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  1. NTU Theses and Dissertations Repository
  2. 理學院
  3. 物理學系
請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/56374
完整後設資料紀錄
DC 欄位值語言
dc.contributor.advisor陳政維(Jeng-Wei Chen)
dc.contributor.authorChi-Shen Lien
dc.contributor.author李啟申zh_TW
dc.date.accessioned2021-06-16T05:25:39Z-
dc.date.available2014-08-21
dc.date.copyright2014-08-21
dc.date.issued2014
dc.date.submitted2014-08-14
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Mater. 322 (2010) 2537.
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Chem. Mater. 11 (1999) 1760.
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J. Appl. Phys. 86 (1999) 1657.
[7] R. von Helmolt, J. Wecker, B. Holzapfel, L. Schultz, K. Samwer, Phys. Rev. Lett.
71 (1993) 2331.
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[9] X.X. Zhang, J. Tejada, Y. Xin, G.F. Sun, K.W. Wong, X. Bohigas, Appl. Phys. Lett. 69 (1996) 3596.
[10] A. Daoudi and G. Le Flem, J. Solid State Chem. 5 (1972) 57.
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[16] Hewlett-Packard Inc., Basics of Measuring the Dielectric Properties of Materials, Application Note 1217-1.
[17] D. C. Sinclair F. D. Morrison, and A. R. West, J. Am. Ceram. Soc. 84 (2001) 31.
dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/56374-
dc.description.abstract本論文研究稀土取代鈣錳氧化物 [Ca2-xLnxMnO4, 其中 Ln = Nd and Y] 的製作、特性、介電性質,而介電性質在絕對溫度20 K ~ 300 K之間以20 Hz ~ 1 MHz外加電壓頻率作研究。
Ln = Nd或Y時,在x > 0.3時觀察低溫的介電的相,活化能會隨著取代量x增加而增加。研究介電常數、損耗因子、熱激發的活化能、模數和柯爾柯爾圖等極化性質。
zh_TW
dc.description.abstractThe synthesis, characterization and dielectric properties of rare earths substituted calcium manganese oxides [Ca2-xLnxMnO4, where Ln = Nd and Y] compounds were investigated. The dielectric properties of these compounds were studied in the frequency range from 20 Hz to 1 MHz between 20 K and 300 K.
The low temperature dielectric properties is studied when x > 0.3 for Ln = Nd and Y. The activation energies increase as the amount of substitution x increase. Compounds for x > 0.3 are studied in dielectric permittivity, dissipation factor, activation energy with thermally activated process, modulus spectra, and cole-cole plot.
en
dc.description.provenanceMade available in DSpace on 2021-06-16T05:25:39Z (GMT). No. of bitstreams: 1
ntu-103-R01222058-1.pdf: 1872466 bytes, checksum: 0b754cab0794b4ba356b2f00c0081388 (MD5)
Previous issue date: 2014
en
dc.description.tableofcontents致 謝 i
摘 要 ii
Abstract iii
Tables of Contents iv
List of Pictures vi
List of Tables xi
Chapter 1 Introduction 1
Chapter 2 General Background 3
a. Complex Permittivity 3
b. The Mechanism of Polarization 5
c. Debye Equations 8
d. Arrhenius law 11
Chapter 3 Experimental Details 12
A. Sample Preparation 12
a.Ca2MnO4 12
b.Ca2-xNdxMnO4 13
c.Ca2-xYxMnO4 14
B. X-ray diffraction 15
C. Dielectric Properties Measurement 16
Chapter 4 Results and Discussion 17
a. Ca2MnO4 17
b.Ca1.7Nd0.3MnO4 24
c. Ca1.6Nd0.4MnO4 31
d. Ca1.5Nd0.5MnO4 38
e. Ca1.7Y0.3MnO4 47
f. Ca1.6Y0.4MnO4 54
g. Ca1.5Y0.5MnO4 62
h. CaYMnO4 70
Chapter 5 Conclusion 78
References 81
dc.language.isozh-TW
dc.subject釹zh_TW
dc.subject活化能zh_TW
dc.subject介電常數zh_TW
dc.subject鈣錳氧化物zh_TW
dc.subject釔zh_TW
dc.subject損耗因子zh_TW
dc.subjectactivation energyen
dc.subjectCalcium Manganese Oxidesen
dc.subjectNeodymiumen
dc.subjectYttriumen
dc.subjectdielectric permittivityen
dc.subjectdissipation factoren
dc.title稀土取代鈣錳氧化物的介電性質zh_TW
dc.titleDielectric Response of Rare Earths Substituted Calcium Manganese Oxidesen
dc.typeThesis
dc.date.schoolyear102-2
dc.description.degree碩士
dc.contributor.oralexamcommittee陳銘堯(Ming-Yau Chern),傅昭銘(Chao-Ming Fu)
dc.subject.keyword鈣錳氧化物,釹,釔,介電常數,損耗因子,活化能,zh_TW
dc.subject.keywordCalcium Manganese Oxides,Neodymium,Yttrium,dielectric permittivity,dissipation factor,activation energy,en
dc.relation.page82
dc.rights.note有償授權
dc.date.accepted2014-08-15
dc.contributor.author-college理學院zh_TW
dc.contributor.author-dept物理研究所zh_TW
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