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  1. NTU Theses and Dissertations Repository
  2. 工學院
  3. 機械工程學系
請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/56913
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dc.contributor.advisor蔡曜陽(Yao-Yang Hsiao)
dc.contributor.authorHung-Chun Hsiaoen
dc.contributor.author蕭鴻鈞zh_TW
dc.date.accessioned2021-06-16T06:31:09Z-
dc.date.available2016-08-16
dc.date.copyright2014-08-16
dc.date.issued2014
dc.date.submitted2014-08-07
dc.identifier.citation[1] J. Chae, S.S. Park, T. Freiheit,“Investigation of micro-cutting operations,”International Journal of Machine Tools and Manufacture, Vol. 46, pp. 313-332, 2006.
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[4] X. Lai, H. Li, C. Li, Z. Lin, J. Ni,“Modelling and analysis of micro scale milling considering size effect, micro cutter edge radius and minimum chip thickness,”International Journal of Machine Tools and Manufacture, Vol. 48, pp. 1-14, 2008.
[5] X. Liu, R.E. Devor, S.G. Kapoor, K.F. Ehmann, “The Mechanics of Machining at the Microscale: Assessment of the Current State of the Science.” Journal of Manufacturing Science and Engineering. Vol. 126, pp. 666-678, 2004.
[6] G. Schueler, J. Engmann, T. Marx, R. Haberland, J. Aurich, J.C. Aurich, D.Dornfeld,“Burr Formation and Surface Characteristics in Micro-End Milling of Titanium Alloys,”Burrs - Analysis, Control and Removal, Springer – Verlag Berlin Heidelberg, pp. 129-138, 2010.
[7] A. L. Yerokhin, X. Nie, A. Leyland, A. Matthews and S. J. Dowey,“Plasma electrolysis for surface engineering”, Surface and Coatings Technology, 73-93, 1997.
[8] Kalpakjian, S., Schmid, S., “Manufacturing Engineering And Technology 5푡푡ℎ Edition“ , Prentice Hall Inc., 2006.
[9] Lutjering, G., Williams, J.C., “Titanium - 2푒푒푒푒 Edition” , Springer Verlag, 2007.
[10] N. Vidakis , A. Antoniadis , N. Bilalis , “The VDI 3198 indentation test evaluation of a reliable qualitative control for layered compounds”, Journal of Materials Processing Technology, Vol 143-144, pp. 481-485, 2003.
[11] 曾俊雄, “模具鋼經熱反應擴散沉積製程與傳統熱處理後的分析研究”, 國立台灣大學機械工程學研究所碩士論文, 1994.
[12] Tuğrul Ozel, Frank Pfefferkorn, “Pulsed Laser Assisted Micromilling for Die/Mold Manufacturing” ,ASME,2007.
[13] 侯貫智, “2006非鐵金屬年鑑-鈦合金篇”, 經濟部技術處產業技術知識服務(IT IS)計畫出版品, 2006.
[14] T. B. Van, S. D. Brown, and G. P. Wirtz, “Mechanism of anodic spark Deposition”, American Ceramic Society Bulletin Emerging Ceramics and Glass Technology, 563, 1977.
[15] V.N. Duradzhy, A.S. Parsadanyan, “Metal Heating in Electrolytic Plasma”, Shtiintsa, Kishinev, in Russian, 1988.
[16] V.I. Tchernenko, L.A. Snezhko, I.I. Papanova, “Coatings by Anodic Spark Electrolysis”, Khimiya, Leningrad, in Russian , 1991.
[17] P.S. Gordienko, “Coating Formation on Anodically Polarised Electrodes at the Potentials of Sparking and Breakdown”, Dal- Tnauka, Vladivostok, in Russian, 1996.
[18] A. L. Yerokhin, X. Nie, A. Leyland, A. Matthews, “Characterization of Oxide Films Produced by Plasma Electrolytic Oxidation of A Ti-6Al-4V Alloy”, Surface and Coatings Technology, 195-206, 2000.
