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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 吳志毅(Chih-I Wu) | |
| dc.contributor.author | Hsiang-Cheng Wang | en |
| dc.contributor.author | 王翔正 | zh_TW |
| dc.date.accessioned | 2021-06-16T09:29:14Z | - |
| dc.date.available | 2017-06-12 | |
| dc.date.copyright | 2017-06-12 | |
| dc.date.issued | 2017 | |
| dc.date.submitted | 2017-03-27 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/59593 | - |
| dc.description.abstract | 本論文研究一些界面改質的方法，利用這些改質方法，堆疊式有機太陽能電池與石墨烯陰極太陽能電池得以以濕式製程製作出來，並探討元件最佳化過程與界面改質前後的性質變化。
本論文第一部分先討論主動層材料選擇，將其製作成單層太陽能電池並最佳化，接著討論堆疊式太陽能電池的中間連接層性質與適合的材料，為了讓中間連接層可以以濕式旋轉圖佈方式成膜，紫外光表面處理(UV-Ozone)與氧電漿表面處理(O2 plasma)被應用在主動層表面，改善其疏水的性質。堆疊式太陽能電池的主動層厚度設計過以得到相匹配電流，原件成功做出並達到5.129%的效率。被紫外光臭氧與氧電漿處理過的主動層表面進一步以儀器量測表面性質的變化，並且找到為何以紫外光表面處理的元件會表現不好的原因。 本論文第二部分研究以石墨烯當做陰極的倒置型單層太陽能電池，為了改善石磨烯表面疏水的性質，一種親疏水介面材料HBC-6ImBr被用來改變石墨烯表面性質，借由連續堆疊三層石墨烯，以PTB7:PC71BM為主動層的石墨烯陰極太陽能電池達到3.515%的效率。 | zh_TW |
| dc.description.abstract | In this thesis, several ways of surface modification are investigated. Tandem polymer solar cells and single junction solar cells with graphene as cathode are successfully fabricated via surface modification. The performance of solar cells and the property change after surface modification are carefully studied.
In the first topic, we discuss the candidate materials for tandem solar cell. Single junction solar cells are optimized based on our front cell and rear cell material. Interconnection layer is then discussed. In order to let interconnection layer be coated on active layer, two commonly-used surface modification methods, UV-Ozone and O2 plasma, are introduced. Tandem solar cells are carefully designed and put into experiment. Devices are successfully fabricated with PCE of 5.129%. The surface properties of polymer film after UV-Ozone and O2 plasma pretreatment are further investigated. The reasons for poor performance of UV-Ozone-modified devices are found In the second topic, a single junction solar cell based on graphene cathode is fabricated. Hydrophobicity of graphene is improved with the aid of HBC-6ImBr. Three layers of graphene are transferred on glass substrate as cathode, and PCE of 3.515% is achieved based on PTB7:PC71BM. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T09:29:14Z (GMT). No. of bitstreams: 1 ntu-106-R03941052-1.pdf: 2847022 bytes, checksum: d3a0214d9a4df16c19c5913472f1d439 (MD5) Previous issue date: 2017 | en |
| dc.description.tableofcontents | 口試委員會審定書 #
誌謝 i 中文摘要 iii ABSTRACT iv CONTENTS v LIST OF FIGURES viii LIST OF TABLES x Chapter 1 Introduction 1 1.1 Overview 1 1.2 Polymer Solar Cell 2 1.2.1 Background 2 1.2.2 Principle 4 1.2.3 Operation Mechanism 5 Chapter 2 Experimental Setup and Materials 8 2.1 Experimental Equipment 8 2.1.1 Glove Box 8 2.1.2 Solar Simulator 9 2.1.3 Ultraviolet and X-ray Photoelectron Spectroscopy 9 2.1.4 External Quantum Efficiency 10 2.2 Materials 11 2.2.1 Substrate 11 2.2.2 Electron Transport Layer 11 2.2.3 Hole Transport Layer 13 2.2.4 Active Layer 14 2.3 Device Fabrication 18 2.3.1 Solution Preparation 18 2.3.2 Fabrication of Solar Cell 19 Chapter 3 Tandem Solar Cell 21 3.1 Introduction 21 3.1.1 Motivation 21 3.1.2 Overview 21 3.1.3 Principle of tandem solar cell 24 3.2 Active layer 25 3.2.1 Active layer materials 25 3.2.2 Optimization of single junction solar cells 26 3.3 Interconnection layer 30 3.3.1 Material selection 30 3.3.2 Surface modification 33 3.4 Tandem solar cells 34 3.4.1 Tandem solar cells design 34 3.4.2 Using UV-Ozone to modify the surface property 35 3.4.3 Using O2 plasma to modify the surface property 38 3.5 Investigating two different surface modification methods 43 3.5.1 Single junction solar cell with different treatment on P3HT:ICBA 43 3.5.2 Absorption and EQE measurement 45 3.5.3 XPS and UPS measurement 47 3.5.4 UV light time test 49 3.6 Conclusion 50 Chapter 4 Use Graphene as Electrode in Solar Cell 51 4.1 Introduction 51 4.1.1 Motivation 51 4.1.2 Overview 52 4.2 Graphene solar cell 53 4.2.1 Graphene transfer 53 4.2.2 Inverted solar cell with graphene cathode 54 4.3 Conclusion 57 Chapter 5 Conclusion and Future Work 58 5.1 Conclusion 58 5.2 Future Work 59 REFERENCE 60 | |
| dc.language.iso | en | |
| dc.title | 堆疊式有機太陽能電池與石墨烯陰極太陽能電池之研究 | zh_TW |
| dc.title | Investigation of Tandem Polymer Solar Cell and Graphene Cathode Inverted Solar Cell | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 105-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳美杏,吳育任,陳奕君,吳肇欣 | |
| dc.subject.keyword | 聚合物有機太陽能電池,界面改質,堆疊式太陽能電池,石墨烯陰極, | zh_TW |
| dc.subject.keyword | Polymer solar cell,surface modification,tandem solar cell,graphene cathode, | en |
| dc.relation.page | 65 | |
| dc.identifier.doi | 10.6342/NTU201700682 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2017-03-28 | |
| dc.contributor.author-college | 電機資訊學院 | zh_TW |
| dc.contributor.author-dept | 光電工程學研究所 | zh_TW |
| 顯示於系所單位： | 光電工程學研究所 | |
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