一掌性異構物的金屬串：以H2( | zh_TW |
| dc.description.abstract | Chirality chemistry is the important and interesting subject recently. In the field, chirality control of helixes with the Δ (P) or Λ (M) form is interesting in various fields such as EMACs, in which the metal backbones are helically warped by four ligands. Up to now, there is no research on the helical control for EMACs through chiral ligands.
Herein, we report synthesis of four chiral EMACs by chiral ligands attached with champhor group: right-handed Δ-[Ni5( | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T09:39:52Z (GMT). No. of bitstreams: 1 ntu-106-F00223141-1.pdf: 18783206 bytes, checksum: e2a853f18d559b191f9e249e3b0af0fa (MD5) Previous issue date: 2017 | en |
| dc.description.tableofcontents | 中文摘要 I
Abstract III Table of Contents V List of Figures VI List of Tables X Chapter 1 Introduction 1 1-1 The Development of Chirality 1 1-2 The Helixes of Extended Metal Atomic Chains 6 1-3 Concept of Designing and Investigating Chiral Helical Metal Strings in These Studies 10 Chapter 2 Experimental Section 11 2-1 Chemicals 11 2-2 Techniques 12 2-3 Preparations 14 Chapter 3 Chiral Helixes of Penta and Tetra Nickel Linear Complexes 24 3-1 Synthesis and Characteristic Spectra 24 3-2 Structure Results 32 3-3 Electronic and Circular Dichroism Spectra 47 3-4 Theoretical Calculation 53 3-5 Magnetic Properties 57 3-6 Electrochemistry 62 Chapter 4 Conclusion 65 References 67 Appendix 71 | |
| dc.language.iso | en | |
| dc.subject | 配位化學 | zh_TW |
| dc.subject | 金屬串 | zh_TW |
| dc.subject | 掌性 | zh_TW |
| dc.subject | chirality | en |
| dc.subject | metal string | en |
| dc.subject | coordination chemistry | en |
| dc.title | 掌性配基調控直線型金屬串四螺旋的掌性 | zh_TW |
| dc.title | Chirality Control of Quadruple Helixes of Metal Strings
by Peripheral Chiral Ligands | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 105-1 | |
| dc.description.degree | 博士 | |
| dc.contributor.oralexamcommittee | 陳俊顯(Chun-hsien Chen),金必耀(Bih-Yaw Jin),呂光烈(Kuang-Lieh Lu),王志傑(Chih-Chieh Wan),陳益佳(I-Chia Chen) | |
| dc.subject.keyword | 掌性,金屬串,配位化學, | zh_TW |
| dc.subject.keyword | chirality,metal string,coordination chemistry, | en |
| dc.relation.page | 166 | |
| dc.identifier.doi | 10.6342/NTU201700394 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2017-02-08 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-106-1.pdf 未授權公開取用 | 18.34 MB | Adobe PDF |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。