[19] L. H. Li, Y. M. Kong, H. W. Kim, Y. W. Kim, H. E. Kim, S. J. Heo, and J. Y. Koak, “Improved biological performance of Ti implants due to surface modification by micro-arc oxidation”, Biomaterials,2867-2875, 2004.
[20] G. L. Chern, “Analysis of Burr Formation and Breakout in Metal Cutting”, Ph.D. Thesis, University of California at Berkeley, Berkeley, CA, 1993.
[21] M. Hashimura, , J. Hassamamontr, , D.A. Dornfeld, , “Effect and Thickness in Face Milling Operation”, Transactions of the ASME, Journal of Manufacturing Science and Engineering 121(1):13-19, 1999.
[22] K. Lee, D.A. Dornfeld, 'An experimental study on burr formation in micro milling aluminum an copper,' Transactions of the NAMRI/SME, Vol. 30, pp.1-8, 2002.
[23] K. Lee, D.A. Dornfeld, “Micro-burr formation and minimization through process control,” Precision Engineering, Vol. 29, pp. 246-252, 2005.
[24] S. Filiz, C.M. Conley, M.B. Wasserman, O.B. Ozdoganlar,“An experimental investigation of micro-machinability of copper 101 using tungsten carbide micro-endmills,” International Journal of Machine Tools and Manufacture, Vol. 47, pp. 1088-1100, 2007.
[25] G. L. Chern, “Experimental observation and analysis of burr formation mechanisms in face milling of aluminum alloys”, International Journal of Machine
Toosl & Manufacture 46, pp. 1517-1525, 2006.
[26] E. Bemporad, M. Sevastiani, D. De Felicis, F. Carassiti, R. Valle, F. Casadei, “Production and characterization of duplex coatings on Ti-6Al-4V substrate”, International conference on surfaces, coatings and nanostructured materials, Vol 515, pp. 186-194, 2006.
[27] M. P. Vogler, , R. E DeVor,., and S. G. Dapoor, , “On the Modeling and Analysis of Machining Aluminum and Copper” Trans. NAMRI/SME, 30,pp.1-8,2004.
[28] L.K. Gillespie, , P.T. Blotter, , “The Formation and Properties of Machining Burrs,Transactions of the ASME”, Journal of Engineering for Industry 98:66–74,1976.
[29] M. Hashimura, , J. Hassamamontr, , D.A. Dornfeld, , “Effect of In-plane Exit Angle and Rake Angles on Burr Height and Thickness in Face Milling Operation”, Transactions of the ASME, Journal of Manufacturing Science and Engineering 121(1):13–19,1999.
[30] Y. Wang, T. Lei, L. Guo, and B. Jiang, 'Fretting wear behaviour of microarc oxidation coatings formed on titanium alloy against steel in unlubrication and oil lubrication', Applied Surface Science, 8113-8120, 2006.
[31] S Xin,. L Song,. R Zhao,. and X Hu,. “Influence of cathodic current on composition, structure and properties of 퐴퐴퐴 2푂푂3 coatings on aluminum alloy prepared by micro-arc oxidation process”, Thin Solid Films, 59, 237-242, 2005.
[32] G Sundararajan, , “Mechanisms underlying the formation of thick alumina coatings through the MAO coating technology”, Surface and Coatings Technology, 167, 269-277, 2003.
[33] V.I. Chernenko, L.A Snezhko, I.I. Papanova, Coating by Anodic Spark Electrolysis, Khimiya, Leningrad, 1991 (in Russian, ISBN 5-7245-0588-6)
[34] W. Krysmann, P. Kurze, K. H. Dittrich, H. G. Schneider, “Process characteristics and parameters of Anodic Oxidation by spark discharge (ANOF)”, Crystal Research and Technology, Vol 19, pp 973-979, 1984.
[35] A.L. Yerokhin, X. Nie, A. Leyland, A. Matthews, “Characterisation of oxide films produced by plasma electrolytic oxidation of a Ti-6Al-4V”, Surface and Coatings Technology, Vol 130, pp. 195-206, 2000.
