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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 梁文傑 | |
dc.contributor.author | Yu-Lin Chiang | en |
dc.contributor.author | 江祐鱗 | zh_TW |
dc.date.accessioned | 2021-06-16T05:20:16Z | - |
dc.date.available | 2019-09-02 | |
dc.date.copyright | 2014-09-02 | |
dc.date.issued | 2014 | |
dc.date.submitted | 2014-08-15 | |
dc.identifier.citation | 第五章 參考文獻
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/56243 | - |
dc.description.abstract | 本篇論文合成出一系列雙偶極含 1,2,4-三唑基團的咔唑衍生物,以碳-氮鍵連接 的方式,阻斷分子的共軛系統,維持 9-苯基咔唑之高三重態能階。以 X-Ray 單晶 繞射結果觀察晶體的結構及排列;以紫外-可見光吸收光譜、螢光放射光譜及磷光 放射光譜等方法進行光物理性質測量;以循環伏安法及差式脈波伏安法進行電化 學性質測量並探討。我們發現三唑基團與咔唑基團連接的位置差異,會造成化合 物的排列方式改變,進而影響其熔點高低。此系列化合物的螢光放光基團為 9-苯 基咔唑;而三唑連接位置的不同,會造成磷光放射基團改變。在電化學性質方面, 我們發現化合物的 HOMO 能階,受氮原子的誘導效應影響而改變;LUMO 能階則 由三唑基團的數量所決定。
接著,以所合成之化合物作為主發光體材料,製成多層式有機電激磷光二極 體元件,並測量其效果。在元件的表現上,以化合物 8 的效率 roll-off 表現最佳; 而元件發光效率最高的為化合物 12,達 46.48 cd/A。 | zh_TW |
dc.description.provenance | Made available in DSpace on 2021-06-16T05:20:16Z (GMT). No. of bitstreams: 1 ntu-103-R01223135-1.pdf: 18078901 bytes, checksum: 8eb0fb4815199e219209553a257009ce (MD5) Previous issue date: 2014 | en |
dc.description.tableofcontents | 目錄 I
中文摘要 III Abstract IV 圖目錄 V 表目錄 VIII 流程目錄 IX 化合物之1H與13C光譜目錄 X 化合物的結構式與編號 XII 第一章 緒論 1 1.1 前言 1 1.2 發光原理 1 1.3 有機電激發光二極體的研究發展 2 1.4 有機電激發光二極體的元件結構 4 1.5 有機電激發光二極體的工作原理 5 1.5.1 電激磷光 6 1.5.2 主客混摻發光系統 6 1.5.3 能量轉移 7 1.6 有機電激發光二極體材料 8 1.6.1陽極材料 8 1.6.2陰極材料 9 1.6.3電洞注入材料 9 1.6.4電洞傳導材料 10 1.6.5電子注入材料 11 1.6.6電子傳導材料 11 1.6.7發光材料 12 1.7 近年藍色磷光有機發光二極體之發展 13 第二章 結果與討論 18 2.1 研究動機與分子設計 18 2.2 合成策略與方法 21 2.3 X-Ray晶體結構分析 28 2.4 熱性質 (Thermal properties) 分析 33 2.5 光學性質 (Photophysical properties) 分析 36 2.6 電化學性質 (Electrochemical properties) 分析 44 2.7 有機電激發光元件表現 (Electroluminescent device performance) 49 第三章 結論 64 第四章 實驗部分 65 4.1 實驗儀器與試劑 65 4.1.1 儀器 65 4.1.2 試劑與溶劑 66 4.2 合成步驟 67 第五章 參考文獻 85 附錄一 化合物之DSC圖譜 90 附錄二 化合物之X-Ray晶體參數表、鍵長與鍵角資料 91 附錄三 化合物之氫核磁共振光譜與碳核磁共振光譜 127 | |
dc.language.iso | zh-TW | |
dc.title | "以碳-氮鍵連接之雙偶極含1,2,4-三唑與咔唑化合物之研發及其在藍色磷光有機發光二極體上的應用" | zh_TW |
dc.title | Development of Bipolar C-N Connected 1,2,4-Triazole-Containing Carbazoles and Their Application in Blue Phosphorescent Organic Light Emitting Diodes | en |
dc.type | Thesis | |
dc.date.schoolyear | 102-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 邱天隆,徐秀福 | |
dc.subject.keyword | 雙偶極,1,2,4-三唑,?唑,碳-氮鍵連接,主發光體材料,有機電激磷光二極體, | zh_TW |
dc.subject.keyword | bipolar,1,2,4-triazole,carbazole,N-connectivity,host,electrophosphorescent device, | en |
dc.relation.page | 162 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2014-08-16 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 化學研究所 | zh_TW |
顯示於系所單位: | 化學系 |
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