[36] Z. Liu, W. Wang, H. Liu, T. Wang, M. Qj, “Formation and characterization of titania coatings with cortex-like slots formed on Ti by micro-arc oxidation treatment”, Applied Surface Science 266, pp. 250-255, 2013.
[37] 李宣東、吳曉宏,“微等離子體氧化法在TiO2 膜的光催化活性研究”,稀有金 屬,第27 卷第6 期, 661-664, 2003.
dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/56913-
dc.description.abstract本論文先針對微弧氧化對純鈦金屬所生成之氧化膜做參數和結合度上的探討,再針對微銑削時的毛邊、粗糙度等問題,使用了微弧氧化的製程來輔助微銑削加工鈦金屬,並比較製程前後對試片表面和切屑與刀具狀況的結果。
  在兩種Duty Cycle分別為1/10 和 1/5的參數下,鈦金屬經過微弧氧化,氧化膜厚度都會隨著電壓作用時間(Voltage affect time)增加而增長,但製程時間(Process time)卻相差兩倍。為了抑制撓曲選擇較厚的試片,卻因薄膜生長特性必須使電壓作用時間更長,綜合以上情形所以選擇較有效率Duty Cycle為1/5的加工參數。
  本實驗所使用的刀徑為0.7mm,進給為100mm/min。隨著切深增加,毛邊高度也隨著增高,且銑削溝槽兩邊的毛邊高度也因順逆銑而呈現不同的高度,順銑的毛邊相較逆銑在較小的切深即會產生,產生的高度也較高。在經過微弧氧化電壓作用時間分別為 36s、60s、90s後的薄膜厚度與切深綜合比較,可知產生毛邊當下的毛邊臨界切深(Dc)從2.8μm增加至5.8μm、8.4μm、10μm,亦即經過微弧氧化後,較大的切深才會產生毛邊。
  當銑削深度較淺時,表面粗糙度高於傳統銑削理論值,這代表在這切深下,表面形成機制包括最小切屑厚度、犁切、以及彈性回復。當切深接近20μm至30μm時有最佳的表面粗糙度,之後便又逐漸變差,並與薄膜厚度沒有明顯的關係。
切屑在不同的切削深度下會導致不同的結果,代表氧化膜僅為鈦金屬表面上的物理性堆積,而沒有強力的附著於上。因此,表面氧化膜的切除相當容易,且其亦為脆性切削。
zh_TW
dc.description.abstractThis study first discussed the parameter of the oxide film generated from MAO process, and then use the MAO process to solve the burr and surface roughness problem made by micro-milling. Then, the study compares the results of pre-processed workpiece surfaces with the processed ones.
No matter the parameters of Duty Cycle is 1/10 or 1/5, both of the results show that the oxide film became thicker while the voltage affect time became longer. However, the process time of 1/10 is twice longer than that of 1/5. In addition, the study has to use thicker workpiece to avoid deflection, but it also causes film grow characteristics which will prolong the process time. Thus, this study chooses the parameter Duty Cycle 1/5 for more efficiency.
This study uses the cutter with the diameter of 0.7mm and 100mm/min feed. It was found that the burr height will simultaneously increase when the cutting depth becomes deeper. Also, the different sides of the slot, causing climb or conventional milling, will give rise to different burrs heights too. Compare to the workpieces with conventional milling, the burrs heights of that with climb milling are higher and will occur in smaller cutting depth.
  Comparing the pre-processed workpiece with the workpieces processed by MAO with 36 s, 60 s, and 90 s voltage affect time, the study discovers that the cutting depth which leads to the formation of burrs is increased from 2.8μm to 5.8μm、8.4μm、10μm. In other words, MAO process can moderate the burr problem.
When cutting depth was shallow, the measured surface roughnesses were considerably higher than the theoretical surface roughness. This indicates that the surface generation mechanism at these cutting depth will be affected by not only geometric considerations, but also the minimum chip thickness, ploughing, and elastic recovery effects. Surface roughness, which has no significant relation with the thickness of oxide film, will decrease when cutting depth approach 20μm, but begins to increase again after 20μm~30μm.
Cutting under different cutting depths will result in different ways, which imply that the oxide film is only a physical accumulation on the surface of titanium. Considering that the oxide film doesn’t adhere to the metal strongly, the removal of it is easy and brittle.
en
dc.description.provenanceMade available in DSpace on 2021-06-16T06:31:09Z (GMT). No. of bitstreams: 1
ntu-103-R01522737-1.pdf: 9375660 bytes, checksum: b57b21ddcb18641c55947cf00a12cdc8 (MD5)
Previous issue date: 2014
en
dc.description.tableofcontents口試委員會審定書 #
誌謝 I
中文摘要 II
ABSTRACT III
CONTENTS V
LIST OF FIGURES VIII
LIST OF TABLES XIII
第1章 緒論 1
1.1 研究背景與動機 1
1.2 文獻回顧 4
1.2.1 微銑削加工 4
1.2.2 微弧氧化製程 8
1.2.3 鈦金屬微弧氧化製程 9
1.3 研究目的 10
1.4 論文大綱 11
第2章 相關技術理論 12
2.1 銑削理論 12
2.1.1 逆銑(conventional milling) 12
2.1.2 順銑(climb milling) 12
2.1.3 進給速度 13
2.2 毛邊理論 14
2.3 鈦金屬 18
2.3.1 鈦金屬簡介 18
2.3.2 鈦金屬及鈦合金分類 21
2.3.3 鈦金屬應用 25
2.4 二氧化鈦 25
2.4.1 二氧化鈦簡介 25
2.4.2 鈦金屬陽極氧化反應處理製程介紹 27
2.5 微弧氧化 28
2.5.1 發展歷史 28
2.5.2 電漿電解物理、化學基礎理論 29
2.6 表面粗糙度 36
第3章 實驗內容 40
3.1 實驗規劃 40
3.2 實驗流程 40
3.3 實驗方法 41
3.3.1 材料準備 41
3.3.2 微弧氧化製程 42
3.3.3 測量膜厚 44
3.3.4 測量膜與基材結合度 44
3.3.5 切削測試 45
3.4 實驗設備 47
第4章 實驗結果與討論 55
4.1 微弧氧化參數探討和薄膜製備與量測 55
4.1.1 微弧氧化參數探討和選用 55
4.1.2 不同工件(面積和表面形貌)對於微弧氧化製程探討 60
4.1.3 薄膜結合度試驗和探討 64
4.2 膜厚與切削深度對於工件毛邊的影響 67
4.2.1 膜厚與切削深度對於表面粗糙度的影響 87
4.2.2 切屑探討 94
4.2.3 刀具狀況探討 96
第5章 結論與未來展望 101
5.1 結論 101
5.2 未來展望 103
REFERENCE 105
dc.language.isozh-TW
dc.subject微銑削zh_TW
dc.subject微弧氧化zh_TW
dc.subject毛邊zh_TW
dc.subject鈦zh_TW
dc.subject薄膜結合度zh_TW
dc.subjectmicro-arc oxidationen
dc.subjectmicro-millingen
dc.subjectburren
dc.subjecttitaniumen
dc.subjectfilm adhesionen
dc.title微弧氧化製程輔助鈦金屬微銑削加工之研究zh_TW
dc.titleThe Study of Micro-Arc Oxidation Process Aided Micro Milling on Titaniumen
dc.typeThesis
dc.date.schoolyear102-2
dc.description.degree碩士
dc.contributor.oralexamcommittee王世明(Shih-Ming Wang),盧銘銓(Ming-Chyuan Lu)
dc.subject.keyword微銑削,微弧氧化,毛邊,鈦,薄膜結合度,zh_TW
dc.subject.keywordmicro-milling,micro-arc oxidation,burr,titanium,film adhesion,en
dc.relation.page109
dc.rights.note有償授權
dc.date.accepted2014-08-07
dc.contributor.author-college工學院zh_TW
dc.contributor.author-dept機械工程學研究所zh_TW
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